Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]

Condensation of 8-hy­droxy­quinoline-2-carbaldehyde with 2-amino­phenol gave the (E)-2-[(2-hy­droxy­phenyl­imino)­meth­yl]quinolin-8-ol derivative that reacted with di-n-butyl­tin oxide with release of H2O to yield the chelate title complex, [Sn2(C4H9)4(C16H10N2O2)2]. The compound crystallizes in th...

Full description

Autores:
Camacho Camacho, Carlos
Ortiz Pastrana, Naytzé
garza-ortiz, ariadna
Rojas-Oviedo, Irma
Tipo de recurso:
Article of journal
Fecha de publicación:
2017
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/7259
Acceso en línea:
https://hdl.handle.net/11323/7259
https://doi.org/10.1107/S2056989016018867
https://repositorio.cuc.edu.co/
Palabra clave:
crystal structure
8-quinolino­lates
sevenfold coordination
di­alkyl­ditin(IV) compound
Rights
openAccess
License
Attribution-NonCommercial-ShareAlike 4.0 International
id RCUC2_939b4040c1d110bbb2f9582fedae32d9
oai_identifier_str oai:repositorio.cuc.edu.co:11323/7259
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.spa.fl_str_mv Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
title Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
spellingShingle Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
crystal structure
8-quinolino­lates
sevenfold coordination
di­alkyl­ditin(IV) compound
title_short Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
title_full Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
title_fullStr Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
title_full_unstemmed Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
title_sort Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
dc.creator.fl_str_mv Camacho Camacho, Carlos
Ortiz Pastrana, Naytzé
garza-ortiz, ariadna
Rojas-Oviedo, Irma
dc.contributor.author.spa.fl_str_mv Camacho Camacho, Carlos
Ortiz Pastrana, Naytzé
garza-ortiz, ariadna
Rojas-Oviedo, Irma
dc.subject.spa.fl_str_mv crystal structure
8-quinolino­lates
sevenfold coordination
di­alkyl­ditin(IV) compound
topic crystal structure
8-quinolino­lates
sevenfold coordination
di­alkyl­ditin(IV) compound
description Condensation of 8-hy­droxy­quinoline-2-carbaldehyde with 2-amino­phenol gave the (E)-2-[(2-hy­droxy­phenyl­imino)­meth­yl]quinolin-8-ol derivative that reacted with di-n-butyl­tin oxide with release of H2O to yield the chelate title complex, [Sn2(C4H9)4(C16H10N2O2)2]. The compound crystallizes in the triclinic space group P-1, with two independent centrosymmetric dimers in the unit cell. Each features a typical pincer-type structure where the dianionic ligand is tetra­dentate, coordinating to the central tin atom through both phenolate oxygen atoms, as well as through the quinoline and imine N atoms. Each metal atom adopts a distorted penta­gonal–bipyramidal SnC2N2O3 coordination arising from the N,N′,O,O′-tetra­dentate deprotonated Schiff base, one bridging phenolate O atom of the neighbouring ligand and two butyl groups in the axial sites.
publishDate 2017
dc.date.issued.none.fl_str_mv 2017
dc.date.accessioned.none.fl_str_mv 2020-11-11T16:45:21Z
dc.date.available.none.fl_str_mv 2020-11-11T16:45:21Z
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
format http://purl.org/coar/resource_type/c_6501
status_str acceptedVersion
dc.identifier.issn.spa.fl_str_mv 2056-9890
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/7259
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.1107/S2056989016018867
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv 2056-9890
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/7259
https://doi.org/10.1107/S2056989016018867
https://repositorio.cuc.edu.co/
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.references.spa.fl_str_mv Rasoul-Amini, S., Khalaj, A., Shafiee, A., Daneshtalab, M., Madadkar-Sobhani, M. & Fouladdel, S. (2006). Int. J. Cancer Res. 2, 102–108.
Albrecht, M., Osetska, O. & Fröhlich, R. (2005). Dalton Trans. pp. 3757–3762.
Albrecht, M., Osetska, O., Fröhlich, R., Bünzli, J. G., Aebischer, A., Gumy, F. & Hamacek, J. (2007). J. Am. Chem. Soc. 129, 14178–14179.
Anitha, P., Manikandan, R., Prakash, G., Pachiyappan, B., Viswanathamurthi, P. & Malecki, J. G. (2015). J. Organomet. Chem. 791, 266–273.
Basu Baul, T. S., Mizar, A., Paul, A., Ruisi, G., Willem, R., Biesemans, M. & Linden, A. (2009). J. Organomet. Chem. 694, 2142–2152.
Bruker (2012). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Charles, R. G. & Perrotto, A. (1964). Anal. Chim. Acta, 30, 131–138.
Corcé, V., Renaud, S., Cannie, I., Julienne, K., Gouin, S. G., Loréal, O., Gaboriau, F. & Deniaud, D. (2014). Bioconjugate Chem. 25, 320–334.
Cui, J., Qiao, Y., Yin, H. & Liu, M. Z. (2010). Z. Anorg. Allg. Chem. 636, 2508–2512.
García-Santos, I., Sanmartín, J., García-Deibe, A. M., Fondo, M. & Gómez, E. (2009). Polyhedron, 28, 3055–3059.
Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466–470.
Musiol, R., Jampilek, J., Buchta, V., Silva, L., Niedbala, H., Podeszwa, B., Palka, A., Majerz-Maniecka, K., Oleksyn, B. & Polanski, J. (2006). Bioorg. Med. Chem. 14, 3592–3598.
Nasveld, P. & Kitchener, S. (2005). Trans. R. Soc. Trop. Med. Hyg. 99, 2–5.
Palit, P., Paira, P., Hazra, A., Banerjee, S., Das Gupta, A., Dastidar, S. G. & Mondal, N. B. (2009). Eur. J. Med. Chem. 44, 845–853.
Serda, M., Kalinowski, D., Mrozek-Wilczkiewicz, A., Musiol, R., Szurko, A., Ratuszna, A., Pantarat, N., Kovacevic, Z., Merlot, A. M., Richardson, D. R. & Polanski, J. (2012). Bioorg. Med. Chem. Lett. 22, 5527–5531.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.
Sheldrick, G. M. (2015). Acta Cryst. C71, 3–8.
Sousa, A. T. de, Bessler, K. E., Lemos, S. S., Ellena, J. & Gatto, C. C. (2009). Z. Anorg. Allg. Chem. 635, 106–111.
Sun, W.-H., Shen, M., Zhang, W., Huang, W., Liu, S. & Redshaw, C. (2011). Dalton Trans. 40, 2645–2653.
Vafaee, M., Amini, M. M. & Ng, S. W. (2010). Acta Cryst. E66, m964.
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920–925.
Yan, Q., Sun, Z., Zhang, W., Nomura, K. & Sun, W.-H. (2014). Macromol. Chem. Phys. 215, 1744–1752.
Zhang, W., Liu, S., Yang, W., Hao, X., Glaser, R. & Sun, W.-H. (2012). Organometallics, 31, 8178–8188.
Zhang, H.-X., Wang, S.-Y., Wang, W.-M., Gao, H.-L. & Cui, J.-Z. (2015). Inorg. Chem. Commun. 62, 94–97.
dc.rights.spa.fl_str_mv Attribution-NonCommercial-ShareAlike 4.0 International
dc.rights.uri.spa.fl_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.coar.spa.fl_str_mv http://purl.org/coar/access_right/c_abf2
rights_invalid_str_mv Attribution-NonCommercial-ShareAlike 4.0 International
http://creativecommons.org/licenses/by-nc-sa/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Corporación Universidad de la Costa
dc.source.spa.fl_str_mv Acta Crystallogr E Crystallogr Commun
institution Corporación Universidad de la Costa
dc.source.url.spa.fl_str_mv https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209758/
bitstream.url.fl_str_mv https://repositorio.cuc.edu.co/bitstreams/c941f254-9b4f-41b8-ae2b-4af2b92f151a/download
https://repositorio.cuc.edu.co/bitstreams/a165552a-425c-4663-9fb2-58d7c68b00b0/download
https://repositorio.cuc.edu.co/bitstreams/f415ce66-1017-41c7-9f6d-f78f9de51a17/download
https://repositorio.cuc.edu.co/bitstreams/316fb63e-c2e2-4415-9766-7ec4f23af168/download
https://repositorio.cuc.edu.co/bitstreams/5a8bf11b-579c-4e1c-b55d-c19c2cc13d75/download
bitstream.checksum.fl_str_mv e7bc022eb817a2ab0816535d46cc8267
934f4ca17e109e0a05eaeaba504d7ce4
e30e9215131d99561d40d6b0abbe9bad
9eaf53f1f22e8d848a25168ccabeba18
24e648839aa31918bceb936aff170ec0
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositorio de la Universidad de la Costa CUC
repository.mail.fl_str_mv repdigital@cuc.edu.co
_version_ 1811760811442438144
spelling Camacho Camacho, CarlosOrtiz Pastrana, Naytzégarza-ortiz, ariadnaRojas-Oviedo, Irma2020-11-11T16:45:21Z2020-11-11T16:45:21Z20172056-9890https://hdl.handle.net/11323/7259https://doi.org/10.1107/S2056989016018867Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Condensation of 8-hy­droxy­quinoline-2-carbaldehyde with 2-amino­phenol gave the (E)-2-[(2-hy­droxy­phenyl­imino)­meth­yl]quinolin-8-ol derivative that reacted with di-n-butyl­tin oxide with release of H2O to yield the chelate title complex, [Sn2(C4H9)4(C16H10N2O2)2]. The compound crystallizes in the triclinic space group P-1, with two independent centrosymmetric dimers in the unit cell. Each features a typical pincer-type structure where the dianionic ligand is tetra­dentate, coordinating to the central tin atom through both phenolate oxygen atoms, as well as through the quinoline and imine N atoms. Each metal atom adopts a distorted penta­gonal–bipyramidal SnC2N2O3 coordination arising from the N,N′,O,O′-tetra­dentate deprotonated Schiff base, one bridging phenolate O atom of the neighbouring ligand and two butyl groups in the axial sites.Camacho Camacho, CarlosOrtiz Pastrana, Naytzégarza-ortiz, ariadna-will be generated-orcid-0000-0003-2585-1285-600Rojas-Oviedo, Irma-will be generated-orcid-0000-0003-2807-5402-600application/pdfengCorporación Universidad de la CostaAttribution-NonCommercial-ShareAlike 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Acta Crystallogr E Crystallogr Communhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209758/crystal structure8-quinolino­latessevenfold coordinationdi­alkyl­ditin(IV) compoundCrystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]Artículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionRasoul-Amini, S., Khalaj, A., Shafiee, A., Daneshtalab, M., Madadkar-Sobhani, M. & Fouladdel, S. (2006). Int. J. Cancer Res. 2, 102–108.Albrecht, M., Osetska, O. & Fröhlich, R. (2005). Dalton Trans. pp. 3757–3762.Albrecht, M., Osetska, O., Fröhlich, R., Bünzli, J. G., Aebischer, A., Gumy, F. & Hamacek, J. (2007). J. Am. Chem. Soc. 129, 14178–14179.Anitha, P., Manikandan, R., Prakash, G., Pachiyappan, B., Viswanathamurthi, P. & Malecki, J. G. (2015). J. Organomet. Chem. 791, 266–273.Basu Baul, T. S., Mizar, A., Paul, A., Ruisi, G., Willem, R., Biesemans, M. & Linden, A. (2009). J. Organomet. Chem. 694, 2142–2152.Bruker (2012). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.Charles, R. G. & Perrotto, A. (1964). Anal. Chim. Acta, 30, 131–138.Corcé, V., Renaud, S., Cannie, I., Julienne, K., Gouin, S. G., Loréal, O., Gaboriau, F. & Deniaud, D. (2014). Bioconjugate Chem. 25, 320–334.Cui, J., Qiao, Y., Yin, H. & Liu, M. Z. (2010). Z. Anorg. Allg. Chem. 636, 2508–2512.García-Santos, I., Sanmartín, J., García-Deibe, A. M., Fondo, M. & Gómez, E. (2009). Polyhedron, 28, 3055–3059.Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466–470.Musiol, R., Jampilek, J., Buchta, V., Silva, L., Niedbala, H., Podeszwa, B., Palka, A., Majerz-Maniecka, K., Oleksyn, B. & Polanski, J. (2006). Bioorg. Med. Chem. 14, 3592–3598.Nasveld, P. & Kitchener, S. (2005). Trans. R. Soc. Trop. Med. Hyg. 99, 2–5.Palit, P., Paira, P., Hazra, A., Banerjee, S., Das Gupta, A., Dastidar, S. G. & Mondal, N. B. (2009). Eur. J. Med. Chem. 44, 845–853.Serda, M., Kalinowski, D., Mrozek-Wilczkiewicz, A., Musiol, R., Szurko, A., Ratuszna, A., Pantarat, N., Kovacevic, Z., Merlot, A. M., Richardson, D. R. & Polanski, J. (2012). Bioorg. Med. Chem. Lett. 22, 5527–5531.Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.Sheldrick, G. M. (2015). Acta Cryst. C71, 3–8.Sousa, A. T. de, Bessler, K. E., Lemos, S. S., Ellena, J. & Gatto, C. C. (2009). Z. Anorg. Allg. Chem. 635, 106–111.Sun, W.-H., Shen, M., Zhang, W., Huang, W., Liu, S. & Redshaw, C. (2011). Dalton Trans. 40, 2645–2653.Vafaee, M., Amini, M. M. & Ng, S. W. (2010). Acta Cryst. E66, m964.Westrip, S. P. (2010). J. Appl. Cryst. 43, 920–925.Yan, Q., Sun, Z., Zhang, W., Nomura, K. & Sun, W.-H. (2014). Macromol. Chem. Phys. 215, 1744–1752.Zhang, W., Liu, S., Yang, W., Hao, X., Glaser, R. & Sun, W.-H. (2012). Organometallics, 31, 8178–8188.Zhang, H.-X., Wang, S.-Y., Wang, W.-M., Gao, H.-L. & Cui, J.-Z. (2015). Inorg. Chem. Commun. 62, 94–97.PublicationORIGINALCrystal structure of bis{[mu]-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-[kappa]4O,N,N',O'}bis[dibutyltin(IV)] _ Enhanced Reader.pdfCrystal structure of bis{[mu]-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-[kappa]4O,N,N',O'}bis[dibutyltin(IV)] _ Enhanced Reader.pdfapplication/pdf8128835https://repositorio.cuc.edu.co/bitstreams/c941f254-9b4f-41b8-ae2b-4af2b92f151a/downloade7bc022eb817a2ab0816535d46cc8267MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-81031https://repositorio.cuc.edu.co/bitstreams/a165552a-425c-4663-9fb2-58d7c68b00b0/download934f4ca17e109e0a05eaeaba504d7ce4MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/f415ce66-1017-41c7-9f6d-f78f9de51a17/downloade30e9215131d99561d40d6b0abbe9badMD53THUMBNAILCrystal structure of bis{[mu]-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-[kappa]4O,N,N',O'}bis[dibutyltin(IV)] _ Enhanced Reader.pdf.jpgCrystal structure of bis{[mu]-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-[kappa]4O,N,N',O'}bis[dibutyltin(IV)] _ Enhanced Reader.pdf.jpgimage/jpeg62315https://repositorio.cuc.edu.co/bitstreams/316fb63e-c2e2-4415-9766-7ec4f23af168/download9eaf53f1f22e8d848a25168ccabeba18MD54TEXTCrystal structure of bis{[mu]-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-[kappa]4O,N,N',O'}bis[dibutyltin(IV)] _ Enhanced Reader.pdf.txtCrystal structure of bis{[mu]-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-[kappa]4O,N,N',O'}bis[dibutyltin(IV)] _ Enhanced Reader.pdf.txttext/plain17https://repositorio.cuc.edu.co/bitstreams/5a8bf11b-579c-4e1c-b55d-c19c2cc13d75/download24e648839aa31918bceb936aff170ec0MD5511323/7259oai:repositorio.cuc.edu.co:11323/72592024-09-17 12:48:23.272http://creativecommons.org/licenses/by-nc-sa/4.0/Attribution-NonCommercial-ShareAlike 4.0 Internationalopen.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.coQXV0b3Jpem8gKGF1dG9yaXphbW9zKSBhIGxhIEJpYmxpb3RlY2EgZGUgbGEgSW5zdGl0dWNpw7NuIHBhcmEgcXVlIGluY2x1eWEgdW5hIGNvcGlhLCBpbmRleGUgeSBkaXZ1bGd1ZSBlbiBlbCBSZXBvc2l0b3JpbyBJbnN0aXR1Y2lvbmFsLCBsYSBvYnJhIG1lbmNpb25hZGEgY29uIGVsIGZpbiBkZSBmYWNpbGl0YXIgbG9zIHByb2Nlc29zIGRlIHZpc2liaWxpZGFkIGUgaW1wYWN0byBkZSBsYSBtaXNtYSwgY29uZm9ybWUgYSBsb3MgZGVyZWNob3MgcGF0cmltb25pYWxlcyBxdWUgbWUobm9zKSBjb3JyZXNwb25kZShuKSB5IHF1ZSBpbmNsdXllbjogbGEgcmVwcm9kdWNjacOzbiwgY29tdW5pY2FjacOzbiBww7pibGljYSwgZGlzdHJpYnVjacOzbiBhbCBww7pibGljbywgdHJhbnNmb3JtYWNpw7NuLCBkZSBjb25mb3JtaWRhZCBjb24gbGEgbm9ybWF0aXZpZGFkIHZpZ2VudGUgc29icmUgZGVyZWNob3MgZGUgYXV0b3IgeSBkZXJlY2hvcyBjb25leG9zIHJlZmVyaWRvcyBlbiBhcnQuIDIsIDEyLCAzMCAobW9kaWZpY2FkbyBwb3IgZWwgYXJ0IDUgZGUgbGEgbGV5IDE1MjAvMjAxMiksIHkgNzIgZGUgbGEgbGV5IDIzIGRlIGRlIDE5ODIsIExleSA0NCBkZSAxOTkzLCBhcnQuIDQgeSAxMSBEZWNpc2nDs24gQW5kaW5hIDM1MSBkZSAxOTkzIGFydC4gMTEsIERlY3JldG8gNDYwIGRlIDE5OTUsIENpcmN1bGFyIE5vIDA2LzIwMDIgZGUgbGEgRGlyZWNjacOzbiBOYWNpb25hbCBkZSBEZXJlY2hvcyBkZSBhdXRvciwgYXJ0LiAxNSBMZXkgMTUyMCBkZSAyMDEyLCBsYSBMZXkgMTkxNSBkZSAyMDE4IHkgZGVtw6FzIG5vcm1hcyBzb2JyZSBsYSBtYXRlcmlhLg0KDQpBbCByZXNwZWN0byBjb21vIEF1dG9yKGVzKSBtYW5pZmVzdGFtb3MgY29ub2NlciBxdWU6DQoNCi0gTGEgYXV0b3JpemFjacOzbiBlcyBkZSBjYXLDoWN0ZXIgbm8gZXhjbHVzaXZhIHkgbGltaXRhZGEsIGVzdG8gaW1wbGljYSBxdWUgbGEgbGljZW5jaWEgdGllbmUgdW5hIHZpZ2VuY2lhLCBxdWUgbm8gZXMgcGVycGV0dWEgeSBxdWUgZWwgYXV0b3IgcHVlZGUgcHVibGljYXIgbyBkaWZ1bmRpciBzdSBvYnJhIGVuIGN1YWxxdWllciBvdHJvIG1lZGlvLCBhc8OtIGNvbW8gbGxldmFyIGEgY2FibyBjdWFscXVpZXIgdGlwbyBkZSBhY2Npw7NuIHNvYnJlIGVsIGRvY3VtZW50by4NCg0KLSBMYSBhdXRvcml6YWNpw7NuIHRlbmRyw6EgdW5hIHZpZ2VuY2lhIGRlIGNpbmNvIGHDsW9zIGEgcGFydGlyIGRlbCBtb21lbnRvIGRlIGxhIGluY2x1c2nDs24gZGUgbGEgb2JyYSBlbiBlbCByZXBvc2l0b3JpbywgcHJvcnJvZ2FibGUgaW5kZWZpbmlkYW1lbnRlIHBvciBlbCB0aWVtcG8gZGUgZHVyYWNpw7NuIGRlIGxvcyBkZXJlY2hvcyBwYXRyaW1vbmlhbGVzIGRlbCBhdXRvciB5IHBvZHLDoSBkYXJzZSBwb3IgdGVybWluYWRhIHVuYSB2ZXogZWwgYXV0b3IgbG8gbWFuaWZpZXN0ZSBwb3IgZXNjcml0byBhIGxhIGluc3RpdHVjacOzbiwgY29uIGxhIHNhbHZlZGFkIGRlIHF1ZSBsYSBvYnJhIGVzIGRpZnVuZGlkYSBnbG9iYWxtZW50ZSB5IGNvc2VjaGFkYSBwb3IgZGlmZXJlbnRlcyBidXNjYWRvcmVzIHkvbyByZXBvc2l0b3Jpb3MgZW4gSW50ZXJuZXQgbG8gcXVlIG5vIGdhcmFudGl6YSBxdWUgbGEgb2JyYSBwdWVkYSBzZXIgcmV0aXJhZGEgZGUgbWFuZXJhIGlubWVkaWF0YSBkZSBvdHJvcyBzaXN0ZW1hcyBkZSBpbmZvcm1hY2nDs24gZW4gbG9zIHF1ZSBzZSBoYXlhIGluZGV4YWRvLCBkaWZlcmVudGVzIGFsIHJlcG9zaXRvcmlvIGluc3RpdHVjaW9uYWwgZGUgbGEgSW5zdGl0dWNpw7NuLCBkZSBtYW5lcmEgcXVlIGVsIGF1dG9yKHJlcykgdGVuZHLDoW4gcXVlIHNvbGljaXRhciBsYSByZXRpcmFkYSBkZSBzdSBvYnJhIGRpcmVjdGFtZW50ZSBhIG90cm9zIHNpc3RlbWFzIGRlIGluZm9ybWFjacOzbiBkaXN0aW50b3MgYWwgZGUgbGEgSW5zdGl0dWNpw7NuIHNpIGRlc2VhIHF1ZSBzdSBvYnJhIHNlYSByZXRpcmFkYSBkZSBpbm1lZGlhdG8uDQoNCi0gTGEgYXV0b3JpemFjacOzbiBkZSBwdWJsaWNhY2nDs24gY29tcHJlbmRlIGVsIGZvcm1hdG8gb3JpZ2luYWwgZGUgbGEgb2JyYSB5IHRvZG9zIGxvcyBkZW3DoXMgcXVlIHNlIHJlcXVpZXJhIHBhcmEgc3UgcHVibGljYWNpw7NuIGVuIGVsIHJlcG9zaXRvcmlvLiBJZ3VhbG1lbnRlLCBsYSBhdXRvcml6YWNpw7NuIHBlcm1pdGUgYSBsYSBpbnN0aXR1Y2nDs24gZWwgY2FtYmlvIGRlIHNvcG9ydGUgZGUgbGEgb2JyYSBjb24gZmluZXMgZGUgcHJlc2VydmFjacOzbiAoaW1wcmVzbywgZWxlY3Ryw7NuaWNvLCBkaWdpdGFsLCBJbnRlcm5ldCwgaW50cmFuZXQsIG8gY3VhbHF1aWVyIG90cm8gZm9ybWF0byBjb25vY2lkbyBvIHBvciBjb25vY2VyKS4NCg0KLSBMYSBhdXRvcml6YWNpw7NuIGVzIGdyYXR1aXRhIHkgc2UgcmVudW5jaWEgYSByZWNpYmlyIGN1YWxxdWllciByZW11bmVyYWNpw7NuIHBvciBsb3MgdXNvcyBkZSBsYSBvYnJhLCBkZSBhY3VlcmRvIGNvbiBsYSBsaWNlbmNpYSBlc3RhYmxlY2lkYSBlbiBlc3RhIGF1dG9yaXphY2nDs24uDQoNCi0gQWwgZmlybWFyIGVzdGEgYXV0b3JpemFjacOzbiwgc2UgbWFuaWZpZXN0YSBxdWUgbGEgb2JyYSBlcyBvcmlnaW5hbCB5IG5vIGV4aXN0ZSBlbiBlbGxhIG5pbmd1bmEgdmlvbGFjacOzbiBhIGxvcyBkZXJlY2hvcyBkZSBhdXRvciBkZSB0ZXJjZXJvcy4gRW4gY2FzbyBkZSBxdWUgZWwgdHJhYmFqbyBoYXlhIHNpZG8gZmluYW5jaWFkbyBwb3IgdGVyY2Vyb3MgZWwgbyBsb3MgYXV0b3JlcyBhc3VtZW4gbGEgcmVzcG9uc2FiaWxpZGFkIGRlbCBjdW1wbGltaWVudG8gZGUgbG9zIGFjdWVyZG9zIGVzdGFibGVjaWRvcyBzb2JyZSBsb3MgZGVyZWNob3MgcGF0cmltb25pYWxlcyBkZSBsYSBvYnJhIGNvbiBkaWNobyB0ZXJjZXJvLg0KDQotIEZyZW50ZSBhIGN1YWxxdWllciByZWNsYW1hY2nDs24gcG9yIHRlcmNlcm9zLCBlbCBvIGxvcyBhdXRvcmVzIHNlcsOhbiByZXNwb25zYWJsZXMsIGVuIG5pbmfDum4gY2FzbyBsYSByZXNwb25zYWJpbGlkYWQgc2Vyw6EgYXN1bWlkYSBwb3IgbGEgaW5zdGl0dWNpw7NuLg0KDQotIENvbiBsYSBhdXRvcml6YWNpw7NuLCBsYSBpbnN0aXR1Y2nDs24gcHVlZGUgZGlmdW5kaXIgbGEgb2JyYSBlbiDDrW5kaWNlcywgYnVzY2Fkb3JlcyB5IG90cm9zIHNpc3RlbWFzIGRlIGluZm9ybWFjacOzbiBxdWUgZmF2b3JlemNhbiBzdSB2aXNpYmlsaWRhZA==