Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen
In this work, a high porous activated carbon from Jacaranda mimosifolia was developed and employed for ketoprofen adsorption. After the pyrolysis process at 973.15 K, the material presented cavities with different sizes allocated on the particle surface. The material presented a pH at the point of z...
- Autores:
-
Georgin, Jordana
de O. Salomón, Yamil L.
Franco, Dison S.P.
Netto, Matias S.
Piccilli, Daniel G.A.
Perondi, Daniele
Silva, Luis F.O.
Foletto, Edson L.
Dotto, Guilherme L.
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2021
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/8437
- Acceso en línea:
- https://hdl.handle.net/11323/8437
https://doi.org/10.1016/j.jece.2021.105676
https://repositorio.cuc.edu.co/
- Palabra clave:
- Activated carbon
Jacaranda mimosifolia
Ketoprofen
Adsorption
- Rights
- openAccess
- License
- Attribution-NonCommercial-NoDerivatives 4.0 International
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| dc.title.spa.fl_str_mv |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen |
| title |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen |
| spellingShingle |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen Activated carbon Jacaranda mimosifolia Ketoprofen Adsorption |
| title_short |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen |
| title_full |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen |
| title_fullStr |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen |
| title_full_unstemmed |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen |
| title_sort |
Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen |
| dc.creator.fl_str_mv |
Georgin, Jordana de O. Salomón, Yamil L. Franco, Dison S.P. Netto, Matias S. Piccilli, Daniel G.A. Perondi, Daniele Silva, Luis F.O. Foletto, Edson L. Dotto, Guilherme L. |
| dc.contributor.author.spa.fl_str_mv |
Georgin, Jordana de O. Salomón, Yamil L. Franco, Dison S.P. Netto, Matias S. Piccilli, Daniel G.A. Perondi, Daniele Silva, Luis F.O. Foletto, Edson L. Dotto, Guilherme L. |
| dc.subject.spa.fl_str_mv |
Activated carbon Jacaranda mimosifolia Ketoprofen Adsorption |
| topic |
Activated carbon Jacaranda mimosifolia Ketoprofen Adsorption |
| description |
In this work, a high porous activated carbon from Jacaranda mimosifolia was developed and employed for ketoprofen adsorption. After the pyrolysis process at 973.15 K, the material presented cavities with different sizes allocated on the particle surface. The material presented a pH at the point of zero charge of 4.1 with the best adsorption at pH 2. The best adsorbent dosage was 0.72 g L−1, corresponding to a removal of 96%. The system reached the adsorption equilibrium after 120 min and was described by the linear driving force model. The isotherms revealed that the adsorption capacity decreased with the temperature and followed the Langmuir model, with a maximum adsorption capacity of 303.9 mg g−1. This high capacity can be associated with the high surface area (928 m2 g−1) and pore volume (0.521 cm3 g−1) values. The thermodynamic values indicated that the adsorption system is spontaneous and exothermic. The enthalpy value indicates that the interactions between the adsorbent and adsorbate are physical. Regeneration tests showed a decreasing percentage of removal of 7.86% after 5 cycles. Finally, the adsorbent showed efficiency when treating a simulated effluent containing drugs and inorganic salts, showing the removal of 71.43%. |
| publishDate |
2021 |
| dc.date.accessioned.none.fl_str_mv |
2021-06-29T21:40:50Z |
| dc.date.available.none.fl_str_mv |
2021-06-29T21:40:50Z |
| dc.date.issued.none.fl_str_mv |
2021 |
| dc.type.spa.fl_str_mv |
Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
| format |
http://purl.org/coar/resource_type/c_6501 |
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acceptedVersion |
| dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/8437 |
| dc.identifier.doi.spa.fl_str_mv |
https://doi.org/10.1016/j.jece.2021.105676 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
| url |
https://hdl.handle.net/11323/8437 https://doi.org/10.1016/j.jece.2021.105676 https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.references.spa.fl_str_mv |
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Georgin, Jordana9b324b2f70fcd3715202ec8676bf9abede O. Salomón, Yamil L.23a5c05d142fc3a00ae40cb903ca7753Franco, Dison S.P.a31048682d15d92916c5efad2f1caea4Netto, Matias S.bbafe7978c27efedfcbbfaf18ef632b6Piccilli, Daniel G.A.7ef1afbafe4b0172b98da9aeb6c9e13dPerondi, Daniele3e9fb5d8c02b91cc3c8da7ff1a64f856Silva, Luis F.O.8859d8def09b06a41e4d7807d6a70603Foletto, Edson L.bcfa5f178e78f39b6a3c8c0095845667300Dotto, Guilherme L.c0e5bf3f141757792fd1a91aaeb9fc0c2021-06-29T21:40:50Z2021-06-29T21:40:50Z2021https://hdl.handle.net/11323/8437https://doi.org/10.1016/j.jece.2021.105676Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/In this work, a high porous activated carbon from Jacaranda mimosifolia was developed and employed for ketoprofen adsorption. After the pyrolysis process at 973.15 K, the material presented cavities with different sizes allocated on the particle surface. The material presented a pH at the point of zero charge of 4.1 with the best adsorption at pH 2. The best adsorbent dosage was 0.72 g L−1, corresponding to a removal of 96%. The system reached the adsorption equilibrium after 120 min and was described by the linear driving force model. The isotherms revealed that the adsorption capacity decreased with the temperature and followed the Langmuir model, with a maximum adsorption capacity of 303.9 mg g−1. This high capacity can be associated with the high surface area (928 m2 g−1) and pore volume (0.521 cm3 g−1) values. The thermodynamic values indicated that the adsorption system is spontaneous and exothermic. The enthalpy value indicates that the interactions between the adsorbent and adsorbate are physical. Regeneration tests showed a decreasing percentage of removal of 7.86% after 5 cycles. Finally, the adsorbent showed efficiency when treating a simulated effluent containing drugs and inorganic salts, showing the removal of 71.43%.application/pdfengAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Journal of Environmental Chemical Engineeringhttps://www.sciencedirect.com/science/article/abs/pii/S2213343721006539Activated carbonJacaranda mimosifoliaKetoprofenAdsorptionDevelopment of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofenArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionA. Zenker, M.R. Cicero, F. Prestinaci, P. Bottoni, M. 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Technol., 81 (2020), pp. 1461-1470, 10.2166/wst.2020.193ORIGINALDevelopment of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen.pdfDevelopment of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen.pdfapplication/pdf109683https://repositorio.cuc.edu.co/bitstream/11323/8437/1/Development%20of%20highly%20porous%20activated%20carbon%20from%20Jacaranda%20mimosifolia%20seed%20pods%20for%20remarkable%20removal%20of%20aqueous-phase%20ketoprofen.pdf9e0256b7e199f4a16430f6342c5fd59cMD51open accessCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805https://repositorio.cuc.edu.co/bitstream/11323/8437/2/license_rdf4460e5956bc1d1639be9ae6146a50347MD52open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstream/11323/8437/3/license.txte30e9215131d99561d40d6b0abbe9badMD53open accessTHUMBNAILDevelopment 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