Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp

In this work, endocarp of the species Butia capitata was employed as precursor material to prepare a novel activated carbon with intrinsic properties to remove ketoprofen and paracetamol from water efficiently. The activated carbon presented a predominantly microporous structure, with an average por...

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Autores:
M. Kerkhoff, Carolina
da Boit Martinello, Katia
S.P. Franco, Dison
S. Netto, Matias
Georgin, Jordana
L. Foletto, Edson
G.A. Piccilli, Daniel
F.O. Silva, Luis
L. Dotto, Guilherme
Tipo de recurso:
Article of journal
Fecha de publicación:
2021
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/8600
Acceso en línea:
https://hdl.handle.net/11323/8600
https://doi.org/10.1016/j.molliq.2021.117184
https://repositorio.cuc.edu.co/
Palabra clave:
Butia capitata
Activated carbon
Ketoprofen
Paracetamol
Synthetic mixture
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openAccess
License
Attribution-NonCommercial-NoDerivatives 4.0 International
id RCUC2_90a71b6674960aeea72f512c63dca61b
oai_identifier_str oai:repositorio.cuc.edu.co:11323/8600
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.spa.fl_str_mv Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
title Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
spellingShingle Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
Butia capitata
Activated carbon
Ketoprofen
Paracetamol
Synthetic mixture
title_short Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
title_full Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
title_fullStr Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
title_full_unstemmed Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
title_sort Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp
dc.creator.fl_str_mv M. Kerkhoff, Carolina
da Boit Martinello, Katia
S.P. Franco, Dison
S. Netto, Matias
Georgin, Jordana
L. Foletto, Edson
G.A. Piccilli, Daniel
F.O. Silva, Luis
L. Dotto, Guilherme
dc.contributor.author.spa.fl_str_mv M. Kerkhoff, Carolina
da Boit Martinello, Katia
S.P. Franco, Dison
S. Netto, Matias
Georgin, Jordana
L. Foletto, Edson
G.A. Piccilli, Daniel
F.O. Silva, Luis
L. Dotto, Guilherme
dc.subject.spa.fl_str_mv Butia capitata
Activated carbon
Ketoprofen
Paracetamol
Synthetic mixture
topic Butia capitata
Activated carbon
Ketoprofen
Paracetamol
Synthetic mixture
description In this work, endocarp of the species Butia capitata was employed as precursor material to prepare a novel activated carbon with intrinsic properties to remove ketoprofen and paracetamol from water efficiently. The activated carbon presented a predominantly microporous structure, with an average pore diameter of 1.23 nm, a total pore volume of 0.449 cm3 g−1, and a high specific surface area, 820 m2 g−1. The adsorption kinetics showed a rapid initial decay for both pharmaceuticals, with the system entering equilibrium after 120 min for ketoprofen and 180 min for paracetamol. The pseudo-second-order model presented the best fit for ketoprofen and the Elovich model for paracetamol. The adsorption equilibrium data show that temperature can increase or decrease the adsorption capacity, being found a maximum adsorption capacity of 108.79 and 100.60 mg g−1 for the ketoprofen and paracetamol, respectively. The Freundlich and Langmuir models presented the best statistical adjustments for the adsorption of ketoprofen and paracetamol, respectively. The thermodynamic analysis confirmed an endothermic process for ketoprofen (ΔH0 = 11.98 kJ mol−1) and exothermic for paracetamol (ΔH0 = -13.37 kJ mol−1). The recycle tests revealed that the adsorbent has an average decrease for removal percentage of only 1.88 % for ketoprofen and 1.57 % for paracetamol. Estimations costs indicate that the price of 1 kg of activated carbon costs is 2.39 USD at minimum. Last, the material presented a highly efficient adsorptive activity to treat a synthetic mixture containing several pharmaceutical compounds and salts, reaching 84.82% removal.
publishDate 2021
dc.date.accessioned.none.fl_str_mv 2021-09-01T17:20:32Z
dc.date.available.none.fl_str_mv 2021-09-01T17:20:32Z
dc.date.issued.none.fl_str_mv 2021
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
format http://purl.org/coar/resource_type/c_6501
status_str acceptedVersion
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/8600
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.1016/j.molliq.2021.117184
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
url https://hdl.handle.net/11323/8600
https://doi.org/10.1016/j.molliq.2021.117184
https://repositorio.cuc.edu.co/
identifier_str_mv Corporación Universidad de la Costa
REDICUC - Repositorio CUC
dc.language.iso.none.fl_str_mv eng
language eng
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spelling M. Kerkhoff, Carolinada Boit Martinello, KatiaS.P. Franco, DisonS. Netto, MatiasGeorgin, JordanaL. Foletto, EdsonG.A. Piccilli, DanielF.O. Silva, LuisL. Dotto, Guilherme2021-09-01T17:20:32Z2021-09-01T17:20:32Z2021https://hdl.handle.net/11323/8600https://doi.org/10.1016/j.molliq.2021.117184Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/In this work, endocarp of the species Butia capitata was employed as precursor material to prepare a novel activated carbon with intrinsic properties to remove ketoprofen and paracetamol from water efficiently. The activated carbon presented a predominantly microporous structure, with an average pore diameter of 1.23 nm, a total pore volume of 0.449 cm3 g−1, and a high specific surface area, 820 m2 g−1. The adsorption kinetics showed a rapid initial decay for both pharmaceuticals, with the system entering equilibrium after 120 min for ketoprofen and 180 min for paracetamol. The pseudo-second-order model presented the best fit for ketoprofen and the Elovich model for paracetamol. The adsorption equilibrium data show that temperature can increase or decrease the adsorption capacity, being found a maximum adsorption capacity of 108.79 and 100.60 mg g−1 for the ketoprofen and paracetamol, respectively. The Freundlich and Langmuir models presented the best statistical adjustments for the adsorption of ketoprofen and paracetamol, respectively. The thermodynamic analysis confirmed an endothermic process for ketoprofen (ΔH0 = 11.98 kJ mol−1) and exothermic for paracetamol (ΔH0 = -13.37 kJ mol−1). The recycle tests revealed that the adsorbent has an average decrease for removal percentage of only 1.88 % for ketoprofen and 1.57 % for paracetamol. Estimations costs indicate that the price of 1 kg of activated carbon costs is 2.39 USD at minimum. Last, the material presented a highly efficient adsorptive activity to treat a synthetic mixture containing several pharmaceutical compounds and salts, reaching 84.82% removal.M. Kerkhoff, Carolinada Boit Martinello, KatiaS.P. Franco, DisonS. Netto, MatiasGeorgin, JordanaL. Foletto, EdsonG.A. Piccilli, DanielF.O. Silva, LuisL. Dotto, Guilhermeapplication/pdfengAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Journal of Molecular Liquidshttps://www.sciencedirect.com/science/article/abs/pii/S0167732221019085?via%3DihubButia capitataActivated carbonKetoprofenParacetamolSynthetic mixtureAdsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarpArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionH. Zeng, M. Gao, T. Shen, F. Ding Organo silica nanosheets with gemini surfactants for rapid adsorption of ibuprofen from aqueous solutions J. Taiwan Inst. Chem. Eng., 93 (2018), pp. 329-335, 10.1016/j.jtice.2018.07.038Y. Zhao, S. Lin, J.W. Choi, J.K. 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Eng., 9 (2) (2021), p. 104980, 10.1016/j.jece:2020.104980Ying Zhang, Xiaolan Song, Pu Zhang, Hongpeng Gao, Cuiyun Ou, Xiaodong Kong Production of activated carbons from four wastes via one-step activation and their applications in Pb2+ adsorption: Insight of ash content Chemosphere., 245 (2020), p. 125587, 10.1016/j.chemosphere.2019.125587PublicationORIGINALAdsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from.pdfAdsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from.pdfapplication/pdf131493https://repositorio.cuc.edu.co/bitstreams/89d2331d-56b6-45e5-919e-e22ab0cc9b4d/download51dd9de4edeafcd08774021c07076550MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805https://repositorio.cuc.edu.co/bitstreams/788855a3-1d93-4ac3-ad97-87d3077ead67/download4460e5956bc1d1639be9ae6146a50347MD52LICENSElicense.txtlicense.txttext/plain; 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