Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America

The study of the presence of bisphenol analogs in the environment has been very relevant in recent years because their toxic potential has been discovered, and since they are not regulated like bisphenol A, their use and presence in industry has been excessive. This study identifies and quantifies f...

Full description

Autores:
Hernández Fernández, Joaquín
CANO CUADRO, HEIDIS PATRICIA
Puello, Esneyder
Tipo de recurso:
Article of investigation
Fecha de publicación:
2022
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/9558
Acceso en línea:
https://hdl.handle.net/11323/9558
https://repositorio.cuc.edu.co/
Palabra clave:
Bisphenol A
Bisphenol analogs
Wastewater treatment plants
Pollutions
Polypropylene manufacturing
Rights
openAccess
License
Atribución 4.0 Internacional (CC BY 4.0)
id RCUC2_8353a802b85a20853502c716278fd3e8
oai_identifier_str oai:repositorio.cuc.edu.co:11323/9558
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.eng.fl_str_mv Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
title Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
spellingShingle Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
Bisphenol A
Bisphenol analogs
Wastewater treatment plants
Pollutions
Polypropylene manufacturing
title_short Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
title_full Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
title_fullStr Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
title_full_unstemmed Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
title_sort Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South America
dc.creator.fl_str_mv Hernández Fernández, Joaquín
CANO CUADRO, HEIDIS PATRICIA
Puello, Esneyder
dc.contributor.author.none.fl_str_mv Hernández Fernández, Joaquín
CANO CUADRO, HEIDIS PATRICIA
Puello, Esneyder
dc.subject.proposal.eng.fl_str_mv Bisphenol A
Bisphenol analogs
Wastewater treatment plants
Pollutions
Polypropylene manufacturing
topic Bisphenol A
Bisphenol analogs
Wastewater treatment plants
Pollutions
Polypropylene manufacturing
description The study of the presence of bisphenol analogs in the environment has been very relevant in recent years because their toxic potential has been discovered, and since they are not regulated like bisphenol A, their use and presence in industry has been excessive. This study identifies and quantifies for the first time the presence of bisphenol A and four uncommon bisphenol analogs in waste from polypropylene (PP) and polyethylene terephthalate (PET) production processes that may originate from the degradation of some compounds used during resin synthesis in Colombia to determine the effectiveness of removal of these components. The data obtained show that the treatments used in these waters are insufficient to eliminate 40% of the bisphenols present in them, and when evaluating the profiles of compounds, it is clear that the compound with the highest removal during the PP process was D-BPA-1, while the compound with the highest removal during the PET process was D-BPA-4, indicating that identification and elimination systems for bisphenols are rudimentary.
publishDate 2022
dc.date.accessioned.none.fl_str_mv 2022-10-03T14:07:34Z
dc.date.available.none.fl_str_mv 2022-10-03T14:07:34Z
dc.date.issued.none.fl_str_mv 2022-09-01
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.coarversion.spa.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
format http://purl.org/coar/resource_type/c_2df8fbb1
status_str publishedVersion
dc.identifier.citation.spa.fl_str_mv Hernández-Fernández, J.; Cano-Cuadro, H.; Puello-Polo, E. Emission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production Processes of Polypropylene and Polyethylene Terephthalate in South America. Sustainability 2022, 14, 10919. https://doi.org/10.3390/ su141710919
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/11323/9558
dc.identifier.doi.none.fl_str_mv 10.3390/ su141710919
dc.identifier.eissn.spa.fl_str_mv 2071-1050
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv Hernández-Fernández, J.; Cano-Cuadro, H.; Puello-Polo, E. Emission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production Processes of Polypropylene and Polyethylene Terephthalate in South America. Sustainability 2022, 14, 10919. https://doi.org/10.3390/ su141710919
10.3390/ su141710919
2071-1050
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/9558
https://repositorio.cuc.edu.co/
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournal.spa.fl_str_mv Sustainability
dc.relation.references.spa.fl_str_mv 1. Owczarek, K.; Kudłak, B.; Simeonov, V.; Mazerska, Z.; Namie´snik, J. Binary Mixtures of Selected Bisphenols in the Environment: Their Toxicity in Relationship to Individual Constituents. Molecules 2018, 23, 3226. [CrossRef] [PubMed]
2. Cimmino, I.; Fiory, F.; Perruolo, G.; Miele, C.; Beguinot, F.; Formisano, P.; Oriente, F. Potential Mechanisms of Bisphenol A (BPA) Contributing to Human Disease. Int. J. Mol. Sci. 2020, 21, 5761. [CrossRef] [PubMed]
3. Gao, H.; Yang, B.-J.; Li, N.; Feng, L.-M.; Shi, X.-Y.; Zhao, W.-H.; Liu, S.-J. Bisphenol A and Hormone-Associated Cancers: Current Progress and Perspectives. Medicine 2015, 94, e211. [CrossRef] [PubMed]
4. Corrales, J.; Kristofco, L.A.; Steele, W.B.; Yates, B.S.; Breed, C.S.; Williams, E.S.; Brooks, B.W. Global Assessment of Bisphenol A in the Environment: Review and Analysis of Its Occurrence and Bioaccumulation. Dose-Response Publ. Int. Hormesis Soc. 2015, 13, 1–29. [CrossRef] [PubMed]
5. Kadasala, N.R.; Narayanan, B.; Liu, Y. International Trade Regulations on BPA: Global Health and Economic Implications. Asian Dev. Policy Rev. 2016, 4, 134–142. [CrossRef]
6. Frankowski, R.; Zgoła-Grze´skowiak, A.; Grze´skowiak, T.; Sójka, K. The Presence of Bisphenol A in the Thermal Paper in the Face of Changing European Regulations—A Comparative Global Research. Environ. Pollut. 2020, 265, 114879. [CrossRef] [PubMed]
7. Liao, C.; Liu, F.; Kannan, K. Bisphenol S, a New Bisphenol Analogue, in Paper Products and Currency Bills and Its Association with Bisphenol A Residues. Environ. Sci. Technol. 2012, 46, 6515–6522. [CrossRef] [PubMed]
8. Yamazaki, E.; Yamashita, N.; Taniyasu, S.; Lam, J.; Lam, P.K.S.; Moon, H.-B.; Jeong, Y.; Kannan, P.; Achyuthan, H.; Munuswamy, N.; et al. Bisphenol A and Other Bisphenol Analogues Including BPS and BPF in Surface Water Samples from Japan, China, Korea and India. Ecotoxicol. Environ. Saf. 2015, 122, 565–572. [CrossRef] [PubMed]
9. Chen, D.; Kannan, K.; Tan, H.; Zheng, Z.; Feng, Y.-L.; Wu, Y.; Widelka, M. Bisphenol Analogues Other Than BPA: Environmental Occurrence, Human Exposure, and Toxicity—A Review. Environ. Sci. Technol. 2016, 50, 5438–5453. [CrossRef] [PubMed]
10. Delfosse, V.; Grimaldi, M.; Pons, J.-L.; Boulahtouf, A.; le Maire, A.; Cavailles, V.; Labesse, G.; Bourguet, W.; Balaguer, P. Structural and Mechanistic Insights into Bisphenols Action Provide Guidelines for Risk Assessment and Discovery of Bisphenol A Substitutes. Proc. Natl. Acad. Sci. USA 2012, 109, 14930–14935. [CrossRef] [PubMed]
11. Xue, J.; Kannan, P.; Kumosani, T.A.; Al-Malki, A.L.; Kannan, K. Resin-Based Dental Sealants as a Source of Human Exposure to Bisphenol Analogues, Bisphenol A Diglycidyl Ether, and Its Derivatives. Environ. Res. 2018, 162, 35–40. [CrossRef]
12. Goldinger, D.M.; Demierre, A.-L.; Zoller, O.; Rupp, H.; Reinhard, H.; Magnin, R.; Becker, T.W.; Bourqui-Pittet, M. Endocrine Activity of Alternatives to BPA Found in Thermal Paper in Switzerland. Regul. Toxicol. Pharmacol. 2015, 71, 453–462. [CrossRef]
13. Lee, S.; Liao, C.; Song, G.-J.; Ra, K.; Kannan, K.; Moon, H.-B. Emission of Bisphenol Analogues Including Bisphenol A and Bisphenol F from Wastewater Treatment Plants in Korea. Chemosphere 2015, 119, 1000–1006. [CrossRef]
14. Ziv-Gal, A.; Flaws, J.A. Evidence for Bisphenol A-Induced Female Infertility: A Review (2007–2016). Fertil. Steril. 2016, 106, 827–856. [CrossRef] [PubMed]
15. Yan, Z.; Liu, Y.; Yan, K.; Wu, S.; Han, Z.; Guo, R.; Chen, M.; Yang, Q.; Zhang, S.; Chen, J. Bisphenol Analogues in Surface Water and Sediment from the Shallow Chinese Freshwater Lakes: Occurrence, Distribution, Source Apportionment, and Ecological and Human Health Risk. Chemosphere 2017, 184, 318–328. [CrossRef] [PubMed]
16. Zhang, H.; Zhang, Y.; Li, J.; Yang, M. Occurrence and Exposure Assessment of Bisphenol Analogues in Source Water and Drinking Water in China. Sci. Total Environ. 2019, 655, 607–613. [CrossRef] [PubMed]
17. Ruan, T.; Liang, D.; Song, S.; Song, M.; Wang, H.; Jiang, G. Evaluation of the in Vitro Estrogenicity of Emerging Bisphenol Analogs and Their Respective Estrogenic Contributions in Municipal Sewage Sludge in China. Chemosphere 2015, 124, 150–155. [CrossRef]
18. Xue, J.; Kannan, K. Mass Flows and Removal of Eight Bisphenol Analogs, Bisphenol A Diglycidyl Ether and Its Derivatives in Two Wastewater Treatment Plants in New York State, USA. Sci. Total Environ. 2019, 648, 442–449. [CrossRef]
19. Jin, H.; Zhu, L. Occurrence and Partitioning of Bisphenol Analogues in Water and Sediment from Liaohe River Basin and Taihu Lake, China. Water Res. 2016, 103, 343–351. [CrossRef]
20. Karthikraj, R.; Kannan, K. Mass Loading and Removal of Benzotriazoles, Benzothiazoles, Benzophenones, and Bisphenols in Indian Sewage Treatment Plants. Chemosphere 2017, 181, 216–223. [CrossRef]
21. Sun, Q.; Wang, Y.; Li, Y.; Ashfaq, M.; Dai, L.; Xie, X.; Yu, C.-P. Fate and Mass Balance of Bisphenol Analogues in Wastewater Treatment Plants in Xiamen City, China. Environ. Pollut. 2017, 225, 542–549. [CrossRef] [PubMed]
22. Peña-Guzmán, C.; Ulloa-Sánchez, S.; Mora, K.; Helena-Bustos, R.; Lopez-Barrera, E.; Alvarez, J.; Rodriguez-Pinzón, M. Emerging Pollutants in the Urban Water Cycle in Latin America: A Review of the Current Literature. J. Environ. Manag. 2019, 237, 408–423. [CrossRef] [PubMed]
23. Jardim, W.F.; Montagner, C.C.; Pescara, I.C.; Umbuzeiro, G.A.; Di Dea Bergamasco, A.M.; Eldridge, M.L.; Sodré, F.F. An Integrated Approach to Evaluate Emerging Contaminants in Drinking Water. Sep. Purif. Technol. 2012, 84, 3–8. [CrossRef]
24. Fang, Y.-X.; Ying, G.-G.; Zhao, J.-L.; Chen, F.; Liu, S.; Zhang, L.-J.; Yang, B. Assessment of Hormonal Activities and Genotoxicity of Industrial Effluents Using in Vitro Bioassays Combined with Chemical Analysis. Environ. Toxicol. Chem. 2012, 31, 1273–1282. [CrossRef]
25. Balabaniˇc, D.; Filipiˇc, M.; Krivograd Klemenˇciˇc, A.; Žegura, B. Raw and Biologically Treated Paper Mill Wastewater Effluents and the Recipient Surface Waters: Cytotoxic and Genotoxic Activity and the Presence of Endocrine Disrupting Compounds. Sci. Total Environ. 2017, 574, 78–89. [CrossRef]
26. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Quantification and Elimination of Substituted Synthetic Phenols and Volatile Organic Compounds in the Wastewater Treatment Plant during the Production of Industrial Scale Polypropylene. Chemosphere 2021, 263, 128027. [CrossRef]
27. Hernández-Fernández, J. Quantification of Arsine and Phosphine in Industrial Atmospheric Emissions in Spain and Colombia. Implementation of Modified Zeolites to Reduce the Environmental Impact of Emissions. Atmos. Pollut. Res. 2021, 12, 167–176. [CrossRef]
28. Hernández-Fernández, J. Quantification of Oxygenates, Sulphides, Thiols and Permanent Gases in Propylene. A Multiple Linear Regression Model to Predict the Loss of Efficiency in Polypropylene Production on an Industrial Scale. J. Chromatogr. A 2020, 1628, 461478. [CrossRef]
29. Joaquin, H.-F.; Juan, L. Quantification of Poisons for Ziegler Natta Catalysts and Effects on the Production of Polypropylene by Gas Chromatographic with Simultaneous Detection: Pulsed Discharge Helium Ionization, Mass Spectrometry and Flame Ionization. J. Chromatogr. A 2020, 1614, 460736. [CrossRef]
30. Joaquin, H.-F.; Juan, L.-M. Autocatalytic Influence of Different Levels of Arsine on the Thermal Stability and Pyrolysis of Polypropylene. J. Anal. Appl. Pyrolysis 2022, 161, 105385. [CrossRef]
31. Hernández-Fernandez, J.; Rodríguez, E. Determination of Phenolic Antioxidants Additives in Industrial Wastewater from Polypropylene Production Using Solid Phase Extraction with High-Performance Liquid Chromatography. J. Chromatogr. A 2019, 1607, 460442. [CrossRef] [PubMed]
32. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Development and Validation of a Methodology for Quantifying Partsper-Billion Levels of Arsine and Phosphine in Nitrogen, Hydrogen and Liquefied Petroleum Gas Using a Variable Pressure Sampler Coupled to Gas Chromatography-Mass Spectrometry. J. Chromatogr. A 2021, 1637, 461833. [CrossRef]
33. Gómez-Contreras, P.; Figueroa-Lopez, K.J.; Hernández-Fernández, J.; Cortés Rodríguez, M.; Ortega-Toro, R. Effect of Different Essential Oils on the Properties of Edible Coatings Based on Yam (Dioscorea rotundata L.) Starch and Its Application in Strawberry (Fragaria vesca L.) Preservation. Appl. Sci. 2021, 11, 11057. [CrossRef]
34. Hernández-Fernández, J.; Rayón, E.; López, J.; Arrieta, M.P. Enhancing the Thermal Stability of Polypropylene by Blending with Low Amounts of Natural Antioxidants. Macromol. Mater. Eng. 2019, 304, 1900379. [CrossRef]
35. Hernández-Fernández, J.; López-Martínez, J. Experimental Study of the Auto-Catalytic Effect of Triethylaluminum and TiCl4 Residuals at the Onset of Non-Additive Polypropylene Degradation and Their Impact on Thermo-Oxidative Degradation and Pyrolysis. J. Anal. Appl. Pyrolysis 2021, 155, 105052. [CrossRef]
36. Huang, Z.; Zhao, J.-L.; Zhang, C.-Y.; Rao, W.-L.; Liang, G.-H.; Zhang, H.; Liu, Y.-H.; Guan, Y.-F.; Zhang, H.-Y.; Ying, G.-G. Profile and Removal of Bisphenol Analogues in Hospital Wastewater, Landfill Leachate, and Municipal Wastewater in South China. Sci. Total Environ. 2021, 790, 148269. [CrossRef] [PubMed]
37. Huang, Z.; Zhao, J.-L.; Yang, Y.-Y.; Jia, Y.-W.; Zhang, Q.-Q.; Chen, C.-E.; Liu, Y.-S.; Yang, B.; Xie, L.; Ying, G.-G. Occurrence, Mass Loads and Risks of Bisphenol Analogues in the Pearl River Delta Region, South China: Urban Rainfall Runoff as a Potential Source for Receiving Rivers. Environ. Pollut. 2020, 263, 114361. [CrossRef] [PubMed]
38. Yan, Q.; Gao, X.; Huang, L.; Gan, X.-M.; Zhang, Y.-X.; Chen, Y.-P.; Peng, X.-Y.; Guo, J.-S. Occurrence and Fate of Pharmaceutically Active Compounds in the Largest Municipal Wastewater Treatment Plant in Southwest China: Mass Balance Analysis and Consumption Back-Calculated Model. Chemosphere 2014, 99, 160–170. [CrossRef]
39. Hu, Y.; Zhu, Q.; Yan, X.; Liao, C.; Jiang, G. Occurrence, Fate and Risk Assessment of BPA and Its Substituents in Wastewater Treatment Plant: A Review. Environ. Res. 2019, 178, 108732. [CrossRef] [PubMed]
40. Wang, H.; Liu, Z.; Zhang, J.; Huang, R.; Yin, H.; Dang, Z.; Wu, P.; Liu, Y. Insights into Removal Mechanisms of Bisphenol A and Its Analogues in Municipal Wastewater Treatment Plants. Sci. Total Environ. 2019, 692, 107–116. [CrossRef]
41. Melcer, H.; Kleˇcka, G. Treatment of Wastewaters Containing Bisphenol A: State of the Science Review. Water Environ. Res. 2011, 83, 650–666. [CrossRef] [PubMed]
dc.relation.citationendpage.spa.fl_str_mv 10
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.relation.citationissue.spa.fl_str_mv 17
dc.relation.citationvolume.spa.fl_str_mv 14
dc.rights.eng.fl_str_mv © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
dc.rights.license.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
dc.rights.uri.spa.fl_str_mv https://creativecommons.org/licenses/by/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.coar.spa.fl_str_mv http://purl.org/coar/access_right/c_abf2
rights_invalid_str_mv Atribución 4.0 Internacional (CC BY 4.0)
© 2022 by the authors. Licensee MDPI, Basel, Switzerland.
https://creativecommons.org/licenses/by/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.extent.spa.fl_str_mv 10 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.coverage.spatial.none.fl_str_mv South America
dc.publisher.spa.fl_str_mv MDPI AG
dc.publisher.place.spa.fl_str_mv Switzerland
dc.source.spa.fl_str_mv https://www.mdpi.com/2071-1050/14/17/10919
institution Corporación Universidad de la Costa
bitstream.url.fl_str_mv https://repositorio.cuc.edu.co/bitstream/11323/9558/1/Emission%20of%20Bisphenol%20A%20and%20Four%20New%20Analogs%20from%20Industrial%20Wastewater%20Treatment%20Plants%20in%20the%20Production.pdf
https://repositorio.cuc.edu.co/bitstream/11323/9558/2/license.txt
https://repositorio.cuc.edu.co/bitstream/11323/9558/3/Emission%20of%20Bisphenol%20A%20and%20Four%20New%20Analogs%20from%20Industrial%20Wastewater%20Treatment%20Plants%20in%20the%20Production.pdf.txt
https://repositorio.cuc.edu.co/bitstream/11323/9558/4/Emission%20of%20Bisphenol%20A%20and%20Four%20New%20Analogs%20from%20Industrial%20Wastewater%20Treatment%20Plants%20in%20the%20Production.pdf.jpg
bitstream.checksum.fl_str_mv a3221d982120cd1a6709e66178719ddb
2f9959eaf5b71fae44bbf9ec84150c7a
7d37c725fc01f814f4b3df23a88c0559
203572f7717f7a1676a71daf24d1617c
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositorio Universidad de La Costa
repository.mail.fl_str_mv bdigital@metabiblioteca.com
_version_ 1808400230406684672
spelling Atribución 4.0 Internacional (CC BY 4.0)© 2022 by the authors. Licensee MDPI, Basel, Switzerland.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Hernández Fernández, Joaquínf147f031134bad8d2d7977937c12f3f3600CANO CUADRO, HEIDIS PATRICIAb2d50e2c705762f48a6e5e910bf52450600Puello, Esneyderc52f6dab26380550b511b1cca5368d02600South America2022-10-03T14:07:34Z2022-10-03T14:07:34Z2022-09-01Hernández-Fernández, J.; Cano-Cuadro, H.; Puello-Polo, E. Emission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production Processes of Polypropylene and Polyethylene Terephthalate in South America. Sustainability 2022, 14, 10919. https://doi.org/10.3390/ su141710919https://hdl.handle.net/11323/955810.3390/ su1417109192071-1050Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The study of the presence of bisphenol analogs in the environment has been very relevant in recent years because their toxic potential has been discovered, and since they are not regulated like bisphenol A, their use and presence in industry has been excessive. This study identifies and quantifies for the first time the presence of bisphenol A and four uncommon bisphenol analogs in waste from polypropylene (PP) and polyethylene terephthalate (PET) production processes that may originate from the degradation of some compounds used during resin synthesis in Colombia to determine the effectiveness of removal of these components. The data obtained show that the treatments used in these waters are insufficient to eliminate 40% of the bisphenols present in them, and when evaluating the profiles of compounds, it is clear that the compound with the highest removal during the PP process was D-BPA-1, while the compound with the highest removal during the PET process was D-BPA-4, indicating that identification and elimination systems for bisphenols are rudimentary.10 páginasapplication/pdfengMDPI AGSwitzerlandhttps://www.mdpi.com/2071-1050/14/17/10919Emission of bisphenol a and four new analogs from industrial wastewater treatment plants in the production processes of polypropylene and polyethylene terephthalate in South AmericaArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Sustainability1. Owczarek, K.; Kudłak, B.; Simeonov, V.; Mazerska, Z.; Namie´snik, J. Binary Mixtures of Selected Bisphenols in the Environment: Their Toxicity in Relationship to Individual Constituents. Molecules 2018, 23, 3226. [CrossRef] [PubMed]2. Cimmino, I.; Fiory, F.; Perruolo, G.; Miele, C.; Beguinot, F.; Formisano, P.; Oriente, F. Potential Mechanisms of Bisphenol A (BPA) Contributing to Human Disease. Int. J. Mol. Sci. 2020, 21, 5761. [CrossRef] [PubMed]3. Gao, H.; Yang, B.-J.; Li, N.; Feng, L.-M.; Shi, X.-Y.; Zhao, W.-H.; Liu, S.-J. Bisphenol A and Hormone-Associated Cancers: Current Progress and Perspectives. Medicine 2015, 94, e211. [CrossRef] [PubMed]4. Corrales, J.; Kristofco, L.A.; Steele, W.B.; Yates, B.S.; Breed, C.S.; Williams, E.S.; Brooks, B.W. Global Assessment of Bisphenol A in the Environment: Review and Analysis of Its Occurrence and Bioaccumulation. Dose-Response Publ. Int. Hormesis Soc. 2015, 13, 1–29. [CrossRef] [PubMed]5. Kadasala, N.R.; Narayanan, B.; Liu, Y. International Trade Regulations on BPA: Global Health and Economic Implications. Asian Dev. Policy Rev. 2016, 4, 134–142. [CrossRef]6. Frankowski, R.; Zgoła-Grze´skowiak, A.; Grze´skowiak, T.; Sójka, K. The Presence of Bisphenol A in the Thermal Paper in the Face of Changing European Regulations—A Comparative Global Research. Environ. Pollut. 2020, 265, 114879. [CrossRef] [PubMed]7. Liao, C.; Liu, F.; Kannan, K. Bisphenol S, a New Bisphenol Analogue, in Paper Products and Currency Bills and Its Association with Bisphenol A Residues. Environ. Sci. Technol. 2012, 46, 6515–6522. [CrossRef] [PubMed]8. Yamazaki, E.; Yamashita, N.; Taniyasu, S.; Lam, J.; Lam, P.K.S.; Moon, H.-B.; Jeong, Y.; Kannan, P.; Achyuthan, H.; Munuswamy, N.; et al. Bisphenol A and Other Bisphenol Analogues Including BPS and BPF in Surface Water Samples from Japan, China, Korea and India. Ecotoxicol. Environ. Saf. 2015, 122, 565–572. [CrossRef] [PubMed]9. Chen, D.; Kannan, K.; Tan, H.; Zheng, Z.; Feng, Y.-L.; Wu, Y.; Widelka, M. Bisphenol Analogues Other Than BPA: Environmental Occurrence, Human Exposure, and Toxicity—A Review. Environ. Sci. Technol. 2016, 50, 5438–5453. [CrossRef] [PubMed]10. Delfosse, V.; Grimaldi, M.; Pons, J.-L.; Boulahtouf, A.; le Maire, A.; Cavailles, V.; Labesse, G.; Bourguet, W.; Balaguer, P. Structural and Mechanistic Insights into Bisphenols Action Provide Guidelines for Risk Assessment and Discovery of Bisphenol A Substitutes. Proc. Natl. Acad. Sci. USA 2012, 109, 14930–14935. [CrossRef] [PubMed]11. Xue, J.; Kannan, P.; Kumosani, T.A.; Al-Malki, A.L.; Kannan, K. Resin-Based Dental Sealants as a Source of Human Exposure to Bisphenol Analogues, Bisphenol A Diglycidyl Ether, and Its Derivatives. Environ. Res. 2018, 162, 35–40. [CrossRef]12. Goldinger, D.M.; Demierre, A.-L.; Zoller, O.; Rupp, H.; Reinhard, H.; Magnin, R.; Becker, T.W.; Bourqui-Pittet, M. Endocrine Activity of Alternatives to BPA Found in Thermal Paper in Switzerland. Regul. Toxicol. Pharmacol. 2015, 71, 453–462. [CrossRef]13. Lee, S.; Liao, C.; Song, G.-J.; Ra, K.; Kannan, K.; Moon, H.-B. Emission of Bisphenol Analogues Including Bisphenol A and Bisphenol F from Wastewater Treatment Plants in Korea. Chemosphere 2015, 119, 1000–1006. [CrossRef]14. Ziv-Gal, A.; Flaws, J.A. Evidence for Bisphenol A-Induced Female Infertility: A Review (2007–2016). Fertil. Steril. 2016, 106, 827–856. [CrossRef] [PubMed]15. Yan, Z.; Liu, Y.; Yan, K.; Wu, S.; Han, Z.; Guo, R.; Chen, M.; Yang, Q.; Zhang, S.; Chen, J. Bisphenol Analogues in Surface Water and Sediment from the Shallow Chinese Freshwater Lakes: Occurrence, Distribution, Source Apportionment, and Ecological and Human Health Risk. Chemosphere 2017, 184, 318–328. [CrossRef] [PubMed]16. Zhang, H.; Zhang, Y.; Li, J.; Yang, M. Occurrence and Exposure Assessment of Bisphenol Analogues in Source Water and Drinking Water in China. Sci. Total Environ. 2019, 655, 607–613. [CrossRef] [PubMed]17. Ruan, T.; Liang, D.; Song, S.; Song, M.; Wang, H.; Jiang, G. Evaluation of the in Vitro Estrogenicity of Emerging Bisphenol Analogs and Their Respective Estrogenic Contributions in Municipal Sewage Sludge in China. Chemosphere 2015, 124, 150–155. [CrossRef]18. Xue, J.; Kannan, K. Mass Flows and Removal of Eight Bisphenol Analogs, Bisphenol A Diglycidyl Ether and Its Derivatives in Two Wastewater Treatment Plants in New York State, USA. Sci. Total Environ. 2019, 648, 442–449. [CrossRef]19. Jin, H.; Zhu, L. Occurrence and Partitioning of Bisphenol Analogues in Water and Sediment from Liaohe River Basin and Taihu Lake, China. Water Res. 2016, 103, 343–351. [CrossRef]20. Karthikraj, R.; Kannan, K. Mass Loading and Removal of Benzotriazoles, Benzothiazoles, Benzophenones, and Bisphenols in Indian Sewage Treatment Plants. Chemosphere 2017, 181, 216–223. [CrossRef]21. Sun, Q.; Wang, Y.; Li, Y.; Ashfaq, M.; Dai, L.; Xie, X.; Yu, C.-P. Fate and Mass Balance of Bisphenol Analogues in Wastewater Treatment Plants in Xiamen City, China. Environ. Pollut. 2017, 225, 542–549. [CrossRef] [PubMed]22. Peña-Guzmán, C.; Ulloa-Sánchez, S.; Mora, K.; Helena-Bustos, R.; Lopez-Barrera, E.; Alvarez, J.; Rodriguez-Pinzón, M. Emerging Pollutants in the Urban Water Cycle in Latin America: A Review of the Current Literature. J. Environ. Manag. 2019, 237, 408–423. [CrossRef] [PubMed]23. Jardim, W.F.; Montagner, C.C.; Pescara, I.C.; Umbuzeiro, G.A.; Di Dea Bergamasco, A.M.; Eldridge, M.L.; Sodré, F.F. An Integrated Approach to Evaluate Emerging Contaminants in Drinking Water. Sep. Purif. Technol. 2012, 84, 3–8. [CrossRef]24. Fang, Y.-X.; Ying, G.-G.; Zhao, J.-L.; Chen, F.; Liu, S.; Zhang, L.-J.; Yang, B. Assessment of Hormonal Activities and Genotoxicity of Industrial Effluents Using in Vitro Bioassays Combined with Chemical Analysis. Environ. Toxicol. Chem. 2012, 31, 1273–1282. [CrossRef]25. Balabaniˇc, D.; Filipiˇc, M.; Krivograd Klemenˇciˇc, A.; Žegura, B. Raw and Biologically Treated Paper Mill Wastewater Effluents and the Recipient Surface Waters: Cytotoxic and Genotoxic Activity and the Presence of Endocrine Disrupting Compounds. Sci. Total Environ. 2017, 574, 78–89. [CrossRef]26. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Quantification and Elimination of Substituted Synthetic Phenols and Volatile Organic Compounds in the Wastewater Treatment Plant during the Production of Industrial Scale Polypropylene. Chemosphere 2021, 263, 128027. [CrossRef]27. Hernández-Fernández, J. Quantification of Arsine and Phosphine in Industrial Atmospheric Emissions in Spain and Colombia. Implementation of Modified Zeolites to Reduce the Environmental Impact of Emissions. Atmos. Pollut. Res. 2021, 12, 167–176. [CrossRef]28. Hernández-Fernández, J. Quantification of Oxygenates, Sulphides, Thiols and Permanent Gases in Propylene. A Multiple Linear Regression Model to Predict the Loss of Efficiency in Polypropylene Production on an Industrial Scale. J. Chromatogr. A 2020, 1628, 461478. [CrossRef]29. Joaquin, H.-F.; Juan, L. Quantification of Poisons for Ziegler Natta Catalysts and Effects on the Production of Polypropylene by Gas Chromatographic with Simultaneous Detection: Pulsed Discharge Helium Ionization, Mass Spectrometry and Flame Ionization. J. Chromatogr. A 2020, 1614, 460736. [CrossRef]30. Joaquin, H.-F.; Juan, L.-M. Autocatalytic Influence of Different Levels of Arsine on the Thermal Stability and Pyrolysis of Polypropylene. J. Anal. Appl. Pyrolysis 2022, 161, 105385. [CrossRef]31. Hernández-Fernandez, J.; Rodríguez, E. Determination of Phenolic Antioxidants Additives in Industrial Wastewater from Polypropylene Production Using Solid Phase Extraction with High-Performance Liquid Chromatography. J. Chromatogr. A 2019, 1607, 460442. [CrossRef] [PubMed]32. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Development and Validation of a Methodology for Quantifying Partsper-Billion Levels of Arsine and Phosphine in Nitrogen, Hydrogen and Liquefied Petroleum Gas Using a Variable Pressure Sampler Coupled to Gas Chromatography-Mass Spectrometry. J. Chromatogr. A 2021, 1637, 461833. [CrossRef]33. Gómez-Contreras, P.; Figueroa-Lopez, K.J.; Hernández-Fernández, J.; Cortés Rodríguez, M.; Ortega-Toro, R. Effect of Different Essential Oils on the Properties of Edible Coatings Based on Yam (Dioscorea rotundata L.) Starch and Its Application in Strawberry (Fragaria vesca L.) Preservation. Appl. Sci. 2021, 11, 11057. [CrossRef]34. Hernández-Fernández, J.; Rayón, E.; López, J.; Arrieta, M.P. Enhancing the Thermal Stability of Polypropylene by Blending with Low Amounts of Natural Antioxidants. Macromol. Mater. Eng. 2019, 304, 1900379. [CrossRef]35. Hernández-Fernández, J.; López-Martínez, J. Experimental Study of the Auto-Catalytic Effect of Triethylaluminum and TiCl4 Residuals at the Onset of Non-Additive Polypropylene Degradation and Their Impact on Thermo-Oxidative Degradation and Pyrolysis. J. Anal. Appl. Pyrolysis 2021, 155, 105052. [CrossRef]36. Huang, Z.; Zhao, J.-L.; Zhang, C.-Y.; Rao, W.-L.; Liang, G.-H.; Zhang, H.; Liu, Y.-H.; Guan, Y.-F.; Zhang, H.-Y.; Ying, G.-G. Profile and Removal of Bisphenol Analogues in Hospital Wastewater, Landfill Leachate, and Municipal Wastewater in South China. Sci. Total Environ. 2021, 790, 148269. [CrossRef] [PubMed]37. Huang, Z.; Zhao, J.-L.; Yang, Y.-Y.; Jia, Y.-W.; Zhang, Q.-Q.; Chen, C.-E.; Liu, Y.-S.; Yang, B.; Xie, L.; Ying, G.-G. Occurrence, Mass Loads and Risks of Bisphenol Analogues in the Pearl River Delta Region, South China: Urban Rainfall Runoff as a Potential Source for Receiving Rivers. Environ. Pollut. 2020, 263, 114361. [CrossRef] [PubMed]38. Yan, Q.; Gao, X.; Huang, L.; Gan, X.-M.; Zhang, Y.-X.; Chen, Y.-P.; Peng, X.-Y.; Guo, J.-S. Occurrence and Fate of Pharmaceutically Active Compounds in the Largest Municipal Wastewater Treatment Plant in Southwest China: Mass Balance Analysis and Consumption Back-Calculated Model. Chemosphere 2014, 99, 160–170. [CrossRef]39. Hu, Y.; Zhu, Q.; Yan, X.; Liao, C.; Jiang, G. Occurrence, Fate and Risk Assessment of BPA and Its Substituents in Wastewater Treatment Plant: A Review. Environ. Res. 2019, 178, 108732. [CrossRef] [PubMed]40. Wang, H.; Liu, Z.; Zhang, J.; Huang, R.; Yin, H.; Dang, Z.; Wu, P.; Liu, Y. Insights into Removal Mechanisms of Bisphenol A and Its Analogues in Municipal Wastewater Treatment Plants. Sci. Total Environ. 2019, 692, 107–116. [CrossRef]41. Melcer, H.; Kleˇcka, G. Treatment of Wastewaters Containing Bisphenol A: State of the Science Review. Water Environ. Res. 2011, 83, 650–666. [CrossRef] [PubMed]1011714Bisphenol ABisphenol analogsWastewater treatment plantsPollutionsPolypropylene manufacturingORIGINALEmission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production.pdfEmission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production.pdfArtículoapplication/pdf965325https://repositorio.cuc.edu.co/bitstream/11323/9558/1/Emission%20of%20Bisphenol%20A%20and%20Four%20New%20Analogs%20from%20Industrial%20Wastewater%20Treatment%20Plants%20in%20the%20Production.pdfa3221d982120cd1a6709e66178719ddbMD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstream/11323/9558/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTEmission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production.pdf.txtEmission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production.pdf.txtExtracted texttext/plain37600https://repositorio.cuc.edu.co/bitstream/11323/9558/3/Emission%20of%20Bisphenol%20A%20and%20Four%20New%20Analogs%20from%20Industrial%20Wastewater%20Treatment%20Plants%20in%20the%20Production.pdf.txt7d37c725fc01f814f4b3df23a88c0559MD53open accessTHUMBNAILEmission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production.pdf.jpgEmission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production.pdf.jpgGenerated Thumbnailimage/jpeg16143https://repositorio.cuc.edu.co/bitstream/11323/9558/4/Emission%20of%20Bisphenol%20A%20and%20Four%20New%20Analogs%20from%20Industrial%20Wastewater%20Treatment%20Plants%20in%20the%20Production.pdf.jpg203572f7717f7a1676a71daf24d1617cMD54open access11323/9558oai:repositorio.cuc.edu.co:11323/95582022-10-04 03:02:43.319An error occurred on the license name.|||https://creativecommons.org/licenses/by/4.0/open accessRepositorio Universidad de La Costabdigital@metabiblioteca.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