Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)

Introducción: Entre los metales pesados descargados en fuentes hídricas se encuentran el Cromo (VI) y el Níquel (II), los cuales causan efectos peligrosos a la salud. Objetivo: Optimizar el efecto de la concentración inicial de contaminante, temperatura y dosis de adsorbente usando residuos del proc...

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Autores:: Tejada Tovar, Candelaria Nahir
Villabona Ortíz, Ángel
Ramírez Vásquez, Paula Andrea

Tipo de recurso:: Article of journal

Fecha de publicación:: 2020

Institución:: Corporación Universidad de la Costa

Repositorio:: REDICUC - Repositorio CUC

Idioma:: spa

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dc.title.spa.fl_str_mv	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)
dc.title.translated.eng.fl_str_mv	Waste valorization of starch obtained from hawthorn yam as bioadsorbent on Chromium (VI) and Nickel (II) removal
title	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)
spellingShingle	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II) kinetics dioscorea rotundata adsorption isotherms surface response methodology optimization cinética dioscorea rotundata isotermas de adsorción metodología superficie respuesta optimización
title_short	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)
title_full	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)
title_fullStr	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)
title_full_unstemmed	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)
title_sort	Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)
dc.creator.fl_str_mv	Tejada Tovar, Candelaria Nahir Villabona Ortíz, Ángel Ramírez Vásquez, Paula Andrea
dc.contributor.author.spa.fl_str_mv	Tejada Tovar, Candelaria Nahir Villabona Ortíz, Ángel Ramírez Vásquez, Paula Andrea
dc.subject.eng.fl_str_mv	kinetics dioscorea rotundata adsorption isotherms surface response methodology optimization
topic	kinetics dioscorea rotundata adsorption isotherms surface response methodology optimization cinética dioscorea rotundata isotermas de adsorción metodología superficie respuesta optimización
dc.subject.spa.fl_str_mv	cinética dioscorea rotundata isotermas de adsorción metodología superficie respuesta optimización
description	Introducción: Entre los metales pesados descargados en fuentes hídricas se encuentran el Cromo (VI) y el Níquel (II), los cuales causan efectos peligrosos a la salud. Objetivo: Optimizar el efecto de la concentración inicial de contaminante, temperatura y dosis de adsorbente usando residuos del proceso de obtención de almidón de ñame espino (D. rotundata) en la remoción de Cromo (VI) y Níquel (II). Metodología: Se optimizó aplicando la Metodología Superficie Respuesta (RSM), realizando el estudio cinético y de equilibrio a la condición óptima encontrada, evaluando el ajuste de los datos de cinética a los modelos de pseudo-primer orden, pseudo-segundo orden, Elovich; los de isotermas a los modelos de Langmuir y Freundlich. Se calcularon los parámetros termodinámicos: Energía libre de Gibbs (ΔG°), Entalpía (ΔH°) y Entropía (ΔS°), por el método gráfico de Van’t Hoff. Resultados: De la MSR se encontró que las condiciones óptimas para Cr(VI) fueron 76.6 ºC, 0.14 g y 368,18 ppm, y para Ni(II) 70 ºC, 1,19 g y 31,82 ppm. La capacidad de adsorción máxima fue de 66,25 mg/g de Cr(VI) y 17.67 mg/g de Ni(II). El modelo cinético de pseudo-segundo orden ajusta los datos de adsorción de Cr(VI) y el de Elovich ajusta los de Ni(II); por su parte el modelo de isoterma de Freundlich mostró el mejor ajuste de los datos de adsorción de los iones en estudio. De los valores de ΔG°, ΔS°, y ΔH° se establece que el proceso para Cr (VI) es endotérmico, no espontáneo no favorable y reversible; para Ni (II) que es no espontaneo, exotérmico y controlado por fisisorción. Conclusiones: Los residuos del proceso de extracción de almidón de ñame son un adsorbente efectivo para la remoción de Cr(VI) y Ni(II) presentes en solución acuosa y la MSR arrojó valores óptimos que sirven de base para la escalabilidad del proceso.
publishDate	2020
dc.date.accessioned.none.fl_str_mv	2020-01-27 00:00:00 2024-04-09T20:15:31Z
dc.date.available.none.fl_str_mv	2020-01-27 00:00:00 2024-04-09T20:15:31Z
dc.date.issued.none.fl_str_mv	2020-01-27
dc.type.spa.fl_str_mv	Artículo de revista
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dc.type.local.eng.fl_str_mv	Journal article
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dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/11323/12241
dc.identifier.url.none.fl_str_mv	https://doi.org/10.17981/ingecuc.16.1.2020.02
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spelling	Tejada Tovar, Candelaria NahirVillabona Ortíz, ÁngelRamírez Vásquez, Paula Andrea2020-01-27 00:00:002024-04-09T20:15:31Z2020-01-27 00:00:002024-04-09T20:15:31Z2020-01-270122-6517https://hdl.handle.net/11323/12241https://doi.org/10.17981/ingecuc.16.1.2020.0210.17981/ingecuc.16.1.2020.022382-4700Introducción: Entre los metales pesados descargados en fuentes hídricas se encuentran el Cromo (VI) y el Níquel (II), los cuales causan efectos peligrosos a la salud. Objetivo: Optimizar el efecto de la concentración inicial de contaminante, temperatura y dosis de adsorbente usando residuos del proceso de obtención de almidón de ñame espino (D. rotundata) en la remoción de Cromo (VI) y Níquel (II). Metodología: Se optimizó aplicando la Metodología Superficie Respuesta (RSM), realizando el estudio cinético y de equilibrio a la condición óptima encontrada, evaluando el ajuste de los datos de cinética a los modelos de pseudo-primer orden, pseudo-segundo orden, Elovich; los de isotermas a los modelos de Langmuir y Freundlich. Se calcularon los parámetros termodinámicos: Energía libre de Gibbs (ΔG°), Entalpía (ΔH°) y Entropía (ΔS°), por el método gráfico de Van’t Hoff. Resultados: De la MSR se encontró que las condiciones óptimas para Cr(VI) fueron 76.6 ºC, 0.14 g y 368,18 ppm, y para Ni(II) 70 ºC, 1,19 g y 31,82 ppm. La capacidad de adsorción máxima fue de 66,25 mg/g de Cr(VI) y 17.67 mg/g de Ni(II). El modelo cinético de pseudo-segundo orden ajusta los datos de adsorción de Cr(VI) y el de Elovich ajusta los de Ni(II); por su parte el modelo de isoterma de Freundlich mostró el mejor ajuste de los datos de adsorción de los iones en estudio. De los valores de ΔG°, ΔS°, y ΔH° se establece que el proceso para Cr (VI) es endotérmico, no espontáneo no favorable y reversible; para Ni (II) que es no espontaneo, exotérmico y controlado por fisisorción. Conclusiones: Los residuos del proceso de extracción de almidón de ñame son un adsorbente efectivo para la remoción de Cr(VI) y Ni(II) presentes en solución acuosa y la MSR arrojó valores óptimos que sirven de base para la escalabilidad del proceso.Introduction: Among the heavy metals discharged on water sources the Chromium (VI) and Nickel (II) cause dangerous health effects. Objective: Optimize the effect of the initial concentration of pollutant, temperature and adsorbent dose using residues of the starch obtaining process from hawthorn yam (D.rotundata) in the removal of Chromium (VI) and Nickel (II). Method: The optimization was carried out by applying the Response Surface Methodology (RSM), performing the kinetic and equilibrium study to the optimal condition found, evaluating the fit of the kinetic data to the pseudo-first-order, pseudo-second-order, and Elovich models; those of isotherms to the models of Langmuir and Freundlich. The thermodynamic parameters: Gibbs free Energy (ΔG°), Enthalpy (ΔH°) and Entropy (ΔS°), were calculated using the Van't Hoff graphical method. Results: From the MSR it was found that the optimal conditions for Cr (VI) were 76.6 ° C, 0.14 g and 368.18 ppm, and for Ni (II) 70 °C, 1.19 g and 31.82 ppm. The maximum adsorption capacity was 66.25 mg/g Cr (VI) and 17.67 mg/g Ni (II). The pseudo-second-order kinetic model adjusts the adsorption data of Cr (VI) and that of Elovich adjusts the Ni (II) data; on the other hand, the Freundlich isotherm model showed the best adjustment of the adsorption data of the ions under study. The values of ΔG°, ΔS°, and ΔH° established that the process for Cr (VI) is endothermic, not spontaneous, not favorable and reversible; for Ni (II) which is non-spontaneous, exothermic and controlled by physisorption. Conclusions: The residues of the hawthorn yam starch extraction process are an effective adsorbent for the removal of Cr (VI) and Ni (II) present in aqueous solution and the MSR yielded optimal values that serve as the basis for the scalability of the process.application/pdftext/htmlapplication/xmlspaUniversidad de la CostaINGE CUC - 2020http://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessEsta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.http://purl.org/coar/access_right/c_abf2https://revistascientificas.cuc.edu.co/ingecuc/article/view/2534kineticsdioscorea rotundataadsorption isothermssurface response methodologyoptimizationcinéticadioscorea rotundataisotermas de adsorciónmetodología superficie respuestaoptimizaciónValorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)Waste valorization of starch obtained from hawthorn yam as bioadsorbent on Chromium (VI) and Nickel (II) removalArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articleJournal articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Inge Cuc A. 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Valorización de residuos de la obtención de almidón de ñame espino para su uso como bioadsorbente en la remoción de Cromo (VI) y Níquel (II)

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