Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption
The residual husks of the edible fruits of Psidium cattleianum were carbonized with FeCl3 as an activating agent and used as an adsorbent to remove the toxic herbicide. After the carbonization step, changes in the material’s structure were found. Activated carbon showed characteristics of microporou...
- Autores:
-
Lazarotto, Joseane
DA BOIT MARTINELLO, KATIA
georgin, jordana
Franco, Dison S.P.
Netto, Matias S.
Piccilli, Daniel G.A.
Silva, Luis F.O.
Lima, Eder Claudio
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/9254
- Acceso en línea:
- https://hdl.handle.net/11323/9254
https://repositorio.cuc.edu.co/
- Palabra clave:
- Adsorption
Atrazine
Activated carbon
Adsorption thermodynamics
Biomass-based adsorbent
- Rights
- embargoedAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
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| dc.title.eng.fl_str_mv |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption |
| title |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption |
| spellingShingle |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption Adsorption Atrazine Activated carbon Adsorption thermodynamics Biomass-based adsorbent |
| title_short |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption |
| title_full |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption |
| title_fullStr |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption |
| title_full_unstemmed |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption |
| title_sort |
Application of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption |
| dc.creator.fl_str_mv |
Lazarotto, Joseane DA BOIT MARTINELLO, KATIA georgin, jordana Franco, Dison S.P. Netto, Matias S. Piccilli, Daniel G.A. Silva, Luis F.O. Lima, Eder Claudio Dotto, Guilherme Luiz |
| dc.contributor.author.spa.fl_str_mv |
Lazarotto, Joseane DA BOIT MARTINELLO, KATIA georgin, jordana Franco, Dison S.P. Netto, Matias S. Piccilli, Daniel G.A. Silva, Luis F.O. Lima, Eder Claudio Dotto, Guilherme Luiz |
| dc.subject.proposal.none.fl_str_mv |
Adsorption Atrazine Activated carbon Adsorption thermodynamics Biomass-based adsorbent |
| topic |
Adsorption Atrazine Activated carbon Adsorption thermodynamics Biomass-based adsorbent |
| description |
The residual husks of the edible fruits of Psidium cattleianum were carbonized with FeCl3 as an activating agent and used as an adsorbent to remove the toxic herbicide. After the carbonization step, changes in the material’s structure were found. Activated carbon showed characteristics of microporous materials with a pore volume of 0.280 cm3 g−1 and surface area of 431 m2 g−1. Micrographs revealed the emergence of new cavities with a uniform and circular shape. The FTIR spectra showed the disappearance of some bands, remaining bands belonging to functional groups containing carbon, oxygen, and hydrogen. The XRD patterns confirmed the amorphous structure of the material even after the carbonization step, composed of amorphous graphitic carbon. EDS analysis showed that the carbon percentage increased and the oxygen decreased after the carbonization. The experiments were performed at neutral pH using 1 g L−1 of adsorbent. In equilibrium isotherms, the temperature played a considerable role in the adsorption capacity, increasing from 26.39 mg g−1 to 35.67 mg g−1 when the temperature varied from 298 to 328 K. The Liu isotherms were the ones that best fit the isotherm data. The changes in the adsorption enthalpy were endothermic (ΔH° 129.5 kJ mol−1). The general order kinetic model was the most adequate for kinetic data, presenting the lowest values of the Bayesian Information Criterion. Thus, activated carbon developed from the residues of the “araça” fruit showed promise in removing atrazine from aqueous solutions, with the great advantage of its high efficiency under neutral pH solutions and mild temperatures. |
| publishDate |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2022-06-14T16:19:57Z |
| dc.date.available.none.fl_str_mv |
2022-06-14T16:19:57Z 2024-04 |
| dc.date.issued.none.fl_str_mv |
2022-04 |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
| format |
http://purl.org/coar/resource_type/c_6501 |
| dc.identifier.citation.spa.fl_str_mv |
Joseane S. Lazarotto, Kátia da Boit Martinello, Jordana Georgin, Dison S.P. Franco, Matias S. Netto, Daniel G.A. Piccilli, Luis F.O. Silva, Eder C. Lima, Guilherme L. Dotto, Application of araçá fruit husks (Psidium cattleianum) in the reparation of activated carbon with FeCl3 for atrazine herbicide adsorption, Chemical Engineering Research and Design, Volume 180, 2022, Pages 67-78, ISSN 0263-8762, https://doi.org/10.1016/j.cherd.2022.01.044. |
| dc.identifier.issn.spa.fl_str_mv |
0263-8762 |
| dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/9254 |
| dc.identifier.doi.spa.fl_str_mv |
10.1016/j.cherd.2022.01.044. |
| dc.identifier.eissn.spa.fl_str_mv |
17443563 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Joseane S. Lazarotto, Kátia da Boit Martinello, Jordana Georgin, Dison S.P. Franco, Matias S. Netto, Daniel G.A. Piccilli, Luis F.O. Silva, Eder C. Lima, Guilherme L. Dotto, Application of araçá fruit husks (Psidium cattleianum) in the reparation of activated carbon with FeCl3 for atrazine herbicide adsorption, Chemical Engineering Research and Design, Volume 180, 2022, Pages 67-78, ISSN 0263-8762, https://doi.org/10.1016/j.cherd.2022.01.044. 0263-8762 10.1016/j.cherd.2022.01.044. 17443563 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/9254 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Chemical Engineering Research and Design |
| dc.relation.references.spa.fl_str_mv |
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Lazarotto, JoseaneDA BOIT MARTINELLO, KATIAgeorgin, jordanaFranco, Dison S.P.Netto, Matias S.Piccilli, Daniel G.A.Silva, Luis F.O.Lima, Eder ClaudioDotto, Guilherme Luiz2022-06-14T16:19:57Z2024-042022-06-14T16:19:57Z2022-04Joseane S. Lazarotto, Kátia da Boit Martinello, Jordana Georgin, Dison S.P. Franco, Matias S. Netto, Daniel G.A. Piccilli, Luis F.O. Silva, Eder C. Lima, Guilherme L. Dotto, Application of araçá fruit husks (Psidium cattleianum) in the reparation of activated carbon with FeCl3 for atrazine herbicide adsorption, Chemical Engineering Research and Design, Volume 180, 2022, Pages 67-78, ISSN 0263-8762, https://doi.org/10.1016/j.cherd.2022.01.044.0263-8762https://hdl.handle.net/11323/925410.1016/j.cherd.2022.01.044.17443563Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The residual husks of the edible fruits of Psidium cattleianum were carbonized with FeCl3 as an activating agent and used as an adsorbent to remove the toxic herbicide. After the carbonization step, changes in the material’s structure were found. Activated carbon showed characteristics of microporous materials with a pore volume of 0.280 cm3 g−1 and surface area of 431 m2 g−1. Micrographs revealed the emergence of new cavities with a uniform and circular shape. The FTIR spectra showed the disappearance of some bands, remaining bands belonging to functional groups containing carbon, oxygen, and hydrogen. The XRD patterns confirmed the amorphous structure of the material even after the carbonization step, composed of amorphous graphitic carbon. EDS analysis showed that the carbon percentage increased and the oxygen decreased after the carbonization. The experiments were performed at neutral pH using 1 g L−1 of adsorbent. In equilibrium isotherms, the temperature played a considerable role in the adsorption capacity, increasing from 26.39 mg g−1 to 35.67 mg g−1 when the temperature varied from 298 to 328 K. The Liu isotherms were the ones that best fit the isotherm data. The changes in the adsorption enthalpy were endothermic (ΔH° 129.5 kJ mol−1). The general order kinetic model was the most adequate for kinetic data, presenting the lowest values of the Bayesian Information Criterion. Thus, activated carbon developed from the residues of the “araça” fruit showed promise in removing atrazine from aqueous solutions, with the great advantage of its high efficiency under neutral pH solutions and mild temperatures.12 paginasapplication/pdfengInstitution of Chemical EngineersUnited KingdomAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)© 2022 Institution of Chemical Engineers. Published by Elsevier Ltd. All rights reserved.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfApplication of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorptionArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85https://www.sciencedirect.com/science/article/pii/S0263876222000521Chemical Engineering Research and DesignAfolabi, I.C., Popoola, S.I., Bello, O.S. Modeling pseudo-second-order kinetics of orange peel-paracetamol adsorption process using artificial neural network (2020) Chemometrics and Intelligent Laboratory Systems, 203, art. no. 104053. Cited 20 times. www.elsevier.com/locate/chemometrics doi: 10.1016/j.chemolab.2020.104053Alahabadi, A., Moussavi, G. 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Technol., 320 (2021), Article 124264, 10.1016/j.biortech.2020.1242647867180AdsorptionAtrazineActivated carbonAdsorption thermodynamicsBiomass-based adsorbentPublicationORIGINALApplication of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption.pdfApplication of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption.pdfapplication/pdf3554337https://repositorio.cuc.edu.co/bitstreams/27460a23-4fad-4749-b765-651e77bbd65c/download6d6cb2cac3b1a0b4c519cc54fad3356cMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/4597959b-1dfc-4d3f-b190-cd5142483d3b/downloade30e9215131d99561d40d6b0abbe9badMD52TEXTApplication of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption.pdf.txtApplication of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption.pdf.txttext/plain64658https://repositorio.cuc.edu.co/bitstreams/40e121cc-e408-4a13-ae70-d37ff8ffd047/download9f895384e6940eab8b3816503c56387aMD53THUMBNAILApplication of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption.pdf.jpgApplication of araçá fruit husks (Psidium cattleianum) in the preparation of activated carbon with FeCl3 for atrazine herbicide adsorption.pdf.jpgimage/jpeg14444https://repositorio.cuc.edu.co/bitstreams/541ee403-0684-4d31-80fa-1cf6361c2b2c/download7afb4b4c5a35d0510bc5398ee70e57beMD5411323/9254oai:repositorio.cuc.edu.co:11323/92542024-09-17 10:58:45.838https://creativecommons.org/licenses/by-nc-nd/4.0/Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa 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