Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption

In the present work, multi-walled carbon nanotubes (MWCNTs) were used as support material for the impregnation of metallic nanoparticles (MNPs) produced by green synthesis. The influences of the plant extracts (pomegranate (Punica Granatum), Eucalyptus, and pecan (Carya illinoinensis, leaves), metal...

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Autores:
Diel, Júlia C.
P. Franco, Dison S.
Igansi, Andrei V.
S. Cadaval Jr., Tito R.
Pereira, Hércules A.
S. Nunes, Isaac dos
Basso, Charles W.
M. Alves, Maria do Carmo
Morais, Jonder
Pinto, Diana
Dotto, Guilherme L.
Tipo de recurso:
Article of journal
Fecha de publicación:
2021
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/8491
Acceso en línea:
https://hdl.handle.net/11323/8491
https://doi.org/10.1016/j.chemosphere.2021.131193
https://repositorio.cuc.edu.co/
Palabra clave:
Glyphosate
Adsorption
Carbon nanotubes
Nanoparticles
Green synthesis
XPS analyses
Rights
openAccess
License
Attribution-NonCommercial-NoDerivatives 4.0 International
id RCUC2_5a9b2fc3ceb7bbc8edcc17ef9e244ca0
oai_identifier_str oai:repositorio.cuc.edu.co:11323/8491
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.spa.fl_str_mv Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
title Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
spellingShingle Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
Glyphosate
Adsorption
Carbon nanotubes
Nanoparticles
Green synthesis
XPS analyses
title_short Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
title_full Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
title_fullStr Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
title_full_unstemmed Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
title_sort Green synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorption
dc.creator.fl_str_mv Diel, Júlia C.
P. Franco, Dison S.
Igansi, Andrei V.
S. Cadaval Jr., Tito R.
Pereira, Hércules A.
S. Nunes, Isaac dos
Basso, Charles W.
M. Alves, Maria do Carmo
Morais, Jonder
Pinto, Diana
Dotto, Guilherme L.
dc.contributor.author.spa.fl_str_mv Diel, Júlia C.
P. Franco, Dison S.
Igansi, Andrei V.
S. Cadaval Jr., Tito R.
Pereira, Hércules A.
S. Nunes, Isaac dos
Basso, Charles W.
M. Alves, Maria do Carmo
Morais, Jonder
Pinto, Diana
Dotto, Guilherme L.
dc.subject.spa.fl_str_mv Glyphosate
Adsorption
Carbon nanotubes
Nanoparticles
Green synthesis
XPS analyses
topic Glyphosate
Adsorption
Carbon nanotubes
Nanoparticles
Green synthesis
XPS analyses
description In the present work, multi-walled carbon nanotubes (MWCNTs) were used as support material for the impregnation of metallic nanoparticles (MNPs) produced by green synthesis. The influences of the plant extracts (pomegranate (Punica Granatum), Eucalyptus, and pecan (Carya illinoinensis, leaves), metal species (copper and iron), metallic concentrations, and type of functionalization (OH and COOH) on the characteristics of the obtained materials were studied. The precursor and impregnated MWCNTs were characterized through X-ray diffraction, Fourier transformed infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, point of charge, N2 adsorption/desorption isotherms and, X-ray photoelectron spectroscopy. All the synthesized materials were tested as adsorbents to remove glyphosate (GLY) in an aqueous medium. The MWCNTs were resistant to withstand the synthesis process, preserving its structure and morphological characteristics. The copper and iron on the surface of MWCNTS confirm the successful synthesis and impregnation of the MNPs. The MWCNTs impregnated with high metallic concentrations showed favorable adsorption of GLY. The adsorption capacity and percentage of removal were 21.17 mg g−1 and 84.08%, respectively, for the MWCNTs impregnated with iron MNPs using the pecan leaves as a reducing agent. The results indicated that an advanced adsorbent for GLY could be obtained by green synthesis, using MWCNTs as precursors and pecan leaves as a reducing agent.
publishDate 2021
dc.date.accessioned.none.fl_str_mv 2021-07-27T13:39:54Z
dc.date.available.none.fl_str_mv 2021-07-27T13:39:54Z
dc.date.issued.none.fl_str_mv 2021
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
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dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
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dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/8491
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.1016/j.chemosphere.2021.131193
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
url https://hdl.handle.net/11323/8491
https://doi.org/10.1016/j.chemosphere.2021.131193
https://repositorio.cuc.edu.co/
identifier_str_mv Corporación Universidad de la Costa
REDICUC - Repositorio CUC
dc.language.iso.none.fl_str_mv eng
language eng
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spelling Diel, Júlia C.P. Franco, Dison S.Igansi, Andrei V.S. Cadaval Jr., Tito R.Pereira, Hércules A.S. Nunes, Isaac dosBasso, Charles W.M. Alves, Maria do CarmoMorais, JonderPinto, DianaDotto, Guilherme L.2021-07-27T13:39:54Z2021-07-27T13:39:54Z2021https://hdl.handle.net/11323/8491https://doi.org/10.1016/j.chemosphere.2021.131193Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/In the present work, multi-walled carbon nanotubes (MWCNTs) were used as support material for the impregnation of metallic nanoparticles (MNPs) produced by green synthesis. The influences of the plant extracts (pomegranate (Punica Granatum), Eucalyptus, and pecan (Carya illinoinensis, leaves), metal species (copper and iron), metallic concentrations, and type of functionalization (OH and COOH) on the characteristics of the obtained materials were studied. The precursor and impregnated MWCNTs were characterized through X-ray diffraction, Fourier transformed infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, point of charge, N2 adsorption/desorption isotherms and, X-ray photoelectron spectroscopy. All the synthesized materials were tested as adsorbents to remove glyphosate (GLY) in an aqueous medium. The MWCNTs were resistant to withstand the synthesis process, preserving its structure and morphological characteristics. The copper and iron on the surface of MWCNTS confirm the successful synthesis and impregnation of the MNPs. The MWCNTs impregnated with high metallic concentrations showed favorable adsorption of GLY. The adsorption capacity and percentage of removal were 21.17 mg g−1 and 84.08%, respectively, for the MWCNTs impregnated with iron MNPs using the pecan leaves as a reducing agent. The results indicated that an advanced adsorbent for GLY could be obtained by green synthesis, using MWCNTs as precursors and pecan leaves as a reducing agent.Diel, Júlia C.P. Franco, Dison S.Igansi, Andrei V.S. Cadaval Jr., Tito R.Pereira, Hércules A.S. Nunes, Isaac dosBasso, Charles W.M. Alves, Maria do CarmoMorais, JonderPinto, DianaDotto, Guilherme L.application/pdfengAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Chemospherehttps://www.sciencedirect.com/science/article/abs/pii/S0045653521016659GlyphosateAdsorptionCarbon nanotubesNanoparticlesGreen synthesisXPS analysesGreen synthesis of carbon nanotubes impregnated with metallic nanoparticles: Characterization and application in glyphosate adsorptionArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionM. Abu-dalo, A. Jaradat, B.A. Albiss, N.A.F. Al-rawashdeh Green synthesis of TiO2 NPs/pristine pomegranate peel extract nanocomposite and its antimicrobial activity for water disinfection J. Environ. Chem. 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Jiang Fluid Phase Equilibria Study on behavior of alkalescent fiber FFA-1 adsorbing glyphosate from production wastewater of glyphosate Fluid Phase Equil., 362 (2014), pp. 69-73, 10.1016/j.fluid.2013.09.00PublicationORIGINALGreen synthesis of carbon nanotubes impregnated with metallic nanoparticles.pdfGreen synthesis of carbon nanotubes impregnated with metallic nanoparticles.pdfapplication/pdf110555https://repositorio.cuc.edu.co/bitstreams/b2c62b00-7de4-4e33-bb6b-07770e2fb380/downloadd3fcb5f3764b1e372a3704c08bb6c661MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805https://repositorio.cuc.edu.co/bitstreams/77dacc7b-bfb6-4774-9558-7a967cc843d5/download4460e5956bc1d1639be9ae6146a50347MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/2430be6a-8c98-4664-a3be-4bef83e48453/downloade30e9215131d99561d40d6b0abbe9badMD53THUMBNAILGreen synthesis of carbon nanotubes impregnated with metallic nanoparticles.pdf.jpgGreen 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