Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water
The valorization of agro-industrial residues can be improved through their full use, making the production of second-generation ethanol viable. In this scenario, hydrolyzed soybean straw generated from a subcritical water process was applied to the basic fuchsin adsorption. At pH eight, a high adsor...
- Autores:
-
Caponi, Natiela
Silva Oliveira, Luis Felipe
Silva Oliveira, Marcos Leandro
Dison S.P., Franco
Netto, Matias S.
Vedovatto, Felipe
Tres, Marcus V.
Zabot, Giovani L.
Abaide, Ederson R.
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/13297
- Acceso en línea:
- https://hdl.handle.net/11323/13297
https://repositorio.cuc.edu.co/
- Palabra clave:
- Soybean residue
Hydrolyzed solids
Dye
Adsorption
Pollutant
- Rights
- embargoedAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
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Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water |
| title |
Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water |
| spellingShingle |
Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water Soybean residue Hydrolyzed solids Dye Adsorption Pollutant |
| title_short |
Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water |
| title_full |
Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water |
| title_fullStr |
Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water |
| title_full_unstemmed |
Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water |
| title_sort |
Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water |
| dc.creator.fl_str_mv |
Caponi, Natiela Silva Oliveira, Luis Felipe Silva Oliveira, Marcos Leandro Dison S.P., Franco Netto, Matias S. Vedovatto, Felipe Tres, Marcus V. Zabot, Giovani L. Abaide, Ederson R. Dotto, Guilherme Luiz |
| dc.contributor.author.none.fl_str_mv |
Caponi, Natiela Silva Oliveira, Luis Felipe Silva Oliveira, Marcos Leandro Dison S.P., Franco Netto, Matias S. Vedovatto, Felipe Tres, Marcus V. Zabot, Giovani L. Abaide, Ederson R. Dotto, Guilherme Luiz |
| dc.subject.proposal.eng.fl_str_mv |
Soybean residue Hydrolyzed solids Dye Adsorption Pollutant |
| topic |
Soybean residue Hydrolyzed solids Dye Adsorption Pollutant |
| description |
The valorization of agro-industrial residues can be improved through their full use, making the production of second-generation ethanol viable. In this scenario, hydrolyzed soybean straw generated from a subcritical water process was applied to the basic fuchsin adsorption. At pH eight, a high adsorption capacity was obtained. The mass test results showed that basic fuchsin’s removal and adsorption capacity could be maximized with an adsorbent dosage of 0.9 g L−1. The linear driving force model was suitable for predicting the kinetic profile, and the kinetic curves showed that equilibrium was reached with only 30 min of contact time. Besides, the Langmuir model was the best to predict the adsorption isotherms. The thermodynamic parameters revealed a spontaneous and endothermic process. At 328 K, there is maximum adsorption capacity (72.9 mg g−1). Therefore, it can be stated that this material could be competitive in terms of adsorption capacity coupled with the idea of full use of waste. |
| publishDate |
2022 |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.date.available.none.fl_str_mv |
2023 2024-09-05T23:49:36Z |
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2024-09-05T23:49:36Z |
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Artículo de revista |
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Caponi, N., Silva, L.F.O., Oliveira, M.L.S. et al. Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water. Environ Sci Pollut Res 29, 68547–68554 (2022). https://doi.org/10.1007/s11356-022-20652-w |
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0944-1344 |
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https://hdl.handle.net/11323/13297 |
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10.1007/s11356-022-20652-w |
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1614-7499 |
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Corporación Universidad de la Costa |
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REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Caponi, N., Silva, L.F.O., Oliveira, M.L.S. et al. Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water. Environ Sci Pollut Res 29, 68547–68554 (2022). https://doi.org/10.1007/s11356-022-20652-w 0944-1344 10.1007/s11356-022-20652-w 1614-7499 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/13297 https://repositorio.cuc.edu.co/ |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Environmental Science and Pollution Research |
| dc.relation.references.spa.fl_str_mv |
Abaide ER, Dotto GL, Tres MV et al (2019a) Adsorption of 2-nitrophenol using rice straw and rice husks hydrolyzed by subcritical water. Bioresour Technol 284:25–35. https://doi.org/10.1016/j.biortech.2019.03.110 Abaide ER, Mortari SR, Ugalde G et al (2019b) Subcritical water hydrolysis of rice straw in a semi-continuous mode. J Clean Prod 209:386–397. https://doi.org/10.1016/j.jclepro.2018.10.259 Abaide ER, Tres MV, Zabot GL et al (2019c) Reasons for processing of rice coproducts: reality and expectations. Biom Bioenerg 120:240–256. https://doi.org/10.1016/j.biombioe.2018.11.032 Abaide ER, Ugalde G, Di Luccio M et al (2019d) Obtaining fermentable sugars and bioproducts from rice husks by subcritical water hydrolysis in a semi-continuous mode. Bioresour Technol 272:510–520. https://doi.org/10.1016/j.biortech.2018.10.075 Belmabrouk H, Selmi M, Alshahrani T et al (2022) Experimental and theoretical study of methylene blue biosorption using a new biomaterial Pergularia tomentosa L. fruit. Int J Environ Sci Techno. https://doi.org/10.1007/s13762-022-03979-2 Côrtes LN, Druzian SP, Streit AFM et al (2019) Preparation of carbonaceous materials from pyrolysis of chicken bones and its application for fuchsine adsorption. Environ Sci Pollut Res 26:28574–28583. https://doi.org/10.1007/s11356-018-3679-2 De Corato U, De Bari I, Viola E et al (2018) Assessing the main opportunities of integrated biorefining from agro-bioenergy co/by-products and agroindustrial residues into high-value added products associated to some emerging markets: a review. Renew Sustain Energ Rev 88:326–346. https://doi.org/10.1016/j.rser.2018.02.041 El Haddad M (2016) Removal of Basic Fuchsin dye from water using mussel shell biomass waste as an adsorbent: equilibrium, kinetics, and thermodynamics. J Taibah Univ Sci 10:664–674. https://doi.org/10.1016/j.jtusci.2015.08.007 Dotto GL, McKay G (2020) Current scenario and challenges in adsorption for water treatment. J Environ Chem Eng 8:103988. https://doi.org/10.1016/j.jece.2020.103988 Dotto GL, Vieira MLG, Gonçalves JO et al (2011) Removal of acid blue 9, food yellow 3 and FD&C yellow n° 5 dyes from aqueous solutions using activated carbon, activated earth, diatomaceous earth, chitin and chitosan: equilibrium studies and thermodynamic. Quim Nova 34:1193–1199. https://doi.org/10.1590/s0100-40422011000700017 FAO, 2018. Production of crops. FAO-Food Agric. Organ, United Nations [WWW Document]. URL http://www.fao.org/faostat/en/#data/QC Freitas JV, Nogueira FGE, Farinas CS (2019) Coconut shell activated carbon as an alternative adsorbent of inhibitors from lignocellulosic biomass pretreatment. Ind Crop Prod 137:16–23. https://doi.org/10.1016/j.indcrop.2019.05.018 Freundlich H (1906) Over the adsorption in solution. J Phys Chem 57:385–471 Fröhlich AC, dos Reis GS, Pavan PA et al (2018) Improvement of activated carbon characteristics by sonication and its application for pharmaceutical contaminant adsorption. Environ Sci Pollut Res 25:24713–24725. https://doi.org/10.1007/s11356-018-2525-x Georgin J, Franco DSP, Schadeck Netto M et al (2021) Transforming shrub waste into a high-efficiency adsorbent: application of Physalis peruvian chalice treated with strong acid to remove the 2,4-dichlorophenoxyacetic acid herbicide. J Environ Chem Eng 9:104574. https://doi.org/10.1016/j.jece.2020.104574 Ibrahim AG, Sayed AZ, Abd El-Wahab H et al (2020) Synthesis of a hydrogel by grafting of acrylamide-co-sodium methacrylate onto chitosan for effective adsorption of Fuchsin basic dye. Int J Biol Macromol 159:422–432. https://doi.org/10.1016/j.ijbiomac.2020.05.039 Inseemeesak B, Areeprasert C (2020) Fiber extraction and energy recovery from Cocos nucifera Linn mesocarp residues employing steam explosion and anaerobic digestion. Ind Crop Prod 147:112180. https://doi.org/10.1016/j.indcrop.2020.112180 Jain R, Mendiratta S, Kumar L, Srivastava A (2021) Green synthesis of iron nanoparticles using Artocarpus heterophyllus peel extract and their application as a heterogeneous Fenton-like catalyst for the degradation of Fuchsin Basic dye. Curr Res Green Sustain Chem 4https://doi.org/10.1016/j.crgsc.2021.100086 Khan TA, Khan EA, Shahjahan (2015) Removal of basic dyes from aqueous solution by adsorption onto binary iron-manganese oxide coated kaolinite: non-linear isotherm and kinetics modeling. Appl Clay Sci 107:70–77. https://doi.org/10.1016/j.clay.2015.01.005 Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403 Lima EC, Hosseini-Bandegharaei A, Moreno-Piraján JC, Anastopoulos I (2019) A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van’t Hoof equation for calculation of thermodynamic parameters of adsorption. J Mol Liq 273:425–434. https://doi.org/10.1016/j.molliq.2018.10.048 Li C, Chen D, Ding J et al (2020a) A novel hetero-exopolysaccharide for the adsorption of methylene blue from aqueous solutions: isotherm, kinetic, and mechanism studies. J Clean Prod 265:121800. https://doi.org/10.1016/j.jclepro.2020.121800 Li J, Lu M, Guo X et al (2018) Insights into the improvement of alkaline hydrogen peroxide (AHP) pretreatment on the enzymatic hydrolysis of corn stover: chemical and microstructural analyses. Bioresour Technol 265:1–7. https://doi.org/10.1016/j.biortech.2018.05.082 Li Z, Sellaoui L, Franco DSP et al (2020b) Adsorption of hazardous dyes on functionalized multiwalled carbon nanotubes in single and binary systems: experimental study and physicochemical interpretation of the adsorption mechanism. Chem Eng J 389:124467. https://doi.org/10.1016/j.cej.2020.124467 Marques FP, Silva LMA, Lomonaco D et al (2020) Steam explosion pretreatment to obtain eco-friendly building blocks from oil palm mesocarp fiber. Ind Crop Prod 143:111907. https://doi.org/10.1016/j.indcrop.2019.111907 Miao Q, Tang Y, Xu J et al (2013) Activated carbon prepared from soybean straw for phenol adsorption. J Taiwan Inst Chem Eng 44:458–465. https://doi.org/10.1016/j.jtice.2012.12.006 Möller M, Harnisch F, Schröder U (2013) Hydrothermal liquefaction of cellulose in subcritical water-the role of crystallinity on the cellulose reactivity. RSC Adv 3:11035–11044. https://doi.org/10.1039/c3ra41582a Nguyen C, Do DD (2001) The Dubinin-Radushkevich equation and the underlying microscopic adsorption description. Carbon 39:1327–1336. https://doi.org/10.1016/S0008-6223(00)00265-7 Pang X, Sellaoui L, Franco D et al (2019) Adsorption of crystal violet on biomasses from pecan nutshell, para chestnut husk, araucaria bark and palm cactus: experimental study and theoretical modeling via monolayer and double layer statistical physics models. Chem Eng J 378:122101. https://doi.org/10.1016/j.cej.2019.122101 Pang X, Sellaoui L, Franco D, et al (2020) Preparation and characterization of a novel mountain soursop seeds powder adsorbent and its application for the removal of crystal violet and methylene blue from aqueous solutions. Chem Eng J 391 https://doi.org/10.1016/j.cej.2019.123617 Pinheiro Nascimento PF, Barros Neto EL (2021) Steam explosion: hydrothermal pretreatment in the production of an adsorbent material using coconut husk. Bioenerg Res 14:153–162. https://doi.org/10.1007/s12155-020-10159-y Prado JM, Lachos-Perez D, Forster-Carneiro T et al (2016) Sub- and supercritical water hydrolysis of agricultural and food industry residues for the production of fermentable sugars: a review. Food Bioprod Process 98:95–123. https://doi.org/10.1016/j.fbp.2015.11.004 Qu J, Meng X, Jiang X et al (2018) Enhanced removal of Cd(II) from water using sulfur-functionalized rice husk: characterization, adsorptive performance and mechanism exploration. J Clean Prod 183:880–886. https://doi.org/10.1016/j.jclepro.2018.02.208 Shen Z, Zhang K, Si M et al (2018) Synergy of lignocelluloses pretreatment by sodium carbonate and bacterium to enhance enzymatic hydrolysis of rice straw. Bioresour Technol 249:154–160. https://doi.org/10.1016/j.biortech.2017.10.008 Tóth J (2002) Adsorption: theory, modeling and analysis. New York: Marcel Dekker. Surfactant Sci Ser volume 107 Vedovatto F, Bonatto C, Bazoti SF et al. (2021a) production of biofuels from soybean straw and hull hydrolysates obtained by subcritical water hydrolysis. Bioresour Technol 328 https://doi.org/10.1016/j.biortech.2021.124837 Vedovatto F, Ugalde G, Bonatto C et al (2021b) Subcritical water hydrolysis of soybean residues for obtaining fermentable sugars. J Supercrit Fluids 167:105043. https://doi.org/10.1016/j.supflu.2020.105043 Xu F, Yu J, Tesso T et al (2013) Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: a mini-review. Appl Energ 104:801–809. https://doi.org/10.1016/j.apenergy.2012.12.019 Xue H, Wang X, Xu Q, et al (2022) Adsorption of methylene blue from aqueous solution on activated carbons and composite prepared from an agricultural waste biomass: a comparative study by experimental and advanced modeling analysis. Chem Eng J 430 https://doi.org/10.1016/j.cej.2021.132801 Yadav M, Gupta R, Sharma RK (2018) Chapter 14 — green and sustainable pathways for wastewater purification. In: Advances in Water Purification Techniques: Meeting the Needs of Developed and Developing Countries. Elsevier, pp 355–383 Yamil YL, Georgin J, dos Reis GS et al (2020) Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin. Environ Sci Pollut Res 27:33307–33320. https://doi.org/10.1007/s11356-020-09471-z You X, Wang R, Zhu Y et al (2021) Comparison of adsorption properties of a cellulose-rich modified rice husk for the removal of methylene blue and aluminum (III) from their aqueous solution. Ind Crop Prod 170:113687. https://doi.org/10.1016/j.indcrop.2021.113687 |
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Atribución 4.0 Internacional (CC BY 4.0)© 2024 Springer Naturehttps://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfCaponi, NatielaSilva Oliveira, Luis FelipeSilva Oliveira, Marcos LeandroDison S.P., FrancoNetto, Matias S.Vedovatto, FelipeTres, Marcus V.Zabot, Giovani L.Abaide, Ederson R.Dotto, Guilherme Luiz2024-09-05T23:49:36Z20232024-09-05T23:49:36Z2022Caponi, N., Silva, L.F.O., Oliveira, M.L.S. et al. Adsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water. Environ Sci Pollut Res 29, 68547–68554 (2022). https://doi.org/10.1007/s11356-022-20652-w0944-1344https://hdl.handle.net/11323/1329710.1007/s11356-022-20652-w1614-7499Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The valorization of agro-industrial residues can be improved through their full use, making the production of second-generation ethanol viable. In this scenario, hydrolyzed soybean straw generated from a subcritical water process was applied to the basic fuchsin adsorption. At pH eight, a high adsorption capacity was obtained. The mass test results showed that basic fuchsin’s removal and adsorption capacity could be maximized with an adsorbent dosage of 0.9 g L−1. The linear driving force model was suitable for predicting the kinetic profile, and the kinetic curves showed that equilibrium was reached with only 30 min of contact time. Besides, the Langmuir model was the best to predict the adsorption isotherms. The thermodynamic parameters revealed a spontaneous and endothermic process. At 328 K, there is maximum adsorption capacity (72.9 mg g−1). Therefore, it can be stated that this material could be competitive in terms of adsorption capacity coupled with the idea of full use of waste.5 páginasapplication/pdfengSpringerGermanyhttps://link.springer.com/article/10.1007/s11356-022-20652-wAdsorption of basic fuchsin using soybean straw hydrolyzed by subcritical waterArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/drafthttp://purl.org/coar/version/c_b1a7d7d4d402bcceEnvironmental Science and Pollution ResearchAbaide ER, Dotto GL, Tres MV et al (2019a) Adsorption of 2-nitrophenol using rice straw and rice husks hydrolyzed by subcritical water. Bioresour Technol 284:25–35. https://doi.org/10.1016/j.biortech.2019.03.110Abaide ER, Mortari SR, Ugalde G et al (2019b) Subcritical water hydrolysis of rice straw in a semi-continuous mode. J Clean Prod 209:386–397. https://doi.org/10.1016/j.jclepro.2018.10.259Abaide ER, Tres MV, Zabot GL et al (2019c) Reasons for processing of rice coproducts: reality and expectations. Biom Bioenerg 120:240–256. https://doi.org/10.1016/j.biombioe.2018.11.032Abaide ER, Ugalde G, Di Luccio M et al (2019d) Obtaining fermentable sugars and bioproducts from rice husks by subcritical water hydrolysis in a semi-continuous mode. Bioresour Technol 272:510–520. https://doi.org/10.1016/j.biortech.2018.10.075Belmabrouk H, Selmi M, Alshahrani T et al (2022) Experimental and theoretical study of methylene blue biosorption using a new biomaterial Pergularia tomentosa L. fruit. Int J Environ Sci Techno. https://doi.org/10.1007/s13762-022-03979-2Côrtes LN, Druzian SP, Streit AFM et al (2019) Preparation of carbonaceous materials from pyrolysis of chicken bones and its application for fuchsine adsorption. Environ Sci Pollut Res 26:28574–28583. https://doi.org/10.1007/s11356-018-3679-2De Corato U, De Bari I, Viola E et al (2018) Assessing the main opportunities of integrated biorefining from agro-bioenergy co/by-products and agroindustrial residues into high-value added products associated to some emerging markets: a review. Renew Sustain Energ Rev 88:326–346. https://doi.org/10.1016/j.rser.2018.02.041El Haddad M (2016) Removal of Basic Fuchsin dye from water using mussel shell biomass waste as an adsorbent: equilibrium, kinetics, and thermodynamics. J Taibah Univ Sci 10:664–674. https://doi.org/10.1016/j.jtusci.2015.08.007Dotto GL, McKay G (2020) Current scenario and challenges in adsorption for water treatment. J Environ Chem Eng 8:103988. https://doi.org/10.1016/j.jece.2020.103988Dotto GL, Vieira MLG, Gonçalves JO et al (2011) Removal of acid blue 9, food yellow 3 and FD&C yellow n° 5 dyes from aqueous solutions using activated carbon, activated earth, diatomaceous earth, chitin and chitosan: equilibrium studies and thermodynamic. Quim Nova 34:1193–1199. https://doi.org/10.1590/s0100-40422011000700017FAO, 2018. Production of crops. FAO-Food Agric. Organ, United Nations [WWW Document]. URL http://www.fao.org/faostat/en/#data/QCFreitas JV, Nogueira FGE, Farinas CS (2019) Coconut shell activated carbon as an alternative adsorbent of inhibitors from lignocellulosic biomass pretreatment. Ind Crop Prod 137:16–23. https://doi.org/10.1016/j.indcrop.2019.05.018Freundlich H (1906) Over the adsorption in solution. J Phys Chem 57:385–471Fröhlich AC, dos Reis GS, Pavan PA et al (2018) Improvement of activated carbon characteristics by sonication and its application for pharmaceutical contaminant adsorption. Environ Sci Pollut Res 25:24713–24725. https://doi.org/10.1007/s11356-018-2525-xGeorgin J, Franco DSP, Schadeck Netto M et al (2021) Transforming shrub waste into a high-efficiency adsorbent: application of Physalis peruvian chalice treated with strong acid to remove the 2,4-dichlorophenoxyacetic acid herbicide. J Environ Chem Eng 9:104574. https://doi.org/10.1016/j.jece.2020.104574Ibrahim AG, Sayed AZ, Abd El-Wahab H et al (2020) Synthesis of a hydrogel by grafting of acrylamide-co-sodium methacrylate onto chitosan for effective adsorption of Fuchsin basic dye. Int J Biol Macromol 159:422–432. https://doi.org/10.1016/j.ijbiomac.2020.05.039Inseemeesak B, Areeprasert C (2020) Fiber extraction and energy recovery from Cocos nucifera Linn mesocarp residues employing steam explosion and anaerobic digestion. Ind Crop Prod 147:112180. https://doi.org/10.1016/j.indcrop.2020.112180Jain R, Mendiratta S, Kumar L, Srivastava A (2021) Green synthesis of iron nanoparticles using Artocarpus heterophyllus peel extract and their application as a heterogeneous Fenton-like catalyst for the degradation of Fuchsin Basic dye. Curr Res Green Sustain Chem 4https://doi.org/10.1016/j.crgsc.2021.100086Khan TA, Khan EA, Shahjahan (2015) Removal of basic dyes from aqueous solution by adsorption onto binary iron-manganese oxide coated kaolinite: non-linear isotherm and kinetics modeling. Appl Clay Sci 107:70–77. https://doi.org/10.1016/j.clay.2015.01.005Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. 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Ind Crop Prod 170:113687. https://doi.org/10.1016/j.indcrop.2021.11368768554685474529Soybean residueHydrolyzed solidsDyeAdsorptionPollutantPublicationORIGINALAdsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water.pdfAdsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water.pdfArtículoapplication/pdf185077https://repositorio.cuc.edu.co/bitstreams/8b8513ab-62fa-4894-87b6-715bfe353b0e/download24406eb8baf0865b9db507c202ca9f90MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstreams/587c452c-2f55-413b-aa1d-5e3c9580c46a/download2f9959eaf5b71fae44bbf9ec84150c7aMD52TEXTAdsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water.pdf.txtAdsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water.pdf.txtExtracted texttext/plain11467https://repositorio.cuc.edu.co/bitstreams/0b965d38-847c-4570-8d12-fe54175f10ad/downloadc4cb61f9a8b59a6541100ebbae313e81MD53THUMBNAILAdsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water.pdf.jpgAdsorption of basic fuchsin using soybean straw hydrolyzed by subcritical water.pdf.jpgGenerated Thumbnailimage/jpeg14252https://repositorio.cuc.edu.co/bitstreams/16bb545c-5638-4789-99f3-26c98a32a81f/download734027fd5e4266a7958ec3bd5516e2b9MD5411323/13297oai:repositorio.cuc.edu.co:11323/132972024-09-17 14:14:02.294https://creativecommons.org/licenses/by/4.0/© 2024 Springer Natureopen.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa 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ada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
 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