Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru
Dissociative adsorption of H2 was carried out on the @13 cluster (@ = Ag, Co, Cu and Ru) according to the number of nH2 molecules (n = 1–10) and it was compared with H2 adsorption on the surface (1 1 1) of the same metals using Density Functional Theory. The adsorption of H2 is energetically more fa...
- Autores:
-
Amaya Roncancio, S.
Toncón Leal, C.F.
Arellano Ramírez, I.D.
Torres Cerón, Darwin Augusto
Restrepo Parra, E.
Sapag, K.
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/13638
- Acceso en línea:
- https://hdl.handle.net/11323/13638
https://repositorio.cuc.edu.co/
- Palabra clave:
- Density functional theory
Hydrogen dissociative adsorption
Cluster
Metal surface
Chemisorption
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
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| dc.title.eng.fl_str_mv |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru |
| title |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru |
| spellingShingle |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru Density functional theory Hydrogen dissociative adsorption Cluster Metal surface Chemisorption |
| title_short |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru |
| title_full |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru |
| title_fullStr |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru |
| title_full_unstemmed |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru |
| title_sort |
Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru |
| dc.creator.fl_str_mv |
Amaya Roncancio, S. Toncón Leal, C.F. Arellano Ramírez, I.D. Torres Cerón, Darwin Augusto Restrepo Parra, E. Sapag, K. |
| dc.contributor.author.none.fl_str_mv |
Amaya Roncancio, S. Toncón Leal, C.F. Arellano Ramírez, I.D. Torres Cerón, Darwin Augusto Restrepo Parra, E. Sapag, K. |
| dc.subject.proposal.eng.fl_str_mv |
Density functional theory Hydrogen dissociative adsorption Cluster Metal surface Chemisorption |
| topic |
Density functional theory Hydrogen dissociative adsorption Cluster Metal surface Chemisorption |
| description |
Dissociative adsorption of H2 was carried out on the @13 cluster (@ = Ag, Co, Cu and Ru) according to the number of nH2 molecules (n = 1–10) and it was compared with H2 adsorption on the surface (1 1 1) of the same metals using Density Functional Theory. The adsorption of H2 is energetically more favorable on the @13 clusters than on the surfaces for all metals studied. Charge population analysis and density of states were calculated to understand the electronic behavior of hydrogen on the @13 cluster and on the (1 1 1) surface. In all the cases studied, hydrogen takes more charge from the @13 metal cluster than on (1 1 1) surfaces. The ab-initio thermodynamics shows the favorable ranges of pressure, energy, and chemical potential for dissociative adsorption of H2 for all the coverages studied on the metal clusters. Additionally, XPS and chemisorption results for supported nanoparticles and bulk material are presented for cobalt. |
| publishDate |
2022 |
| dc.date.issued.none.fl_str_mv |
2022-04-18 |
| dc.date.accessioned.none.fl_str_mv |
2024-11-05T12:51:07Z |
| dc.date.available.none.fl_str_mv |
2024-11-05T12:51:07Z |
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Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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S. Amaya-Roncancio, C.F. Toncón-Leal, I.D. Arellano-Ramírez, Darwin Augusto Torres-Cerón, E. Restrepo-Parra, K. Sapag, Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru, Chemical Physics, Volume 559, 2022, 111546, ISSN 0301-0104, https://doi.org/10.1016/j.chemphys.2022.111546. |
| dc.identifier.issn.none.fl_str_mv |
0301-0104 |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/11323/13638 |
| dc.identifier.doi.none.fl_str_mv |
10.1016/j.chemphys.2022.111546 |
| dc.identifier.eissn.none.fl_str_mv |
1873-4421 |
| dc.identifier.instname.none.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.none.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.none.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
S. Amaya-Roncancio, C.F. Toncón-Leal, I.D. Arellano-Ramírez, Darwin Augusto Torres-Cerón, E. Restrepo-Parra, K. Sapag, Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru, Chemical Physics, Volume 559, 2022, 111546, ISSN 0301-0104, https://doi.org/10.1016/j.chemphys.2022.111546. 0301-0104 10.1016/j.chemphys.2022.111546 1873-4421 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/13638 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.none.fl_str_mv |
Chemical Physics |
| dc.relation.references.none.fl_str_mv |
I. Swart, F.M.F. de Groot, B.M. Weckhuysen, P. Gruene, G. Meijer, A. Fielicke, H2 Adsorption on 3d Transition Metal Clusters: A Combined Infrared Spectroscopy and Density Functional Study, J. Phys. Chem. A. 112 (2008) 1139–1149, https://doi. org/10.1021/jp076702t. V. Jain, B. Kandasubramanian, Functionalized graphene materials for hydrogen storage, J. Mater. Sci. 55 (2020) 1865–1903, https://doi.org/10.1007/s10853- 019-04150-y. C. Wang, J. Tuninetti, Z. Wang, C. Zhang, R. Ciganda, L. Salmon, S. Moya, J. Ruiz, D. Astruc, Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release, J. Am. Chem. Soc. 139 (2017) 11610–11615, https://doi.org/10.1021/jacs.7b06859. G. Chen, R. Wang, W. Zhao, B. Kang, D. Gao, C. Li, J.Y. Lee, Effect of Ru crystal phase on the catalytic activity of hydrolytic dehydrogenation of ammonia borane, J. Power Sources 396 (2018) 148–154, https://doi.org/10.1016/j. jpowsour.2018.06.028. A. Montoya, A. Schlunke, B.S. Haynes, Reaction of Hydrogen with Ag(111): Binding States, Minimum Energy Paths, and Kinetics, J. Phys. Chem. B 110 (2006) 17145–17154, https://doi.org/10.1021/jp062725g. A. Schneemann, J.L. White, S. Kang, S. Jeong, L.F. Wan, E.S. Cho, T.W. Heo, D. Prendergast, J.J. Urban, B.C. Wood, M.D. Allendorf, V. Stavila, Nanostructured Metal Hydrides for Hydrogen Storage, Chem. Rev. 118 (2018) 10775–10839, https://doi.org/10.1021/acs.chemrev.8b00313. K. García-Díez, J. Fern´ andez-Fern´ andez, J.A. Alonso, M.J. Lopez, ´ Theoretical study of the adsorption of hydrogen on cobalt clusters, PCCP 20 (2018) 21163–21176, https://doi.org/10.1039/C8CP03048K. H. Akbarzadeh, A.N. Shamkhali, H2 adsorption on Ag-nanocluster/single-walled carbon nanotube composites: A molecular dynamics study on the effects of nanocluster size, diameter, and chirality of nanotube, J. Comput. Chem. 36 (2015) 433–440, https://doi.org/10.1002/jcc.23817. M. Yu, L. Liu, Q. Wang, L. Jia, B. Hou, Y. Si, D. Li, Y. Zhao, High coverage H2 adsorption and dissociation on fcc Co surfaces from DFT and thermodynamics, International Journal of Hydrogen Energy. 43 (2018) 5576–5590. https://doi.org/ https://doi.org/10.1016/j.ijhydene.2018.01.165. A. Nakhaei Pour, Z. Keyvanloo, M. Izadyar, S.M. Modaresi, Dissociative hydrogen adsorption on the cubic cobalt surfaces: A DFT study, Int. J. Hydrogen Energy 40 (2015) 7064–7071, https://doi.org/10.1016/j.ijhydene.2015.04.028. K. Mudiyanselage, Y. Yang, F.M. Hoffmann, O.J. Furlong, J. Hrbek, M.G. White, P. Liu, D.J. Stacchiola, Adsorption of hydrogen on the surface and sub-surface of Cu (111), The Journal of Chemical Physics. 139 (2013) 044712. https://doi.org/ 10.1063/1.4816515. K. Cao, G. Füchsel, A.W. Kleyn, L.B.F. Juurlink, Hydrogen adsorption and desorption from Cu(111) and Cu(211), PCCP 20 (2018) 22477–22488, https://doi. org/10.1039/C8CP03386B. P. Zhao, Y. He, D.B. Cao, X. Wen, H. Xiang, Y.W. Li, J. Wang, H. Jiao, High coverage adsorption and co-adsorption of CO and H<inf>2</inf> on Ru(0001) from DFT and thermodynamics, PCCP 17 (2015) 19446–19456, https://doi.org/ 10.1039/c5cp02486b. I. Yarovsky, A. Goldberg, DFT study of hydrogen adsorption on Al 13 clusters, Mol. Simul. 31 (2005) 475–481, https://doi.org/10.1080/08927020412331337041. S. Amaya-Roncancio, A.A. García Blanco, D.H. Linares, K. Sapag, DFT study of hydrogen adsorption on Ni/graphene, Appl. Surf. Sci. 447 (2018) 254–260, https://doi.org/10.1016/j.apsusc.2018.03.233. P. Felício-Sousa, K.F. Andriani, J.L.F. Da Silva, Ab initioinvestigation of the role of the d-states occupation on the adsorption properties of H2, CO, CH4and CH3OH on the Fe13, Co13, Ni13and Cu13clusters, PCCP 23 (2021) 8739–8751, https://doi. org/10.1039/d0cp06091g. S. Amaya-Roncancio, L. Reinaudi, M. Cecilia, Gimenez, Adsorption and dissociation of CO on metal clusters, Materials Today, Communications. 24 (2020), 101158, https://doi.org/10.1016/j.mtcomm.2020.101158. M.R. Dehghan, S. Ahmadi, Z. Mosapour Kotena, M. Niakousari, A computational study of N2 adsorption on aromatic metal Mg16M;(M=Be, Mg, and Ca) nanoclusters, J. Mol. Graph. Model. 105 (2021), 107862, https://doi.org/10.1016/ j.jmgm.2021.107862. P. Giannozzi, S. Baroni, N. Bonini, M. Calandra, R. Car, C. Cavazzoni, D. Ceresoli, G.L. Chiarotti, M. Cococcioni, I. Dabo, A. Dal Corso, S. De Gironcoli, S. Fabris, G. Fratesi, R. Gebauer, U. Gerstmann, C. Gougoussis, A. Kokalj, M. Lazzeri, L. MartinSamos, N. Marzari, F. Mauri, R. Mazzarello, S. Paolini, A. Pasquarello, L. Paulatto, C. Sbraccia, S. Scandolo, G. Sclauzero, A.P. Seitsonen, A. Smogunov, P. Umari, R. M. Wentzcovitch, QUANTUM ESPRESSO: A modular and open-source software project for quantum simulations of materials, Journal of Physics Condensed Matter. 21 (2009) 395502. https://doi.org/10.1088/0953-8984/21/39/395502. M.D. the E. Transition, QUANTUMESPRESSO, (n.d.). https://www.quantumespresso.org/resources/faq/pseudopotentials (accessed March 5, 2021). (No Title), (n.d.). https://www.quantum-espresso.org/upf_files/H.pbe-rrkjus_ psl.1.0.0.UPF (accessed June 2, 2021). (No Title), (n.d.). https://www.quantum-espresso.org/upf_files/Ru.pbe-spn-rrkjus_ psl.1.0.0.UPF (accessed June 2, 2021). (No Title), (n.d.). https://www.quantum-espresso.org/upf_files/Cu.pbe-d-rrkjus. UPF (accessed June 2, 2021). (No Title), (n.d.). https://www.quantum-espresso.org/upf_files/Co.rel-pbe-ndrrkjus.UPF (accessed June 2, 2021). J.P. Perdew, K. Burke, M. Ernzerhof, Generalized Gradient Approximation Made Simple, Phys. Rev. Lett. 77 (1996) 3865–3868, https://doi.org/10.1103/ PhysRevLett.77.3865. M.C. Payne, M.P. Teter, D.C. Allan, T.A. Arias, J.D. Joannopoulos, Iterative minimization techniques for ab initio total-energy calculations: Molecular dynamics and conjugate gradients, Rev. Mod. Phys. 64 (1992) 1045–1097, https:// doi.org/10.1103/RevModPhys.64.1045. Z.Z. Lin, X. Chen, C. Yin, H. Tang, Y.C. Hu, X.J. Ning, Theoretical prediction of the growth and surface structure of Pt and Ni nanoparticles, EPL (Europhysics Letters). 96 (2011) 66005, https://doi.org/10.1209/0295-5075/96/66005. X. Liu, D. Tian, C. Meng, DFT study on the adsorption and dissociation of H2 on Pdn (n=4, 6, 13, 19, 55) clusters, Journal of Molecular Structure. 1080 (2015) 105–110. https://doi.org/https://doi.org/10.1016/j.molstruc.2014.09.078. C. Kittel, Introduction to Solid State Physics, eigth, Jhon Wiley & Sons, New York, 2005. H.J. Monkhorst, J.D. Pack, Special points for Brillouin-zone integrations, Physical Review B. 13 (1976) 5188–5192, https://doi.org/10.1103/PhysRevB.13.5188. G. Henkelman, B.P. Uberuaga, H. Jonsson, ´ Climbing image nudged elastic band method for finding saddle points and minimum energy paths, J. Chem. Phys. 113 (2000) 9901–9904, https://doi.org/10.1063/1.1329672. A. Kokalj, Computer graphics and graphical user interfaces as tools in simulations of matter at the atomic scale, in, Computational Materials Science, Elsevier (2003) 155–168, https://doi.org/10.1016/S0927-0256(03)00104-6. F. Silveri, M.G. Quesne, A. Roldan, N.H. de Leeuw, C.R.A. Catlow, Hydrogen adsorption on transition metal carbides: a DFT study, PCCP 21 (2019) 5335–5343, https://doi.org/10.1039/C8CP05975F. W. Bergermayer, H. Schweiger, E. Wimmer, Ab initio thermodynamics of oxide surfaces: O2 on Fe2O3(0001), Physical Review B. 69 (2004), 195409, https://doi. org/10.1103/PhysRevB.69.195409. S.A. Tacey, B.W.J. Chen, T. Szilvasi, ´ M. Mavrikakis, An automated cluster surface scanning method for exploring reaction paths on metal-cluster surfaces, Comput. Mater. Sci. 186 (2021), 110010, https://doi.org/10.1016/j. commatsci.2020.110010. Y. Kunisada, H. Kasai, Hindered rotational physisorption states of H2 on Ag(111) surfaces, PCCP 17 (2015) 19625–19630, https://doi.org/10.1039/C5CP01701G. B. Jiang, H. Guo, Six-dimensional quantum dynamics for dissociative chemisorption of H2 and D2 on Ag(111) on a permutation invariant potential energy surface, PCCP 16 (2014) 24704–24715, https://doi.org/10.1039/ C4CP03761H. P. Hirunsit, K. Shimizu, R. Fukuda, S. Namuangruk, Y. Morikawa, M. Ehara, Cooperative H 2 Activation at Ag Cluster/θ-Al 2 O 3 (110) Dual Perimeter Sites: A Density Functional Theory Study, The Journal of Physical Chemistry C. 118 (2014) 7996–8006, https://doi.org/10.1021/jp5000792. H.-W.-H.-P.-D.-L.-Z.-H.-Z.-U.-O. Zhi-Jun, CO and H2 Molecules Adsorption on Cu (111) Surface and Solvent Effects, Acta Phys. -Chim. Sin. 25 (2009) 2507–2512. G.H. Guvelioglu, P. Ma, X. He, R.C. Forrey, H. Cheng, First principles studies on the growth of small Cu clusters and the dissociative chemisorption of H2, Physical Review B - Condensed Matter and Materials Physics. 73 (2006), 155436, https:// doi.org/10.1103/PhysRevB.73.155436. M.J.S. Spencer, G.L. Nyberg, DFT modelling of hydrogen on Cu(110)- and (111)- type clusters, Mol. Simul. 28 (8-9) (2002) 807–825. G.X. Ge, H.X. Yan, Q. Jing, Y.H. Luo, Theoretical Study of Hydrogen Adsorption on Ruthenium Clusters, J. Cluster Sci. 22 (2011) 473–489, https://doi.org/10.1007/ s10876-011-0395-1. |
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© 2022 Elsevier B.V. |
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Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0) |
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Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)© 2022 Elsevier B.V.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Amaya Roncancio, S.Toncón Leal, C.F.Arellano Ramírez, I.D.Torres Cerón, Darwin AugustoRestrepo Parra, E.Sapag, K.2024-11-05T12:51:07Z2024-11-05T12:51:07Z2022-04-18S. Amaya-Roncancio, C.F. Toncón-Leal, I.D. Arellano-Ramírez, Darwin Augusto Torres-Cerón, E. Restrepo-Parra, K. Sapag, Dissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and Ru, Chemical Physics, Volume 559, 2022, 111546, ISSN 0301-0104, https://doi.org/10.1016/j.chemphys.2022.111546.0301-0104https://hdl.handle.net/11323/1363810.1016/j.chemphys.2022.1115461873-4421Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Dissociative adsorption of H2 was carried out on the @13 cluster (@ = Ag, Co, Cu and Ru) according to the number of nH2 molecules (n = 1–10) and it was compared with H2 adsorption on the surface (1 1 1) of the same metals using Density Functional Theory. The adsorption of H2 is energetically more favorable on the @13 clusters than on the surfaces for all metals studied. Charge population analysis and density of states were calculated to understand the electronic behavior of hydrogen on the @13 cluster and on the (1 1 1) surface. In all the cases studied, hydrogen takes more charge from the @13 metal cluster than on (1 1 1) surfaces. The ab-initio thermodynamics shows the favorable ranges of pressure, energy, and chemical potential for dissociative adsorption of H2 for all the coverages studied on the metal clusters. Additionally, XPS and chemisorption results for supported nanoparticles and bulk material are presented for cobalt.11 páginasapplication/pdfengElsevier B.V.Netherlandshttps://www-sciencedirect-com.ezproxy.cuc.edu.co/science/article/pii/S030101042200101X?via%3DihubDissociative adsorption of H2 on metal cluster and (111) surface of Ag, Co, Cu and RuArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Chemical PhysicsI. Swart, F.M.F. de Groot, B.M. Weckhuysen, P. Gruene, G. Meijer, A. Fielicke, H2 Adsorption on 3d Transition Metal Clusters: A Combined Infrared Spectroscopy and Density Functional Study, J. Phys. Chem. A. 112 (2008) 1139–1149, https://doi. org/10.1021/jp076702t.V. Jain, B. Kandasubramanian, Functionalized graphene materials for hydrogen storage, J. Mater. Sci. 55 (2020) 1865–1903, https://doi.org/10.1007/s10853- 019-04150-y.C. Wang, J. Tuninetti, Z. Wang, C. Zhang, R. Ciganda, L. Salmon, S. Moya, J. Ruiz, D. Astruc, Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release, J. Am. Chem. Soc. 139 (2017) 11610–11615, https://doi.org/10.1021/jacs.7b06859.G. Chen, R. Wang, W. Zhao, B. Kang, D. Gao, C. Li, J.Y. Lee, Effect of Ru crystal phase on the catalytic activity of hydrolytic dehydrogenation of ammonia borane, J. Power Sources 396 (2018) 148–154, https://doi.org/10.1016/j. jpowsour.2018.06.028.A. Montoya, A. Schlunke, B.S. Haynes, Reaction of Hydrogen with Ag(111): Binding States, Minimum Energy Paths, and Kinetics, J. Phys. Chem. B 110 (2006) 17145–17154, https://doi.org/10.1021/jp062725g.A. Schneemann, J.L. White, S. Kang, S. Jeong, L.F. Wan, E.S. Cho, T.W. Heo, D. Prendergast, J.J. Urban, B.C. Wood, M.D. Allendorf, V. Stavila, Nanostructured Metal Hydrides for Hydrogen Storage, Chem. Rev. 118 (2018) 10775–10839, https://doi.org/10.1021/acs.chemrev.8b00313.K. García-Díez, J. Fern´ andez-Fern´ andez, J.A. Alonso, M.J. Lopez, ´ Theoretical study of the adsorption of hydrogen on cobalt clusters, PCCP 20 (2018) 21163–21176, https://doi.org/10.1039/C8CP03048K.H. Akbarzadeh, A.N. Shamkhali, H2 adsorption on Ag-nanocluster/single-walled carbon nanotube composites: A molecular dynamics study on the effects of nanocluster size, diameter, and chirality of nanotube, J. Comput. Chem. 36 (2015) 433–440, https://doi.org/10.1002/jcc.23817.M. Yu, L. Liu, Q. Wang, L. Jia, B. Hou, Y. Si, D. Li, Y. Zhao, High coverage H2 adsorption and dissociation on fcc Co surfaces from DFT and thermodynamics, International Journal of Hydrogen Energy. 43 (2018) 5576–5590. https://doi.org/ https://doi.org/10.1016/j.ijhydene.2018.01.165.A. Nakhaei Pour, Z. Keyvanloo, M. Izadyar, S.M. Modaresi, Dissociative hydrogen adsorption on the cubic cobalt surfaces: A DFT study, Int. J. Hydrogen Energy 40 (2015) 7064–7071, https://doi.org/10.1016/j.ijhydene.2015.04.028.K. Mudiyanselage, Y. Yang, F.M. Hoffmann, O.J. Furlong, J. Hrbek, M.G. White, P. Liu, D.J. Stacchiola, Adsorption of hydrogen on the surface and sub-surface of Cu (111), The Journal of Chemical Physics. 139 (2013) 044712. https://doi.org/ 10.1063/1.4816515.K. Cao, G. Füchsel, A.W. Kleyn, L.B.F. Juurlink, Hydrogen adsorption and desorption from Cu(111) and Cu(211), PCCP 20 (2018) 22477–22488, https://doi. org/10.1039/C8CP03386B.P. Zhao, Y. He, D.B. Cao, X. Wen, H. Xiang, Y.W. Li, J. Wang, H. Jiao, High coverage adsorption and co-adsorption of CO and H<inf>2</inf> on Ru(0001) from DFT and thermodynamics, PCCP 17 (2015) 19446–19456, https://doi.org/ 10.1039/c5cp02486b.I. Yarovsky, A. Goldberg, DFT study of hydrogen adsorption on Al 13 clusters, Mol. Simul. 31 (2005) 475–481, https://doi.org/10.1080/08927020412331337041.S. Amaya-Roncancio, A.A. García Blanco, D.H. Linares, K. Sapag, DFT study of hydrogen adsorption on Ni/graphene, Appl. Surf. Sci. 447 (2018) 254–260, https://doi.org/10.1016/j.apsusc.2018.03.233.P. Felício-Sousa, K.F. Andriani, J.L.F. Da Silva, Ab initioinvestigation of the role of the d-states occupation on the adsorption properties of H2, CO, CH4and CH3OH on the Fe13, Co13, Ni13and Cu13clusters, PCCP 23 (2021) 8739–8751, https://doi. org/10.1039/d0cp06091g.S. Amaya-Roncancio, L. Reinaudi, M. Cecilia, Gimenez, Adsorption and dissociation of CO on metal clusters, Materials Today, Communications. 24 (2020), 101158, https://doi.org/10.1016/j.mtcomm.2020.101158.M.R. Dehghan, S. Ahmadi, Z. Mosapour Kotena, M. Niakousari, A computational study of N2 adsorption on aromatic metal Mg16M;(M=Be, Mg, and Ca) nanoclusters, J. Mol. Graph. Model. 105 (2021), 107862, https://doi.org/10.1016/ j.jmgm.2021.107862.P. Giannozzi, S. Baroni, N. Bonini, M. Calandra, R. Car, C. Cavazzoni, D. Ceresoli, G.L. Chiarotti, M. Cococcioni, I. Dabo, A. Dal Corso, S. De Gironcoli, S. Fabris, G. Fratesi, R. Gebauer, U. Gerstmann, C. Gougoussis, A. Kokalj, M. Lazzeri, L. MartinSamos, N. Marzari, F. Mauri, R. Mazzarello, S. Paolini, A. Pasquarello, L. Paulatto, C. Sbraccia, S. Scandolo, G. Sclauzero, A.P. Seitsonen, A. Smogunov, P. Umari, R. M. Wentzcovitch, QUANTUM ESPRESSO: A modular and open-source software project for quantum simulations of materials, Journal of Physics Condensed Matter. 21 (2009) 395502. https://doi.org/10.1088/0953-8984/21/39/395502.M.D. the E. Transition, QUANTUMESPRESSO, (n.d.). https://www.quantumespresso.org/resources/faq/pseudopotentials (accessed March 5, 2021).(No Title), (n.d.). https://www.quantum-espresso.org/upf_files/H.pbe-rrkjus_ psl.1.0.0.UPF (accessed June 2, 2021).(No Title), (n.d.). https://www.quantum-espresso.org/upf_files/Ru.pbe-spn-rrkjus_ psl.1.0.0.UPF (accessed June 2, 2021).(No Title), (n.d.). https://www.quantum-espresso.org/upf_files/Cu.pbe-d-rrkjus. UPF (accessed June 2, 2021).(No Title), (n.d.). https://www.quantum-espresso.org/upf_files/Co.rel-pbe-ndrrkjus.UPF (accessed June 2, 2021).J.P. Perdew, K. Burke, M. Ernzerhof, Generalized Gradient Approximation Made Simple, Phys. Rev. Lett. 77 (1996) 3865–3868, https://doi.org/10.1103/ PhysRevLett.77.3865.M.C. Payne, M.P. Teter, D.C. Allan, T.A. Arias, J.D. Joannopoulos, Iterative minimization techniques for ab initio total-energy calculations: Molecular dynamics and conjugate gradients, Rev. Mod. Phys. 64 (1992) 1045–1097, https:// doi.org/10.1103/RevModPhys.64.1045.Z.Z. Lin, X. Chen, C. Yin, H. Tang, Y.C. Hu, X.J. Ning, Theoretical prediction of the growth and surface structure of Pt and Ni nanoparticles, EPL (Europhysics Letters). 96 (2011) 66005, https://doi.org/10.1209/0295-5075/96/66005.X. Liu, D. Tian, C. Meng, DFT study on the adsorption and dissociation of H2 on Pdn (n=4, 6, 13, 19, 55) clusters, Journal of Molecular Structure. 1080 (2015) 105–110. https://doi.org/https://doi.org/10.1016/j.molstruc.2014.09.078.C. Kittel, Introduction to Solid State Physics, eigth, Jhon Wiley & Sons, New York, 2005.H.J. Monkhorst, J.D. Pack, Special points for Brillouin-zone integrations, Physical Review B. 13 (1976) 5188–5192, https://doi.org/10.1103/PhysRevB.13.5188.G. Henkelman, B.P. Uberuaga, H. Jonsson, ´ Climbing image nudged elastic band method for finding saddle points and minimum energy paths, J. Chem. Phys. 113 (2000) 9901–9904, https://doi.org/10.1063/1.1329672.A. Kokalj, Computer graphics and graphical user interfaces as tools in simulations of matter at the atomic scale, in, Computational Materials Science, Elsevier (2003) 155–168, https://doi.org/10.1016/S0927-0256(03)00104-6.F. Silveri, M.G. Quesne, A. Roldan, N.H. de Leeuw, C.R.A. Catlow, Hydrogen adsorption on transition metal carbides: a DFT study, PCCP 21 (2019) 5335–5343, https://doi.org/10.1039/C8CP05975F.W. Bergermayer, H. Schweiger, E. Wimmer, Ab initio thermodynamics of oxide surfaces: O2 on Fe2O3(0001), Physical Review B. 69 (2004), 195409, https://doi. org/10.1103/PhysRevB.69.195409.S.A. Tacey, B.W.J. Chen, T. Szilvasi, ´ M. Mavrikakis, An automated cluster surface scanning method for exploring reaction paths on metal-cluster surfaces, Comput. Mater. Sci. 186 (2021), 110010, https://doi.org/10.1016/j. commatsci.2020.110010.Y. Kunisada, H. Kasai, Hindered rotational physisorption states of H2 on Ag(111) surfaces, PCCP 17 (2015) 19625–19630, https://doi.org/10.1039/C5CP01701G.B. Jiang, H. Guo, Six-dimensional quantum dynamics for dissociative chemisorption of H2 and D2 on Ag(111) on a permutation invariant potential energy surface, PCCP 16 (2014) 24704–24715, https://doi.org/10.1039/ C4CP03761H.P. Hirunsit, K. Shimizu, R. Fukuda, S. Namuangruk, Y. Morikawa, M. Ehara, Cooperative H 2 Activation at Ag Cluster/θ-Al 2 O 3 (110) Dual Perimeter Sites: A Density Functional Theory Study, The Journal of Physical Chemistry C. 118 (2014) 7996–8006, https://doi.org/10.1021/jp5000792.H.-W.-H.-P.-D.-L.-Z.-H.-Z.-U.-O. Zhi-Jun, CO and H2 Molecules Adsorption on Cu (111) Surface and Solvent Effects, Acta Phys. -Chim. Sin. 25 (2009) 2507–2512.G.H. Guvelioglu, P. Ma, X. He, R.C. Forrey, H. Cheng, First principles studies on the growth of small Cu clusters and the dissociative chemisorption of H2, Physical Review B - Condensed Matter and Materials Physics. 73 (2006), 155436, https:// doi.org/10.1103/PhysRevB.73.155436.M.J.S. Spencer, G.L. Nyberg, DFT modelling of hydrogen on Cu(110)- and (111)- type clusters, Mol. Simul. 28 (8-9) (2002) 807–825.G.X. Ge, H.X. Yan, Q. Jing, Y.H. Luo, Theoretical Study of Hydrogen Adsorption on Ruthenium Clusters, J. Cluster Sci. 22 (2011) 473–489, https://doi.org/10.1007/ s10876-011-0395-1.111559Density functional theoryHydrogen dissociative adsorptionClusterMetal surfaceChemisorptionPublicationORIGINALDissociative adsorption of H2 on metal cluster and (1 1 1) surface of Ag, Co, Cu and Ru.pdfDissociative adsorption of H2 on metal cluster and (1 1 1) surface of Ag, Co, Cu and Ru.pdfapplication/pdf8603882https://repositorio.cuc.edu.co/bitstreams/64fdca68-4532-4b4a-83d8-41310db2ad69/download1c049627ea83198edd0b9989f8778c72MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-815543https://repositorio.cuc.edu.co/bitstreams/5f0a178e-9224-4adc-a1cc-3cb87258abfa/download73a5432e0b76442b22b026844140d683MD52TEXTDissociative adsorption of H2 on metal cluster and (1 1 1) surface of Ag, Co, Cu and Ru.pdf.txtDissociative adsorption of H2 on metal cluster and (1 1 1) surface of Ag, Co, Cu and Ru.pdf.txtExtracted 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ara ejercer estos derechos sobre la Obra tal y como se indica a continuación:</p>
    <ol type="a">
      <li>Reproducir la Obra, incorporar la Obra en una o más Obras Colectivas, y reproducir la Obra incorporada en las Obras Colectivas.</li>
      <li>Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.</li>
      <li>Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.</li>
    </ol>
    <p>Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).</p>
  </li>
  <br/>
  <li>
    Restricciones.
    <p>La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:</p>
    <ol type="a">
      <li>Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).</li>
      <li>Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.</li>
      <li>Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.</li>
      <li>
        Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
        <ol type="i">
          <li>Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.</li>
          <li>Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
        </ol>
      </li>
      <li>Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
    </ol>
  </li>
  <br/>
  <li>
    Representaciones, Garantías y Limitaciones de Responsabilidad.
    <p>A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Limitación de responsabilidad.
    <p>A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Término.
    <ol type="a">
      <li>Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.</li>
      <li>Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.</li>
    </ol>
  </li>
  <br/>
  <li>
    Varios.
    <ol type="a">
      <li>Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.</li>
      <li>Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.</li>
      <li>Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.</li>
      <li>Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.</li>
    </ol>
  </li>
  <br/>
</ol>
 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