Quantification of the synthetic phenolic antioxidant cyanox 1790 in bottled water with SPE-HPLC/MS/MS and determination of the impact of the use of recycled packaging on its generation

One route of exposure to SPAs is through bottled water since the polymers used to make plastic bottles contain these SPAs, which migrate from the plastic to the water. Solid-phase extraction (SPE), HPLC-MS, FTIR, and DSC are used to identify and quantify these SPAs in water. Interday measurements of...

Full description

Autores:
Hernández-Fernández, Joaquín
Ortega-Toro, Rodrigo
Castro, john
Tipo de recurso:
Article of investigation
Fecha de publicación:
2023
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/10474
Acceso en línea:
https://hdl.handle.net/11323/10474
https://repositorio.cuc.edu.co/
Palabra clave:
Bottled water
Synthetic phenolic antioxidant
Cyanox 1790
Recycled packaging
Non-recycled packaging
Additive migration
Rights
openAccess
License
Atribución 4.0 Internacional (CC BY 4.0)
Description
Summary:One route of exposure to SPAs is through bottled water since the polymers used to make plastic bottles contain these SPAs, which migrate from the plastic to the water. Solid-phase extraction (SPE), HPLC-MS, FTIR, and DSC are used to identify and quantify these SPAs in water. Interday measurements of cyanox 1790 in water with HPLC showed RSD, error, and R2 lower than 3.78, 9.3, and 0.99995, respectively. For intraday measurements of cyanox 1790 in water, the RSD, error, and R2 were less than 4.1, 11.2, and 0.99995, respectively. Concentrations of Cyanox 1790 in water from non-recycled bottles ranged from 0.01 ± 0.0004 to 4.15 ± 0. 14 ppm, while the levels of cyanox 1790 in water in recycled bottles ranged between 0.01 ± 0.0005 and 11.27 ± 0.12 ppm. In the tests carried out, an increase in the migration of Cyanox 1790 from plastic bottles to water was identified, since the ppm of Cyanox increased in the water as the days of storage increased at 40 °C.