Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene
A route based on pyrolysis and physical activation with H2O and CO2 was proposed to reuse citrus waste traditionally discarded. The citrus wastes were orange peel (OP), mandarine peel (MP), rangpur lime peel (RLP), and sweet lime peel (SLP). The main aim was to use the solid products of this new rou...
- Autores:
-
da Silva, Mariele D.
DA BOIT MARTINELLO, KATIA
Knani, Salah
Frantz Lütke, Sabrina
Machado, Lauren M.M.
Manera, Christian
Perondi, Daniele
Godinho, Marcelo
Collazzo, Gabriela C.
Silva Oliveira, Luis Felipe
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/10742
- Acceso en línea:
- https://hdl.handle.net/11323/10742
https://repositorio.cuc.edu.co/
- Palabra clave:
- Adsorbent
Bio-oil
Cu(II) adsorption
D-limonene
Physical activation
- Rights
- embargoedAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
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| dc.title.eng.fl_str_mv |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene |
| title |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene |
| spellingShingle |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene Adsorbent Bio-oil Cu(II) adsorption D-limonene Physical activation |
| title_short |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene |
| title_full |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene |
| title_fullStr |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene |
| title_full_unstemmed |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene |
| title_sort |
Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene |
| dc.creator.fl_str_mv |
da Silva, Mariele D. DA BOIT MARTINELLO, KATIA Knani, Salah Frantz Lütke, Sabrina Machado, Lauren M.M. Manera, Christian Perondi, Daniele Godinho, Marcelo Collazzo, Gabriela C. Silva Oliveira, Luis Felipe Dotto, Guilherme Luiz |
| dc.contributor.author.none.fl_str_mv |
da Silva, Mariele D. DA BOIT MARTINELLO, KATIA Knani, Salah Frantz Lütke, Sabrina Machado, Lauren M.M. Manera, Christian Perondi, Daniele Godinho, Marcelo Collazzo, Gabriela C. Silva Oliveira, Luis Felipe Dotto, Guilherme Luiz |
| dc.subject.proposal.eng.fl_str_mv |
Adsorbent Bio-oil Cu(II) adsorption D-limonene Physical activation |
| topic |
Adsorbent Bio-oil Cu(II) adsorption D-limonene Physical activation |
| description |
A route based on pyrolysis and physical activation with H2O and CO2 was proposed to reuse citrus waste traditionally discarded. The citrus wastes were orange peel (OP), mandarine peel (MP), rangpur lime peel (RLP), and sweet lime peel (SLP). The main aim was to use the solid products of this new route as adsorbents for Cu(II) ions. Copper ions are among the most important water pollutants due to their non-degradability, toxicity, and bioaccumulation, facilitating their inclusion and long persistence in the food chain. Besides the solid products, the liquid and gaseous fractions were evaluated for possible applications. Results showed that the citrus waste composition favored the thermochemical treatment. In addition, the following yields were obtained from the pyrolysis process: approximately 30 % wt. of biochar, 40 % wt. of non-condensable gases, and 30 % wt. of bio-oil. The biochars did not present a high specific surface area. Nevertheless, activated carbons with CO2 and H2O presented specific surface areas of 212.4 m2/g and 399.4 m2/g, respectively, and reached Cu(II) adsorption capacities of 28.2 mg g−1 and 27.8 mg g−1. The adsorption kinetic study revealed that the equilibrium was attained at 60 min and the pseudo-second-order model presented a better fit to the experimental data. The main generated gases were CO2, which could be employed as an activating agent for activated carbon production. d-limonene, used for food and medicinal purposes, was the main constituent of the bio-oil. |
| publishDate |
2022 |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.date.available.none.fl_str_mv |
2023 2024-02-20T17:43:41Z |
| dc.date.accessioned.none.fl_str_mv |
2024-02-20T17:43:41Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.coarversion.spa.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| format |
http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
| dc.identifier.citation.spa.fl_str_mv |
Mariele D. da Silva, Kátia da Boit Martinello, Salah Knani, Sabrina F. Lütke, Lauren M.M. Machado, Christian Manera, Daniele Perondi, Marcelo Godinho, Gabriela C. Collazzo, Luis F.O. Silva, Guilherme L. Dotto, Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene, Waste Management, Volume 152, 2022, Pages 17-29, ISSN 0956-053X, https://doi.org/10.1016/j.wasman.2022.07.024 |
| dc.identifier.issn.spa.fl_str_mv |
0956-053X |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/11323/10742 |
| dc.identifier.doi.none.fl_str_mv |
10.1016/j.wasman.2022.07.024 |
| dc.identifier.eissn.spa.fl_str_mv |
1879-2456 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC – Repositorio CUC |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Mariele D. da Silva, Kátia da Boit Martinello, Salah Knani, Sabrina F. Lütke, Lauren M.M. Machado, Christian Manera, Daniele Perondi, Marcelo Godinho, Gabriela C. Collazzo, Luis F.O. Silva, Guilherme L. Dotto, Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene, Waste Management, Volume 152, 2022, Pages 17-29, ISSN 0956-053X, https://doi.org/10.1016/j.wasman.2022.07.024 0956-053X 10.1016/j.wasman.2022.07.024 1879-2456 Corporación Universidad de la Costa REDICUC – Repositorio CUC |
| url |
https://hdl.handle.net/11323/10742 https://repositorio.cuc.edu.co/ |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Waste Management |
| dc.relation.references.spa.fl_str_mv |
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Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)© 2022 Elsevier Ltd. All rights reserved.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfda Silva, Mariele D.DA BOIT MARTINELLO, KATIAKnani, SalahFrantz Lütke, SabrinaMachado, Lauren M.M.Manera, ChristianPerondi, DanieleGodinho, MarceloCollazzo, Gabriela C.Silva Oliveira, Luis FelipeDotto, Guilherme Luiz2024-02-20T17:43:41Z20232024-02-20T17:43:41Z2022Mariele D. da Silva, Kátia da Boit Martinello, Salah Knani, Sabrina F. Lütke, Lauren M.M. Machado, Christian Manera, Daniele Perondi, Marcelo Godinho, Gabriela C. Collazzo, Luis F.O. Silva, Guilherme L. Dotto, Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene, Waste Management, Volume 152, 2022, Pages 17-29, ISSN 0956-053X, https://doi.org/10.1016/j.wasman.2022.07.0240956-053Xhttps://hdl.handle.net/11323/1074210.1016/j.wasman.2022.07.0241879-2456Corporación Universidad de la CostaREDICUC – Repositorio CUChttps://repositorio.cuc.edu.co/A route based on pyrolysis and physical activation with H2O and CO2 was proposed to reuse citrus waste traditionally discarded. The citrus wastes were orange peel (OP), mandarine peel (MP), rangpur lime peel (RLP), and sweet lime peel (SLP). The main aim was to use the solid products of this new route as adsorbents for Cu(II) ions. Copper ions are among the most important water pollutants due to their non-degradability, toxicity, and bioaccumulation, facilitating their inclusion and long persistence in the food chain. Besides the solid products, the liquid and gaseous fractions were evaluated for possible applications. Results showed that the citrus waste composition favored the thermochemical treatment. In addition, the following yields were obtained from the pyrolysis process: approximately 30 % wt. of biochar, 40 % wt. of non-condensable gases, and 30 % wt. of bio-oil. The biochars did not present a high specific surface area. Nevertheless, activated carbons with CO2 and H2O presented specific surface areas of 212.4 m2/g and 399.4 m2/g, respectively, and reached Cu(II) adsorption capacities of 28.2 mg g−1 and 27.8 mg g−1. The adsorption kinetic study revealed that the equilibrium was attained at 60 min and the pseudo-second-order model presented a better fit to the experimental data. The main generated gases were CO2, which could be employed as an activating agent for activated carbon production. d-limonene, used for food and medicinal purposes, was the main constituent of the bio-oil.13 páginasapplication/pdfengElsevier Ltd.United Kingdomhttps://www.sciencedirect.com/science/article/pii/S0956053X22003725Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limoneneArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Waste ManagementAburto, J., Moran, M., Galano, A., Torres-García, E., 2015. Non-isothermal pyrolysis of pectin: a thermochemical and kinetic approach. J. Anal. Appl. Pyrolysis 112, 94–104. https://doi.org/10.1016/j.jaap.2015.02.012.Ahmad, Z., Gao, B., Mosa, A., Yu, H., Yin, X., Bashir, A., Ghoveisi, H., Wang, S., 2018. 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Food Funct. 12, 7214–7226. https://doi.org/10.1039/d0fo02675a.2917152AdsorbentBio-oilCu(II) adsorptionD-limonenePhysical activationPublicationORIGINALPyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene.pdfPyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene.pdfArtículoapplication/pdf4632975https://repositorio.cuc.edu.co/bitstreams/da769dc7-80bb-407d-95e5-6987cd8ac5d0/download08566cf0bc49acea2f9d42c54884e2dcMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstreams/e5506629-7b75-4550-9742-b9c7325166f4/download2f9959eaf5b71fae44bbf9ec84150c7aMD52TEXTPyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene.pdf.txtPyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene.pdf.txtExtracted texttext/plain90609https://repositorio.cuc.edu.co/bitstreams/c9ca6150-9e93-4e1a-9b25-fd21ab865880/download0e0d3632e5b5edd1463e71919485091eMD53THUMBNAILPyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene.pdf.jpgPyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene.pdf.jpgGenerated Thumbnailimage/jpeg14476https://repositorio.cuc.edu.co/bitstreams/b7509390-817f-45cb-8710-e43fe047ef50/downloade334709b101d443f9b593784f780ae9cMD5411323/10742oai:repositorio.cuc.edu.co:11323/107422024-09-16 16:39:28.823https://creativecommons.org/licenses/by-nc-nd/4.0/© 2022 Elsevier Ltd. 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ada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
 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