New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations
The present work used a statistical physics approach to present new insights into the adsorption of the pesticide glyphosate on modified carbon nanotubes via green synthesis (MWCNT/MPNs-Fe). The experimental equilibrium curves obtained for this system under pH 4 at temperatures 298, 308, 318, and 32...
- Autores:
-
Diel, Júlia
DA BOIT MARTINELLO, KATIA
da Silveira, Christian L.
Pereira, Hércules A.
P. Franco, Dison S.
O. Silva, Luis F.
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2021
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/9291
- Acceso en línea:
- https://hdl.handle.net/11323/9291
https://doi.org/10.1016/j.cej.2021.134095
https://repositorio.cuc.edu.co/
- Palabra clave:
- Glyphosate
Carbon nanotubes
Green synthesis
Adsorption isotherms
Statistical physics
Adsorption mechanism
- Rights
- embargoedAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
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RCUC2 |
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| dc.title.eng.fl_str_mv |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations |
| title |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations |
| spellingShingle |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations Glyphosate Carbon nanotubes Green synthesis Adsorption isotherms Statistical physics Adsorption mechanism |
| title_short |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations |
| title_full |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations |
| title_fullStr |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations |
| title_full_unstemmed |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations |
| title_sort |
New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretations |
| dc.creator.fl_str_mv |
Diel, Júlia DA BOIT MARTINELLO, KATIA da Silveira, Christian L. Pereira, Hércules A. P. Franco, Dison S. O. Silva, Luis F. Dotto, Guilherme Luiz |
| dc.contributor.author.spa.fl_str_mv |
Diel, Júlia DA BOIT MARTINELLO, KATIA da Silveira, Christian L. Pereira, Hércules A. P. Franco, Dison S. O. Silva, Luis F. Dotto, Guilherme Luiz |
| dc.subject.proposal.eng.fl_str_mv |
Glyphosate Carbon nanotubes Green synthesis Adsorption isotherms Statistical physics Adsorption mechanism |
| topic |
Glyphosate Carbon nanotubes Green synthesis Adsorption isotherms Statistical physics Adsorption mechanism |
| description |
The present work used a statistical physics approach to present new insights into the adsorption of the pesticide glyphosate on modified carbon nanotubes via green synthesis (MWCNT/MPNs-Fe). The experimental equilibrium curves obtained for this system under pH 4 at temperatures 298, 308, 318, and 328 K were simulated from monolayer, double layer, and multilayer models, with 1 and 2 energies, considering real and ideal fluid approaches. Taking into account the statistical indicators and the physical meaning of the parameters, exploring simplifying hypotheses, the Hill model with 1 energy and ideal fluid approach (M1) presented the best prediction of the experimental data, indicating that glyphosate adsorption occurs by the formation of a monolayer and that pesticide interaction with MWCNT/MPNs-Fe are characterized by only one energy. Based on this approach, to assess the steric aspects of the system, the number of molecules adsorbed per site (n), the density of receptor sites (Nm), adsorption capacity at saturation (Qsat), and concentration at half-saturation (W) were interpreted. As for the energetic aspects, the adsorption energy (ΔE) was inferred. The combination of parameters to its evolution with temperature and the magnitude of ΔE indicated an exothermic process involving a physical interaction mechanism. Finally, the new insights showed that the MWCNT/MPNs-Fe adsorbent favored pesticide adsorption by interacting glyphosate molecules with the metallic iron nanoparticles present on the adsorbent surface. © 2021 Elsevier B.V. |
| publishDate |
2021 |
| dc.date.issued.none.fl_str_mv |
2021-12-08 |
| dc.date.accessioned.none.fl_str_mv |
2022-06-23T14:07:14Z |
| dc.date.available.none.fl_str_mv |
2022-06-23T14:07:14Z 2023-12-08 |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
| format |
http://purl.org/coar/resource_type/c_6501 |
| dc.identifier.citation.spa.fl_str_mv |
Júlia C. Diel, Kátia da Boit Martinello, Christian L. da Silveira, Hércules A. Pereira, Dison S.P. Franco, Luis F.O. Silva, Guilherme L. Dotto, New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: Statistical physical modeling and steric and energetic interpretations, Chemical Engineering Journal, Volume 431, Part 2, 2022, 134095, ISSN 1385-8947,https://doi.org/10.1016/j.cej.2021.134095 (https://www.sciencedirect.com/science/article/pii/S1385894721056692) |
| dc.identifier.issn.spa.fl_str_mv |
1385-8947 |
| dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/9291 |
| dc.identifier.url.spa.fl_str_mv |
https://doi.org/10.1016/j.cej.2021.134095 |
| dc.identifier.doi.spa.fl_str_mv |
10.1016/j.cej.2021.134095 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Júlia C. Diel, Kátia da Boit Martinello, Christian L. da Silveira, Hércules A. Pereira, Dison S.P. Franco, Luis F.O. Silva, Guilherme L. Dotto, New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: Statistical physical modeling and steric and energetic interpretations, Chemical Engineering Journal, Volume 431, Part 2, 2022, 134095, ISSN 1385-8947,https://doi.org/10.1016/j.cej.2021.134095 (https://www.sciencedirect.com/science/article/pii/S1385894721056692) 1385-8947 10.1016/j.cej.2021.134095 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/9291 https://doi.org/10.1016/j.cej.2021.134095 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Chemical Engineering Journal |
| dc.relation.references.spa.fl_str_mv |
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Diel, JúliaDA BOIT MARTINELLO, KATIAda Silveira, Christian L.Pereira, Hércules A.P. Franco, Dison S.O. Silva, Luis F.Dotto, Guilherme Luiz2022-06-23T14:07:14Z2023-12-082022-06-23T14:07:14Z2021-12-08Júlia C. Diel, Kátia da Boit Martinello, Christian L. da Silveira, Hércules A. Pereira, Dison S.P. Franco, Luis F.O. Silva, Guilherme L. Dotto, New insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: Statistical physical modeling and steric and energetic interpretations, Chemical Engineering Journal, Volume 431, Part 2, 2022, 134095, ISSN 1385-8947,https://doi.org/10.1016/j.cej.2021.134095 (https://www.sciencedirect.com/science/article/pii/S1385894721056692)1385-8947https://hdl.handle.net/11323/9291https://doi.org/10.1016/j.cej.2021.13409510.1016/j.cej.2021.134095Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The present work used a statistical physics approach to present new insights into the adsorption of the pesticide glyphosate on modified carbon nanotubes via green synthesis (MWCNT/MPNs-Fe). The experimental equilibrium curves obtained for this system under pH 4 at temperatures 298, 308, 318, and 328 K were simulated from monolayer, double layer, and multilayer models, with 1 and 2 energies, considering real and ideal fluid approaches. Taking into account the statistical indicators and the physical meaning of the parameters, exploring simplifying hypotheses, the Hill model with 1 energy and ideal fluid approach (M1) presented the best prediction of the experimental data, indicating that glyphosate adsorption occurs by the formation of a monolayer and that pesticide interaction with MWCNT/MPNs-Fe are characterized by only one energy. Based on this approach, to assess the steric aspects of the system, the number of molecules adsorbed per site (n), the density of receptor sites (Nm), adsorption capacity at saturation (Qsat), and concentration at half-saturation (W) were interpreted. As for the energetic aspects, the adsorption energy (ΔE) was inferred. The combination of parameters to its evolution with temperature and the magnitude of ΔE indicated an exothermic process involving a physical interaction mechanism. Finally, the new insights showed that the MWCNT/MPNs-Fe adsorbent favored pesticide adsorption by interacting glyphosate molecules with the metallic iron nanoparticles present on the adsorbent surface. © 2021 Elsevier B.V.10 páginasapplication/pdfengElsevierNetherlandsAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)© 2021 Elsevier B.V. All rights reserved.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfNew insights into glyphosate adsorption on modified carbon nanotubes via green synthesis: statistical physical modeling and steric and energetic interpretationsArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85https://www.sciencedirect.com/science/article/pii/S1385894721056692?via%3DihubChemical Engineering Journal[1] B. Fern´ andez-Reyes, K. Ortiz-Martínez, J.A. Lasalde-Ramírez, A.J. Hernandez- ´ Maldonado, Engineered adsorbents for the removal of contaminants of emerging concern from water, in: Contaminants of Emerging Concern in Water and Wastewater, Elsevier Inc., 2020, pp. 3–45, https://doi.org/10.1016/B978-0-12- 813561-7.00001-8.[2] J. Scaria, A. Gopinath, P.V. 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Chem. 13 (2020) 4691–4702, https://doi.org/10.1016/j.arabjc.2019.11.004.101431GlyphosateCarbon nanotubesGreen synthesisAdsorption isothermsStatistical physicsAdsorption mechanismPublicationORIGINAL1-s2.0-S1385894721056692-main.pdf1-s2.0-S1385894721056692-main.pdfapplication/pdf1270792https://repositorio.cuc.edu.co/bitstreams/f30eab6b-c54a-42bc-8d7f-a9f335c65886/download326760fa55fe46f6fbda2a6875690ebfMD51LICENSElicense.txtlicense.txttext/plain; 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