Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model

In this work, physical statistical models were employed to provide reasonable information regarding the adsorption of naproxen onto different activated carbons. The activated carbons were prepared from different biomasses (pitaya peels, jabuticaba peels, or grape residues from the winery process) us...

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Autores:: Franco, Dison S.P.
Georgin, Jordana
Netto, Matias S.
da Boit Martinello, Katia
Silva, Luis F.O.

Tipo de recurso:: Article of investigation

Fecha de publicación:: 2022

Institución:: Corporación Universidad de la Costa

Repositorio:: REDICUC - Repositorio CUC

Idioma:: eng

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network_acronym_str	RCUC2
network_name_str	REDICUC - Repositorio CUC
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dc.title.eng.fl_str_mv	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model
title	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model
spellingShingle	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model Activated carbons Adsorption modeling Naproxen Physics statistics
title_short	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model
title_full	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model
title_fullStr	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model
title_full_unstemmed	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model
title_sort	Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model
dc.creator.fl_str_mv	Franco, Dison S.P. Georgin, Jordana Netto, Matias S. da Boit Martinello, Katia Silva, Luis F.O.
dc.contributor.author.none.fl_str_mv	Franco, Dison S.P. Georgin, Jordana Netto, Matias S. da Boit Martinello, Katia Silva, Luis F.O.
dc.subject.proposal.eng.fl_str_mv	Activated carbons Adsorption modeling Naproxen Physics statistics
topic	Activated carbons Adsorption modeling Naproxen Physics statistics
description	In this work, physical statistical models were employed to provide reasonable information regarding the adsorption of naproxen onto different activated carbons. The activated carbons were prepared from different biomasses (pitaya peels, jabuticaba peels, or grape residues from the winery process) using ZnCl2 as an activator. All the adsorbents were characterized regarding their functional groups and morphological surfaces. The maximum capacity obtained for the activated carbons (at 328 K) was found to be: 167.0 mg g−1 for jabuticaba peels at pH 4; 158.81 mg g−1 for pitaya peels at pH 6.7; and last., grape residues the capacity was 176.0 mg g−1 at pH 7. The equilibrium data of the three adsorbents were well fitted to the monolayer with two energy sites adsorption model, assuming that NPX adsorption on the carbon surfaces occurs via two different functional groups. This statistical physics model calculated the number of NPX molecules bound on the surface and the saturated adsorption capacity for both functional groups at different temperatures. The obtained results indicate that the naproxen molecules can be adsorbed in a parallel and horizontal manner according to the material employed. The receptor density tends to increase with the temperature evolution, indicating that thermal energy and solubility play an important role in adsorption. Configurational entropy indicates similar thermodynamic behavior for all materials where higher disorder is found at the early stages of the adsorption, followed by and decrease a possible organization of the molecules on the surface. The Gibbs free energy shows that adsorption of naproxen is spontaneous in all cases and internal energy is proportional to the adsorption capacity indicating that the system releases energy as the adsorption occurs. Therefore, this article reports new findings to understand the adsorption mechanism of naproxen molecules on activated carbons prepared from lignocellulosic biomass.
publishDate	2022
dc.date.issued.none.fl_str_mv	2022-06-15
dc.date.accessioned.none.fl_str_mv	2024-03-21T14:48:54Z
dc.date.available.none.fl_str_mv	2024-03-21T14:48:54Z
dc.type.spa.fl_str_mv	Artículo de revista
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dc.type.content.spa.fl_str_mv	Text
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/publishedVersion
dc.type.coarversion.spa.fl_str_mv	http://purl.org/coar/version/c_970fb48d4fbd8a85
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dc.identifier.citation.spa.fl_str_mv	Franco, D. S. P., Georgin, J., Netto, M. S., da Boit Martinello, K., & Silva, L. F. O. (2022). Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): Analytical interpretation via statistical physical model. Journal of Molecular Liquids, 356, 119021. https://doi.org/10.1016/j.molliq.2022.119021
dc.identifier.issn.spa.fl_str_mv	0167-7322
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/11323/10904
dc.identifier.doi.none.fl_str_mv	10.1016/j.molliq.2022.119021
dc.identifier.instname.spa.fl_str_mv	Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv	REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.cuc.edu.co
identifier_str_mv	Franco, D. S. P., Georgin, J., Netto, M. S., da Boit Martinello, K., & Silva, L. F. O. (2022). Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): Analytical interpretation via statistical physical model. Journal of Molecular Liquids, 356, 119021. https://doi.org/10.1016/j.molliq.2022.119021 0167-7322 10.1016/j.molliq.2022.119021 Corporación Universidad de la Costa REDICUC - Repositorio CUC
url	https://hdl.handle.net/11323/10904 https://repositorio.cuc.edu.co
dc.language.iso.spa.fl_str_mv	eng
language	eng
dc.relation.ispartofjournal.spa.fl_str_mv	Journal of Molecular Liquids
dc.relation.references.spa.fl_str_mv	[1] S. Terzic´, I. Senta, M. Ahel, M. Gros, M. Petrovic´, D. Barcelo, J. Müller, T. Knepper, I. Martí, F. Ventura, P. Jovancˇic´, D. Jabucˇar, Occurrence and fate of emerging wastewater contaminants in Western Balkan Region, Sci. Total Environ. 399 (1-3) (2008) 66–77, https://doi.org/10.1016/j.scitotenv.2008.03.003. [2] S.L. Rice, S. Mitra, Microwave-assisted solvent extraction of solid matrices and subsequent detection of pharmaceuticals and personal care products (PPCPs) using gas chromatography-mass spectrometry, Anal. Chim. Acta. 589 (1) (2007) 125–132, https://doi.org/10.1016/j.aca.2007.02.051. [3] S. Zhu, Y.-G. Liu, S.-b. Liu, G.-M. Zeng, L.-H. Jiang, X.-F. Tan, L.u. Zhou, W. Zeng, T.-T. Li, C.-P. Yang, Adsorption of emerging contaminant metformin using graphene oxide, Chemosphere 179 (2017) 20–28, https://doi.org/10.1016/j. chemosphere.2017.03.071. [4] H.B. Quesada, A.T.A. Baptista, L.F. Cusioli, D. Seibert, C. de Oliveira Bezerra, R. Bergamasco, Surface water pollution by pharmaceuticals and an alternative of removal by low-cost adsorbents: A review, Chemosphere 222 (2019) 766–780, https://doi.org/10.1016/j.chemosphere.2019.02.009. [5] L. Feng, E.D. van Hullebusch, M.A. Rodrigo, G. Esposito, M.A. Oturan, Removal of residual anti-inflammatory and analgesic pharmaceuticals from aqueous systems by electrochemical advanced oxidation processes. A review, Chem. Eng. J. 228 (2013) 944–964, https://doi.org/10.1016/j.cej.2013.05.061. [6] Y. Shao, Z. Chen, H. Hollert, S. Zhou, B. Deutschmann, T.B. Seiler, Toxicity of 10 organic micropollutants and their mixture: Implications for aquatic risk assessment, Sci. Total Environ. 666 (2019) 1273–1282, https://doi.org/ 10.1016/j.scitotenv.2019.02.047. [7] B. de Diego-Díaz, A. Duran, M.R. Álvarez-García, J. Fernández-Rodríguez, New trends in physicochemical characterization of solid lignocellulosic waste in anaerobic digestion, Fuel 245 (2019) 240–246, https://doi.org/10.1016/ j.fuel.2019.02.051. [8] F. Tomul, Y. Arslan, B. Kabak, D. Trak, E. Kendüzler, E.C. Lima, H.N. Tran, Peanut shells-derived biochars prepared from different carbonization processes: Comparison of characterization and mechanism of naproxen adsorption in water, Sci. Total Environ. 726 (2020) 137828, https://doi.org/10.1016/j. scitotenv.2020.137828. [9] M.H. Ahmad, M. Fatima, M. Hossain, A.C. Mondal, Evaluation of naproxeninduced oxidative stress, hepatotoxicity and in-vivo genotoxicity in male Wistar rats, J. Pharm. Anal. 8 (6) (2018) 400–406, https://doi.org/10.1016/j. jpha.2018.04.002. [10] D. Liu, Y.i. Zhu, Z. Li, D. Tian, L. Chen, P. Chen, Chitin nanofibrils for rapid and efficient removal of metal ions from water system, Carbohydr. Polym. 98 (1) (2013) 483–489, https://doi.org/10.1016/j.carbpol.2013.06.015. [11] L.F. Cusioli, H.B. Quesada, A.L. de Brito Portela Castro, R.G. Gomes, R. Bergamasco, Development of a new low-cost adsorbent functionalized with iron nanoparticles for removal of metformin from contaminated water, Chemosphere 247 (2020) 125852, https://doi.org/10.1016/j. chemosphere.2020.125852. [12] J. Qu, Y. Yuan, Q. Meng, G. Zhang, F. Deng, L. Wang, Y. Tao, Z. Jiang, Y. Zhang, Simultaneously enhanced removal and stepwise recovery of atrazine and Pb (II) from water using b–cyclodextrin functionalized cellulose: Characterization, adsorptive performance and mechanism exploration, J. Hazard. Mater. 400 (2020) 123142, https://doi.org/10.1016/j. jhazmat.2020.123142. [13] L. Sellaoui, A. Yazidi, S. Taamalli, A. Bonilla-Petriciolet, F. Louis, A. El Bakali, M. Badawi, E.C. Lima, D.R. Lima, Z. Chen, Adsorption of 3-aminophenol and resorcinol on avocado seed activated carbon: Mathematical modelling, thermodynamic study and description of adsorbent performance, J. Mol. Liq. 342 (2021) 116952, https://doi.org/10.1016/j.molliq.2021.116952. [14] M. Paredes-Laverde, M. Salamanca, J.D. Diaz-Corrales, E. Flórez, J. Silva-Agredo, R.A. Torres-Palma, Understanding the removal of an anionic dye in textile wastewaters by adsorption on ZnCl2activated carbons from rice and coffee husk wastes: A combined experimental and theoretical study, J. Environ. Chem. Eng. 9 (4) (2021) 105685, https://doi.org/10.1016/j.jece:2021.105685. [15] S.M. Kharrazi, M. Soleimani, M. Jokar, T. Richards, A. Pettersson, N. Mirghaffari, Pretreatment of lignocellulosic waste as a precursor for synthesis of high porous activated carbon and its application for Pb (II) and Cr (VI) adsorption from aqueous solutions, Int. J. Biol. Macromol. 180 (2021) 299–310, https:// doi.org/10.1016/j.ijbiomac.2021.03.078. [16] A. Medhat, H.H. El-Maghrabi, A. Abdelghany, N.M. Abdel Menem, P. Raynaud, Y.M. Moustafa, M.A. Elsayed, A.A. Nada, Efficiently activated carbons from corn cob for methylene blue adsorption, Appl. Surf. Sci. Adv. 3 (2021) 100037, https://doi.org/10.1016/j.apsadv.2020.100037. [17] C.M. Kerkhoff, K.d. Boit Martinello, D.S.P. Franco, M.S. Netto, J. Georgin, E.L. Foletto, D.G.A. Piccilli, L.F.O. Silva, G.L. Dotto, Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp, J. Mol. Liq. 339 (2021) 117184, https:// doi.org/10.1016/j.molliq.2021.117184. [18] F.M. Onaga Medina, M.B. Aguiar, M.E. Parolo, M.J. Avena, Insights of competitive adsorption on activated carbon of binary caffeine and diclofenac solutions, J. Environ. Manage. 278 (2021) 111523, https://doi.org/10.1016/ j.jenvman.2020.111523. [19] J. Georgin, G.L. Dotto, M.A. Mazutti, E.L. Foletto, Preparation of activated carbon from peanut shell by conventional pyrolysis and microwave irradiation-pyrolysis to remove organic dyes from aqueous solutions, J. Environ. Chem. Eng. 4 (1) (2016) 266–275. [20] R.L.T. Costa, R.A. do Nascimento, R.C.S. de Araújo, M.G.A. Vieira, M.G.C. da Silva, S.M.L. de Carvalho, L.J.G. de Faria, Removal of non-steroidal anti-inflammatory drugs (NSAIDs) from water with activated carbons synthetized from waste murumuru (Astrocaryum murumuru Mart.): Characterization and adsorption studies, J. Mol. Liq. 343 (2021) 116980, https://doi.org/10.1016/ j.molliq.2021.116980. [21] A. Nasrullah, A.S. Khan, A.H. Bhat, I.U. Din, A. Inayat, N. Muhammad, E.M. Bakhsh, S.B. Khan, Effect of short time ball milling on physicochemical and adsorption performance of activated carbon prepared from mangosteen peel waste, Renew. Energy 168 (2021) 723–733, https://doi.org/10.1016/j. renene.2020.12.077. [22] H.K. Yag˘mur, _ I. Kaya, Synthesis and characterization of magnetic ZnCl2- activated carbon produced from coconut shell for the adsorption of methylene blue, J. Mol. Struct. 1232 (2021) 130071, https://doi.org/10.1016/ j.molstruc.2021.130071. [23] A. Wong, F.M. de Oliveira, C.R.T. Tarley, M., Del Pilar Taboada Sotomayor, Study on the cross-linked molecularly imprinted poly(methacrylic acid) and poly(acrylic acid) towards selective adsorption of diuron, React. Funct. Polym. 100 (2016) 26–36, https://doi.org/10.1016/j. reactfunctpolym.2016.01.006. [24] H. Xue, X. Wang, Q.i. Xu, F. Dhaouadi, L. Sellaoui, M.K. Seliem, A. Ben Lamine, H. Belmabrouk, A. Bajahzar, A. Bonilla-Petriciolet, Z. Li, Q. Li, Adsorption of methylene blue from aqueous solution on activated carbons and composite prepared from an agricultural waste biomass: A comparative study by experimental and advanced modeling analysis, Chem. Eng. J. 430 (2022) 132801, https://doi.org/10.1016/j. cej.2021.132801. [25] I. Anastopoulos, M.J. Ahmed, E.H. Hummadi, Eucalyptus-based materials as adsorbents of heavy metals and dyes pollutants from (waste)waters, J. Mol. Liq. (2022) 118864, https://doi.org/10.1016/j.molliq.2022.118864. [26] I. Anastopoulos, I. Pashalidis, A. Hosseini-Bandegharaei, D.A. Giannakoudakis, A. Robalds, M. Usman, L.B. Escudero, Y. Zhou, J.C. Colmenares, A. NúñezDelgado, É.C. Lima, Agricultural biomass/waste as adsorbents for toxic metal decontamination of aqueous solutions, J. Mol. Liq. 295 (2019) 111684, https:// doi.org/10.1016/j.molliq.2019.111684. [27] H.B. Quesada, T.P. de Araújo, L.F. Cusioli, M.A.S.D. de Barros, R.G. Gomes, R. Bergamasco, Evaluation of novel activated carbons from chichá-do-cerrado (Sterculia striata St. Hil. et Naud) fruit shells on metformin adsorption and treatment of a synthetic mixture, J. Environ. Chem. Eng. 9 (1) (2021) 104914, https://doi.org/10.1016/j.jece:2020.104914. [28] T.H. Do, V.T. Nguyen, N.Q. Dung, M.N. Chu, D. Van Kiet, T.T.K. Ngan, L. Van Tan, Study on methylene blue adsorption of activated carbon made from Moringa oleifera leaf, Mater. Today Proc. 38 (2020) 3405–3413, https://doi.org/ 10.1016/j.matpr.2020.10.834. [29] G.K.P. Lopes, H.G. Zanella, L. Spessato, A. Ronix, P. Viero, J.M. Fonseca, J.T.C. Yokoyama, A.L. Cazetta, V.C. Almeida, Steam-activated carbon from malt bagasse: Optimization of preparation conditions and adsorption studies of sunset yellow food dye, Arab. J. Chem. 14 (3) (2021) 103001, https://doi.org/ 10.1016/j.arabjc.2021.103001. [30] G. Kaur, N. Singh, A. Rajor, Adsorption of doxycycline hydrochloride onto powdered activated carbon synthesized from pumpkin seed shell by microwave-assisted pyrolysis, Environ. Technol. Innov. 23 (2021) 101601, https://doi.org/10.1016/j.eti.2021.101601. [31] Q. Han, J. Wang, B.A. Goodman, J. Xie, Z. Liu, High adsorption of methylene blue by activated carbon prepared from phosphoric acid treated eucalyptus residue, Powder Technol. 366 (2020) 239–248, https://doi.org/10.1016/j. powtec.2020.02.013. [32] M.C. Silva, L. Spessato, T.L. Silva, G.K.P. Lopes, H.G. Zanella, J.T.C. Yokoyama, A.L. Cazetta, V.C. Almeida, H3PO4–activated carbon fibers of high surface area from banana tree pseudo-stem fibers: Adsorption studies of methylene blue dye in batch and fixed bed systems, J. Mol. Liq. 324 (2021) 114771, https://doi.org/ 10.1016/j.molliq.2020.114771. [33] X. Pang, L. Sellaoui, D. Franco, G.L. Dotto, J. Georgin, A. Bajahzar, H. Belmabrouk, A. Ben Lamine, A. Bonilla-Petriciolet, Z. Li, Adsorption of crystal violet on biomasses from pecan nutshell, para chestnut husk, araucaria peel and palm cactus: Experimental study and theoretical modeling via monolayer and double layer statistical physics models, Chem. Eng. J. 378 (2019), https:// doi.org/10.1016/j.cej.2019.122101 122101. [34] X. Pang, L. Sellaoui, D. Franco, M.S. Netto, J. Georgin, G. Luiz Dotto, M.K. Abu Shayeb, H. Belmabrouk, A. Bonilla-Petriciolet, Z. Li, Preparation and characterization of a novel mountain soursop seeds powder adsorbent and its application for the removal of crystal violet and methylene blue from aqueous solutions, Chem. Eng. J. 391 (2020) 123617, https://doi.org/10.1016/j. cej.2019.123617. [35] K. Philippou, I. Anastopoulos, I. Pashalidis, A. Hosseini-Bandegharaei, M. Usman, M. Kornaros, M. Omirou, D. Kalderis, J.V. Milojkovic´, Z.R. Lopicˇic´, M. Abatal, Chapter 6 – The application of pine-based adsorbents to remove potentially toxic elements from aqueous solutions, in: A. Núñez-Delgado (Ed.), Sorbents Mater. Control. Environ. Pollut., Elsevier, 2021, pp. 113–133, https:// doi.org/10.1016/B978-0-12-820042-1.00016-X. [36] I. Anastopoulos, I. Pashalidis, Environmental applications of Luffa cylindricabased adsorbents, J. Mol. Liq. 319 (2020) 114127, https://doi.org/10.1016/ j.molliq.2020.114127. [37] H.Y. Leong, C.W. Ooi, C.L. Law, A.L. Julkifle, G.T. Pan, P.L. Show, Investigation of betacyanins stability from peel and flesh of red-purple pitaya with food additives supplementation and pH treatments, Lwt 98 (2018) 546–558, https://doi.org/10.1016/j.lwt.2018.09.021. [38] Q. Wu, Y. Zhou, Z. Zhang, T. Li, Y. Jiang, H. Gao, Z.e. Yun, Effect of blue light on primary metabolite and volatile compound profiling in the peel of red pitaya, Postharvest Biol. Technol. 160 (2020) 111059, https://doi.org/10.1016/ j.postharvbio.2019.111059. [39] R.S. Bueno, J.B. Ressutte, N.N.Y. Hata, F.C. Henrique-Bana, K.B. Guergoletto, A.G. de Oliveira, W.A. Spinosa, Quality and shelf life assessment of a new beverage produced from water kefir grains and red pitaya, Lwt 140 (2021) 110770, https://doi.org/10.1016/j.lwt.2020.110770. [40] Y. Gong, X. Bi, L. Deng, J. Hu, S. Jiang, L. Tan, T. Wang, X. Luo, Z.B. Xu, D.Q. Chen, J.Y. Liu, Comparative Study on Cold Resistance Physiology of Red Pulp Pitaya and White Pulp Pitaya, E3S Web Conf. 131 (2019) 01113, https://doi.org/ 10.1051/e3sconf/201913101113. [41] Q. Hua, C. Chen, N. Tel Zur, H. Wang, J. Wu, J. Chen, Z. Zhang, J. Zhao, G. Hu, Y. Qin, Metabolomic characterization of pitaya fruit from three red-skinned cultivars with different pulp colors, Plant Physiol. Biochem. 126 (2018) 117– 125, https://doi.org/10.1016/j.plaphy.2018.02.027. [42] D.S. Magalhães, J.D. Ramos, L.A.S. Pio, E.V.D.B. Vilas Boas, M. Pasqual, F.A. Rodrigues, J.C.M. Rufini, V.A.D. Santos, V.A. dos Santos, Physical and physicochemical modifications of white-fleshed pitaya throughout its development, Sci. Hortic. (Amsterdam) 243 (2019) 537–543, https://doi.org/ 10.1016/j.scienta.2018.08.029. [43] S.S. Lam, R.K. Liew, C.K. Cheng, N. Rasit, C.K. Ooi, N.L. Ma, J.H. Ng, W.H. Lam, C.T. Chong, H.A. Chase, Pyrolysis production of fruit peel biochar for potential use in treatment of palm oil mill effluent, J. Environ. Manage. 213 (2018) 400–408, https://doi.org/10.1016/j.jenvman.2018.02.092. [44] T.A. Sial, M.N. Khan, Z. Lan, F. Kumbhar, Z. Ying, J. Zhang, D. Sun, X. Li, Contrasting effects of banana peels waste and its biochar on greenhouse gas emissions and soil biochemical properties, Process Saf. Environ. Prot. 122 (2019) 366–377, https://doi.org/10.1016/j.psep.2018.10.030. [45] L.L. Borges, E.C. Conceição, D. Silveira, Active compounds and medicinal properties of Myrciaria genus, Food Chem. 153 (2014) 224–233, https://doi. org/10.1016/j.foodchem.2013.12.064. [46] A. Gasparotto Junior, P. de Souza, F.A.D.R. Lívero, Plinia cauliflora (Mart.) Kausel: A comprehensive ethnopharmacological review of a genuinely Brazilian species, J. Ethnopharmacol. 245 (2019) 112169, https://doi.org/ 10.1016/j.jep.2019.112169. [47] K.O.P. Inada, A.A. Oliveira, T.B. Revorêdo, A.B.N. Martins, E.C.Q. Lacerda, A.S. Freire, B.F. Braz, R.E. Santelli, A.G. Torres, D. Perrone, M.C. Monteiro, Screening of the chemical composition and occurring antioxidants in jabuticaba (Myrciaria jaboticaba) and jussara (Euterpe edulis) fruits and their fractions, J. Funct. Foods 17 (2015) 422–433, https://doi.org/10.1016/j.jff.2015.06.002. [48] L.O. Stefanello, R. Schwalbert, R.A. Schwalbert, G.L. Drescher, L. De Conti, L.P. Pott, A. Tassinari, M.S.d.S. Kulmann, I.C.B. da Silva, G. Brunetto, Ideal nitrogen concentration in leaves for the production of high-quality grapes cv ‘Alicante Bouschet’ (Vitis vinifera L.) subjected to modes of application and nitrogen doses, Eur. J. Agron. 123 (2021) 126200, https://doi.org/10.1016/j. eja.2020.126200. [49] L.O. Stefanello, R. Schwalbert, R.A. Schwalbert, L. De Conti, M.S.d.S. Kulmann, L. P. Garlet, M.L.R. Silveira, C.K. Sautter, G.W.B. de Melo, D.E. Rozane, G. Brunetto, Nitrogen supply method affects growth, yield and must composition of young grape vines (Vitis vinifera L. cv Alicante Bouschet) in southern Brazil, Sci. Hortic. (Amsterdam) 261 (2020) 108910, https://doi.org/10.1016/ j.scienta.2019.108910. [50] M. Bartoli, L. Rosi, A. Giovannelli, P. Frediani, M. Passaponti, M. Frediani, Microwave assisted pyrolysis of crop residues from Vitis vinifera, J. Anal. Appl. Pyrolysis 130 (2018) 249–255, https://doi.org/10.1016/j.jaap.2017.12.018. [51] M. Khalfaoui, M.H.V. Baouab, R. Gauthier, A., Ben Lamine, Statistical physics modelling of dye adsorption on modified cotton, Adsorpt. Sci. Technol. 20 (2002) 17–32, https://doi.org/10.1260/026361702760120908. [52] S. Knani, M. Mathlouthi, A. Ben Lamine, Modeling of the psychophysical response curves using the grand canonical ensemble in statistical physics, Food Biophys. 2 (4) (2007) 183–192, https://doi.org/10.1007/s11483-007- 9042-7. [53] M. Khalfaoui, M.H.V. Baouab, R. Gauthier, A., Ben Lamine, Dye adsorption by modified cotton. Steric and energetic interpretations of model parameter behaviours, Adsorpt. Sci. Technol. 20 (2002) 33–48, https://doi.org/10.1260/ 026361702760120917. [54] E.C. Lima, A.A. Gomes, H.N. Tran, Comparison of the nonlinear and linear forms of the van’t Hoff equation for calculation of adsorption thermodynamic parameters (DS and DH), J. Mol. Liq. 311 (2020) 113315, https://doi.org/ 10.1016/j.molliq.2020.113315. [55] X. Zhou, Z. Jia, A. Feng, K. Wang, X. Liu, L. Chen, H. Cao, G. Wu, Dependency of tunable electromagnetic wave absorption performance on morphologycontrolled 3D porous carbon fabricated by biomass, Compos. Commun. 21 (2020) 100404, https://doi.org/10.1016/j.coco.2020.100404. [56] O. Üner, Ü. Geçgel, Y. Bayrak, Preparation and characterization of mesoporous activated carbons from waste watermelon rind by using the chemical activation method with zinc chloride, Arab. J. Chem. 12 (8) (2019) 3621– 3627, https://doi.org/10.1016/j.arabjc.2015.12.004 [57] M. Thommes, K. Kaneko, A.V. Neimark, J.P. Olivier, F. Rodriguez-Reinoso, J. Rouquerol, K.S.W. Sing, Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report), Pure Appl. Chem. 87 (2015) 1051–1069, https://doi.org/10.1515/pac-2014- 1117. [58] K.S.W. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984), Pure Appl. Chem. 57 (1985) 603–619, https://doi. org/10.1351/pac198557040603. [59] M. Danish, T. Ahmad, R. Hashim, N. Said, M.N. Akhtar, J. Mohamad-Saleh, O. Sulaiman, Comparison of surface properties of wood biomass activated carbons and their application against rhodamine B and methylene blue dye, Elsevier B.V., 2018, https://doi.org/10.1016/j.surfin.2018.02.001. [60] D.R. Lima, A. Hosseini-Bandegharaei, P.S. Thue, E.C. Lima, Y.R.T. de Albuquerque, G.S. dos Reis, C.S. Umpierres, S.L.P. Dias, H.N. Tran, Efficient acetaminophen removal from water and hospital effluents treatment by activated carbons derived from Brazil nutshells, Colloids Surf. A Physicochem. Eng. Asp. 583 (2019) 123966, https://doi.org/10.1016/ j.colsurfa.2019.123966. [61] M.R. Cunha, E.C. Lima, D.R. Lima, R.S. da Silva, P.S. Thue, M.K. Seliem, F. Sher, G. S. dos Reis, S.H. Larsson, Removal of captopril pharmaceutical from synthetic pharmaceutical-industry wastewaters: Use of activated carbon derived from Butia catarinensis, J. Environ. Chem. Eng. 8 (2020), https://doi.org/10.1016/ j.jece.2020.104506 104506. [62] F.M. Kasperiski, E.C. Lima, C.S. Umpierres, G.S. dos Reis, P.S. Thue, D.R. Lima, S.L. P. Dias, C. Saucier, J.B. da Costa, Production of porous activated carbons from Caesalpinia ferrea seed pod wastes: Highly efficient removal of captopril from aqueous solutions, J. Clean. Prod. 197 (2018) 919–929, https://doi.org/ 10.1016/j.jclepro.2018.06.146. [63] Y.L.D.O. Salomón, J. Georgin, D.S.P. Franco, M.S. Netto, D.G.A. Piccilli, E.L. Foletto, L.F.S. Oliveira, G.L. Dotto, High-performance removal of 2,4- dichlorophenoxyacetic acid herbicide in water using activated carbon derived from Queen palm fruit endocarp (Syagrus romanzoffiana), J. Environ. Chem. Eng. 9 (1) (2021) 104911, https://doi.org/10.1016/j.jece:2020.104911. [64] J. Georgin, Y.L.D.O. Salomón, D.S.P. Franco, M.S. Netto, D.G.A. Piccilli, D. Perondi, L.F.O. Silva, E.L. Foletto, G.L. Dotto, Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen, J. Environ. Chem. Eng. 9 (4) (2021) 105676, https://doi.org/10.1016/j.jece:2021.105676. [65] D.S.P. Franco, J. Georgin, M.S. Netto, D. Allasia, M.L.S. Oliveira, E.L. Foletto, G.L. Dotto, Highly effective adsorption of synthetic phenol effluent by a novel activated carbon prepared from fruit wastes of the Ceiba speciosa forest species, J. Environ. Chem. Eng. 9 (5) (2021) 105927, https://doi.org/10.1016/ j.jece:2021.105927. [66] N. Soltani, A. Bahrami, M.I. Pech-Canul, L.A. González, Review on the physicochemical treatments of rice husk for production of advanced materials, Chem. Eng. J. 264 (2015) 899–935, https://doi.org/10.1016/j. cej.2014.11.056. [67] A.F.M.M. Streit, G.C. Collazzo, S.P. Druzian, R.S. Verdi, E.L. Foletto, L.F.S.S. Oliveira, G.L. Dotto, F.M. Streit, G.C. Collazzo, S.P. Druzian, R.S. Verdi, E.L. Foletto, L.F.S.S. Oliveira, G.L. Dotto, Adsorption of ibuprofen, ketoprofen, and paracetamol onto activated carbon prepared from effluent treatment plant sludge of the beverage industry, Chemosphere 262 (2020), https://doi.org/ 10.1016/j.chemosphere.2020.128322 128322. [68] Y.L. Salomón, J. Georgin, D.S.P. Franco, M.S. Netto, D.G.A. Piccilli, E.L. Foletto, D. Pinto, M.L.S. Oliveira, G.L. Dotto, Adsorption of atrazine herbicide from water by diospyros kaki fruit waste activated carbon, J. Mol. Liq. 347 (2022) 117990, https://doi.org/10.1016/j.molliq.2021.117990. [69] C. Anchieta, A. Cancelier, M. Mazutti, S. Jahn, R. Kuhn, A. Gündel, O. ChiavoneFilho, E. Foletto, Effects of Solvent Diols on the Synthesis of ZnFe2O4 Particles and Their Use as Heterogeneous Photo-Fenton Catalysts, Materials (Basel) 7 (2014) 6281–6290, https://doi.org/10.3390/ma7096281. [70] A. Sionkowska, M. Wisniewski, J. Skopinska, C.J. Kennedy, T.J. Wess, Molecular interactions in collagen and chitosan blends, Biomaterials 25 (2004) 795–801, https://doi.org/10.1016/S0142-9612(03)00595-7. [71] A. Elena, I. Gozescu, A. Dabici, P. Sfirloaga, Z. Szabadai, Organic Compounds FTIR Spectroscopy, in: Macro To Nano Spectrosc, InTech, 2012, https://doi.org/ 10.5772/50183. [72] S. Xue, B. Tu, Z. Li, X. Ma, Y. Xu, M. Li, C. Fang, H. Tao, Enhanced adsorption of Rhodamine B over Zoysia sinica Hance-based carbon activated by amminium chloride and sodium hydroxide treatments, Colloids Surf. A Physicochem. Eng. Asp. 618 (2021) 126489, https://doi.org/10.1016/j.colsurfa.2021.126489. [73] L. Sellaoui, S. Knani, A. Erto, M.A. Hachicha, A., Ben Lamine, Equilibrium isotherm simulation of tetrachlorethylene on activated carbon using the double layer model with two energies: Steric and energetic interpretations, Fluid Phase Equilib. 408 (2016) 259–264, https://doi.org/10.1016/j. fluid.2015.09.022. [74] L. Sellaoui, D.S.P. Franco, G.L. Dotto, É.C. Lima, A. Ben Lamine, Single and binary adsorption of cobalt and methylene blue on modified chitin: Application of the Hill and exclusive extended Hill models, J. Mol. Liq. 233 (2017) 543–550, https://doi.org/10.1016/j.molliq.2016.10.079. [75] A. Yazidi, L. Sellaoui, G.L. Dotto, A. Bonilla-Petriciolet, A.C. Fröhlich, A. Ben Lamine, Monolayer and multilayer adsorption of pharmaceuticals on activated carbon: Application of advanced statistical physics models, J. Mol. Liq. 283 (2019) 276–286, https://doi.org/10.1016/j.molliq.2019.03.101. [76] M. Khalfaoui, A. Nakhli, C. Aguir, A. Omri, M.F. M’henni, A. Ben Lamine, Statistical thermodynamics of adsorption of dye DR75 onto natural materials and its modifications: Double-layer model with two adsorption energies, Environ. Sci. Pollut. Res. 21 (4) (2014) 3134–3144, https://doi.org/10.1007/ s11356-013-2263-z. [77] L. Sellaoui, T. Depci, A.R. Kul, S. Knani, A. Ben Lamine, A new statistical physics model to interpret the binary adsorption isotherms of lead and zinc on activated carbon, J. Mol. Liq. 214 (2016) 220–230, https://doi.org/10.1016/ j.molliq.2015.12.080. [78] S. Knani, M. Khalfaoui, M.A. Hachicha, M. Mathlouthi, A., Ben Lamine, Interpretation of psychophysics response curves using statistical physics, Food Chem. 151 (2014) 487–499, https://doi.org/10.1016/j.foodchem.2013.11.114. [79] A. Nakhli, M. Khalfaoui, C. Aguir, M. Bergaoui, M.F. M’henni, A. Ben Lamine, Statistical Physics Studies of Multilayer Adsorption on Solid Surface: Adsorption of Basic Blue 41 Dye onto Functionalized Posidonia Biomass, Sep. Sci. Technol. 49 (16) (2014) 2525–2533, https://doi.org/10.1080/ 01496395.2014.929703. [80] A. Nakhli, M. Bergaoui, C. Aguir, M. Khalfaoui, M.F. M’henni, A. Ben Lamine, Adsorption thermodynamics in the framework of the statistical physics formalism: basic blue 41 adsorption onto Posidonia biomass, Desalin. Water Treat. 57 (27) (2016) 12730–12742, https://doi.org/10.1080/ 19443994.2015.1052564. [81] M. Bergaoui, C. Aguir, M. Khalfaoui, E. Enciso, L. Duclaux, L. Reinert, J.L.G. Fierro, New insights in the adsorption of Bovine Serum Albumin onto carbon nanoparticles derived from organic resin: Experimental and theoretical studies, Microporous Mesoporous Mater. 241 (2017) 418–428, https://doi. org/10.1016/j.micromeso.2016.12.017. [82] D.R. Delgado, M.A. Ruidiaz, S.M. Gómez, M. Gantiva, F. Martínez, Thermodynamic study of the solubility of sodium naproxen in some ethanol + water mixtures, Quim. Nova. 33 (2010) 1923–1927, https://doi. org/10.1590/S0100-40422010000900019. [83] A.H. Almuqrin, S. Wjihi, F. Aouaini, A.B. Lamine, New insights on physicochemical investigation of bisphosphonate adsorption isotherm into apatite substrate using statistical physics treatment, J. Mol. Liq. 310 (2020) 113230, https://doi.org/10.1016/j.molliq.2020.113230.
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dc.relation.citationissue.spa.fl_str_mv	119021
dc.relation.citationvolume.spa.fl_str_mv	356
dc.rights.eng.fl_str_mv	Copyright 2022 Elsevier B.V., All rights reserved.
dc.rights.license.spa.fl_str_mv	Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)
dc.rights.uri.spa.fl_str_mv	https://creativecommons.org/licenses/by-nc/4.0/
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rights_invalid_str_mv	Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0) Copyright 2022 Elsevier B.V., All rights reserved. https://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2
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dc.format.extent.spa.fl_str_mv	12 páginas
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dc.publisher.spa.fl_str_mv	Elsevier
dc.publisher.place.spa.fl_str_mv	Netherlands
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spelling	Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)Copyright 2022 Elsevier B.V., All rights reserved.https://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Franco, Dison S.P.Georgin, JordanaNetto, Matias S.da Boit Martinello, KatiaSilva, Luis F.O.2024-03-21T14:48:54Z2024-03-21T14:48:54Z2022-06-15Franco, D. S. P., Georgin, J., Netto, M. S., da Boit Martinello, K., & Silva, L. F. O. (2022). Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): Analytical interpretation via statistical physical model. Journal of Molecular Liquids, 356, 119021. https://doi.org/10.1016/j.molliq.2022.1190210167-7322https://hdl.handle.net/11323/1090410.1016/j.molliq.2022.119021Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.coIn this work, physical statistical models were employed to provide reasonable information regarding the adsorption of naproxen onto different activated carbons. The activated carbons were prepared from different biomasses (pitaya peels, jabuticaba peels, or grape residues from the winery process) using ZnCl2 as an activator. All the adsorbents were characterized regarding their functional groups and morphological surfaces. The maximum capacity obtained for the activated carbons (at 328 K) was found to be: 167.0 mg g−1 for jabuticaba peels at pH 4; 158.81 mg g−1 for pitaya peels at pH 6.7; and last., grape residues the capacity was 176.0 mg g−1 at pH 7. The equilibrium data of the three adsorbents were well fitted to the monolayer with two energy sites adsorption model, assuming that NPX adsorption on the carbon surfaces occurs via two different functional groups. This statistical physics model calculated the number of NPX molecules bound on the surface and the saturated adsorption capacity for both functional groups at different temperatures. The obtained results indicate that the naproxen molecules can be adsorbed in a parallel and horizontal manner according to the material employed. The receptor density tends to increase with the temperature evolution, indicating that thermal energy and solubility play an important role in adsorption. Configurational entropy indicates similar thermodynamic behavior for all materials where higher disorder is found at the early stages of the adsorption, followed by and decrease a possible organization of the molecules on the surface. The Gibbs free energy shows that adsorption of naproxen is spontaneous in all cases and internal energy is proportional to the adsorption capacity indicating that the system releases energy as the adsorption occurs. Therefore, this article reports new findings to understand the adsorption mechanism of naproxen molecules on activated carbons prepared from lignocellulosic biomass.12 páginasapplication/pdfengElsevierNetherlandshttps://www.scopus.com/record/display.uri?eid=2-s2.0-85127522740&doi=10.1016%2fj.molliq.2022.119021&origin=inward&txGid=629f3b113236df5362c53d6e8142bd68Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical modelArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Journal of Molecular Liquids[1] S. Terzic´, I. Senta, M. Ahel, M. Gros, M. Petrovic´, D. Barcelo, J. Müller, T. Knepper, I. Martí, F. Ventura, P. Jovancˇic´, D. Jabucˇar, Occurrence and fate of emerging wastewater contaminants in Western Balkan Region, Sci. Total Environ. 399 (1-3) (2008) 66–77, https://doi.org/10.1016/j.scitotenv.2008.03.003.[2] S.L. Rice, S. Mitra, Microwave-assisted solvent extraction of solid matrices and subsequent detection of pharmaceuticals and personal care products (PPCPs) using gas chromatography-mass spectrometry, Anal. Chim. Acta. 589 (1) (2007) 125–132, https://doi.org/10.1016/j.aca.2007.02.051.[3] S. Zhu, Y.-G. Liu, S.-b. Liu, G.-M. Zeng, L.-H. Jiang, X.-F. Tan, L.u. Zhou, W. Zeng, T.-T. Li, C.-P. Yang, Adsorption of emerging contaminant metformin using graphene oxide, Chemosphere 179 (2017) 20–28, https://doi.org/10.1016/j. chemosphere.2017.03.071.[4] H.B. Quesada, A.T.A. Baptista, L.F. Cusioli, D. Seibert, C. de Oliveira Bezerra, R. Bergamasco, Surface water pollution by pharmaceuticals and an alternative of removal by low-cost adsorbents: A review, Chemosphere 222 (2019) 766–780, https://doi.org/10.1016/j.chemosphere.2019.02.009.[5] L. Feng, E.D. van Hullebusch, M.A. Rodrigo, G. Esposito, M.A. Oturan, Removal of residual anti-inflammatory and analgesic pharmaceuticals from aqueous systems by electrochemical advanced oxidation processes. A review, Chem. Eng. J. 228 (2013) 944–964, https://doi.org/10.1016/j.cej.2013.05.061.[6] Y. Shao, Z. Chen, H. Hollert, S. Zhou, B. Deutschmann, T.B. Seiler, Toxicity of 10 organic micropollutants and their mixture: Implications for aquatic risk assessment, Sci. Total Environ. 666 (2019) 1273–1282, https://doi.org/ 10.1016/j.scitotenv.2019.02.047.[7] B. de Diego-Díaz, A. Duran, M.R. Álvarez-García, J. Fernández-Rodríguez, New trends in physicochemical characterization of solid lignocellulosic waste in anaerobic digestion, Fuel 245 (2019) 240–246, https://doi.org/10.1016/ j.fuel.2019.02.051.[8] F. Tomul, Y. Arslan, B. Kabak, D. Trak, E. Kendüzler, E.C. Lima, H.N. Tran, Peanut shells-derived biochars prepared from different carbonization processes: Comparison of characterization and mechanism of naproxen adsorption in water, Sci. Total Environ. 726 (2020) 137828, https://doi.org/10.1016/j. scitotenv.2020.137828.[9] M.H. Ahmad, M. Fatima, M. Hossain, A.C. Mondal, Evaluation of naproxeninduced oxidative stress, hepatotoxicity and in-vivo genotoxicity in male Wistar rats, J. Pharm. Anal. 8 (6) (2018) 400–406, https://doi.org/10.1016/j. jpha.2018.04.002.[10] D. Liu, Y.i. Zhu, Z. Li, D. Tian, L. Chen, P. Chen, Chitin nanofibrils for rapid and efficient removal of metal ions from water system, Carbohydr. Polym. 98 (1) (2013) 483–489, https://doi.org/10.1016/j.carbpol.2013.06.015.[11] L.F. Cusioli, H.B. Quesada, A.L. de Brito Portela Castro, R.G. Gomes, R. Bergamasco, Development of a new low-cost adsorbent functionalized with iron nanoparticles for removal of metformin from contaminated water, Chemosphere 247 (2020) 125852, https://doi.org/10.1016/j. chemosphere.2020.125852.[12] J. Qu, Y. Yuan, Q. Meng, G. Zhang, F. Deng, L. Wang, Y. Tao, Z. Jiang, Y. Zhang, Simultaneously enhanced removal and stepwise recovery of atrazine and Pb (II) from water using b–cyclodextrin functionalized cellulose: Characterization, adsorptive performance and mechanism exploration, J. Hazard. Mater. 400 (2020) 123142, https://doi.org/10.1016/j. jhazmat.2020.123142.[13] L. Sellaoui, A. Yazidi, S. Taamalli, A. Bonilla-Petriciolet, F. Louis, A. El Bakali, M. Badawi, E.C. Lima, D.R. Lima, Z. Chen, Adsorption of 3-aminophenol and resorcinol on avocado seed activated carbon: Mathematical modelling, thermodynamic study and description of adsorbent performance, J. Mol. Liq. 342 (2021) 116952, https://doi.org/10.1016/j.molliq.2021.116952.[14] M. Paredes-Laverde, M. Salamanca, J.D. Diaz-Corrales, E. Flórez, J. Silva-Agredo, R.A. Torres-Palma, Understanding the removal of an anionic dye in textile wastewaters by adsorption on ZnCl2activated carbons from rice and coffee husk wastes: A combined experimental and theoretical study, J. Environ. Chem. Eng. 9 (4) (2021) 105685, https://doi.org/10.1016/j.jece:2021.105685.[15] S.M. Kharrazi, M. Soleimani, M. Jokar, T. Richards, A. Pettersson, N. Mirghaffari, Pretreatment of lignocellulosic waste as a precursor for synthesis of high porous activated carbon and its application for Pb (II) and Cr (VI) adsorption from aqueous solutions, Int. J. Biol. Macromol. 180 (2021) 299–310, https:// doi.org/10.1016/j.ijbiomac.2021.03.078.[16] A. Medhat, H.H. El-Maghrabi, A. Abdelghany, N.M. Abdel Menem, P. Raynaud, Y.M. Moustafa, M.A. Elsayed, A.A. Nada, Efficiently activated carbons from corn cob for methylene blue adsorption, Appl. Surf. Sci. Adv. 3 (2021) 100037, https://doi.org/10.1016/j.apsadv.2020.100037.[17] C.M. Kerkhoff, K.d. Boit Martinello, D.S.P. Franco, M.S. Netto, J. Georgin, E.L. Foletto, D.G.A. Piccilli, L.F.O. Silva, G.L. Dotto, Adsorption of ketoprofen and paracetamol and treatment of a synthetic mixture by novel porous carbon derived from Butia capitata endocarp, J. Mol. Liq. 339 (2021) 117184, https:// doi.org/10.1016/j.molliq.2021.117184.[18] F.M. Onaga Medina, M.B. Aguiar, M.E. Parolo, M.J. Avena, Insights of competitive adsorption on activated carbon of binary caffeine and diclofenac solutions, J. Environ. Manage. 278 (2021) 111523, https://doi.org/10.1016/ j.jenvman.2020.111523.[19] J. Georgin, G.L. Dotto, M.A. Mazutti, E.L. Foletto, Preparation of activated carbon from peanut shell by conventional pyrolysis and microwave irradiation-pyrolysis to remove organic dyes from aqueous solutions, J. Environ. Chem. Eng. 4 (1) (2016) 266–275.[20] R.L.T. Costa, R.A. do Nascimento, R.C.S. de Araújo, M.G.A. Vieira, M.G.C. da Silva, S.M.L. de Carvalho, L.J.G. de Faria, Removal of non-steroidal anti-inflammatory drugs (NSAIDs) from water with activated carbons synthetized from waste murumuru (Astrocaryum murumuru Mart.): Characterization and adsorption studies, J. Mol. Liq. 343 (2021) 116980, https://doi.org/10.1016/ j.molliq.2021.116980.[21] A. Nasrullah, A.S. Khan, A.H. Bhat, I.U. Din, A. Inayat, N. Muhammad, E.M. Bakhsh, S.B. Khan, Effect of short time ball milling on physicochemical and adsorption performance of activated carbon prepared from mangosteen peel waste, Renew. Energy 168 (2021) 723–733, https://doi.org/10.1016/j. renene.2020.12.077.[22] H.K. Yag˘mur, _ I. Kaya, Synthesis and characterization of magnetic ZnCl2- activated carbon produced from coconut shell for the adsorption of methylene blue, J. Mol. Struct. 1232 (2021) 130071, https://doi.org/10.1016/ j.molstruc.2021.130071.[23] A. Wong, F.M. de Oliveira, C.R.T. Tarley, M., Del Pilar Taboada Sotomayor, Study on the cross-linked molecularly imprinted poly(methacrylic acid) and poly(acrylic acid) towards selective adsorption of diuron, React. Funct. Polym. 100 (2016) 26–36, https://doi.org/10.1016/j. reactfunctpolym.2016.01.006.[24] H. Xue, X. Wang, Q.i. Xu, F. Dhaouadi, L. Sellaoui, M.K. Seliem, A. Ben Lamine, H. Belmabrouk, A. Bajahzar, A. Bonilla-Petriciolet, Z. Li, Q. Li, Adsorption of methylene blue from aqueous solution on activated carbons and composite prepared from an agricultural waste biomass: A comparative study by experimental and advanced modeling analysis, Chem. Eng. J. 430 (2022) 132801, https://doi.org/10.1016/j. cej.2021.132801.[25] I. Anastopoulos, M.J. Ahmed, E.H. Hummadi, Eucalyptus-based materials as adsorbents of heavy metals and dyes pollutants from (waste)waters, J. Mol. Liq. (2022) 118864, https://doi.org/10.1016/j.molliq.2022.118864.[26] I. Anastopoulos, I. Pashalidis, A. Hosseini-Bandegharaei, D.A. Giannakoudakis, A. Robalds, M. Usman, L.B. Escudero, Y. Zhou, J.C. Colmenares, A. NúñezDelgado, É.C. Lima, Agricultural biomass/waste as adsorbents for toxic metal decontamination of aqueous solutions, J. Mol. Liq. 295 (2019) 111684, https:// doi.org/10.1016/j.molliq.2019.111684.[27] H.B. Quesada, T.P. de Araújo, L.F. Cusioli, M.A.S.D. de Barros, R.G. Gomes, R. Bergamasco, Evaluation of novel activated carbons from chichá-do-cerrado (Sterculia striata St. Hil. et Naud) fruit shells on metformin adsorption and treatment of a synthetic mixture, J. Environ. Chem. Eng. 9 (1) (2021) 104914, https://doi.org/10.1016/j.jece:2020.104914.[28] T.H. Do, V.T. Nguyen, N.Q. Dung, M.N. Chu, D. Van Kiet, T.T.K. Ngan, L. Van Tan, Study on methylene blue adsorption of activated carbon made from Moringa oleifera leaf, Mater. Today Proc. 38 (2020) 3405–3413, https://doi.org/ 10.1016/j.matpr.2020.10.834.[29] G.K.P. Lopes, H.G. Zanella, L. Spessato, A. Ronix, P. Viero, J.M. Fonseca, J.T.C. Yokoyama, A.L. Cazetta, V.C. Almeida, Steam-activated carbon from malt bagasse: Optimization of preparation conditions and adsorption studies of sunset yellow food dye, Arab. J. Chem. 14 (3) (2021) 103001, https://doi.org/ 10.1016/j.arabjc.2021.103001.[30] G. Kaur, N. Singh, A. Rajor, Adsorption of doxycycline hydrochloride onto powdered activated carbon synthesized from pumpkin seed shell by microwave-assisted pyrolysis, Environ. Technol. Innov. 23 (2021) 101601, https://doi.org/10.1016/j.eti.2021.101601.[31] Q. Han, J. Wang, B.A. Goodman, J. Xie, Z. Liu, High adsorption of methylene blue by activated carbon prepared from phosphoric acid treated eucalyptus residue, Powder Technol. 366 (2020) 239–248, https://doi.org/10.1016/j. powtec.2020.02.013.[32] M.C. Silva, L. Spessato, T.L. Silva, G.K.P. Lopes, H.G. Zanella, J.T.C. Yokoyama, A.L. Cazetta, V.C. Almeida, H3PO4–activated carbon fibers of high surface area from banana tree pseudo-stem fibers: Adsorption studies of methylene blue dye in batch and fixed bed systems, J. Mol. Liq. 324 (2021) 114771, https://doi.org/ 10.1016/j.molliq.2020.114771.[33] X. Pang, L. Sellaoui, D. Franco, G.L. Dotto, J. Georgin, A. Bajahzar, H. Belmabrouk, A. Ben Lamine, A. Bonilla-Petriciolet, Z. Li, Adsorption of crystal violet on biomasses from pecan nutshell, para chestnut husk, araucaria peel and palm cactus: Experimental study and theoretical modeling via monolayer and double layer statistical physics models, Chem. Eng. J. 378 (2019), https:// doi.org/10.1016/j.cej.2019.122101 122101.[34] X. Pang, L. Sellaoui, D. Franco, M.S. Netto, J. Georgin, G. Luiz Dotto, M.K. Abu Shayeb, H. Belmabrouk, A. Bonilla-Petriciolet, Z. Li, Preparation and characterization of a novel mountain soursop seeds powder adsorbent and its application for the removal of crystal violet and methylene blue from aqueous solutions, Chem. Eng. J. 391 (2020) 123617, https://doi.org/10.1016/j. cej.2019.123617.[35] K. Philippou, I. Anastopoulos, I. Pashalidis, A. Hosseini-Bandegharaei, M. Usman, M. Kornaros, M. Omirou, D. Kalderis, J.V. Milojkovic´, Z.R. Lopicˇic´, M. Abatal, Chapter 6 – The application of pine-based adsorbents to remove potentially toxic elements from aqueous solutions, in: A. Núñez-Delgado (Ed.), Sorbents Mater. Control. Environ. Pollut., Elsevier, 2021, pp. 113–133, https:// doi.org/10.1016/B978-0-12-820042-1.00016-X.[36] I. Anastopoulos, I. Pashalidis, Environmental applications of Luffa cylindricabased adsorbents, J. Mol. Liq. 319 (2020) 114127, https://doi.org/10.1016/ j.molliq.2020.114127.[37] H.Y. Leong, C.W. Ooi, C.L. Law, A.L. Julkifle, G.T. Pan, P.L. Show, Investigation of betacyanins stability from peel and flesh of red-purple pitaya with food additives supplementation and pH treatments, Lwt 98 (2018) 546–558, https://doi.org/10.1016/j.lwt.2018.09.021.[38] Q. Wu, Y. Zhou, Z. Zhang, T. Li, Y. Jiang, H. Gao, Z.e. Yun, Effect of blue light on primary metabolite and volatile compound profiling in the peel of red pitaya, Postharvest Biol. Technol. 160 (2020) 111059, https://doi.org/10.1016/ j.postharvbio.2019.111059.[39] R.S. Bueno, J.B. Ressutte, N.N.Y. Hata, F.C. Henrique-Bana, K.B. Guergoletto, A.G. de Oliveira, W.A. Spinosa, Quality and shelf life assessment of a new beverage produced from water kefir grains and red pitaya, Lwt 140 (2021) 110770, https://doi.org/10.1016/j.lwt.2020.110770.[40] Y. Gong, X. Bi, L. Deng, J. Hu, S. Jiang, L. Tan, T. Wang, X. Luo, Z.B. Xu, D.Q. Chen, J.Y. Liu, Comparative Study on Cold Resistance Physiology of Red Pulp Pitaya and White Pulp Pitaya, E3S Web Conf. 131 (2019) 01113, https://doi.org/ 10.1051/e3sconf/201913101113.[41] Q. Hua, C. Chen, N. Tel Zur, H. Wang, J. Wu, J. Chen, Z. Zhang, J. Zhao, G. Hu, Y. Qin, Metabolomic characterization of pitaya fruit from three red-skinned cultivars with different pulp colors, Plant Physiol. Biochem. 126 (2018) 117– 125, https://doi.org/10.1016/j.plaphy.2018.02.027.[42] D.S. Magalhães, J.D. Ramos, L.A.S. Pio, E.V.D.B. Vilas Boas, M. Pasqual, F.A. Rodrigues, J.C.M. Rufini, V.A.D. Santos, V.A. dos Santos, Physical and physicochemical modifications of white-fleshed pitaya throughout its development, Sci. Hortic. (Amsterdam) 243 (2019) 537–543, https://doi.org/ 10.1016/j.scienta.2018.08.029.[43] S.S. Lam, R.K. Liew, C.K. Cheng, N. Rasit, C.K. Ooi, N.L. Ma, J.H. Ng, W.H. Lam, C.T. Chong, H.A. Chase, Pyrolysis production of fruit peel biochar for potential use in treatment of palm oil mill effluent, J. Environ. Manage. 213 (2018) 400–408, https://doi.org/10.1016/j.jenvman.2018.02.092.[44] T.A. Sial, M.N. Khan, Z. Lan, F. Kumbhar, Z. Ying, J. Zhang, D. Sun, X. Li, Contrasting effects of banana peels waste and its biochar on greenhouse gas emissions and soil biochemical properties, Process Saf. Environ. Prot. 122 (2019) 366–377, https://doi.org/10.1016/j.psep.2018.10.030.[45] L.L. Borges, E.C. Conceição, D. Silveira, Active compounds and medicinal properties of Myrciaria genus, Food Chem. 153 (2014) 224–233, https://doi. org/10.1016/j.foodchem.2013.12.064.[46] A. Gasparotto Junior, P. de Souza, F.A.D.R. Lívero, Plinia cauliflora (Mart.) Kausel: A comprehensive ethnopharmacological review of a genuinely Brazilian species, J. Ethnopharmacol. 245 (2019) 112169, https://doi.org/ 10.1016/j.jep.2019.112169.[47] K.O.P. Inada, A.A. Oliveira, T.B. Revorêdo, A.B.N. Martins, E.C.Q. Lacerda, A.S. Freire, B.F. Braz, R.E. Santelli, A.G. Torres, D. Perrone, M.C. Monteiro, Screening of the chemical composition and occurring antioxidants in jabuticaba (Myrciaria jaboticaba) and jussara (Euterpe edulis) fruits and their fractions, J. Funct. Foods 17 (2015) 422–433, https://doi.org/10.1016/j.jff.2015.06.002.[48] L.O. Stefanello, R. Schwalbert, R.A. Schwalbert, G.L. Drescher, L. De Conti, L.P. Pott, A. Tassinari, M.S.d.S. Kulmann, I.C.B. da Silva, G. Brunetto, Ideal nitrogen concentration in leaves for the production of high-quality grapes cv ‘Alicante Bouschet’ (Vitis vinifera L.) subjected to modes of application and nitrogen doses, Eur. J. Agron. 123 (2021) 126200, https://doi.org/10.1016/j. eja.2020.126200.[49] L.O. Stefanello, R. Schwalbert, R.A. Schwalbert, L. De Conti, M.S.d.S. Kulmann, L. P. Garlet, M.L.R. Silveira, C.K. Sautter, G.W.B. de Melo, D.E. Rozane, G. Brunetto, Nitrogen supply method affects growth, yield and must composition of young grape vines (Vitis vinifera L. cv Alicante Bouschet) in southern Brazil, Sci. Hortic. (Amsterdam) 261 (2020) 108910, https://doi.org/10.1016/ j.scienta.2019.108910.[50] M. Bartoli, L. Rosi, A. Giovannelli, P. Frediani, M. Passaponti, M. Frediani, Microwave assisted pyrolysis of crop residues from Vitis vinifera, J. Anal. Appl. Pyrolysis 130 (2018) 249–255, https://doi.org/10.1016/j.jaap.2017.12.018.[51] M. Khalfaoui, M.H.V. Baouab, R. Gauthier, A., Ben Lamine, Statistical physics modelling of dye adsorption on modified cotton, Adsorpt. Sci. Technol. 20 (2002) 17–32, https://doi.org/10.1260/026361702760120908.[52] S. Knani, M. Mathlouthi, A. Ben Lamine, Modeling of the psychophysical response curves using the grand canonical ensemble in statistical physics, Food Biophys. 2 (4) (2007) 183–192, https://doi.org/10.1007/s11483-007- 9042-7.[53] M. Khalfaoui, M.H.V. Baouab, R. Gauthier, A., Ben Lamine, Dye adsorption by modified cotton. Steric and energetic interpretations of model parameter behaviours, Adsorpt. Sci. Technol. 20 (2002) 33–48, https://doi.org/10.1260/ 026361702760120917.[54] E.C. Lima, A.A. Gomes, H.N. Tran, Comparison of the nonlinear and linear forms of the van’t Hoff equation for calculation of adsorption thermodynamic parameters (DS and DH), J. Mol. Liq. 311 (2020) 113315, https://doi.org/ 10.1016/j.molliq.2020.113315.[55] X. Zhou, Z. Jia, A. Feng, K. Wang, X. Liu, L. Chen, H. Cao, G. Wu, Dependency of tunable electromagnetic wave absorption performance on morphologycontrolled 3D porous carbon fabricated by biomass, Compos. Commun. 21 (2020) 100404, https://doi.org/10.1016/j.coco.2020.100404.[56] O. Üner, Ü. Geçgel, Y. Bayrak, Preparation and characterization of mesoporous activated carbons from waste watermelon rind by using the chemical activation method with zinc chloride, Arab. J. Chem. 12 (8) (2019) 3621– 3627, https://doi.org/10.1016/j.arabjc.2015.12.004[57] M. Thommes, K. Kaneko, A.V. Neimark, J.P. Olivier, F. Rodriguez-Reinoso, J. Rouquerol, K.S.W. Sing, Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report), Pure Appl. Chem. 87 (2015) 1051–1069, https://doi.org/10.1515/pac-2014- 1117.[58] K.S.W. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984), Pure Appl. Chem. 57 (1985) 603–619, https://doi. org/10.1351/pac198557040603.[59] M. Danish, T. Ahmad, R. Hashim, N. Said, M.N. Akhtar, J. Mohamad-Saleh, O. Sulaiman, Comparison of surface properties of wood biomass activated carbons and their application against rhodamine B and methylene blue dye, Elsevier B.V., 2018, https://doi.org/10.1016/j.surfin.2018.02.001.[60] D.R. Lima, A. Hosseini-Bandegharaei, P.S. Thue, E.C. Lima, Y.R.T. de Albuquerque, G.S. dos Reis, C.S. Umpierres, S.L.P. Dias, H.N. Tran, Efficient acetaminophen removal from water and hospital effluents treatment by activated carbons derived from Brazil nutshells, Colloids Surf. A Physicochem. Eng. Asp. 583 (2019) 123966, https://doi.org/10.1016/ j.colsurfa.2019.123966.[61] M.R. Cunha, E.C. Lima, D.R. Lima, R.S. da Silva, P.S. Thue, M.K. Seliem, F. Sher, G. S. dos Reis, S.H. Larsson, Removal of captopril pharmaceutical from synthetic pharmaceutical-industry wastewaters: Use of activated carbon derived from Butia catarinensis, J. Environ. Chem. Eng. 8 (2020), https://doi.org/10.1016/ j.jece.2020.104506 104506.[62] F.M. Kasperiski, E.C. Lima, C.S. Umpierres, G.S. dos Reis, P.S. Thue, D.R. Lima, S.L. P. Dias, C. Saucier, J.B. da Costa, Production of porous activated carbons from Caesalpinia ferrea seed pod wastes: Highly efficient removal of captopril from aqueous solutions, J. Clean. Prod. 197 (2018) 919–929, https://doi.org/ 10.1016/j.jclepro.2018.06.146.[63] Y.L.D.O. Salomón, J. Georgin, D.S.P. Franco, M.S. Netto, D.G.A. Piccilli, E.L. Foletto, L.F.S. Oliveira, G.L. Dotto, High-performance removal of 2,4- dichlorophenoxyacetic acid herbicide in water using activated carbon derived from Queen palm fruit endocarp (Syagrus romanzoffiana), J. Environ. Chem. Eng. 9 (1) (2021) 104911, https://doi.org/10.1016/j.jece:2020.104911.[64] J. Georgin, Y.L.D.O. Salomón, D.S.P. Franco, M.S. Netto, D.G.A. Piccilli, D. Perondi, L.F.O. Silva, E.L. Foletto, G.L. Dotto, Development of highly porous activated carbon from Jacaranda mimosifolia seed pods for remarkable removal of aqueous-phase ketoprofen, J. Environ. Chem. Eng. 9 (4) (2021) 105676, https://doi.org/10.1016/j.jece:2021.105676.[65] D.S.P. Franco, J. Georgin, M.S. Netto, D. Allasia, M.L.S. Oliveira, E.L. Foletto, G.L. Dotto, Highly effective adsorption of synthetic phenol effluent by a novel activated carbon prepared from fruit wastes of the Ceiba speciosa forest species, J. Environ. Chem. Eng. 9 (5) (2021) 105927, https://doi.org/10.1016/ j.jece:2021.105927.[66] N. Soltani, A. Bahrami, M.I. Pech-Canul, L.A. González, Review on the physicochemical treatments of rice husk for production of advanced materials, Chem. Eng. J. 264 (2015) 899–935, https://doi.org/10.1016/j. cej.2014.11.056.[67] A.F.M.M. Streit, G.C. Collazzo, S.P. Druzian, R.S. Verdi, E.L. Foletto, L.F.S.S. Oliveira, G.L. Dotto, F.M. Streit, G.C. Collazzo, S.P. Druzian, R.S. Verdi, E.L. Foletto, L.F.S.S. Oliveira, G.L. Dotto, Adsorption of ibuprofen, ketoprofen, and paracetamol onto activated carbon prepared from effluent treatment plant sludge of the beverage industry, Chemosphere 262 (2020), https://doi.org/ 10.1016/j.chemosphere.2020.128322 128322.[68] Y.L. Salomón, J. Georgin, D.S.P. Franco, M.S. Netto, D.G.A. Piccilli, E.L. Foletto, D. Pinto, M.L.S. Oliveira, G.L. Dotto, Adsorption of atrazine herbicide from water by diospyros kaki fruit waste activated carbon, J. Mol. Liq. 347 (2022) 117990, https://doi.org/10.1016/j.molliq.2021.117990.[69] C. Anchieta, A. Cancelier, M. Mazutti, S. Jahn, R. Kuhn, A. Gündel, O. ChiavoneFilho, E. Foletto, Effects of Solvent Diols on the Synthesis of ZnFe2O4 Particles and Their Use as Heterogeneous Photo-Fenton Catalysts, Materials (Basel) 7 (2014) 6281–6290, https://doi.org/10.3390/ma7096281.[70] A. Sionkowska, M. Wisniewski, J. Skopinska, C.J. Kennedy, T.J. Wess, Molecular interactions in collagen and chitosan blends, Biomaterials 25 (2004) 795–801, https://doi.org/10.1016/S0142-9612(03)00595-7.[71] A. Elena, I. Gozescu, A. Dabici, P. Sfirloaga, Z. Szabadai, Organic Compounds FTIR Spectroscopy, in: Macro To Nano Spectrosc, InTech, 2012, https://doi.org/ 10.5772/50183.[72] S. Xue, B. Tu, Z. Li, X. Ma, Y. Xu, M. Li, C. Fang, H. Tao, Enhanced adsorption of Rhodamine B over Zoysia sinica Hance-based carbon activated by amminium chloride and sodium hydroxide treatments, Colloids Surf. A Physicochem. Eng. Asp. 618 (2021) 126489, https://doi.org/10.1016/j.colsurfa.2021.126489.[73] L. Sellaoui, S. Knani, A. Erto, M.A. Hachicha, A., Ben Lamine, Equilibrium isotherm simulation of tetrachlorethylene on activated carbon using the double layer model with two energies: Steric and energetic interpretations, Fluid Phase Equilib. 408 (2016) 259–264, https://doi.org/10.1016/j. fluid.2015.09.022.[74] L. Sellaoui, D.S.P. Franco, G.L. Dotto, É.C. Lima, A. Ben Lamine, Single and binary adsorption of cobalt and methylene blue on modified chitin: Application of the Hill and exclusive extended Hill models, J. Mol. Liq. 233 (2017) 543–550, https://doi.org/10.1016/j.molliq.2016.10.079.[75] A. Yazidi, L. Sellaoui, G.L. Dotto, A. Bonilla-Petriciolet, A.C. Fröhlich, A. Ben Lamine, Monolayer and multilayer adsorption of pharmaceuticals on activated carbon: Application of advanced statistical physics models, J. Mol. Liq. 283 (2019) 276–286, https://doi.org/10.1016/j.molliq.2019.03.101.[76] M. Khalfaoui, A. Nakhli, C. Aguir, A. Omri, M.F. M’henni, A. Ben Lamine, Statistical thermodynamics of adsorption of dye DR75 onto natural materials and its modifications: Double-layer model with two adsorption energies, Environ. Sci. Pollut. Res. 21 (4) (2014) 3134–3144, https://doi.org/10.1007/ s11356-013-2263-z.[77] L. Sellaoui, T. Depci, A.R. Kul, S. Knani, A. Ben Lamine, A new statistical physics model to interpret the binary adsorption isotherms of lead and zinc on activated carbon, J. Mol. Liq. 214 (2016) 220–230, https://doi.org/10.1016/ j.molliq.2015.12.080.[78] S. Knani, M. Khalfaoui, M.A. Hachicha, M. Mathlouthi, A., Ben Lamine, Interpretation of psychophysics response curves using statistical physics, Food Chem. 151 (2014) 487–499, https://doi.org/10.1016/j.foodchem.2013.11.114.[79] A. Nakhli, M. Khalfaoui, C. Aguir, M. Bergaoui, M.F. M’henni, A. Ben Lamine, Statistical Physics Studies of Multilayer Adsorption on Solid Surface: Adsorption of Basic Blue 41 Dye onto Functionalized Posidonia Biomass, Sep. Sci. Technol. 49 (16) (2014) 2525–2533, https://doi.org/10.1080/ 01496395.2014.929703.[80] A. Nakhli, M. Bergaoui, C. Aguir, M. Khalfaoui, M.F. M’henni, A. Ben Lamine, Adsorption thermodynamics in the framework of the statistical physics formalism: basic blue 41 adsorption onto Posidonia biomass, Desalin. Water Treat. 57 (27) (2016) 12730–12742, https://doi.org/10.1080/ 19443994.2015.1052564.[81] M. Bergaoui, C. Aguir, M. Khalfaoui, E. Enciso, L. Duclaux, L. Reinert, J.L.G. Fierro, New insights in the adsorption of Bovine Serum Albumin onto carbon nanoparticles derived from organic resin: Experimental and theoretical studies, Microporous Mesoporous Mater. 241 (2017) 418–428, https://doi. org/10.1016/j.micromeso.2016.12.017.[82] D.R. Delgado, M.A. Ruidiaz, S.M. Gómez, M. Gantiva, F. Martínez, Thermodynamic study of the solubility of sodium naproxen in some ethanol + water mixtures, Quim. Nova. 33 (2010) 1923–1927, https://doi. org/10.1590/S0100-40422010000900019.[83] A.H. Almuqrin, S. Wjihi, F. Aouaini, A.B. Lamine, New insights on physicochemical investigation of bisphosphonate adsorption isotherm into apatite substrate using statistical physics treatment, J. Mol. Liq. 310 (2020) 113230, https://doi.org/10.1016/j.molliq.2020.113230.121119021356Activated carbonsAdsorption modelingNaproxenPhysics statisticsPublicationORIGINALPreparation of activated carbons from fruit residues for the removal of.pdfPreparation of activated carbons from fruit residues for the removal of.pdfArtículoapplication/pdf970071https://repositorio.cuc.edu.co/bitstreams/a42cab65-a9d0-40ff-a4dc-5c84f31dfd72/download172a582ce1f7215678e4884b50cf4509MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstreams/bb477331-255d-4998-9d71-2b12bffc3798/download2f9959eaf5b71fae44bbf9ec84150c7aMD52TEXTPreparation of activated carbons from fruit residues for the removal of.pdf.txtPreparation of activated carbons from fruit residues for the removal of.pdf.txtExtracted texttext/plain66570https://repositorio.cuc.edu.co/bitstreams/36eeb402-d286-481c-ab93-6c6177bcfa1f/downloada2ab019312c606ac1d30e57f2b8a7129MD53THUMBNAILPreparation of activated 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ada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.


Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): analytical interpretation via statistical physical model

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