Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin

Wastes from the Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds were studied as biosorbents for the removal of basic fuchsin from waters. Both biosorbents were prepared and characterized by different analytical methods. The characterization data showed...

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Autores:
de O. Salomón, Yamil L.
georgin, jordana
Reis, Glaydson
Lima, Éder Claudio
S. Oliveira, Marcos L
Franco, Dison
Schadeck Netto, Matias
Allasia, Daniel
Dotto, Guilherme Luiz
Tipo de recurso:
http://purl.org/coar/resource_type/c_816b
Fecha de publicación:
2020
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
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oai:repositorio.cuc.edu.co:11323/7033
Acceso en línea:
https://hdl.handle.net/11323/7033
https://repositorio.cuc.edu.co/
Palabra clave:
Pacara earpod tree seeds
Ironwood
Basic fuchsin from the waters
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closedAccess
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oai_identifier_str oai:repositorio.cuc.edu.co:11323/7033
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.spa.fl_str_mv Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
title Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
spellingShingle Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
Pacara earpod tree seeds
Ironwood
Basic fuchsin from the waters
title_short Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
title_full Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
title_fullStr Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
title_full_unstemmed Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
title_sort Utilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsin
dc.creator.fl_str_mv de O. Salomón, Yamil L.
georgin, jordana
Reis, Glaydson
Lima, Éder Claudio
S. Oliveira, Marcos L
Franco, Dison
Schadeck Netto, Matias
Allasia, Daniel
Dotto, Guilherme Luiz
dc.contributor.author.spa.fl_str_mv de O. Salomón, Yamil L.
georgin, jordana
Reis, Glaydson
Lima, Éder Claudio
S. Oliveira, Marcos L
Franco, Dison
Schadeck Netto, Matias
Allasia, Daniel
Dotto, Guilherme Luiz
dc.subject.spa.fl_str_mv Pacara earpod tree seeds
Ironwood
Basic fuchsin from the waters
topic Pacara earpod tree seeds
Ironwood
Basic fuchsin from the waters
description Wastes from the Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds were studied as biosorbents for the removal of basic fuchsin from waters. Both biosorbents were prepared and characterized by different analytical methods. The characterization data showed that both materials were mainly composed of lignin, cellulose, and hemicellulose. Both biosorbents exhibited roughened surfaces and surface functional groups such as C-H, C=O, C=C, C-O, C-N, and OH bonds. Furthermore, the XRD pattern shows an amorphous phase with a wide peak from 10 to 30° due to the lignin. In terms of dosage and pH, the use of 1 g L−1 and 9.0, respectively, is recommended. The initial concentrations for the biosorption kinetics ranged from 50 to 500 mg L−1, where the Pacara ear and the Ironwood reached an adsorption capacity of 145.62 and 100.743 mg g−1 for the 500 mg L−1. The pseudo-second-order was found to be the proper model for describing biosorption of basic fuchsin onto Pacara Earpod tree and Ironwood, respectively. For the isotherm experiments, the maximum experimental biosorption capacity was found to be 166.858 and 110.317 mg g−1 for the Pacara Earpod and Ironwood for the initial concentration of 500 mg L−1 at 328 K. The Langmuir and the Tóth models were the best for representing the equilibrium curves for the basic fuchsin on the Pacara Earpod and the Ironwood, respectively. Maximum adsorption capacities of 177.084 mg g−1 and 136.526 mg g−1 were achieved for the Pacara Earpod tree and Ironwood, respectively. The biosorption process was spontaneous, endothermic, and favorable for both biosorbents. The biosorbents were also applied for coloration removal of simulated textile effluents, reaching 66% and 54% for the Pacara Earpod and Ironwood, respectively. For the final application, the materials were used in fixed-bed biosorption, with an initial concentration of 200 mg L−1, reaching breakthrough times of 710 and 415 min, leading to biosorption capacities of the column of 124.5 and 76.5 mg g−1, for the Pacara Earpod and Ironwood, respectively.
publishDate 2020
dc.date.accessioned.none.fl_str_mv 2020-08-27T20:23:33Z
dc.date.available.none.fl_str_mv 2020-08-27T20:23:33Z
dc.date.issued.none.fl_str_mv 2020-06-12
dc.type.spa.fl_str_mv Pre-Publicación
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_816b
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/preprint
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ARTOTR
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
format http://purl.org/coar/resource_type/c_816b
status_str acceptedVersion
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/7033
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
url https://hdl.handle.net/11323/7033
https://repositorio.cuc.edu.co/
identifier_str_mv Corporación Universidad de la Costa
REDICUC - Repositorio CUC
dc.language.iso.none.fl_str_mv eng
language eng
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Archin S, Sharifi SH, Asadpour G (2019) Optimization and modeling of simultaneous ultrasound-assisted adsorption of binary dyes using activated carbon from tobacco residues: response surface methodology. J Clean Prod:239
Babalola JO, Koiki BA, Eniayewu Y, Salimonu A, Olowoyo JO, Oninla VO, Omorogie MO (2016a) Adsorption efficacy of Cedrela odorata seed waste for dyes: non-linear fractal kinetics and non-linear equilibrium studies. J Environ Chem Eng 4:3527–3536
Babalola JO, Olowoyo JO, Durojaiye AO, Olatunde AM, Unuabonah EI, Omorogie MO (2016b) Understanding the removal and regeneration potentials of biogenic wastes for toxic metals and organic dyes. J Taiwan Inst Chem Eng 58:490–499
Babalola JO, Bamidele TM, Adeniji EA, Odozi NW, Olatunde AM, Omorogie MO (2016c) Adsorptive modelling of toxic cations and ionic dyes onto cellulosic extract. Model Earth Syst Environ 2:1–15
Babalola JO, Olayiwola FT, Olowoyo JO, Alabi AH, Unuabonah EI, Ofomaja AE, Omorogie MO (2017) Adsorption and desorption kinetics of toxic organic and inorganic ions using an indigenous biomass: Terminalia ivorensis seed waste. Int J Ind Chem 8:207–220
Bohart GS, Adams EQ (1920) Some aspects of the behavior of charcoal with respect to chlorine. J Amer Chem Soc 42:523–544
Carvalho CDO, Costa Rodrigues DL, Lima EC, Umpierres CS, Caicedo Chaguez DF, Machado FM (2019) Kinetic, equilibrium, and, thermodynamic studies on the adsorption of ciprofloxacin by activated carbon produced from Jeriva (Syagrus romanzoffiana). Environ Sci Pollut Res 26:4690–4702
Da Silva DCC, Pietrobelli JMTDA (2019) Residual biomass of chia seeds (Salvia hispanica) oil extraction as low cost and eco-friendly biosorbent for effective reactive yellow B2R textile dye removal: characterization, kinetic, thermodynamic and isotherm studies. J Environ Chem Eng 7:103008
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dos Reis GS, Cazacliu BG, Correa CR, Ovsyannikova E, Kruse A, Sampaio CH, Lima EC, Dotto GL (2020b) Adsorption and recovery of phosphate from aqueous solution by the construction and demolition wastes sludge and its potential use as phosphate-based fertilizer. J Environ Chem Eng 8:103605
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Georgin J, Drumm FC, Grassi P, Franco D, Allasia D, Dotto GL (2018) Potential of Araucaria angustifolia bark as adsorbent to remove gentian violet dye from aqueous effluents. Water Sci Technol 78:1693–1703
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dc.source.spa.fl_str_mv Environmental Science and Pollution Research
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spelling de O. Salomón, Yamil L.georgin, jordanaReis, GlaydsonLima, Éder ClaudioS. Oliveira, Marcos LFranco, DisonSchadeck Netto, MatiasAllasia, DanielDotto, Guilherme Luiz2020-08-27T20:23:33Z2020-08-27T20:23:33Z2020-06-12https://hdl.handle.net/11323/7033Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Wastes from the Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds were studied as biosorbents for the removal of basic fuchsin from waters. Both biosorbents were prepared and characterized by different analytical methods. The characterization data showed that both materials were mainly composed of lignin, cellulose, and hemicellulose. Both biosorbents exhibited roughened surfaces and surface functional groups such as C-H, C=O, C=C, C-O, C-N, and OH bonds. Furthermore, the XRD pattern shows an amorphous phase with a wide peak from 10 to 30° due to the lignin. In terms of dosage and pH, the use of 1 g L−1 and 9.0, respectively, is recommended. The initial concentrations for the biosorption kinetics ranged from 50 to 500 mg L−1, where the Pacara ear and the Ironwood reached an adsorption capacity of 145.62 and 100.743 mg g−1 for the 500 mg L−1. The pseudo-second-order was found to be the proper model for describing biosorption of basic fuchsin onto Pacara Earpod tree and Ironwood, respectively. For the isotherm experiments, the maximum experimental biosorption capacity was found to be 166.858 and 110.317 mg g−1 for the Pacara Earpod and Ironwood for the initial concentration of 500 mg L−1 at 328 K. The Langmuir and the Tóth models were the best for representing the equilibrium curves for the basic fuchsin on the Pacara Earpod and the Ironwood, respectively. Maximum adsorption capacities of 177.084 mg g−1 and 136.526 mg g−1 were achieved for the Pacara Earpod tree and Ironwood, respectively. The biosorption process was spontaneous, endothermic, and favorable for both biosorbents. The biosorbents were also applied for coloration removal of simulated textile effluents, reaching 66% and 54% for the Pacara Earpod and Ironwood, respectively. For the final application, the materials were used in fixed-bed biosorption, with an initial concentration of 200 mg L−1, reaching breakthrough times of 710 and 415 min, leading to biosorption capacities of the column of 124.5 and 76.5 mg g−1, for the Pacara Earpod and Ironwood, respectively.de O. Salomón, Yamil L.georgin, jordana-will be generated-orcid-0000-0003-1692-565X-600Reis, Glaydson-will be generated-orcid-0000-0002-9493-7317-600Lima, Éder ClaudioS. Oliveira, Marcos LFranco, Dison-will be generated-orcid-0000-0003-3672-998X-600Schadeck Netto, Matias-will be generated-orcid-0000-0002-0479-1220-600Allasia, DanielDotto, Guilherme Luiz-will be generated-orcid-0000-0002-4413-8138-600engCorporación Universidad de la CostaCC0 1.0 Universalhttp://creativecommons.org/publicdomain/zero/1.0/info:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbEnvironmental Science and Pollution Researchhttps://link.springer.com/article/10.1007/s11356-020-09471-zPacara earpod tree seedsIronwoodBasic fuchsin from the watersUtilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsinPre-Publicaciónhttp://purl.org/coar/resource_type/c_816bTextinfo:eu-repo/semantics/preprinthttp://purl.org/redcol/resource_type/ARTOTRinfo:eu-repo/semantics/acceptedVersionAksu Z, Tatli AI, Tunç Ö (2008) A comparative adsorption/biosorption study of Acid Blue 161: effect of temperature on equilibrium and kinetic parameters. Chem Eng J 142:23–39Archin S, Sharifi SH, Asadpour G (2019) Optimization and modeling of simultaneous ultrasound-assisted adsorption of binary dyes using activated carbon from tobacco residues: response surface methodology. J Clean Prod:239Babalola JO, Koiki BA, Eniayewu Y, Salimonu A, Olowoyo JO, Oninla VO, Omorogie MO (2016a) Adsorption efficacy of Cedrela odorata seed waste for dyes: non-linear fractal kinetics and non-linear equilibrium studies. J Environ Chem Eng 4:3527–3536Babalola JO, Olowoyo JO, Durojaiye AO, Olatunde AM, Unuabonah EI, Omorogie MO (2016b) Understanding the removal and regeneration potentials of biogenic wastes for toxic metals and organic dyes. J Taiwan Inst Chem Eng 58:490–499Babalola JO, Bamidele TM, Adeniji EA, Odozi NW, Olatunde AM, Omorogie MO (2016c) Adsorptive modelling of toxic cations and ionic dyes onto cellulosic extract. Model Earth Syst Environ 2:1–15Babalola JO, Olayiwola FT, Olowoyo JO, Alabi AH, Unuabonah EI, Ofomaja AE, Omorogie MO (2017) Adsorption and desorption kinetics of toxic organic and inorganic ions using an indigenous biomass: Terminalia ivorensis seed waste. Int J Ind Chem 8:207–220Bohart GS, Adams EQ (1920) Some aspects of the behavior of charcoal with respect to chlorine. J Amer Chem Soc 42:523–544Carvalho CDO, Costa Rodrigues DL, Lima EC, Umpierres CS, Caicedo Chaguez DF, Machado FM (2019) Kinetic, equilibrium, and, thermodynamic studies on the adsorption of ciprofloxacin by activated carbon produced from Jeriva (Syagrus romanzoffiana). Environ Sci Pollut Res 26:4690–4702Da Silva DCC, Pietrobelli JMTDA (2019) Residual biomass of chia seeds (Salvia hispanica) oil extraction as low cost and eco-friendly biosorbent for effective reactive yellow B2R textile dye removal: characterization, kinetic, thermodynamic and isotherm studies. 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J Iranian Chem Soc 14:1827–1837PublicationORIGINALUTILIZATION OF PACARA EARPOD TREE (ENTEROLOBIUM CONTORTISILQUUM) AND IRONWOOD (CAESALPINIA LEIOSTACHYA) SEEDS AS LOW-COST BIOSORBENTS FOR REMOVAL OF BASIC FUCHSIN.pdfUTILIZATION OF PACARA EARPOD TREE (ENTEROLOBIUM CONTORTISILQUUM) AND IRONWOOD (CAESALPINIA LEIOSTACHYA) SEEDS AS LOW-COST BIOSORBENTS FOR REMOVAL OF BASIC FUCHSIN.pdfapplication/pdf113558https://repositorio.cuc.edu.co/bitstreams/ff457712-388a-46bb-83f9-96c9a5dc2826/download6ff86146ae9035dfe8ced3612a86134fMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8701https://repositorio.cuc.edu.co/bitstreams/e23adfc6-afe5-47d2-b427-095c8a2f3a1e/download42fd4ad1e89814f5e4a476b409eb708cMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/4aea8aed-a9b3-47df-b519-fbececf4358b/downloade30e9215131d99561d40d6b0abbe9badMD53THUMBNAILUTILIZATION OF PACARA EARPOD TREE (ENTEROLOBIUM CONTORTISILQUUM) AND IRONWOOD (CAESALPINIA 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