A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications
Wastewater from industrial processes contains different compounds that can be of great use to improve its circularity. The potential of wastewater can be exploited by applying extraction techniques to obtain compounds of interest and recirculate them in the process. In this study, the residual water...
- Autores:
-
Hernández Fernández, Joaquín
Marulanda, Karen
Puello-Polo, Esneyder
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2023
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/10386
- Acceso en línea:
- https://hdl.handle.net/11323/10386
https://repositorio.cuc.edu.co/
- Palabra clave:
- Recovery
Phenolic compounds
Irganox 1010
Extraction
Circularity
- Rights
- embargoedAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
| id |
RCUC2_0712704d9bfc57c81c68abcc2a581c5c |
|---|---|
| oai_identifier_str |
oai:repositorio.cuc.edu.co:11323/10386 |
| network_acronym_str |
RCUC2 |
| network_name_str |
REDICUC - Repositorio CUC |
| repository_id_str |
|
| dc.title.eng.fl_str_mv |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications |
| title |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications |
| spellingShingle |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications Recovery Phenolic compounds Irganox 1010 Extraction Circularity |
| title_short |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications |
| title_full |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications |
| title_fullStr |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications |
| title_full_unstemmed |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications |
| title_sort |
A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applications |
| dc.creator.fl_str_mv |
Hernández Fernández, Joaquín Marulanda, Karen Puello-Polo, Esneyder |
| dc.contributor.author.none.fl_str_mv |
Hernández Fernández, Joaquín Marulanda, Karen Puello-Polo, Esneyder |
| dc.subject.proposal.eng.fl_str_mv |
Recovery Phenolic compounds Irganox 1010 Extraction Circularity |
| topic |
Recovery Phenolic compounds Irganox 1010 Extraction Circularity |
| description |
Wastewater from industrial processes contains different compounds that can be of great use to improve its circularity. The potential of wastewater can be exploited by applying extraction techniques to obtain compounds of interest and recirculate them in the process. In this study, the residual water generated during the polypropylene deodorization process was evaluated. The residues of the additives used during the synthesis of the resin are extracted from these waters. With this recovery, contamination of water bodies is avoided and the circularity of the polymer production process is increased.Solid phase extraction and HPLC were used to recover the phenolic compound, obtaining a recovery of more than 95%. FTIR and DSC were applied to evaluate the purity of the extracted compound. Finally, the effectiveness of the phenolic compound was evaluated by applying it to the resin and evaluating its thermal stability by TGA, obtaining as a result, that the recovered additive improves the thermal properties of the material. |
| publishDate |
2023 |
| dc.date.accessioned.none.fl_str_mv |
2023-08-14T20:26:13Z |
| dc.date.available.none.fl_str_mv |
2023-08-14T20:26:13Z 2024-02-16 |
| dc.date.issued.none.fl_str_mv |
2023-02-16 |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/draft |
| dc.type.coarversion.spa.fl_str_mv |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| format |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| status_str |
draft |
| dc.identifier.citation.spa.fl_str_mv |
Hernández-Fernández, J., Marulanda, K. & Puello-Polo, E. A new Valorization Route of Petrochemical Wastewater: Recovery of Phenolic Derivatives and their Subsequent Application in a PP Matrix for the Improvement of their Durability in Multiple Applications. J Polym Environ 31, 2902–2911 (2023). https://doi.org/10.1007/s10924-023-02764-7 |
| dc.identifier.issn.spa.fl_str_mv |
1566-2543 |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/11323/10386 |
| dc.identifier.doi.none.fl_str_mv |
10.1007/s10924-023-02764-7 |
| dc.identifier.eissn.spa.fl_str_mv |
1572-8900 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Hernández-Fernández, J., Marulanda, K. & Puello-Polo, E. A new Valorization Route of Petrochemical Wastewater: Recovery of Phenolic Derivatives and their Subsequent Application in a PP Matrix for the Improvement of their Durability in Multiple Applications. J Polym Environ 31, 2902–2911 (2023). https://doi.org/10.1007/s10924-023-02764-7 1566-2543 10.1007/s10924-023-02764-7 1572-8900 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/10386 https://repositorio.cuc.edu.co/ |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Journal of Polymers and the Environment |
| dc.relation.references.spa.fl_str_mv |
Jafarinejad S (2016) Petroleum Waste Treatment and Pollution Control. p. 362 Kumar L, Chugh M, Kumar S, Kumar K, Sharma J, Bharadvaja N (2022) “Remediation of petrorefinery wastewater contaminants: A review on physicochemical and bioremediation strategies,” Process Saf. Environ. Prot, vol. 159, pp. 362–375, Mar. doi: https://doi.org/10.1016/j.psep.2022.01.009 Singh S, Shikha (2019) “Treatment and Recycling of Wastewater from Oil Refinery/Petroleum Industry,” pp.303–332. doi: https://doi.org/10.1007/978-981-13-1468-1_10 “Recent developments (2022) in hazardous pollutants removal from wastewater and water reuse within a circular economy | npj Clean Water.” https://www.nature.com/articles/s41545-022-00154-5 (accessed Aug. 22, Ghimire N, Wang S (2018) Biological Treatment of Petrochemical Wastewater. Intechopen. doi: https://doi.org/10.5772/intechopen.79655 Yu L, Han M, He F (2017) “A review of treating oily wastewater,” Arab. J. Chem, vol. 10, p. 1913–1922, May. doi: https://doi.org/10.1016/j.arabjc.2013.07.020 Hernández-Fernandez J, Rodríguez E (Dec. 2019) Determination of phenolic antioxidants additives in industrial wastewater from polypropylene production using solid phase extraction with high-performance liquid chromatography. J Chromatogr A 1607:460442. doi: https://doi.org/10.1016/j.chroma.2019.460442 Hernández-Fernández J, Lopez-Martinez J, Barceló D (Jan. 2021) Quantification and elimination of substituted synthetic phenols and volatile organic compounds in the wastewater treatment plant during the production of industrial scale polypropylene. Chemosphere 263:128027. doi: https://doi.org/10.1016/j.chemosphere.2020.128027 Hernández Fernández J et al (2022) “Identification and Quantification of Microplastics in Effluents of Wastewater Treatment Plant by Differential Scanning Calorimetry (DSC),” Sustainability, vol. 14, no. 9, p. 4920, doi: https://doi.org/10.3390/su14094920 Mohamad said K, Ismail A, Abdul Karim Z, Abdullah S, Hafeez A (May 2021) A review of Technologies for the Phenolic Compounds recovery and phenol removal from Wastewater. Process Saf Environ Prot 151. doi: https://doi.org/10.1016/j.psep.2021.05.015 Mohd DrA (Mar. 2020) Presence of phenol in wastewater effluent and its removal: an overview. Int J Environ Anal Chem 1–23. doi: https://doi.org/10.1080/03067319.2020.1738412 “Microbial Degradation of Phenol : A Comparative Study.” Accessed: Aug. 22, 2022. [Online]. Available: https://core.ac.uk/download/pdf/53189005.pdf Gucbilmez Y (2022) Physiochemical Properties and removal methods of Phenolic Compounds from Waste Waters. IntechOpen. doi: https://doi.org/10.5772/intechopen.101545 Albuquerque B, Heleno S, Oliveira M, Barros L, Ferreira I (2020) Phenolic compounds: current industrial applications, limitations and future challenges. Food Funct Nov. doi: https://doi.org/10.1039/D0FO02324H Rho S-J, Mun S, Park J, Kim Y-R (2021) “Retarding Oxidative and Enzymatic Degradation of Phenolic Compounds Using Large-Ring Cycloamylose,” Foods, vol. 10, no. 7, p. 1457, Jun. doi: https://doi.org/10.3390/foods10071457 “Degradation of Polymers (2022) ” https://polymerdatabase.com/polymer%20chemistry/Thermal%20Degradation.html Prenzler PD, Ryan D, Robards K (2021) “Chapter 1 Introduction to Basic Principles of Antioxidant Activity,” pp. 1–62, doi: https://doi.org/10.1039/9781839165337-00001 Lobo V, Patil A, Phatak A, Chandra N (2010) Free radicals, antioxidants and functional foods: impact on human health. Pharmacogn Rev 4(8):118–126. doi: https://doi.org/10.4103/0973-7847.70902 Santos-Sánchez NF, Salas-Coronado R, Villanueva-Cañongo C, Hernández-Carlos B (2019) Antioxidant compounds and their antioxidant mechanism. IntechOpen. doi: https://doi.org/10.5772/intechopen.85270 Hernández-Fernández J, Rayón E, López J, Arrieta MP (Nov. 2019) Enhancing the Thermal Stability of Polypropylene by blending with Low amounts of Natural Antioxidants. Macromol Mater Eng 304(11):1900379. doi: https://doi.org/10.1002/mame.201900379 Alsabri A, Tahir F, Al-Ghamdi SG (2022) “Environmental impacts of polypropylene (PP) production and prospects of its recycling in the GCC region,” Mater. Today Proc, vol. 56, pp. 2245–2251, doi: https://doi.org/10.1016/j.matpr.2021.11.574 Thörnblom K, Palmlöf M, Hjertberg T (2011) “The extractability of phenolic antioxidants into water and organic solvents from polyethylene pipe materials – Part I,” Polym. Degrad. Stab, vol. 96, no. 10, pp. 1751–1760, Oct. doi: https://doi.org/10.1016/j.polymdegradstab.2011.07.023 “Determination of BHT (2022) Irganox 1076, and Irganox 1010 antioxidant additives in polyethylene by high performance liquid chromatography | Analytical Chemistry.” https://pubs.acs.org/doi/pdf/10.1021/ac50059a009 Gómez-Contreras P, Figueroa-Lopez KJ, Hernández-Fernández J, Cortés M, Rodríguez, Ortega-Toro R (2021) “Effect of Different Essential Oils on the Properties of Edible Coatings Based on Yam (Dioscorea rotundata L.) Starch and Its Application in Strawberry (Fragaria vesca L.) Preservation,” Appl. Sci, vol. 11, no. 22, p. 11057, Nov. doi: https://doi.org/10.3390/app112211057 Fernández JH, Guerra Y, Cano H (Jan. 2022) Detection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America. Molecules 27 no. 15, Art. no. 15. doi: https://doi.org/10.3390/molecules27154832 “Extraction of polypropylene additives (2022) and their analysis by HPLC | SpringerLink.” https://link.springer.com/article/10.1007/BF02466639 (accessed Aug. 22, Jordan SL, Taylor LT (Jan. 1997) HPLC separation with Solvent Elimination FTIR detection of Polymer Additives. J Chromatogr Sci 35(1):7–13. doi: https://doi.org/10.1093/chromsci/35.1.7 “HPLC Separation with Solvent Elimination FTIR Detection of Polymer Additives (2022) | Journal of Chromatographic Science | Oxford Academic.” https://academic.oup.com/chromsci/article/35/1/7/323477?login=false (accessed Aug. 22, Joaquin H-F, Juan L-M (Jan. 2022) Autocatalytic influence of different levels of arsine on the thermal stability and pyrolysis of polypropylene. J Anal Appl Pyrolysis 161:105385. doi: https://doi.org/10.1016/j.jaap.2021.105385 Chacon H et al (Apr. 2022) Effect of Addition of Polyurea as an Aggregate in Mortars: analysis of microstructure and strength. Polymers 14:1753. doi: https://doi.org/10.3390/polym14091753 Coutinho FMB “Estudo da interação entre as fases da mistura poliestireno/elastômeros butadiênicos: aspectos morfológicos e térmicos,” p.10 “Irganox 1010 - FTIR - Spectrum - SpectraBase,” Aug. 22 (2022) https://spectrabase.com/spectrum/Jmmw3OvuB3P (accessed Aug. 22, 2022) “Irganox 1010 - FTIR (2022) - Spectrum - SpectraBase.” https://spectrabase.com/spectrum/Jmmw3OvuB3P “Quimica_Organica_-_John_McMurry_-_8va_Edicion20200311-84302-4xfc11-with-cover-page-v2.pdf.” Accessed: Aug. 22, 2022. [Online]. Available: https://d1wqtxts1xzle7.cloudfront.net/62339803/Quimica_Organica_-_John_McMurry_-_8va_Edicion20200311-84302-4xfc11-with-cover-page-v2.pdf?Expires=1661155451&Signature=Ovo4EwSevsD17Z1wjV8DW5PLkQhw7CFtoDiWL8ME-Ys3SJLE64B4lvIqK9REMB845uLHhbWz6M15dUeo1xic-SF4XfzFxSD6Vaka7kdbxumosYAWhmv2sZKjVUvW~NaHqVygICL~VFi~RWdB66iK9XSfW2K5M~sV~RHqRgLaNTiKreFDG09Vfepayi9j2sqeX~B3Yy4~fsvEPuA8oJW2z~ZYbq-aBc6qOgxm4QCgMzxPn~0GlGVuFh1FPJPi0apuuZtP438C5~acJrI6jU4jLyCjnxws5LUa6cBKepVoUxpGN7Ymn4tSe40cz032TrqjdrHtzrNj7Aa805WI5CoKpg__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA “Transport of small (1992) molecules in polyolefins. I. Diffusion of irganox 1010 in polyethylene - Földes – 1992 - Journal of Applied Polymer Science - Wiley Online Library.” https://onlinelibrary.wiley.com/doi/abs/10.1002/app.070460317 (accessed Aug. 22, 2022) Hernández-Fernández J (2021) Quantification of arsine and phosphine in industrial atmospheric emissions in Spain and Colombia. Implementation of modified zeolites to reduce the environmental impact of emissions. Atmospheric Pollution Research 12:167–176. https://doi.org/10.1016/j.apr.2021.01.019 Joaquin H-F, Juan L (2020) Quantification of poisons for Ziegler Natta catalysts and ffects on the production of polypropylene by gas chromatographic with simultaneous etection: pulsed discharge helium ionization, mass spectrometry, and flame onization. J Chromatogr A 1614:460736. https://doi.org/10.1016/j.chroma.2019.460736 Hernández-Fernández J Quantification of oxygenates, sulphides, thiols and permanent gases in propylene. A multiple linear regression model to predict the loss of efficiency in polypropylene production on an industrial scale.Journal of Chromatography A2020;1628. https://doi.org/10.1016/j.chroma.2020.461478 Hernández-Fernández J, Lopez-Martinez J (2021) Damià Barceló. Development and validation of a methodology for quantifying parts-per-billion levels of arsine and phosphine in nitrogen, hydrogen and liquefied petroleum gas using a variable pressure sampler coupled to gas chromatography-mass spectrometry. J Chromatogr A 1637:461833. https://doi.org/10.1016/j.chroma.2020.461833 Hernández-Fernández J, López-Martínez J (2021) Experimental study of the auto-catalytic effect of triethylaluminum and TiCl4 residuals at the onset of non-additive polypropylene degradation and their impact on thermo-oxidative degradation and pyrolysis. J Anal Appl Pyrol 155. https://doi.org/10.1016/j.jaap.2021.105052 Heidis, Cano (2022) John Fredy Ríos-Rojas, Joaquin Hernández-Fernández, Wilson Bernal Herrera, Mayka Bautista Betancur, Lorcy De La Hoz Vélez and Lidy Agámez González. Impact of Environmental Pollution in the sustainability of Architectural Heritage: Case Study from Cartagena of India. Colombia Sustain 14:189. https://doi.org/10.3390/su14010189 Pavon C, Aldas M (2021) Joaquín Hernandez-Fernandez, Juan Lopez-Martínez. Comparative characterization of gum rosins for their use as sustainable additives in polymeric matrices. J Appl Polym Sci e51734. https://doi.org/10.1002/app.51734 Pavon C, Aldas M, López-Martínez J (2021) Joaquín Hernández-Fernández and Marina Patricia Arrieta. Films based on thermoplastic starch blended with Pine Resin derivatives for Food Packaging. Foods 10:1171. https://doi.org/10.3390/foods10061171 Joaquín Hernández-Fernández JR, Castro-Suarez AT, Toloza (2022) Iron oxide powder as responsible for the generation of Industrial Polypropylene Waste and as a Co-Catalyst for the pyrolysis of non-additive resins. Int J Mol Sci 23:11708. https://doi.org/10.3390/ijms231911708 Joaquín H-F, Vivas-Reyes R, Carlos AT, Toloza (2022) Experimental study of the impact of Trace amounts of Acetylene and Methylacetylene on the synthesis, Mechanical and Thermal Properties of Polypropylene. Int J Mol Sci 23:12148. https://doi.org/10.3390/ijms232012148 Joaquín Hernández-Fernández Y, Guerra Esneyder Puello-Polo and Edgar Marquez. Effects of Different Concentrations of Arsine on the Synthesis and Final Properties of Polypropylene, Polymers 2022, 14,3123. https://doi.org/10.3390/polym14153123 Joaquín Hernández-Fernández H, Cano M, Aldas Impact of Traces of Hydrogen Sulfide on the Efficiency of Ziegler–Natta Catalyst on the Final Properties of Polypropylene, Polymers 2022, 14,3910. https://doi.org/10.3390/polym14183910 Joaquín Hernández–Fernández, Guerra Y, Espinosa E (2022) Development and application of a principal component analysis model to quantify the Green Ethylene Content in Virgin Impact Copolymer Resins during their synthesis on an Industrial Scale. J Polym Environ. https://doi.org/10.1007/s10924-022-02557-4 |
| dc.relation.citationendpage.spa.fl_str_mv |
2911 |
| dc.relation.citationstartpage.spa.fl_str_mv |
2902 |
| dc.relation.citationvolume.spa.fl_str_mv |
31 |
| dc.rights.eng.fl_str_mv |
© 2023 Springer Nature |
| dc.rights.license.spa.fl_str_mv |
Atribución 4.0 Internacional (CC BY 4.0) |
| dc.rights.uri.spa.fl_str_mv |
https://creativecommons.org/licenses/by/4.0/ |
| dc.rights.accessrights.spa.fl_str_mv |
info:eu-repo/semantics/embargoedAccess |
| dc.rights.coar.spa.fl_str_mv |
http://purl.org/coar/access_right/c_f1cf |
| rights_invalid_str_mv |
Atribución 4.0 Internacional (CC BY 4.0) © 2023 Springer Nature https://creativecommons.org/licenses/by/4.0/ http://purl.org/coar/access_right/c_f1cf |
| eu_rights_str_mv |
embargoedAccess |
| dc.format.extent.spa.fl_str_mv |
1 página |
| dc.format.mimetype.spa.fl_str_mv |
application/pdf |
| dc.publisher.spa.fl_str_mv |
Springer New York |
| dc.publisher.place.spa.fl_str_mv |
United States |
| dc.source.spa.fl_str_mv |
https://link.springer.com/article/10.1007/s10924-023-02764-7 |
| institution |
Corporación Universidad de la Costa |
| bitstream.url.fl_str_mv |
https://repositorio.cuc.edu.co/bitstreams/e83f5ea5-d52f-4e3d-a3aa-4de856ea56dc/download https://repositorio.cuc.edu.co/bitstreams/125530c5-00e3-45fb-9c4b-328b9b3d149b/download https://repositorio.cuc.edu.co/bitstreams/b9baf85a-d9a4-4980-a300-f3d4987cbcc9/download https://repositorio.cuc.edu.co/bitstreams/9b06d4e5-d144-4254-b258-496bbb9feb58/download |
| bitstream.checksum.fl_str_mv |
a1b729afa3439462a398e81caa6a985f 2f9959eaf5b71fae44bbf9ec84150c7a 295fe0ee0f67f5c6b1638167380df650 aec2d38c5f98da86531f62292f201430 |
| bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 MD5 |
| repository.name.fl_str_mv |
Repositorio de la Universidad de la Costa CUC |
| repository.mail.fl_str_mv |
repdigital@cuc.edu.co |
| _version_ |
1811760820800978944 |
| spelling |
Atribución 4.0 Internacional (CC BY 4.0)© 2023 Springer Naturehttps://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfHernández Fernández, JoaquínMarulanda, KarenPuello-Polo, Esneyder2023-08-14T20:26:13Z2024-02-162023-08-14T20:26:13Z2023-02-16Hernández-Fernández, J., Marulanda, K. & Puello-Polo, E. A new Valorization Route of Petrochemical Wastewater: Recovery of Phenolic Derivatives and their Subsequent Application in a PP Matrix for the Improvement of their Durability in Multiple Applications. J Polym Environ 31, 2902–2911 (2023). https://doi.org/10.1007/s10924-023-02764-71566-2543https://hdl.handle.net/11323/1038610.1007/s10924-023-02764-71572-8900Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Wastewater from industrial processes contains different compounds that can be of great use to improve its circularity. The potential of wastewater can be exploited by applying extraction techniques to obtain compounds of interest and recirculate them in the process. In this study, the residual water generated during the polypropylene deodorization process was evaluated. The residues of the additives used during the synthesis of the resin are extracted from these waters. With this recovery, contamination of water bodies is avoided and the circularity of the polymer production process is increased.Solid phase extraction and HPLC were used to recover the phenolic compound, obtaining a recovery of more than 95%. FTIR and DSC were applied to evaluate the purity of the extracted compound. Finally, the effectiveness of the phenolic compound was evaluated by applying it to the resin and evaluating its thermal stability by TGA, obtaining as a result, that the recovered additive improves the thermal properties of the material.1 páginaapplication/pdfengSpringer New YorkUnited Stateshttps://link.springer.com/article/10.1007/s10924-023-02764-7A new valorization route of petrochemical wastewater: recovery of phenolic derivatives and their subsequent application in a pp matrix for the improvement of their durability in multiple applicationsArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/drafthttp://purl.org/coar/version/c_b1a7d7d4d402bcceJournal of Polymers and the EnvironmentJafarinejad S (2016) Petroleum Waste Treatment and Pollution Control. p. 362Kumar L, Chugh M, Kumar S, Kumar K, Sharma J, Bharadvaja N (2022) “Remediation of petrorefinery wastewater contaminants: A review on physicochemical and bioremediation strategies,” Process Saf. Environ. Prot, vol. 159, pp. 362–375, Mar. doi: https://doi.org/10.1016/j.psep.2022.01.009Singh S, Shikha (2019) “Treatment and Recycling of Wastewater from Oil Refinery/Petroleum Industry,” pp.303–332. doi: https://doi.org/10.1007/978-981-13-1468-1_10“Recent developments (2022) in hazardous pollutants removal from wastewater and water reuse within a circular economy | npj Clean Water.” https://www.nature.com/articles/s41545-022-00154-5 (accessed Aug. 22,Ghimire N, Wang S (2018) Biological Treatment of Petrochemical Wastewater. Intechopen. doi: https://doi.org/10.5772/intechopen.79655Yu L, Han M, He F (2017) “A review of treating oily wastewater,” Arab. J. Chem, vol. 10, p. 1913–1922, May. doi: https://doi.org/10.1016/j.arabjc.2013.07.020Hernández-Fernandez J, Rodríguez E (Dec. 2019) Determination of phenolic antioxidants additives in industrial wastewater from polypropylene production using solid phase extraction with high-performance liquid chromatography. J Chromatogr A 1607:460442. doi: https://doi.org/10.1016/j.chroma.2019.460442Hernández-Fernández J, Lopez-Martinez J, Barceló D (Jan. 2021) Quantification and elimination of substituted synthetic phenols and volatile organic compounds in the wastewater treatment plant during the production of industrial scale polypropylene. Chemosphere 263:128027. doi: https://doi.org/10.1016/j.chemosphere.2020.128027Hernández Fernández J et al (2022) “Identification and Quantification of Microplastics in Effluents of Wastewater Treatment Plant by Differential Scanning Calorimetry (DSC),” Sustainability, vol. 14, no. 9, p. 4920, doi: https://doi.org/10.3390/su14094920Mohamad said K, Ismail A, Abdul Karim Z, Abdullah S, Hafeez A (May 2021) A review of Technologies for the Phenolic Compounds recovery and phenol removal from Wastewater. Process Saf Environ Prot 151. doi: https://doi.org/10.1016/j.psep.2021.05.015Mohd DrA (Mar. 2020) Presence of phenol in wastewater effluent and its removal: an overview. Int J Environ Anal Chem 1–23. doi: https://doi.org/10.1080/03067319.2020.1738412“Microbial Degradation of Phenol : A Comparative Study.” Accessed: Aug. 22, 2022. [Online]. Available: https://core.ac.uk/download/pdf/53189005.pdfGucbilmez Y (2022) Physiochemical Properties and removal methods of Phenolic Compounds from Waste Waters. IntechOpen. doi: https://doi.org/10.5772/intechopen.101545Albuquerque B, Heleno S, Oliveira M, Barros L, Ferreira I (2020) Phenolic compounds: current industrial applications, limitations and future challenges. Food Funct Nov. doi: https://doi.org/10.1039/D0FO02324HRho S-J, Mun S, Park J, Kim Y-R (2021) “Retarding Oxidative and Enzymatic Degradation of Phenolic Compounds Using Large-Ring Cycloamylose,” Foods, vol. 10, no. 7, p. 1457, Jun. doi: https://doi.org/10.3390/foods10071457“Degradation of Polymers (2022) ” https://polymerdatabase.com/polymer%20chemistry/Thermal%20Degradation.htmlPrenzler PD, Ryan D, Robards K (2021) “Chapter 1 Introduction to Basic Principles of Antioxidant Activity,” pp. 1–62, doi: https://doi.org/10.1039/9781839165337-00001Lobo V, Patil A, Phatak A, Chandra N (2010) Free radicals, antioxidants and functional foods: impact on human health. Pharmacogn Rev 4(8):118–126. doi: https://doi.org/10.4103/0973-7847.70902Santos-Sánchez NF, Salas-Coronado R, Villanueva-Cañongo C, Hernández-Carlos B (2019) Antioxidant compounds and their antioxidant mechanism. IntechOpen. doi: https://doi.org/10.5772/intechopen.85270Hernández-Fernández J, Rayón E, López J, Arrieta MP (Nov. 2019) Enhancing the Thermal Stability of Polypropylene by blending with Low amounts of Natural Antioxidants. Macromol Mater Eng 304(11):1900379. doi: https://doi.org/10.1002/mame.201900379Alsabri A, Tahir F, Al-Ghamdi SG (2022) “Environmental impacts of polypropylene (PP) production and prospects of its recycling in the GCC region,” Mater. Today Proc, vol. 56, pp. 2245–2251, doi: https://doi.org/10.1016/j.matpr.2021.11.574Thörnblom K, Palmlöf M, Hjertberg T (2011) “The extractability of phenolic antioxidants into water and organic solvents from polyethylene pipe materials – Part I,” Polym. Degrad. Stab, vol. 96, no. 10, pp. 1751–1760, Oct. doi: https://doi.org/10.1016/j.polymdegradstab.2011.07.023“Determination of BHT (2022) Irganox 1076, and Irganox 1010 antioxidant additives in polyethylene by high performance liquid chromatography | Analytical Chemistry.” https://pubs.acs.org/doi/pdf/10.1021/ac50059a009Gómez-Contreras P, Figueroa-Lopez KJ, Hernández-Fernández J, Cortés M, Rodríguez, Ortega-Toro R (2021) “Effect of Different Essential Oils on the Properties of Edible Coatings Based on Yam (Dioscorea rotundata L.) Starch and Its Application in Strawberry (Fragaria vesca L.) Preservation,” Appl. Sci, vol. 11, no. 22, p. 11057, Nov. doi: https://doi.org/10.3390/app112211057Fernández JH, Guerra Y, Cano H (Jan. 2022) Detection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America. Molecules 27 no. 15, Art. no. 15. doi: https://doi.org/10.3390/molecules27154832“Extraction of polypropylene additives (2022) and their analysis by HPLC | SpringerLink.” https://link.springer.com/article/10.1007/BF02466639 (accessed Aug. 22,Jordan SL, Taylor LT (Jan. 1997) HPLC separation with Solvent Elimination FTIR detection of Polymer Additives. J Chromatogr Sci 35(1):7–13. doi: https://doi.org/10.1093/chromsci/35.1.7“HPLC Separation with Solvent Elimination FTIR Detection of Polymer Additives (2022) | Journal of Chromatographic Science | Oxford Academic.” https://academic.oup.com/chromsci/article/35/1/7/323477?login=false (accessed Aug. 22,Joaquin H-F, Juan L-M (Jan. 2022) Autocatalytic influence of different levels of arsine on the thermal stability and pyrolysis of polypropylene. J Anal Appl Pyrolysis 161:105385. doi: https://doi.org/10.1016/j.jaap.2021.105385Chacon H et al (Apr. 2022) Effect of Addition of Polyurea as an Aggregate in Mortars: analysis of microstructure and strength. Polymers 14:1753. doi: https://doi.org/10.3390/polym14091753Coutinho FMB “Estudo da interação entre as fases da mistura poliestireno/elastômeros butadiênicos: aspectos morfológicos e térmicos,” p.10“Irganox 1010 - FTIR - Spectrum - SpectraBase,” Aug. 22 (2022) https://spectrabase.com/spectrum/Jmmw3OvuB3P (accessed Aug. 22, 2022)“Irganox 1010 - FTIR (2022) - Spectrum - SpectraBase.” https://spectrabase.com/spectrum/Jmmw3OvuB3P“Quimica_Organica_-_John_McMurry_-_8va_Edicion20200311-84302-4xfc11-with-cover-page-v2.pdf.” Accessed: Aug. 22, 2022. [Online]. Available: https://d1wqtxts1xzle7.cloudfront.net/62339803/Quimica_Organica_-_John_McMurry_-_8va_Edicion20200311-84302-4xfc11-with-cover-page-v2.pdf?Expires=1661155451&Signature=Ovo4EwSevsD17Z1wjV8DW5PLkQhw7CFtoDiWL8ME-Ys3SJLE64B4lvIqK9REMB845uLHhbWz6M15dUeo1xic-SF4XfzFxSD6Vaka7kdbxumosYAWhmv2sZKjVUvW~NaHqVygICL~VFi~RWdB66iK9XSfW2K5M~sV~RHqRgLaNTiKreFDG09Vfepayi9j2sqeX~B3Yy4~fsvEPuA8oJW2z~ZYbq-aBc6qOgxm4QCgMzxPn~0GlGVuFh1FPJPi0apuuZtP438C5~acJrI6jU4jLyCjnxws5LUa6cBKepVoUxpGN7Ymn4tSe40cz032TrqjdrHtzrNj7Aa805WI5CoKpg__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA“Transport of small (1992) molecules in polyolefins. I. Diffusion of irganox 1010 in polyethylene - Földes – 1992 - Journal of Applied Polymer Science - Wiley Online Library.” https://onlinelibrary.wiley.com/doi/abs/10.1002/app.070460317 (accessed Aug. 22, 2022)Hernández-Fernández J (2021) Quantification of arsine and phosphine in industrial atmospheric emissions in Spain and Colombia. Implementation of modified zeolites to reduce the environmental impact of emissions. Atmospheric Pollution Research 12:167–176. https://doi.org/10.1016/j.apr.2021.01.019Joaquin H-F, Juan L (2020) Quantification of poisons for Ziegler Natta catalysts and ffects on the production of polypropylene by gas chromatographic with simultaneous etection: pulsed discharge helium ionization, mass spectrometry, and flame onization. J Chromatogr A 1614:460736. https://doi.org/10.1016/j.chroma.2019.460736Hernández-Fernández J Quantification of oxygenates, sulphides, thiols and permanent gases in propylene. A multiple linear regression model to predict the loss of efficiency in polypropylene production on an industrial scale.Journal of Chromatography A2020;1628. https://doi.org/10.1016/j.chroma.2020.461478Hernández-Fernández J, Lopez-Martinez J (2021) Damià Barceló. Development and validation of a methodology for quantifying parts-per-billion levels of arsine and phosphine in nitrogen, hydrogen and liquefied petroleum gas using a variable pressure sampler coupled to gas chromatography-mass spectrometry. J Chromatogr A 1637:461833. https://doi.org/10.1016/j.chroma.2020.461833Hernández-Fernández J, López-Martínez J (2021) Experimental study of the auto-catalytic effect of triethylaluminum and TiCl4 residuals at the onset of non-additive polypropylene degradation and their impact on thermo-oxidative degradation and pyrolysis. J Anal Appl Pyrol 155. https://doi.org/10.1016/j.jaap.2021.105052Heidis, Cano (2022) John Fredy Ríos-Rojas, Joaquin Hernández-Fernández, Wilson Bernal Herrera, Mayka Bautista Betancur, Lorcy De La Hoz Vélez and Lidy Agámez González. Impact of Environmental Pollution in the sustainability of Architectural Heritage: Case Study from Cartagena of India. Colombia Sustain 14:189. https://doi.org/10.3390/su14010189Pavon C, Aldas M (2021) Joaquín Hernandez-Fernandez, Juan Lopez-Martínez. Comparative characterization of gum rosins for their use as sustainable additives in polymeric matrices. J Appl Polym Sci e51734. https://doi.org/10.1002/app.51734Pavon C, Aldas M, López-Martínez J (2021) Joaquín Hernández-Fernández and Marina Patricia Arrieta. Films based on thermoplastic starch blended with Pine Resin derivatives for Food Packaging. Foods 10:1171. https://doi.org/10.3390/foods10061171Joaquín Hernández-Fernández JR, Castro-Suarez AT, Toloza (2022) Iron oxide powder as responsible for the generation of Industrial Polypropylene Waste and as a Co-Catalyst for the pyrolysis of non-additive resins. Int J Mol Sci 23:11708. https://doi.org/10.3390/ijms231911708Joaquín H-F, Vivas-Reyes R, Carlos AT, Toloza (2022) Experimental study of the impact of Trace amounts of Acetylene and Methylacetylene on the synthesis, Mechanical and Thermal Properties of Polypropylene. Int J Mol Sci 23:12148. https://doi.org/10.3390/ijms232012148Joaquín Hernández-Fernández Y, Guerra Esneyder Puello-Polo and Edgar Marquez. Effects of Different Concentrations of Arsine on the Synthesis and Final Properties of Polypropylene, Polymers 2022, 14,3123. https://doi.org/10.3390/polym14153123Joaquín Hernández-Fernández H, Cano M, Aldas Impact of Traces of Hydrogen Sulfide on the Efficiency of Ziegler–Natta Catalyst on the Final Properties of Polypropylene, Polymers 2022, 14,3910. https://doi.org/10.3390/polym14183910Joaquín Hernández–Fernández, Guerra Y, Espinosa E (2022) Development and application of a principal component analysis model to quantify the Green Ethylene Content in Virgin Impact Copolymer Resins during their synthesis on an Industrial Scale. J Polym Environ. https://doi.org/10.1007/s10924-022-02557-42911290231RecoveryPhenolic compoundsIrganox 1010ExtractionCircularityPublicationORIGINALA new Valorization Route of Petrochemical Wastewater.pdfA new Valorization Route of Petrochemical Wastewater.pdfArtículoapplication/pdf57945https://repositorio.cuc.edu.co/bitstreams/e83f5ea5-d52f-4e3d-a3aa-4de856ea56dc/downloada1b729afa3439462a398e81caa6a985fMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstreams/125530c5-00e3-45fb-9c4b-328b9b3d149b/download2f9959eaf5b71fae44bbf9ec84150c7aMD52TEXTA new Valorization Route of Petrochemical Wastewater.pdf.txtA new Valorization Route of Petrochemical Wastewater.pdf.txtExtracted texttext/plain1416https://repositorio.cuc.edu.co/bitstreams/b9baf85a-d9a4-4980-a300-f3d4987cbcc9/download295fe0ee0f67f5c6b1638167380df650MD53THUMBNAILA new Valorization Route of Petrochemical Wastewater.pdf.jpgA new Valorization Route of Petrochemical Wastewater.pdf.jpgGenerated Thumbnailimage/jpeg13152https://repositorio.cuc.edu.co/bitstreams/9b06d4e5-d144-4254-b258-496bbb9feb58/downloadaec2d38c5f98da86531f62292f201430MD5411323/10386oai:repositorio.cuc.edu.co:11323/103862024-09-17 12:50:36.255https://creativecommons.org/licenses/by/4.0/© 2023 Springer Natureopen.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.coTEEgT0JSQSAoVEFMIFkgQ09NTyBTRSBERUZJTkUgTcOBUyBBREVMQU5URSkgU0UgT1RPUkdBIEJBSk8gTE9TIFRFUk1JTk9TIERFIEVTVEEgTElDRU5DSUEgUMOaQkxJQ0EgREUgQ1JFQVRJVkUgQ09NTU9OUyAo4oCcTFBDQ+KAnSBPIOKAnExJQ0VOQ0lB4oCdKS4gTEEgT0JSQSBFU1TDgSBQUk9URUdJREEgUE9SIERFUkVDSE9TIERFIEFVVE9SIFkvVSBPVFJBUyBMRVlFUyBBUExJQ0FCTEVTLiBRVUVEQSBQUk9ISUJJRE8gQ1VBTFFVSUVSIFVTTyBRVUUgU0UgSEFHQSBERSBMQSBPQlJBIFFVRSBOTyBDVUVOVEUgQ09OIExBIEFVVE9SSVpBQ0nDk04gUEVSVElORU5URSBERSBDT05GT1JNSURBRCBDT04gTE9TIFTDiVJNSU5PUyBERSBFU1RBIExJQ0VOQ0lBIFkgREUgTEEgTEVZIERFIERFUkVDSE8gREUgQVVUT1IuCgpNRURJQU5URSBFTCBFSkVSQ0lDSU8gREUgQ1VBTFFVSUVSQSBERSBMT1MgREVSRUNIT1MgUVVFIFNFIE9UT1JHQU4gRU4gRVNUQSBMSUNFTkNJQSwgVVNURUQgQUNFUFRBIFkgQUNVRVJEQSBRVUVEQVIgT0JMSUdBRE8gRU4gTE9TIFRFUk1JTk9TIFFVRSBTRSBTRcORQUxBTiBFTiBFTExBLiBFTCBMSUNFTkNJQU5URSBDT05DRURFIEEgVVNURUQgTE9TIERFUkVDSE9TIENPTlRFTklET1MgRU4gRVNUQSBMSUNFTkNJQSBDT05ESUNJT05BRE9TIEEgTEEgQUNFUFRBQ0nDk04gREUgU1VTIFRFUk1JTk9TIFkgQ09ORElDSU9ORVMuCjEuIERlZmluaWNpb25lcwoKYS4JT2JyYSBDb2xlY3RpdmEgZXMgdW5hIG9icmEsIHRhbCBjb21vIHVuYSBwdWJsaWNhY2nDs24gcGVyacOzZGljYSwgdW5hIGFudG9sb2fDrWEsIG8gdW5hIGVuY2ljbG9wZWRpYSwgZW4gbGEgcXVlIGxhIG9icmEgZW4gc3UgdG90YWxpZGFkLCBzaW4gbW9kaWZpY2FjacOzbiBhbGd1bmEsIGp1bnRvIGNvbiB1biBncnVwbyBkZSBvdHJhcyBjb250cmlidWNpb25lcyBxdWUgY29uc3RpdHV5ZW4gb2JyYXMgc2VwYXJhZGFzIGUgaW5kZXBlbmRpZW50ZXMgZW4gc8OtIG1pc21hcywgc2UgaW50ZWdyYW4gZW4gdW4gdG9kbyBjb2xlY3Rpdm8uIFVuYSBPYnJhIHF1ZSBjb25zdGl0dXllIHVuYSBvYnJhIGNvbGVjdGl2YSBubyBzZSBjb25zaWRlcmFyw6EgdW5hIE9icmEgRGVyaXZhZGEgKGNvbW8gc2UgZGVmaW5lIGFiYWpvKSBwYXJhIGxvcyBwcm9ww7NzaXRvcyBkZSBlc3RhIGxpY2VuY2lhLiBhcXVlbGxhIHByb2R1Y2lkYSBwb3IgdW4gZ3J1cG8gZGUgYXV0b3JlcywgZW4gcXVlIGxhIE9icmEgc2UgZW5jdWVudHJhIHNpbiBtb2RpZmljYWNpb25lcywganVudG8gY29uIHVuYSBjaWVydGEgY2FudGlkYWQgZGUgb3RyYXMgY29udHJpYnVjaW9uZXMsIHF1ZSBjb25zdGl0dXllbiBlbiBzw60gbWlzbW9zIHRyYWJham9zIHNlcGFyYWRvcyBlIGluZGVwZW5kaWVudGVzLCBxdWUgc29uIGludGVncmFkb3MgYWwgdG9kbyBjb2xlY3Rpdm8sIHRhbGVzIGNvbW8gcHVibGljYWNpb25lcyBwZXJpw7NkaWNhcywgYW50b2xvZ8OtYXMgbyBlbmNpY2xvcGVkaWFzLgoKYi4JT2JyYSBEZXJpdmFkYSBzaWduaWZpY2EgdW5hIG9icmEgYmFzYWRhIGVuIGxhIG9icmEgb2JqZXRvIGRlIGVzdGEgbGljZW5jaWEgbyBlbiDDqXN0YSB5IG90cmFzIG9icmFzIHByZWV4aXN0ZW50ZXMsIHRhbGVzIGNvbW8gdHJhZHVjY2lvbmVzLCBhcnJlZ2xvcyBtdXNpY2FsZXMsIGRyYW1hdGl6YWNpb25lcywg4oCcZmljY2lvbmFsaXphY2lvbmVz4oCdLCB2ZXJzaW9uZXMgcGFyYSBjaW5lLCDigJxncmFiYWNpb25lcyBkZSBzb25pZG/igJ0sIHJlcHJvZHVjY2lvbmVzIGRlIGFydGUsIHJlc8O6bWVuZXMsIGNvbmRlbnNhY2lvbmVzLCBvIGN1YWxxdWllciBvdHJhIGVuIGxhIHF1ZSBsYSBvYnJhIHB1ZWRhIHNlciB0cmFuc2Zvcm1hZGEsIGNhbWJpYWRhIG8gYWRhcHRhZGEsIGV4Y2VwdG8gYXF1ZWxsYXMgcXVlIGNvbnN0aXR1eWFuIHVuYSBvYnJhIGNvbGVjdGl2YSwgbGFzIHF1ZSBubyBzZXLDoW4gY29uc2lkZXJhZGFzIHVuYSBvYnJhIGRlcml2YWRhIHBhcmEgZWZlY3RvcyBkZSBlc3RhIGxpY2VuY2lhLiAoUGFyYSBldml0YXIgZHVkYXMsIGVuIGVsIGNhc28gZGUgcXVlIGxhIE9icmEgc2VhIHVuYSBjb21wb3NpY2nDs24gbXVzaWNhbCBvIHVuYSBncmFiYWNpw7NuIHNvbm9yYSwgcGFyYSBsb3MgZWZlY3RvcyBkZSBlc3RhIExpY2VuY2lhIGxhIHNpbmNyb25pemFjacOzbiB0ZW1wb3JhbCBkZSBsYSBPYnJhIGNvbiB1bmEgaW1hZ2VuIGVuIG1vdmltaWVudG8gc2UgY29uc2lkZXJhcsOhIHVuYSBPYnJhIERlcml2YWRhIHBhcmEgbG9zIGZpbmVzIGRlIGVzdGEgbGljZW5jaWEpLgoKYy4JTGljZW5jaWFudGUsIGVzIGVsIGluZGl2aWR1byBvIGxhIGVudGlkYWQgdGl0dWxhciBkZSBsb3MgZGVyZWNob3MgZGUgYXV0b3IgcXVlIG9mcmVjZSBsYSBPYnJhIGVuIGNvbmZvcm1pZGFkIGNvbiBsYXMgY29uZGljaW9uZXMgZGUgZXN0YSBMaWNlbmNpYS4KCmQuCUF1dG9yIG9yaWdpbmFsLCBlcyBlbCBpbmRpdmlkdW8gcXVlIGNyZcOzIGxhIE9icmEuCgplLglPYnJhLCBlcyBhcXVlbGxhIG9icmEgc3VzY2VwdGlibGUgZGUgcHJvdGVjY2nDs24gcG9yIGVsIHLDqWdpbWVuIGRlIERlcmVjaG8gZGUgQXV0b3IgeSBxdWUgZXMgb2ZyZWNpZGEgZW4gbG9zIHTDqXJtaW5vcyBkZSBlc3RhIGxpY2VuY2lhCgpmLglVc3RlZCwgZXMgZWwgaW5kaXZpZHVvIG8gbGEgZW50aWRhZCBxdWUgZWplcmNpdGEgbG9zIGRlcmVjaG9zIG90b3JnYWRvcyBhbCBhbXBhcm8gZGUgZXN0YSBMaWNlbmNpYSB5IHF1ZSBjb24gYW50ZXJpb3JpZGFkIG5vIGhhIHZpb2xhZG8gbGFzIGNvbmRpY2lvbmVzIGRlIGxhIG1pc21hIHJlc3BlY3RvIGEgbGEgT2JyYSwgbyBxdWUgaGF5YSBvYnRlbmlkbyBhdXRvcml6YWNpw7NuIGV4cHJlc2EgcG9yIHBhcnRlIGRlbCBMaWNlbmNpYW50ZSBwYXJhIGVqZXJjZXIgbG9zIGRlcmVjaG9zIGFsIGFtcGFybyBkZSBlc3RhIExpY2VuY2lhIHBlc2UgYSB1bmEgdmlvbGFjacOzbiBhbnRlcmlvci4KCjIuIERlcmVjaG9zIGRlIFVzb3MgSG9ucmFkb3MgeSBleGNlcGNpb25lcyBMZWdhbGVzLgpOYWRhIGVuIGVzdGEgTGljZW5jaWEgcG9kcsOhIHNlciBpbnRlcnByZXRhZG8gY29tbyB1bmEgZGlzbWludWNpw7NuLCBsaW1pdGFjacOzbiBvIHJlc3RyaWNjacOzbiBkZSBsb3MgZGVyZWNob3MgZGVyaXZhZG9zIGRlbCB1c28gaG9ucmFkbyB5IG90cmFzIGxpbWl0YWNpb25lcyBvIGV4Y2VwY2lvbmVzIGEgbG9zIGRlcmVjaG9zIGRlbCBhdXRvciBiYWpvIGVsIHLDqWdpbWVuIGxlZ2FsIHZpZ2VudGUgbyBkZXJpdmFkbyBkZSBjdWFscXVpZXIgb3RyYSBub3JtYSBxdWUgc2UgbGUgYXBsaXF1ZS4KCjMuIENvbmNlc2nDs24gZGUgbGEgTGljZW5jaWEuCkJham8gbG9zIHTDqXJtaW5vcyB5IGNvbmRpY2lvbmVzIGRlIGVzdGEgTGljZW5jaWEsIGVsIExpY2VuY2lhbnRlIG90b3JnYSBhIFVzdGVkIHVuYSBsaWNlbmNpYSBtdW5kaWFsLCBsaWJyZSBkZSByZWdhbMOtYXMsIG5vIGV4Y2x1c2l2YSB5IHBlcnBldHVhIChkdXJhbnRlIHRvZG8gZWwgcGVyw61vZG8gZGUgdmlnZW5jaWEgZGUgbG9zIGRlcmVjaG9zIGRlIGF1dG9yKSBwYXJhIGVqZXJjZXIgZXN0b3MgZGVyZWNob3Mgc29icmUgbGEgT2JyYSB0YWwgeSBjb21vIHNlIGluZGljYSBhIGNvbnRpbnVhY2nDs246CgphLglSZXByb2R1Y2lyIGxhIE9icmEsIGluY29ycG9yYXIgbGEgT2JyYSBlbiB1bmEgbyBtw6FzIE9icmFzIENvbGVjdGl2YXMsIHkgcmVwcm9kdWNpciBsYSBPYnJhIGluY29ycG9yYWRhIGVuIGxhcyBPYnJhcyBDb2xlY3RpdmFzLgoKYi4JRGlzdHJpYnVpciBjb3BpYXMgbyBmb25vZ3JhbWFzIGRlIGxhcyBPYnJhcywgZXhoaWJpcmxhcyBww7pibGljYW1lbnRlLCBlamVjdXRhcmxhcyBww7pibGljYW1lbnRlIHkvbyBwb25lcmxhcyBhIGRpc3Bvc2ljacOzbiBww7pibGljYSwgaW5jbHV5w6luZG9sYXMgY29tbyBpbmNvcnBvcmFkYXMgZW4gT2JyYXMgQ29sZWN0aXZhcywgc2Vnw7puIGNvcnJlc3BvbmRhLgoKYy4JRGlzdHJpYnVpciBjb3BpYXMgZGUgbGFzIE9icmFzIERlcml2YWRhcyBxdWUgc2UgZ2VuZXJlbiwgZXhoaWJpcmxhcyBww7pibGljYW1lbnRlLCBlamVjdXRhcmxhcyBww7pibGljYW1lbnRlIHkvbyBwb25lcmxhcyBhIGRpc3Bvc2ljacOzbiBww7pibGljYS4KTG9zIGRlcmVjaG9zIG1lbmNpb25hZG9zIGFudGVyaW9ybWVudGUgcHVlZGVuIHNlciBlamVyY2lkb3MgZW4gdG9kb3MgbG9zIG1lZGlvcyB5IGZvcm1hdG9zLCBhY3R1YWxtZW50ZSBjb25vY2lkb3MgbyBxdWUgc2UgaW52ZW50ZW4gZW4gZWwgZnV0dXJvLiBMb3MgZGVyZWNob3MgYW50ZXMgbWVuY2lvbmFkb3MgaW5jbHV5ZW4gZWwgZGVyZWNobyBhIHJlYWxpemFyIGRpY2hhcyBtb2RpZmljYWNpb25lcyBlbiBsYSBtZWRpZGEgcXVlIHNlYW4gdMOpY25pY2FtZW50ZSBuZWNlc2FyaWFzIHBhcmEgZWplcmNlciBsb3MgZGVyZWNob3MgZW4gb3RybyBtZWRpbyBvIGZvcm1hdG9zLCBwZXJvIGRlIG90cmEgbWFuZXJhIHVzdGVkIG5vIGVzdMOhIGF1dG9yaXphZG8gcGFyYSByZWFsaXphciBvYnJhcyBkZXJpdmFkYXMuIFRvZG9zIGxvcyBkZXJlY2hvcyBubyBvdG9yZ2Fkb3MgZXhwcmVzYW1lbnRlIHBvciBlbCBMaWNlbmNpYW50ZSBxdWVkYW4gcG9yIGVzdGUgbWVkaW8gcmVzZXJ2YWRvcywgaW5jbHV5ZW5kbyBwZXJvIHNpbiBsaW1pdGFyc2UgYSBhcXVlbGxvcyBxdWUgc2UgbWVuY2lvbmFuIGVuIGxhcyBzZWNjaW9uZXMgNChkKSB5IDQoZSkuCgo0LiBSZXN0cmljY2lvbmVzLgpMYSBsaWNlbmNpYSBvdG9yZ2FkYSBlbiBsYSBhbnRlcmlvciBTZWNjacOzbiAzIGVzdMOhIGV4cHJlc2FtZW50ZSBzdWpldGEgeSBsaW1pdGFkYSBwb3IgbGFzIHNpZ3VpZW50ZXMgcmVzdHJpY2Npb25lczoKCmEuCVVzdGVkIHB1ZWRlIGRpc3RyaWJ1aXIsIGV4aGliaXIgcMO6YmxpY2FtZW50ZSwgZWplY3V0YXIgcMO6YmxpY2FtZW50ZSwgbyBwb25lciBhIGRpc3Bvc2ljacOzbiBww7pibGljYSBsYSBPYnJhIHPDs2xvIGJham8gbGFzIGNvbmRpY2lvbmVzIGRlIGVzdGEgTGljZW5jaWEsIHkgVXN0ZWQgZGViZSBpbmNsdWlyIHVuYSBjb3BpYSBkZSBlc3RhIGxpY2VuY2lhIG8gZGVsIElkZW50aWZpY2Fkb3IgVW5pdmVyc2FsIGRlIFJlY3Vyc29zIGRlIGxhIG1pc21hIGNvbiBjYWRhIGNvcGlhIGRlIGxhIE9icmEgcXVlIGRpc3RyaWJ1eWEsIGV4aGliYSBww7pibGljYW1lbnRlLCBlamVjdXRlIHDDumJsaWNhbWVudGUgbyBwb25nYSBhIGRpc3Bvc2ljacOzbiBww7pibGljYS4gTm8gZXMgcG9zaWJsZSBvZnJlY2VyIG8gaW1wb25lciBuaW5ndW5hIGNvbmRpY2nDs24gc29icmUgbGEgT2JyYSBxdWUgYWx0ZXJlIG8gbGltaXRlIGxhcyBjb25kaWNpb25lcyBkZSBlc3RhIExpY2VuY2lhIG8gZWwgZWplcmNpY2lvIGRlIGxvcyBkZXJlY2hvcyBkZSBsb3MgZGVzdGluYXRhcmlvcyBvdG9yZ2Fkb3MgZW4gZXN0ZSBkb2N1bWVudG8uIE5vIGVzIHBvc2libGUgc3VibGljZW5jaWFyIGxhIE9icmEuIFVzdGVkIGRlYmUgbWFudGVuZXIgaW50YWN0b3MgdG9kb3MgbG9zIGF2aXNvcyBxdWUgaGFnYW4gcmVmZXJlbmNpYSBhIGVzdGEgTGljZW5jaWEgeSBhIGxhIGNsw6F1c3VsYSBkZSBsaW1pdGFjacOzbiBkZSBnYXJhbnTDrWFzLiBVc3RlZCBubyBwdWVkZSBkaXN0cmlidWlyLCBleGhpYmlyIHDDumJsaWNhbWVudGUsIGVqZWN1dGFyIHDDumJsaWNhbWVudGUsIG8gcG9uZXIgYSBkaXNwb3NpY2nDs24gcMO6YmxpY2EgbGEgT2JyYSBjb24gYWxndW5hIG1lZGlkYSB0ZWNub2zDs2dpY2EgcXVlIGNvbnRyb2xlIGVsIGFjY2VzbyBvIGxhIHV0aWxpemFjacOzbiBkZSBlbGxhIGRlIHVuYSBmb3JtYSBxdWUgc2VhIGluY29uc2lzdGVudGUgY29uIGxhcyBjb25kaWNpb25lcyBkZSBlc3RhIExpY2VuY2lhLiBMbyBhbnRlcmlvciBzZSBhcGxpY2EgYSBsYSBPYnJhIGluY29ycG9yYWRhIGEgdW5hIE9icmEgQ29sZWN0aXZhLCBwZXJvIGVzdG8gbm8gZXhpZ2UgcXVlIGxhIE9icmEgQ29sZWN0aXZhIGFwYXJ0ZSBkZSBsYSBvYnJhIG1pc21hIHF1ZWRlIHN1amV0YSBhIGxhcyBjb25kaWNpb25lcyBkZSBlc3RhIExpY2VuY2lhLiBTaSBVc3RlZCBjcmVhIHVuYSBPYnJhIENvbGVjdGl2YSwgcHJldmlvIGF2aXNvIGRlIGN1YWxxdWllciBMaWNlbmNpYW50ZSBkZWJlLCBlbiBsYSBtZWRpZGEgZGUgbG8gcG9zaWJsZSwgZWxpbWluYXIgZGUgbGEgT2JyYSBDb2xlY3RpdmEgY3VhbHF1aWVyIHJlZmVyZW5jaWEgYSBkaWNobyBMaWNlbmNpYW50ZSBvIGFsIEF1dG9yIE9yaWdpbmFsLCBzZWfDum4gbG8gc29saWNpdGFkbyBwb3IgZWwgTGljZW5jaWFudGUgeSBjb25mb3JtZSBsbyBleGlnZSBsYSBjbMOhdXN1bGEgNChjKS4KCmIuCVVzdGVkIG5vIHB1ZWRlIGVqZXJjZXIgbmluZ3VubyBkZSBsb3MgZGVyZWNob3MgcXVlIGxlIGhhbiBzaWRvIG90b3JnYWRvcyBlbiBsYSBTZWNjacOzbiAzIHByZWNlZGVudGUgZGUgbW9kbyBxdWUgZXN0w6luIHByaW5jaXBhbG1lbnRlIGRlc3RpbmFkb3MgbyBkaXJlY3RhbWVudGUgZGlyaWdpZG9zIGEgY29uc2VndWlyIHVuIHByb3ZlY2hvIGNvbWVyY2lhbCBvIHVuYSBjb21wZW5zYWNpw7NuIG1vbmV0YXJpYSBwcml2YWRhLiBFbCBpbnRlcmNhbWJpbyBkZSBsYSBPYnJhIHBvciBvdHJhcyBvYnJhcyBwcm90ZWdpZGFzIHBvciBkZXJlY2hvcyBkZSBhdXRvciwgeWEgc2VhIGEgdHJhdsOpcyBkZSB1biBzaXN0ZW1hIHBhcmEgY29tcGFydGlyIGFyY2hpdm9zIGRpZ2l0YWxlcyAoZGlnaXRhbCBmaWxlLXNoYXJpbmcpIG8gZGUgY3VhbHF1aWVyIG90cmEgbWFuZXJhIG5vIHNlcsOhIGNvbnNpZGVyYWRvIGNvbW8gZXN0YXIgZGVzdGluYWRvIHByaW5jaXBhbG1lbnRlIG8gZGlyaWdpZG8gZGlyZWN0YW1lbnRlIGEgY29uc2VndWlyIHVuIHByb3ZlY2hvIGNvbWVyY2lhbCBvIHVuYSBjb21wZW5zYWNpw7NuIG1vbmV0YXJpYSBwcml2YWRhLCBzaWVtcHJlIHF1ZSBubyBzZSByZWFsaWNlIHVuIHBhZ28gbWVkaWFudGUgdW5hIGNvbXBlbnNhY2nDs24gbW9uZXRhcmlhIGVuIHJlbGFjacOzbiBjb24gZWwgaW50ZXJjYW1iaW8gZGUgb2JyYXMgcHJvdGVnaWRhcyBwb3IgZWwgZGVyZWNobyBkZSBhdXRvci4KCmMuCVNpIHVzdGVkIGRpc3RyaWJ1eWUsIGV4aGliZSBww7pibGljYW1lbnRlLCBlamVjdXRhIHDDumJsaWNhbWVudGUgbyBlamVjdXRhIHDDumJsaWNhbWVudGUgZW4gZm9ybWEgZGlnaXRhbCBsYSBPYnJhIG8gY3VhbHF1aWVyIE9icmEgRGVyaXZhZGEgdSBPYnJhIENvbGVjdGl2YSwgVXN0ZWQgZGViZSBtYW50ZW5lciBpbnRhY3RhIHRvZGEgbGEgaW5mb3JtYWNpw7NuIGRlIGRlcmVjaG8gZGUgYXV0b3IgZGUgbGEgT2JyYSB5IHByb3BvcmNpb25hciwgZGUgZm9ybWEgcmF6b25hYmxlIHNlZ8O6biBlbCBtZWRpbyBvIG1hbmVyYSBxdWUgVXN0ZWQgZXN0w6kgdXRpbGl6YW5kbzogKGkpIGVsIG5vbWJyZSBkZWwgQXV0b3IgT3JpZ2luYWwgc2kgZXN0w6EgcHJvdmlzdG8gKG8gc2V1ZMOzbmltbywgc2kgZnVlcmUgYXBsaWNhYmxlKSwgeS9vIChpaSkgZWwgbm9tYnJlIGRlIGxhIHBhcnRlIG8gbGFzIHBhcnRlcyBxdWUgZWwgQXV0b3IgT3JpZ2luYWwgeS9vIGVsIExpY2VuY2lhbnRlIGh1YmllcmVuIGRlc2lnbmFkbyBwYXJhIGxhIGF0cmlidWNpw7NuICh2LmcuLCB1biBpbnN0aXR1dG8gcGF0cm9jaW5hZG9yLCBlZGl0b3JpYWwsIHB1YmxpY2FjacOzbikgZW4gbGEgaW5mb3JtYWNpw7NuIGRlIGxvcyBkZXJlY2hvcyBkZSBhdXRvciBkZWwgTGljZW5jaWFudGUsIHTDqXJtaW5vcyBkZSBzZXJ2aWNpb3MgbyBkZSBvdHJhcyBmb3JtYXMgcmF6b25hYmxlczsgZWwgdMOtdHVsbyBkZSBsYSBPYnJhIHNpIGVzdMOhIHByb3Zpc3RvOyBlbiBsYSBtZWRpZGEgZGUgbG8gcmF6b25hYmxlbWVudGUgZmFjdGlibGUgeSwgc2kgZXN0w6EgcHJvdmlzdG8sIGVsIElkZW50aWZpY2Fkb3IgVW5pZm9ybWUgZGUgUmVjdXJzb3MgKFVuaWZvcm0gUmVzb3VyY2UgSWRlbnRpZmllcikgcXVlIGVsIExpY2VuY2lhbnRlIGVzcGVjaWZpY2EgcGFyYSBzZXIgYXNvY2lhZG8gY29uIGxhIE9icmEsIHNhbHZvIHF1ZSB0YWwgVVJJIG5vIHNlIHJlZmllcmEgYSBsYSBub3RhIHNvYnJlIGxvcyBkZXJlY2hvcyBkZSBhdXRvciBvIGEgbGEgaW5mb3JtYWNpw7NuIHNvYnJlIGVsIGxpY2VuY2lhbWllbnRvIGRlIGxhIE9icmE7IHkgZW4gZWwgY2FzbyBkZSB1bmEgT2JyYSBEZXJpdmFkYSwgYXRyaWJ1aXIgZWwgY3LDqWRpdG8gaWRlbnRpZmljYW5kbyBlbCB1c28gZGUgbGEgT2JyYSBlbiBsYSBPYnJhIERlcml2YWRhICh2LmcuLCAiVHJhZHVjY2nDs24gRnJhbmNlc2EgZGUgbGEgT2JyYSBkZWwgQXV0b3IgT3JpZ2luYWwsIiBvICJHdWnDs24gQ2luZW1hdG9ncsOhZmljbyBiYXNhZG8gZW4gbGEgT2JyYSBvcmlnaW5hbCBkZWwgQXV0b3IgT3JpZ2luYWwiKS4gVGFsIGNyw6lkaXRvIHB1ZWRlIHNlciBpbXBsZW1lbnRhZG8gZGUgY3VhbHF1aWVyIGZvcm1hIHJhem9uYWJsZTsgZW4gZWwgY2Fzbywgc2luIGVtYmFyZ28sIGRlIE9icmFzIERlcml2YWRhcyB1IE9icmFzIENvbGVjdGl2YXMsIHRhbCBjcsOpZGl0byBhcGFyZWNlcsOhLCBjb21vIG3DrW5pbW8sIGRvbmRlIGFwYXJlY2UgZWwgY3LDqWRpdG8gZGUgY3VhbHF1aWVyIG90cm8gYXV0b3IgY29tcGFyYWJsZSB5IGRlIHVuYSBtYW5lcmEsIGFsIG1lbm9zLCB0YW4gZGVzdGFjYWRhIGNvbW8gZWwgY3LDqWRpdG8gZGUgb3RybyBhdXRvciBjb21wYXJhYmxlLgoKZC4JUGFyYSBldml0YXIgdG9kYSBjb25mdXNpw7NuLCBlbCBMaWNlbmNpYW50ZSBhY2xhcmEgcXVlLCBjdWFuZG8gbGEgb2JyYSBlcyB1bmEgY29tcG9zaWNpw7NuIG11c2ljYWw6CgppLglSZWdhbMOtYXMgcG9yIGludGVycHJldGFjacOzbiB5IGVqZWN1Y2nDs24gYmFqbyBsaWNlbmNpYXMgZ2VuZXJhbGVzLiBFbCBMaWNlbmNpYW50ZSBzZSByZXNlcnZhIGVsIGRlcmVjaG8gZXhjbHVzaXZvIGRlIGF1dG9yaXphciBsYSBlamVjdWNpw7NuIHDDumJsaWNhIG8gbGEgZWplY3VjacOzbiBww7pibGljYSBkaWdpdGFsIGRlIGxhIG9icmEgeSBkZSByZWNvbGVjdGFyLCBzZWEgaW5kaXZpZHVhbG1lbnRlIG8gYSB0cmF2w6lzIGRlIHVuYSBzb2NpZWRhZCBkZSBnZXN0acOzbiBjb2xlY3RpdmEgZGUgZGVyZWNob3MgZGUgYXV0b3IgeSBkZXJlY2hvcyBjb25leG9zIChwb3IgZWplbXBsbywgU0FZQ08pLCBsYXMgcmVnYWzDrWFzIHBvciBsYSBlamVjdWNpw7NuIHDDumJsaWNhIG8gcG9yIGxhIGVqZWN1Y2nDs24gcMO6YmxpY2EgZGlnaXRhbCBkZSBsYSBvYnJhIChwb3IgZWplbXBsbyBXZWJjYXN0KSBsaWNlbmNpYWRhIGJham8gbGljZW5jaWFzIGdlbmVyYWxlcywgc2kgbGEgaW50ZXJwcmV0YWNpw7NuIG8gZWplY3VjacOzbiBkZSBsYSBvYnJhIGVzdMOhIHByaW1vcmRpYWxtZW50ZSBvcmllbnRhZGEgcG9yIG8gZGlyaWdpZGEgYSBsYSBvYnRlbmNpw7NuIGRlIHVuYSB2ZW50YWphIGNvbWVyY2lhbCBvIHVuYSBjb21wZW5zYWNpw7NuIG1vbmV0YXJpYSBwcml2YWRhLgoKaWkuCVJlZ2Fsw61hcyBwb3IgRm9ub2dyYW1hcy4gRWwgTGljZW5jaWFudGUgc2UgcmVzZXJ2YSBlbCBkZXJlY2hvIGV4Y2x1c2l2byBkZSByZWNvbGVjdGFyLCBpbmRpdmlkdWFsbWVudGUgbyBhIHRyYXbDqXMgZGUgdW5hIHNvY2llZGFkIGRlIGdlc3Rpw7NuIGNvbGVjdGl2YSBkZSBkZXJlY2hvcyBkZSBhdXRvciB5IGRlcmVjaG9zIGNvbmV4b3MgKHBvciBlamVtcGxvLCBsb3MgY29uc2FncmFkb3MgcG9yIGxhIFNBWUNPKSwgdW5hIGFnZW5jaWEgZGUgZGVyZWNob3MgbXVzaWNhbGVzIG8gYWxnw7puIGFnZW50ZSBkZXNpZ25hZG8sIGxhcyByZWdhbMOtYXMgcG9yIGN1YWxxdWllciBmb25vZ3JhbWEgcXVlIFVzdGVkIGNyZWUgYSBwYXJ0aXIgZGUgbGEgb2JyYSAo4oCcdmVyc2nDs24gY292ZXLigJ0pIHkgZGlzdHJpYnV5YSwgZW4gbG9zIHTDqXJtaW5vcyBkZWwgcsOpZ2ltZW4gZGUgZGVyZWNob3MgZGUgYXV0b3IsIHNpIGxhIGNyZWFjacOzbiBvIGRpc3RyaWJ1Y2nDs24gZGUgZXNhIHZlcnNpw7NuIGNvdmVyIGVzdMOhIHByaW1vcmRpYWxtZW50ZSBkZXN0aW5hZGEgbyBkaXJpZ2lkYSBhIG9idGVuZXIgdW5hIHZlbnRhamEgY29tZXJjaWFsIG8gdW5hIGNvbXBlbnNhY2nDs24gbW9uZXRhcmlhIHByaXZhZGEuCgplLglHZXN0acOzbiBkZSBEZXJlY2hvcyBkZSBBdXRvciBzb2JyZSBJbnRlcnByZXRhY2lvbmVzIHkgRWplY3VjaW9uZXMgRGlnaXRhbGVzIChXZWJDYXN0aW5nKS4gUGFyYSBldml0YXIgdG9kYSBjb25mdXNpw7NuLCBlbCBMaWNlbmNpYW50ZSBhY2xhcmEgcXVlLCBjdWFuZG8gbGEgb2JyYSBzZWEgdW4gZm9ub2dyYW1hLCBlbCBMaWNlbmNpYW50ZSBzZSByZXNlcnZhIGVsIGRlcmVjaG8gZXhjbHVzaXZvIGRlIGF1dG9yaXphciBsYSBlamVjdWNpw7NuIHDDumJsaWNhIGRpZ2l0YWwgZGUgbGEgb2JyYSAocG9yIGVqZW1wbG8sIHdlYmNhc3QpIHkgZGUgcmVjb2xlY3RhciwgaW5kaXZpZHVhbG1lbnRlIG8gYSB0cmF2w6lzIGRlIHVuYSBzb2NpZWRhZCBkZSBnZXN0acOzbiBjb2xlY3RpdmEgZGUgZGVyZWNob3MgZGUgYXV0b3IgeSBkZXJlY2hvcyBjb25leG9zIChwb3IgZWplbXBsbywgQUNJTlBSTyksIGxhcyByZWdhbMOtYXMgcG9yIGxhIGVqZWN1Y2nDs24gcMO6YmxpY2EgZGlnaXRhbCBkZSBsYSBvYnJhIChwb3IgZWplbXBsbywgd2ViY2FzdCksIHN1amV0YSBhIGxhcyBkaXNwb3NpY2lvbmVzIGFwbGljYWJsZXMgZGVsIHLDqWdpbWVuIGRlIERlcmVjaG8gZGUgQXV0b3IsIHNpIGVzdGEgZWplY3VjacOzbiBww7pibGljYSBkaWdpdGFsIGVzdMOhIHByaW1vcmRpYWxtZW50ZSBkaXJpZ2lkYSBhIG9idGVuZXIgdW5hIHZlbnRhamEgY29tZXJjaWFsIG8gdW5hIGNvbXBlbnNhY2nDs24gbW9uZXRhcmlhIHByaXZhZGEuCgo1LiBSZXByZXNlbnRhY2lvbmVzLCBHYXJhbnTDrWFzIHkgTGltaXRhY2lvbmVzIGRlIFJlc3BvbnNhYmlsaWRhZC4KQSBNRU5PUyBRVUUgTEFTIFBBUlRFUyBMTyBBQ09SREFSQU4gREUgT1RSQSBGT1JNQSBQT1IgRVNDUklUTywgRUwgTElDRU5DSUFOVEUgT0ZSRUNFIExBIE9CUkEgKEVOIEVMIEVTVEFETyBFTiBFTCBRVUUgU0UgRU5DVUVOVFJBKSDigJxUQUwgQ1VBTOKAnSwgU0lOIEJSSU5EQVIgR0FSQU5Uw41BUyBERSBDTEFTRSBBTEdVTkEgUkVTUEVDVE8gREUgTEEgT0JSQSwgWUEgU0VBIEVYUFJFU0EsIElNUEzDjUNJVEEsIExFR0FMIE8gQ1VBTFFVSUVSQSBPVFJBLCBJTkNMVVlFTkRPLCBTSU4gTElNSVRBUlNFIEEgRUxMQVMsIEdBUkFOVMONQVMgREUgVElUVUxBUklEQUQsIENPTUVSQ0lBQklMSURBRCwgQURBUFRBQklMSURBRCBPIEFERUNVQUNJw5NOIEEgUFJPUMOTU0lUTyBERVRFUk1JTkFETywgQVVTRU5DSUEgREUgSU5GUkFDQ0nDk04sIERFIEFVU0VOQ0lBIERFIERFRkVDVE9TIExBVEVOVEVTIE8gREUgT1RSTyBUSVBPLCBPIExBIFBSRVNFTkNJQSBPIEFVU0VOQ0lBIERFIEVSUk9SRVMsIFNFQU4gTyBOTyBERVNDVUJSSUJMRVMgKFBVRURBTiBPIE5PIFNFUiBFU1RPUyBERVNDVUJJRVJUT1MpLiBBTEdVTkFTIEpVUklTRElDQ0lPTkVTIE5PIFBFUk1JVEVOIExBIEVYQ0xVU0nDk04gREUgR0FSQU5Uw41BUyBJTVBMw41DSVRBUywgRU4gQ1VZTyBDQVNPIEVTVEEgRVhDTFVTScOTTiBQVUVERSBOTyBBUExJQ0FSU0UgQSBVU1RFRC4KCjYuIExpbWl0YWNpw7NuIGRlIHJlc3BvbnNhYmlsaWRhZC4KQSBNRU5PUyBRVUUgTE8gRVhJSkEgRVhQUkVTQU1FTlRFIExBIExFWSBBUExJQ0FCTEUsIEVMIExJQ0VOQ0lBTlRFIE5PIFNFUsOBIFJFU1BPTlNBQkxFIEFOVEUgVVNURUQgUE9SIERBw5FPIEFMR1VOTywgU0VBIFBPUiBSRVNQT05TQUJJTElEQUQgRVhUUkFDT05UUkFDVFVBTCwgUFJFQ09OVFJBQ1RVQUwgTyBDT05UUkFDVFVBTCwgT0JKRVRJVkEgTyBTVUJKRVRJVkEsIFNFIFRSQVRFIERFIERBw5FPUyBNT1JBTEVTIE8gUEFUUklNT05JQUxFUywgRElSRUNUT1MgTyBJTkRJUkVDVE9TLCBQUkVWSVNUT1MgTyBJTVBSRVZJU1RPUyBQUk9EVUNJRE9TIFBPUiBFTCBVU08gREUgRVNUQSBMSUNFTkNJQSBPIERFIExBIE9CUkEsIEFVTiBDVUFORE8gRUwgTElDRU5DSUFOVEUgSEFZQSBTSURPIEFEVkVSVElETyBERSBMQSBQT1NJQklMSURBRCBERSBESUNIT1MgREHDkU9TLiBBTEdVTkFTIExFWUVTIE5PIFBFUk1JVEVOIExBIEVYQ0xVU0nDk04gREUgQ0lFUlRBIFJFU1BPTlNBQklMSURBRCwgRU4gQ1VZTyBDQVNPIEVTVEEgRVhDTFVTScOTTiBQVUVERSBOTyBBUExJQ0FSU0UgQSBVU1RFRC4KCjcuIFTDqXJtaW5vLgoKYS4JRXN0YSBMaWNlbmNpYSB5IGxvcyBkZXJlY2hvcyBvdG9yZ2Fkb3MgZW4gdmlydHVkIGRlIGVsbGEgdGVybWluYXLDoW4gYXV0b23DoXRpY2FtZW50ZSBzaSBVc3RlZCBpbmZyaW5nZSBhbGd1bmEgY29uZGljacOzbiBlc3RhYmxlY2lkYSBlbiBlbGxhLiBTaW4gZW1iYXJnbywgbG9zIGluZGl2aWR1b3MgbyBlbnRpZGFkZXMgcXVlIGhhbiByZWNpYmlkbyBPYnJhcyBEZXJpdmFkYXMgbyBDb2xlY3RpdmFzIGRlIFVzdGVkIGRlIGNvbmZvcm1pZGFkIGNvbiBlc3RhIExpY2VuY2lhLCBubyB2ZXLDoW4gdGVybWluYWRhcyBzdXMgbGljZW5jaWFzLCBzaWVtcHJlIHF1ZSBlc3RvcyBpbmRpdmlkdW9zIG8gZW50aWRhZGVzIHNpZ2FuIGN1bXBsaWVuZG8gw61udGVncmFtZW50ZSBsYXMgY29uZGljaW9uZXMgZGUgZXN0YXMgbGljZW5jaWFzLiBMYXMgU2VjY2lvbmVzIDEsIDIsIDUsIDYsIDcsIHkgOCBzdWJzaXN0aXLDoW4gYSBjdWFscXVpZXIgdGVybWluYWNpw7NuIGRlIGVzdGEgTGljZW5jaWEuCgpiLglTdWpldGEgYSBsYXMgY29uZGljaW9uZXMgeSB0w6lybWlub3MgYW50ZXJpb3JlcywgbGEgbGljZW5jaWEgb3RvcmdhZGEgYXF1w60gZXMgcGVycGV0dWEgKGR1cmFudGUgZWwgcGVyw61vZG8gZGUgdmlnZW5jaWEgZGUgbG9zIGRlcmVjaG9zIGRlIGF1dG9yIGRlIGxhIG9icmEpLiBObyBvYnN0YW50ZSBsbyBhbnRlcmlvciwgZWwgTGljZW5jaWFudGUgc2UgcmVzZXJ2YSBlbCBkZXJlY2hvIGEgcHVibGljYXIgeS9vIGVzdHJlbmFyIGxhIE9icmEgYmFqbyBjb25kaWNpb25lcyBkZSBsaWNlbmNpYSBkaWZlcmVudGVzIG8gYSBkZWphciBkZSBkaXN0cmlidWlybGEgZW4gbG9zIHTDqXJtaW5vcyBkZSBlc3RhIExpY2VuY2lhIGVuIGN1YWxxdWllciBtb21lbnRvOyBlbiBlbCBlbnRlbmRpZG8sIHNpbiBlbWJhcmdvLCBxdWUgZXNhIGVsZWNjacOzbiBubyBzZXJ2aXLDoSBwYXJhIHJldm9jYXIgZXN0YSBsaWNlbmNpYSBvIHF1ZSBkZWJhIHNlciBvdG9yZ2FkYSAsIGJham8gbG9zIHTDqXJtaW5vcyBkZSBlc3RhIGxpY2VuY2lhKSwgeSBlc3RhIGxpY2VuY2lhIGNvbnRpbnVhcsOhIGVuIHBsZW5vIHZpZ29yIHkgZWZlY3RvIGEgbWVub3MgcXVlIHNlYSB0ZXJtaW5hZGEgY29tbyBzZSBleHByZXNhIGF0csOhcy4gTGEgTGljZW5jaWEgcmV2b2NhZGEgY29udGludWFyw6Egc2llbmRvIHBsZW5hbWVudGUgdmlnZW50ZSB5IGVmZWN0aXZhIHNpIG5vIHNlIGxlIGRhIHTDqXJtaW5vIGVuIGxhcyBjb25kaWNpb25lcyBpbmRpY2FkYXMgYW50ZXJpb3JtZW50ZS4KCjguIFZhcmlvcy4KCmEuCUNhZGEgdmV6IHF1ZSBVc3RlZCBkaXN0cmlidXlhIG8gcG9uZ2EgYSBkaXNwb3NpY2nDs24gcMO6YmxpY2EgbGEgT2JyYSBvIHVuYSBPYnJhIENvbGVjdGl2YSwgZWwgTGljZW5jaWFudGUgb2ZyZWNlcsOhIGFsIGRlc3RpbmF0YXJpbyB1bmEgbGljZW5jaWEgZW4gbG9zIG1pc21vcyB0w6lybWlub3MgeSBjb25kaWNpb25lcyBxdWUgbGEgbGljZW5jaWEgb3RvcmdhZGEgYSBVc3RlZCBiYWpvIGVzdGEgTGljZW5jaWEuCgpiLglTaSBhbGd1bmEgZGlzcG9zaWNpw7NuIGRlIGVzdGEgTGljZW5jaWEgcmVzdWx0YSBpbnZhbGlkYWRhIG8gbm8gZXhpZ2libGUsIHNlZ8O6biBsYSBsZWdpc2xhY2nDs24gdmlnZW50ZSwgZXN0byBubyBhZmVjdGFyw6EgbmkgbGEgdmFsaWRleiBuaSBsYSBhcGxpY2FiaWxpZGFkIGRlbCByZXN0byBkZSBjb25kaWNpb25lcyBkZSBlc3RhIExpY2VuY2lhIHksIHNpbiBhY2Npw7NuIGFkaWNpb25hbCBwb3IgcGFydGUgZGUgbG9zIHN1amV0b3MgZGUgZXN0ZSBhY3VlcmRvLCBhcXXDqWxsYSBzZSBlbnRlbmRlcsOhIHJlZm9ybWFkYSBsbyBtw61uaW1vIG5lY2VzYXJpbyBwYXJhIGhhY2VyIHF1ZSBkaWNoYSBkaXNwb3NpY2nDs24gc2VhIHbDoWxpZGEgeSBleGlnaWJsZS4KCmMuCU5pbmfDum4gdMOpcm1pbm8gbyBkaXNwb3NpY2nDs24gZGUgZXN0YSBMaWNlbmNpYSBzZSBlc3RpbWFyw6EgcmVudW5jaWFkYSB5IG5pbmd1bmEgdmlvbGFjacOzbiBkZSBlbGxhIHNlcsOhIGNvbnNlbnRpZGEgYSBtZW5vcyBxdWUgZXNhIHJlbnVuY2lhIG8gY29uc2VudGltaWVudG8gc2VhIG90b3JnYWRvIHBvciBlc2NyaXRvIHkgZmlybWFkbyBwb3IgbGEgcGFydGUgcXVlIHJlbnVuY2llIG8gY29uc2llbnRhLgoKZC4JRXN0YSBMaWNlbmNpYSByZWZsZWphIGVsIGFjdWVyZG8gcGxlbm8gZW50cmUgbGFzIHBhcnRlcyByZXNwZWN0byBhIGxhIE9icmEgYXF1w60gbGljZW5jaWFkYS4gTm8gaGF5IGFycmVnbG9zLCBhY3VlcmRvcyBvIGRlY2xhcmFjaW9uZXMgcmVzcGVjdG8gYSBsYSBPYnJhIHF1ZSBubyBlc3TDqW4gZXNwZWNpZmljYWRvcyBlbiBlc3RlIGRvY3VtZW50by4gRWwgTGljZW5jaWFudGUgbm8gc2UgdmVyw6EgbGltaXRhZG8gcG9yIG5pbmd1bmEgZGlzcG9zaWNpw7NuIGFkaWNpb25hbCBxdWUgcHVlZGEgc3VyZ2lyIGVuIGFsZ3VuYSBjb211bmljYWNpw7NuIGVtYW5hZGEgZGUgVXN0ZWQuIEVzdGEgTGljZW5jaWEgbm8gcHVlZGUgc2VyIG1vZGlmaWNhZGEgc2luIGVsIGNvbnNlbnRpbWllbnRvIG11dHVvIHBvciBlc2NyaXRvIGRlbCBMaWNlbmNpYW50ZSB5IFVzdGVkLgo= |