Tunable polyesterification of xylitol: from linear to crosslinked structures
The copolymerization by condensation chemistry of succinic acid and xylitol, a byproduct from the sugarcane and alcohol industry, is reported. Two methodologies were studied concerning succinic acid, with and without carboxylic acid activation, yielding crosslinked and linear low molecular weight po...
- Autores:
-
Liz-Andela, Néstor I
Benitez, Ricardo
Martin-Franco, Jaime
Rojas, Giovanni
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2017
- Institución:
- Universidad ICESI
- Repositorio:
- Repositorio ICESI
- Idioma:
- eng
- OAI Identifier:
- oai:repository.icesi.edu.co:10906/82547
- Acceso en línea:
- http://doi.wiley.com/10.1002/pi.5301
http://repository.icesi.edu.co/biblioteca_digital/handle/10906/82547
http://dx.doi.org/10.1002/pi.5301
- Palabra clave:
- Polímeros
Acido succínico
Xilitol
Copolimerización
Espectroscopia infrarroja transformadora de Fourie
Transformaciones (Matemáticas)
Biología
Ecología
Conservación de la biodiversidad
Métodos de investigación en bioquímica
Biology
Ecology
Biodiversity conservation
Research biochemistry
- Rights
- openAccess
- License
- https://creativecommons.org/licenses/by-nc-nd/4.0/
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Liz-Andela, Néstor IBenitez, RicardoMartin-Franco, JaimeRojas, Giovannigrojas@icesi.edu.coLondon de Lat: 51 30 51 N degrees minutes Lat: 51.5142 decimal degrees Long: 000 05 35 W degrees minutes Long: -0.0931 decimal degrees2017-12-19T19:08:14Z2017-12-19T19:08:14Z2017-04-010959-8103http://doi.wiley.com/10.1002/pi.5301http://repository.icesi.edu.co/biblioteca_digital/handle/10906/82547http://dx.doi.org/10.1002/pi.5301instname: Universidad Icesireponame: Biblioteca Digitalrepourl: https://repository.icesi.edu.co/The copolymerization by condensation chemistry of succinic acid and xylitol, a byproduct from the sugarcane and alcohol industry, is reported. Two methodologies were studied concerning succinic acid, with and without carboxylic acid activation, yielding crosslinked and linear low molecular weight polymers, respectively. All polymerizations were carried out at reaction times in the range from 36 to 80 h, with a molar mass ratio of 1:1 and 1:3. Linear and crosslinked polyesters were analyzed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, DSC and TGA, and structural characterization was carried out by Fourier transform infrared spectroscopy and NMR. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry8 páginasDigitalapplication/pdfengJohn Wiley and Sons LtdFacultad de Ciencias NaturalesBiologíaDepartamento de Ciencias BiológicasLondonPolymer International, Vol. 66, No. 4 - 2017EL AUTOR, expresa que la obra objeto de la presente autorización es original y la elaboró sin quebrantar ni suplantar los derechos de autor de terceros, y de tal forma, la obra es de su exclusiva autoría y tiene la titularidad sobre éste. PARÁGRAFO: en caso de queja o acción por parte de un tercero referente a los derechos de autor sobre el artículo, folleto o libro en cuestión, EL AUTOR, asumirá la responsabilidad total, y saldrá en defensa de los derechos aquí autorizados; para todos los efectos, la Universidad Icesi actúa como un tercero de buena fe. Esta autorización, permite a la Universidad Icesi, de forma indefinida, para que en los términos establecidos en la Ley 23 de 1982, la Ley 44 de 1993, leyes y jurisprudencia vigente al respecto, haga publicación de este con fines educativos Todo persona que consulte ya sea la biblioteca o en medio electrónico podrá copiar apartes del texto citando siempre la fuentes, es decir el título del trabajo y el autor.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)http://purl.org/coar/access_right/c_abf2PolímerosAcido succínicoXilitolCopolimerizaciónEspectroscopia infrarroja transformadora de FourieTransformaciones (Matemáticas)BiologíaEcologíaConservación de la biodiversidadMétodos de investigación en bioquímicaBiologyEcologyBiodiversity conservationResearch biochemistryTunable polyesterification of xylitol: from linear to crosslinked structuresinfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1Artículoinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Comunidad Universidad Icesi664532539ORIGINALdocumento.htmldocumento.htmltext/html277http://repository.icesi.edu.co/biblioteca_digital/bitstream/10906/82547/1/documento.htmlfa2def17d230dfd2ec473323355c803cMD5110906/82547oai:repository.icesi.edu.co:10906/825472018-10-05 09:34:48.736Biblioteca Digital - Universidad icesicdcriollo@icesi.edu.co |
| dc.title.none.fl_str_mv |
Tunable polyesterification of xylitol: from linear to crosslinked structures |
| title |
Tunable polyesterification of xylitol: from linear to crosslinked structures |
| spellingShingle |
Tunable polyesterification of xylitol: from linear to crosslinked structures Polímeros Acido succínico Xilitol Copolimerización Espectroscopia infrarroja transformadora de Fourie Transformaciones (Matemáticas) Biología Ecología Conservación de la biodiversidad Métodos de investigación en bioquímica Biology Ecology Biodiversity conservation Research biochemistry |
| title_short |
Tunable polyesterification of xylitol: from linear to crosslinked structures |
| title_full |
Tunable polyesterification of xylitol: from linear to crosslinked structures |
| title_fullStr |
Tunable polyesterification of xylitol: from linear to crosslinked structures |
| title_full_unstemmed |
Tunable polyesterification of xylitol: from linear to crosslinked structures |
| title_sort |
Tunable polyesterification of xylitol: from linear to crosslinked structures |
| dc.creator.fl_str_mv |
Liz-Andela, Néstor I Benitez, Ricardo Martin-Franco, Jaime Rojas, Giovanni |
| dc.contributor.author.spa.fl_str_mv |
Liz-Andela, Néstor I Benitez, Ricardo Martin-Franco, Jaime Rojas, Giovanni |
| dc.subject.spa.fl_str_mv |
Polímeros Acido succínico Xilitol Copolimerización Espectroscopia infrarroja transformadora de Fourie Transformaciones (Matemáticas) Biología Ecología Conservación de la biodiversidad Métodos de investigación en bioquímica |
| topic |
Polímeros Acido succínico Xilitol Copolimerización Espectroscopia infrarroja transformadora de Fourie Transformaciones (Matemáticas) Biología Ecología Conservación de la biodiversidad Métodos de investigación en bioquímica Biology Ecology Biodiversity conservation Research biochemistry |
| dc.subject.eng.fl_str_mv |
Biology Ecology Biodiversity conservation Research biochemistry |
| description |
The copolymerization by condensation chemistry of succinic acid and xylitol, a byproduct from the sugarcane and alcohol industry, is reported. Two methodologies were studied concerning succinic acid, with and without carboxylic acid activation, yielding crosslinked and linear low molecular weight polymers, respectively. All polymerizations were carried out at reaction times in the range from 36 to 80 h, with a molar mass ratio of 1:1 and 1:3. Linear and crosslinked polyesters were analyzed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, DSC and TGA, and structural characterization was carried out by Fourier transform infrared spectroscopy and NMR. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry |
| publishDate |
2017 |
| dc.date.accessioned.none.fl_str_mv |
2017-12-19T19:08:14Z |
| dc.date.available.none.fl_str_mv |
2017-12-19T19:08:14Z |
| dc.date.issued.none.fl_str_mv |
2017-04-01 |
| dc.type.eng.fl_str_mv |
info:eu-repo/semantics/article |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.local.spa.fl_str_mv |
Artículo |
| dc.type.version.eng.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.coarversion.none.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| format |
http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
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0959-8103 |
| dc.identifier.other.none.fl_str_mv |
http://doi.wiley.com/10.1002/pi.5301 |
| dc.identifier.uri.none.fl_str_mv |
http://repository.icesi.edu.co/biblioteca_digital/handle/10906/82547 |
| dc.identifier.doi.none.fl_str_mv |
http://dx.doi.org/10.1002/pi.5301 |
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instname: Universidad Icesi |
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reponame: Biblioteca Digital |
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repourl: https://repository.icesi.edu.co/ |
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0959-8103 instname: Universidad Icesi reponame: Biblioteca Digital repourl: https://repository.icesi.edu.co/ |
| url |
http://doi.wiley.com/10.1002/pi.5301 http://repository.icesi.edu.co/biblioteca_digital/handle/10906/82547 http://dx.doi.org/10.1002/pi.5301 |
| dc.language.iso.eng.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartof.none.fl_str_mv |
Polymer International, Vol. 66, No. 4 - 2017 |
| dc.rights.uri.none.fl_str_mv |
https://creativecommons.org/licenses/by-nc-nd/4.0/ |
| dc.rights.accessrights.eng.fl_str_mv |
info:eu-repo/semantics/openAccess |
| dc.rights.license.none.fl_str_mv |
Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0) |
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http://purl.org/coar/access_right/c_abf2 |
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https://creativecommons.org/licenses/by-nc-nd/4.0/ Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0) http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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8 páginas |
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Digital |
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application/pdf |
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London de Lat: 51 30 51 N degrees minutes Lat: 51.5142 decimal degrees Long: 000 05 35 W degrees minutes Long: -0.0931 decimal degrees |
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John Wiley and Sons Ltd |
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Facultad de Ciencias Naturales |
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Biología |
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Departamento de Ciencias Biológicas |
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London |
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John Wiley and Sons Ltd |
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Universidad ICESI |
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1814094760898461696 |