Microwave-assisted ADMET polymerization
Microwave-assisted ADMET polymerization is reported on a series of α,ω-diene monomers, both polar and non-polar. Investigations indicate that of the multiple microwave modes possible, constant power is the most advantageous, providing polymers up to M‾w=31,000g/mol. Molecular weight values are nearl...
- Autores:
-
Rojas Jiménez, Giovanni
Wagener, Kenneth B.
Williams, Kathryn R.
Gaines, Taylor W.
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2015
- Institución:
- Universidad ICESI
- Repositorio:
- Repositorio ICESI
- Idioma:
- eng
- OAI Identifier:
- oai:repository.icesi.edu.co:10906/79891
- Acceso en línea:
- http://www.sciencedirect.com/science/article/pii/S0040403915007790
https://nebulosa.icesi.edu.co:2180/record/display.uri?eid=2-s2.0-84930179575&origin=resultslist&sort=plf-f&src=s&st1=Microwave-assisted+ADMET+polymerization&st2=&sid=2d7e29caafad42578918533b53e3da5a&sot=b&sdt=b&sl=54&s=TITLE-ABS-KEY%28Microwave-assisted+ADMET+polymerization%29&relpos=0&citeCnt=1&searchTerm=
http://hdl.handle.net/10906/79891
https://doi.org/10.1016/j.tetlet.2015.04.122
- Palabra clave:
- Métodos de investigación en bioquímica
Biochemistry research
Polímeros
Medicamentos
Resonancia magnética nuclear
Polimerización
- Rights
- openAccess
- License
- https://creativecommons.org/licenses/by-nc-nd/4.0/
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Rojas Jiménez, GiovanniWagener, Kenneth B.Williams, Kathryn R.Gaines, Taylor W.grojas@icesi.edu.coAmsterdam de Lat: 52 21 00 N degrees minutes Lat: 52.3500 decimal degrees Long: 004 55 00 E degrees minutes Long: 4.9167 decimal degrees2016-08-30T22:01:57Z2016-08-30T22:01:57Z2015-05-300040-4039http://www.sciencedirect.com/science/article/pii/S0040403915007790https://nebulosa.icesi.edu.co:2180/record/display.uri?eid=2-s2.0-84930179575&origin=resultslist&sort=plf-f&src=s&st1=Microwave-assisted+ADMET+polymerization&st2=&sid=2d7e29caafad42578918533b53e3da5a&sot=b&sdt=b&sl=54&s=TITLE-ABS-KEY%28Microwave-assisted+ADMET+polymerization%29&relpos=0&citeCnt=1&searchTerm=http://hdl.handle.net/10906/79891https://doi.org/10.1016/j.tetlet.2015.04.122instname: Universidad Icesireponame: Biblioteca Digitalrepourl: https://repository.icesi.edu.co/Microwave-assisted ADMET polymerization is reported on a series of α,ω-diene monomers, both polar and non-polar. Investigations indicate that of the multiple microwave modes possible, constant power is the most advantageous, providing polymers up to M‾w=31,000g/mol. Molecular weight values are nearly triple in comparison with conventional oil bath heating. Polymers are characterized by NMR, GPC, TGA, and DSC. Microwave irradiation provides a highly controllable and energy efficient ADMET polymerization technique.4 páginasDigitalapplication/pdfengElsevier LtdFacultad de Ciencias NaturalesQuímica con énfasis en BioquímicaDepartamento Académico Ciencias QuímicasÁmsterdamTetrahedron Letters, Vol. 56, No. 25 - 2015EL AUTOR, expresa que la obra objeto de la presente autorización es original y la elaboró sin quebrantar ni suplantar los derechos de autor de terceros, y de tal forma, la obra es de su exclusiva autoría y tiene la titularidad sobre éste. PARÁGRAFO: en caso de queja o acción por parte de un tercero referente a los derechos de autor sobre el artículo, folleto o libro en cuestión, EL AUTOR, asumirá la responsabilidad total, y saldrá en defensa de los derechos aquí autorizados; para todos los efectos, la Universidad Icesi actúa como un tercero de buena fe. Esta autorización, permite a la Universidad Icesi, de forma indefinida, para que en los términos establecidos en la Ley 23 de 1982, la Ley 44 de 1993, leyes y jurisprudencia vigente al respecto, haga publicación de este con fines educativos. Toda persona que consulte ya sea la biblioteca o en medio electrónico podrá copiar apartes del texto citando siempre la fuentes, es decir el título del trabajo y el autor.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)http://purl.org/coar/access_right/c_abf2Métodos de investigación en bioquímicaBiochemistry researchPolímerosMedicamentosResonancia magnética nuclearPolimerizaciónMicrowave-assisted ADMET polymerizationinfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1Artículoinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Comunidad Universidad Icesi – Investigadores563927253923ORIGINALdocumento.htmldocumento.htmltext/html301http://repository.icesi.edu.co/biblioteca_digital/bitstream/10906/79891/1/documento.html1fc49c85ca2f358b5f500c30f4d9af4eMD5110906/79891oai:repository.icesi.edu.co:10906/798912018-11-22 10:07:11.398Biblioteca Digital - Universidad icesicdcriollo@icesi.edu.co |
| dc.title.spa.fl_str_mv |
Microwave-assisted ADMET polymerization |
| title |
Microwave-assisted ADMET polymerization |
| spellingShingle |
Microwave-assisted ADMET polymerization Métodos de investigación en bioquímica Biochemistry research Polímeros Medicamentos Resonancia magnética nuclear Polimerización |
| title_short |
Microwave-assisted ADMET polymerization |
| title_full |
Microwave-assisted ADMET polymerization |
| title_fullStr |
Microwave-assisted ADMET polymerization |
| title_full_unstemmed |
Microwave-assisted ADMET polymerization |
| title_sort |
Microwave-assisted ADMET polymerization |
| dc.creator.fl_str_mv |
Rojas Jiménez, Giovanni Wagener, Kenneth B. Williams, Kathryn R. Gaines, Taylor W. |
| dc.contributor.author.spa.fl_str_mv |
Rojas Jiménez, Giovanni Wagener, Kenneth B. Williams, Kathryn R. Gaines, Taylor W. |
| dc.subject.none.fl_str_mv |
Métodos de investigación en bioquímica Biochemistry research Polímeros Medicamentos Resonancia magnética nuclear Polimerización |
| topic |
Métodos de investigación en bioquímica Biochemistry research Polímeros Medicamentos Resonancia magnética nuclear Polimerización |
| description |
Microwave-assisted ADMET polymerization is reported on a series of α,ω-diene monomers, both polar and non-polar. Investigations indicate that of the multiple microwave modes possible, constant power is the most advantageous, providing polymers up to M‾w=31,000g/mol. Molecular weight values are nearly triple in comparison with conventional oil bath heating. Polymers are characterized by NMR, GPC, TGA, and DSC. Microwave irradiation provides a highly controllable and energy efficient ADMET polymerization technique. |
| publishDate |
2015 |
| dc.date.issued.none.fl_str_mv |
2015-05-30 |
| dc.date.accessioned.none.fl_str_mv |
2016-08-30T22:01:57Z |
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2016-08-30T22:01:57Z |
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info:eu-repo/semantics/article |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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Artículo |
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info:eu-repo/semantics/publishedVersion |
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0040-4039 |
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http://www.sciencedirect.com/science/article/pii/S0040403915007790 |
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https://nebulosa.icesi.edu.co:2180/record/display.uri?eid=2-s2.0-84930179575&origin=resultslist&sort=plf-f&src=s&st1=Microwave-assisted+ADMET+polymerization&st2=&sid=2d7e29caafad42578918533b53e3da5a&sot=b&sdt=b&sl=54&s=TITLE-ABS-KEY%28Microwave-assisted+ADMET+polymerization%29&relpos=0&citeCnt=1&searchTerm= |
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http://hdl.handle.net/10906/79891 |
| dc.identifier.doi.none.fl_str_mv |
https://doi.org/10.1016/j.tetlet.2015.04.122 |
| dc.identifier.instname.none.fl_str_mv |
instname: Universidad Icesi |
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reponame: Biblioteca Digital |
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repourl: https://repository.icesi.edu.co/ |
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http://www.sciencedirect.com/science/article/pii/S0040403915007790 https://nebulosa.icesi.edu.co:2180/record/display.uri?eid=2-s2.0-84930179575&origin=resultslist&sort=plf-f&src=s&st1=Microwave-assisted+ADMET+polymerization&st2=&sid=2d7e29caafad42578918533b53e3da5a&sot=b&sdt=b&sl=54&s=TITLE-ABS-KEY%28Microwave-assisted+ADMET+polymerization%29&relpos=0&citeCnt=1&searchTerm= http://hdl.handle.net/10906/79891 https://doi.org/10.1016/j.tetlet.2015.04.122 |
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eng |
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eng |
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Tetrahedron Letters, Vol. 56, No. 25 - 2015 |
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https://creativecommons.org/licenses/by-nc-nd/4.0/ |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0) |
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http://purl.org/coar/access_right/c_abf2 |
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https://creativecommons.org/licenses/by-nc-nd/4.0/ Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0) http://purl.org/coar/access_right/c_abf2 |
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4 páginas |
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Amsterdam de Lat: 52 21 00 N degrees minutes Lat: 52.3500 decimal degrees Long: 004 55 00 E degrees minutes Long: 4.9167 decimal degrees |
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Elsevier Ltd |
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Facultad de Ciencias Naturales |
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Química con énfasis en Bioquímica |
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Departamento Académico Ciencias Químicas |
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Ámsterdam |
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Universidad ICESI |
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