Microwave-assisted ADMET polymerization

Microwave-assisted ADMET polymerization is reported on a series of α,ω-diene monomers, both polar and non-polar. Investigations indicate that of the multiple microwave modes possible, constant power is the most advantageous, providing polymers up to M‾w=31,000g/mol. Molecular weight values are nearly triple in comparison with conventional oil bath heating. Polymers are characterized by NMR, GPC, TGA, and DSC. Microwave irradiation provides a highly controllable and energy efficient ADMET polymerization technique.

• Autores: Rojas Jiménez, Giovanni; Wagener, Kenneth B.; Williams, Kathryn R.; Gaines, Taylor W.
• Tipo de recurso: Article of investigation
• Fecha de publicación: 2015
• Institución: Universidad ICESI
• Repositorio: Repositorio ICESI
• Idioma: eng
• OAI Identifier: oai:repository.icesi.edu.co:10906/79891
• Acceso en línea: http://www.sciencedirect.com/science/article/pii/S0040403915007790; https://nebulosa.icesi.edu.co:2180/record/display.uri?eid=2-s2.0-84930179575&origin=resultslist&sort=plf-f&src=s&st1=Microwave-assisted+ADMET+polymerization&st2=&sid=2d7e29caafad42578918533b53e3da5a&sot=b&sdt=b&sl=54&s=TITLE-ABS-KEY%28Microwave-assisted+ADMET+polymerization%29&relpos=0&citeCnt=1&searchTerm=; http://hdl.handle.net/10906/79891; https://doi.org/10.1016/j.tetlet.2015.04.122
• Palabra clave: Métodos de investigación en bioquímica; Biochemistry research; Polímeros; Medicamentos; Resonancia magnética nuclear; Polimerización
• Rights: openAccess
• License: https://creativecommons.org/licenses/by-nc-nd/4.0/