Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.

This article presents the results of improvement in the electrochemical properties of porous type anodic films grown on aluminium alloy AA2024 T3, obtained with the techniques of direct current, pulsed direct current and reverse pulse current, through an electrolyte H2SO4 al 15% v/v. Morphological a...

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Autores:
Aperador Chaparro, William Arnulfo
Delgado Tobón, A.
Bautista, J.
Tipo de recurso:
Article of journal
Fecha de publicación:
2013
Institución:
Escuela Colombiana de Ingeniería Julio Garavito
Repositorio:
Repositorio Institucional ECI
Idioma:
eng
OAI Identifier:
oai:repositorio.escuelaing.edu.co:001/1926
Acceso en línea:
https://repositorio.escuelaing.edu.co/handle/001/1926
Palabra clave:
Películas anódicas
Electroquímica
Análisis electroquímico
Electrochemistry
Electrochemical analysis
pulse current
anodic films
atomic force microscopy
electrochemical impedance spectroscopy
Tafel
Rights
openAccess
License
© 2013 by ESG
id ESCUELAIG2_eae86d9ade14e0765808c040c698103a
oai_identifier_str oai:repositorio.escuelaing.edu.co:001/1926
network_acronym_str ESCUELAIG2
network_name_str Repositorio Institucional ECI
repository_id_str
dc.title.eng.fl_str_mv Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
title Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
spellingShingle Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
Películas anódicas
Electroquímica
Análisis electroquímico
Electrochemistry
Electrochemical analysis
pulse current
anodic films
atomic force microscopy
electrochemical impedance spectroscopy
Tafel
title_short Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
title_full Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
title_fullStr Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
title_full_unstemmed Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
title_sort Improved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.
dc.creator.fl_str_mv Aperador Chaparro, William Arnulfo
Delgado Tobón, A.
Bautista, J.
dc.contributor.author.none.fl_str_mv Aperador Chaparro, William Arnulfo
Delgado Tobón, A.
Bautista, J.
dc.contributor.researchgroup.spa.fl_str_mv Manufactura y Servicios
dc.subject.armarc.esp.fl_str_mv Películas anódicas
Electroquímica
Análisis electroquímico
topic Películas anódicas
Electroquímica
Análisis electroquímico
Electrochemistry
Electrochemical analysis
pulse current
anodic films
atomic force microscopy
electrochemical impedance spectroscopy
Tafel
dc.subject.armarc.eng.fl_str_mv Electrochemistry
Electrochemical analysis
dc.subject.proposal.eng.fl_str_mv pulse current
anodic films
atomic force microscopy
electrochemical impedance spectroscopy
Tafel
description This article presents the results of improvement in the electrochemical properties of porous type anodic films grown on aluminium alloy AA2024 T3, obtained with the techniques of direct current, pulsed direct current and reverse pulse current, through an electrolyte H2SO4 al 15% v/v. Morphological analysis was used atomic force microscopy and scanning electron microscopy allowing to identify the films obtained with inverse pulse current have a grain size smaller than those obtained by the two other deposition techniques. The evaluation of corrosion resistance in the films, we used electrochemical impedance spectroscopy and anodic polarization curves Tafel. These evaluation techniques established that the reverse pulse current deposition can generate deposits which increase the corrosion resistance of the anodic film.
publishDate 2013
dc.date.issued.none.fl_str_mv 2013
dc.date.accessioned.none.fl_str_mv 2021-12-16T15:15:56Z
dc.date.available.none.fl_str_mv 2021-12-16T15:15:56Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.issn.none.fl_str_mv 14523981
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identifier_str_mv 14523981
url https://repositorio.escuelaing.edu.co/handle/001/1926
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.citationendpage.spa.fl_str_mv 9617
dc.relation.citationstartpage.spa.fl_str_mv 9607
dc.relation.citationvolume.spa.fl_str_mv 8
dc.relation.indexed.spa.fl_str_mv N/A
dc.relation.ispartofjournal.eng.fl_str_mv International Journal of Electrochemical Science
dc.relation.references.spa.fl_str_mv G. Mable Pinto, J. Nayak, A. Nityananda Shetty, Int. J. Electrochem. Sci., 4 (2009) 1452
W. Aperador, J. Caballero-Gómez, A. Delgado, Int. J. Electrochem. Sci., 8 (2013) 6154
M. Bethencourt, F.J. Botana, M.J. Cano, M. Marcos, J.M. Sánchez Amaya, L. González Rovira, Corrosion Science, 51 (2009) 518
S. Valizadeh, E.B Svedberg, P. Leisner, Journal of Applied Electrochemistry, 27 (2002) 97
H. Ashassi-Sorkhabi, A. Hagrah, N. Parvini-Ahmadi, J. Manzoori, Surface and Coatings Technology, 140 (2001) 278
H. Chi-Chang, W. Chi-Ming, Surface and Coatings Technology, 176 (2003) 75
A. Stankeviciute, K. leinartas, G. bikulcius, D. virbalyte,. Journal of applied electrochemistry,28 (1998) 89
J. Aldykewicz, H.S. Isaac, A.J. Davenport. J. Electrochem. Soc. 142 (1995) 3342
W. Bensalah, K. Elleuch, M. Feki, M. Wery, M.P. Gigandet, H.F. Ayedi.. Mater. Chem. Phys. 108 (2008) 296
J.P. Sullivan, G.C. Wood, Proc. Roy. Soc. Lond. 317 (1970) 511–543.
S.W. Dean, W.H. Anthony. Degradation of metals in atmosphere. American society of testing and materials, Philadelphia (1988)
H.M. Obispo, L.E. Murr, M. Arrowood, E.A. Trillo, J. Mater. Sci, 35 (2000) 3479
J.V. Kloet, A.W. Hassel, M. Stratmann, Z. Phys. Chem. 219 (2005) 1505
L. Lacroix, L. Ressier, C. Blanc, G. Mankowski. J. Electrochem. Soc. 155 (2008) 131
T.J. Warner, M.P. Schmidt, F. Sommer, D. Bellot. Z. Metallkd. 86 (1995) 494
. P. Campestrini, E.P.M. Van Westing, H.W. Van Rooijen, J.H.W. De Wit. Corros. Sci. 42 (2000) 1853
. J.W. Silva, A.G. Bustamante, E.N. Codaro, R.Z. Nakazato, L.R.O. Hein. Appl. Surf. Sci. 236 (2004) 356
G.O. Llevbare. Corrosion. 56 (2000) 227
W. Aperador, E. Vera, L. M. Ipaz., Revista EIA, 15 (2011) 9.
S. jiang, P. Luo, H.H. Zhou, C. P Fu, Y.F.Kuang, Transactions of Nonferrous Metals Society of China, 18(2008)825.
H.Shih, S. Tzou, Surface and Coatings Technology, 124 (2000)278.
B. Fori, P. Taberna, L. Arurault, J. Bonino, C. Gazeau, P. Bares, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 415(2012)187.
Y. Ma, X. Zhou, G.E. Thompson, M. Curioni, X. Zhong, E. Koroleva, P. Skeldon, P. Thomson, M. Fowles, Corrosion Science, 53 (2011) 4141.
S. A. Fadl-allah, Q. Mohsen, Applied Surface Science, 256 (2010) 5849.
dc.rights.eng.fl_str_mv © 2013 by ESG
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dc.format.extent.spa.fl_str_mv 11 páginas
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dc.publisher.spa.fl_str_mv ESG
dc.publisher.place.spa.fl_str_mv Bogotá, Colombia.
dc.source.spa.fl_str_mv http://www.electrochemsci.org/papers/vol8/80709607.pdf
institution Escuela Colombiana de Ingeniería Julio Garavito
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spelling Aperador Chaparro, William Arnulfofd72a695a50b1659e8dce8335949b6bd600Delgado Tobón, A.6532cdbdceba377ff6d2c04a32fb8ea8600Bautista, J.2a431468603d9b2f76080e3f3b070b7d600Manufactura y Servicios2021-12-16T15:15:56Z2021-12-16T15:15:56Z201314523981https://repositorio.escuelaing.edu.co/handle/001/1926This article presents the results of improvement in the electrochemical properties of porous type anodic films grown on aluminium alloy AA2024 T3, obtained with the techniques of direct current, pulsed direct current and reverse pulse current, through an electrolyte H2SO4 al 15% v/v. Morphological analysis was used atomic force microscopy and scanning electron microscopy allowing to identify the films obtained with inverse pulse current have a grain size smaller than those obtained by the two other deposition techniques. The evaluation of corrosion resistance in the films, we used electrochemical impedance spectroscopy and anodic polarization curves Tafel. These evaluation techniques established that the reverse pulse current deposition can generate deposits which increase the corrosion resistance of the anodic film.Este artículo presenta los resultados de mejora en las propiedades electroquímicas de películas anódicas de tipo poroso crecidas sobre aleación de aluminio AA2024 T3, obtenidas con las técnicas de corriente continua, corriente continua pulsada y corriente inversa, a través de un electrolito H2SO4 al 15% v/v. Se utilizó el análisis morfológico de microscopía de fuerza atómica y microscopía electrónica de barrido, lo que permitió identificar que las películas obtenidas con pulso de corriente inversa tienen un tamaño de grano menor que las obtenidas por las otras dos técnicas de depósito. Para la evaluación de la resistencia a la corrosión en las películas, se utilizó espectroscopía de impedancia electroquímica y curvas de polarización anódica Tafel. Estas técnicas de evaluación establecieron que la deposición de corriente de pulso inverso puede generar depósitos que aumentan la resistencia a la corrosión de la película anódica.11 páginasapplication/pdfengESGBogotá, Colombia.© 2013 by ESGinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2http://www.electrochemsci.org/papers/vol8/80709607.pdfImproved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating.Artículo de revistainfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85961796078N/AInternational Journal of Electrochemical ScienceG. Mable Pinto, J. Nayak, A. Nityananda Shetty, Int. J. Electrochem. Sci., 4 (2009) 1452W. Aperador, J. Caballero-Gómez, A. Delgado, Int. J. Electrochem. Sci., 8 (2013) 6154M. Bethencourt, F.J. Botana, M.J. Cano, M. Marcos, J.M. Sánchez Amaya, L. González Rovira, Corrosion Science, 51 (2009) 518S. Valizadeh, E.B Svedberg, P. Leisner, Journal of Applied Electrochemistry, 27 (2002) 97H. Ashassi-Sorkhabi, A. Hagrah, N. Parvini-Ahmadi, J. Manzoori, Surface and Coatings Technology, 140 (2001) 278H. Chi-Chang, W. Chi-Ming, Surface and Coatings Technology, 176 (2003) 75A. Stankeviciute, K. leinartas, G. bikulcius, D. virbalyte,. Journal of applied electrochemistry,28 (1998) 89J. Aldykewicz, H.S. Isaac, A.J. Davenport. J. Electrochem. Soc. 142 (1995) 3342W. Bensalah, K. Elleuch, M. Feki, M. Wery, M.P. Gigandet, H.F. Ayedi.. Mater. Chem. Phys. 108 (2008) 296J.P. Sullivan, G.C. Wood, Proc. Roy. Soc. Lond. 317 (1970) 511–543.S.W. Dean, W.H. Anthony. Degradation of metals in atmosphere. American society of testing and materials, Philadelphia (1988)H.M. Obispo, L.E. Murr, M. Arrowood, E.A. Trillo, J. Mater. Sci, 35 (2000) 3479J.V. Kloet, A.W. Hassel, M. Stratmann, Z. Phys. Chem. 219 (2005) 1505L. Lacroix, L. Ressier, C. Blanc, G. Mankowski. J. Electrochem. Soc. 155 (2008) 131T.J. Warner, M.P. Schmidt, F. Sommer, D. Bellot. Z. Metallkd. 86 (1995) 494. P. Campestrini, E.P.M. Van Westing, H.W. Van Rooijen, J.H.W. De Wit. Corros. Sci. 42 (2000) 1853. J.W. Silva, A.G. Bustamante, E.N. Codaro, R.Z. Nakazato, L.R.O. Hein. Appl. Surf. Sci. 236 (2004) 356G.O. Llevbare. Corrosion. 56 (2000) 227W. Aperador, E. Vera, L. M. Ipaz., Revista EIA, 15 (2011) 9.S. jiang, P. Luo, H.H. Zhou, C. P Fu, Y.F.Kuang, Transactions of Nonferrous Metals Society of China, 18(2008)825.H.Shih, S. Tzou, Surface and Coatings Technology, 124 (2000)278.B. Fori, P. Taberna, L. Arurault, J. Bonino, C. Gazeau, P. Bares, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 415(2012)187.Y. Ma, X. Zhou, G.E. Thompson, M. Curioni, X. Zhong, E. Koroleva, P. Skeldon, P. Thomson, M. Fowles, Corrosion Science, 53 (2011) 4141.S. A. Fadl-allah, Q. Mohsen, Applied Surface Science, 256 (2010) 5849.Películas anódicasElectroquímicaAnálisis electroquímicoElectrochemistryElectrochemical analysispulse currentanodic filmsatomic force microscopyelectrochemical impedance spectroscopyTafelORIGINALImproved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating..pdfImproved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating..pdfArtículo principal.application/pdf545960https://repositorio.escuelaing.edu.co/bitstream/001/1926/1/Improved%20Corrosion%20Protection%20Properties%20in%20Anodic%20Films%20Type%20Porous%20on%202024%20T3%20Aluminium%20Alloys%20Obtained%20by%20Pulse%20Reverse%20Plating..pdf31d89181e8ede16b65107ab9d872c254MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-81881https://repositorio.escuelaing.edu.co/bitstream/001/1926/2/license.txt5a7ca94c2e5326ee169f979d71d0f06eMD52open accessTEXTImproved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating..pdf.txtImproved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating..pdf.txtExtracted texttext/plain21082https://repositorio.escuelaing.edu.co/bitstream/001/1926/3/Improved%20Corrosion%20Protection%20Properties%20in%20Anodic%20Films%20Type%20Porous%20on%202024%20T3%20Aluminium%20Alloys%20Obtained%20by%20Pulse%20Reverse%20Plating..pdf.txte6acfb3898e40ad6223020e1ce8896e5MD53open accessTHUMBNAILImproved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating..pdf.jpgImproved Corrosion Protection Properties in Anodic Films Type Porous on 2024 T3 Aluminium Alloys Obtained by Pulse Reverse Plating..pdf.jpgGenerated Thumbnailimage/jpeg13570https://repositorio.escuelaing.edu.co/bitstream/001/1926/4/Improved%20Corrosion%20Protection%20Properties%20in%20Anodic%20Films%20Type%20Porous%20on%202024%20T3%20Aluminium%20Alloys%20Obtained%20by%20Pulse%20Reverse%20Plating..pdf.jpg48a364b3792ef98306a0db96b06cc1bbMD54open access001/1926oai:repositorio.escuelaing.edu.co:001/19262022-08-18 12:25:42.132open accessRepositorio Escuela Colombiana de Ingeniería Julio Garavitorepositorio.eci@escuelaing.edu.coU0kgVVNURUQgSEFDRSBQQVJURSBERUwgR1JVUE8gREUgUEFSRVMgRVZBTFVBRE9SRVMgREUgTEEgQ09MRUNDScOTTiAiUEVFUiBSRVZJRVciLCBPTUlUQSBFU1RBIExJQ0VOQ0lBLgoKQXV0b3Jpem8gYSBsYSBFc2N1ZWxhIENvbG9tYmlhbmEgZGUgSW5nZW5pZXLDrWEgSnVsaW8gR2FyYXZpdG8gcGFyYSBwdWJsaWNhciBlbCB0cmFiYWpvIGRlIGdyYWRvLCBhcnTDrWN1bG8sIHZpZGVvLCAKY29uZmVyZW5jaWEsIGxpYnJvLCBpbWFnZW4sIGZvdG9ncmFmw61hLCBhdWRpbywgcHJlc2VudGFjacOzbiB1IG90cm8gKGVuICAgIGFkZWxhbnRlIGRvY3VtZW50bykgcXVlIGVuIGxhIGZlY2hhIAplbnRyZWdvIGVuIGZvcm1hdG8gZGlnaXRhbCwgeSBsZSBwZXJtaXRvIGRlIGZvcm1hIGluZGVmaW5pZGEgcXVlIGxvIHB1YmxpcXVlIGVuIGVsIHJlcG9zaXRvcmlvIGluc3RpdHVjaW9uYWwsIAplbiBsb3MgdMOpcm1pbm9zIGVzdGFibGVjaWRvcyBlbiBsYSBMZXkgMjMgZGUgMTk4MiwgbGEgTGV5IDQ0IGRlIDE5OTMsIHkgZGVtw6FzIGxleWVzIHkganVyaXNwcnVkZW5jaWEgdmlnZW50ZQphbCByZXNwZWN0bywgcGFyYSBmaW5lcyBlZHVjYXRpdm9zIHkgbm8gbHVjcmF0aXZvcy4gRXN0YSBhdXRvcml6YWNpw7NuIGVzIHbDoWxpZGEgcGFyYSBsYXMgZmFjdWx0YWRlcyB5IGRlcmVjaG9zIGRlIAp1c28gc29icmUgbGEgb2JyYSBlbiBmb3JtYXRvIGRpZ2l0YWwsIGVsZWN0csOzbmljbywgdmlydHVhbDsgeSBwYXJhIHVzb3MgZW4gcmVkZXMsIGludGVybmV0LCBleHRyYW5ldCwgeSBjdWFscXVpZXIgCmZvcm1hdG8gbyBtZWRpbyBjb25vY2lkbyBvIHBvciBjb25vY2VyLgpFbiBtaSBjYWxpZGFkIGRlIGF1dG9yLCBleHByZXNvIHF1ZSBlbCBkb2N1bWVudG8gb2JqZXRvIGRlIGxhIHByZXNlbnRlIGF1dG9yaXphY2nDs24gZXMgb3JpZ2luYWwgeSBsbyBlbGFib3LDqSBzaW4gCnF1ZWJyYW50YXIgbmkgc3VwbGFudGFyIGxvcyBkZXJlY2hvcyBkZSBhdXRvciBkZSB0ZXJjZXJvcy4gUG9yIGxvIHRhbnRvLCBlcyBkZSBtaSBleGNsdXNpdmEgYXV0b3LDrWEgeSwgZW4gY29uc2VjdWVuY2lhLCAKdGVuZ28gbGEgdGl0dWxhcmlkYWQgc29icmUgw6lsLiBFbiBjYXNvIGRlIHF1ZWphIG8gYWNjacOzbiBwb3IgcGFydGUgZGUgdW4gdGVyY2VybyByZWZlcmVudGUgYSBsb3MgZGVyZWNob3MgZGUgYXV0b3Igc29icmUgCmVsIGRvY3VtZW50byBlbiBjdWVzdGnDs24sIGFzdW1pcsOpIGxhIHJlc3BvbnNhYmlsaWRhZCB0b3RhbCB5IHNhbGRyw6kgZW4gZGVmZW5zYSBkZSBsb3MgZGVyZWNob3MgYXF1w60gYXV0b3JpemFkb3MuIEVzdG8gCnNpZ25pZmljYSBxdWUsIHBhcmEgdG9kb3MgbG9zIGVmZWN0b3MsIGxhIEVzY3VlbGEgYWN0w7phIGNvbW8gdW4gdGVyY2VybyBkZSBidWVuYSBmZS4KVG9kYSBwZXJzb25hIHF1ZSBjb25zdWx0ZSBlbCBSZXBvc2l0b3JpbyBJbnN0aXR1Y2lvbmFsIGRlIGxhIEVzY3VlbGEsIGVsIENhdMOhbG9nbyBlbiBsw61uZWEgdSBvdHJvIG1lZGlvIGVsZWN0csOzbmljbywgCnBvZHLDoSBjb3BpYXIgYXBhcnRlcyBkZWwgdGV4dG8sIGNvbiBlbCBjb21wcm9taXNvIGRlIGNpdGFyIHNpZW1wcmUgbGEgZnVlbnRlLCBsYSBjdWFsIGluY2x1eWUgZWwgdMOtdHVsbyBkZWwgdHJhYmFqbyB5IGVsIAphdXRvci5Fc3RhIGF1dG9yaXphY2nDs24gbm8gaW1wbGljYSByZW51bmNpYSBhIGxhIGZhY3VsdGFkIHF1ZSB0ZW5nbyBkZSBwdWJsaWNhciB0b3RhbCBvIHBhcmNpYWxtZW50ZSBsYSBvYnJhIGVuIG90cm9zIAptZWRpb3MuRXN0YSBhdXRvcml6YWNpw7NuIGVzdMOhIHJlc3BhbGRhZGEgcG9yIGxhcyBmaXJtYXMgZGVsIChsb3MpIGF1dG9yKGVzKSBkZWwgZG9jdW1lbnRvLiAKU8OtIGF1dG9yaXpvIChhbWJvcykK

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