Study of heterostructures of Cu3BiS3-buffer layer measured by Kelvin probe force microscopy measurements (KPFM)1

The interface formed between Cu3BiS3 thin films and the buffer layer is a potentially limiting factor to the performance of solar cells based on Al/Cu3BiS3/buffer heterojunctions. The buffer layers of ZnS and In2S3 were grown by co-evaporation, and tested as an alternative to the traditional CdS dep...

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Autores:
Tipo de recurso:
Fecha de publicación:
2014
Institución:
Universidad del Rosario
Repositorio:
Repositorio EdocUR - U. Rosario
Idioma:
eng
OAI Identifier:
oai:repository.urosario.edu.co:10336/23627
Acceso en línea:
https://doi.org/10.1139/cjp-2013-0592
https://repository.urosario.edu.co/handle/10336/23627
Palabra clave:
Cadmium sulfide
Grain boundaries
Heterojunctions
Optical waveguides
Probes
Zinc sulfide
Cds
Chemical-bath deposition
Co-evaporations
Doping concentration
Electronic activity
Kelvin probe force microscopy
Buffer layers
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License
http://purl.org/coar/access_right/c_abf2
Description
Summary:The interface formed between Cu3BiS3 thin films and the buffer layer is a potentially limiting factor to the performance of solar cells based on Al/Cu3BiS3/buffer heterojunctions. The buffer layers of ZnS and In2S3 were grown by co-evaporation, and tested as an alternative to the traditional CdS deposited by chemical bath deposition. From the Kelvin probe force microscopy measurements, we found the values of the work function of ZnS, In2S3, and CdS, layers deposited into Cu3BiS3. Additionally, different electronic activity was found for different grain boundaries (GBs), from studies under illumination, we also found the net doping concentration and the density of charged GB states for Cu3BiS3 and Cu 3BiS3/CdS. © 2014 Published by NRC Research Press.