Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.

El cemento dental de ionómero de vidrio es un material de restauración o calza dental, consta de dos componentes: un sólido que es un vidrio básico y un líquido que es un ácido policarboxílico, en este trabajo se desarrolló un componente líquido; realizando la síntesis y caracterización de un copolí...

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Autores:
Cerón Barrera, Jorge Roberto
Saavedra Figueroa, Jhon Jairo
Tipo de recurso:
Tesis
Fecha de publicación:
2018
Institución:
Universidad ECCI
Repositorio:
Repositorio Institucional ECCI
Idioma:
spa
OAI Identifier:
oai:repositorio.ecci.edu.co:001/3212
Acceso en línea:
https://repositorio.ecci.edu.co/handle/001/3212
Palabra clave:
Ácido sórbico
Ácido acrílico
Ionómero de vidrio
Sorbic acid
Acrylic acid
Glass ionomer
Rights
openAccess
License
Derechos Reservados - Universidad ECCI, 2018
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network_acronym_str ECCI2
network_name_str Repositorio Institucional ECCI
repository_id_str
dc.title.spa.fl_str_mv Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
title Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
spellingShingle Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
Ácido sórbico
Ácido acrílico
Ionómero de vidrio
Sorbic acid
Acrylic acid
Glass ionomer
title_short Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
title_full Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
title_fullStr Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
title_full_unstemmed Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
title_sort Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.
dc.creator.fl_str_mv Cerón Barrera, Jorge Roberto
Saavedra Figueroa, Jhon Jairo
dc.contributor.advisor.none.fl_str_mv Castro Pinto, Germán Alfonso
dc.contributor.author.none.fl_str_mv Cerón Barrera, Jorge Roberto
Saavedra Figueroa, Jhon Jairo
dc.contributor.corporatename.spa.fl_str_mv Universidad ECCI
dc.subject.proposal.spa.fl_str_mv Ácido sórbico
Ácido acrílico
Ionómero de vidrio
topic Ácido sórbico
Ácido acrílico
Ionómero de vidrio
Sorbic acid
Acrylic acid
Glass ionomer
dc.subject.proposal.eng.fl_str_mv Sorbic acid
Acrylic acid
Glass ionomer
description El cemento dental de ionómero de vidrio es un material de restauración o calza dental, consta de dos componentes: un sólido que es un vidrio básico y un líquido que es un ácido policarboxílico, en este trabajo se desarrolló un componente líquido; realizando la síntesis y caracterización de un copolímero a partir de un ácido acrílico (AA) y ácido sórbico (AS) y utilizando como iniciador persulfato de amonio. El componente líquido se caracterizó mediante las técnicas cromatografía por exclusión de tamaños (SEC), espectroscopía infrarroja por transformada de Fourier (FTIR) y viscosidad. Posteriormente el componente líquido se mezcló con el componente vidrio de un cemento de ionómero de vidrio comercial marca Fuji II, para verificar sus propiedades mecánicas a compresión y se utilizó la técnica microscopía electrónica de barrido (SEM) para analizar su superficie de fractura.
publishDate 2018
dc.date.issued.none.fl_str_mv 2018
dc.date.accessioned.none.fl_str_mv 2023-01-12T21:47:54Z
dc.date.available.none.fl_str_mv 2023-01-12T21:47:54Z
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dc.relation.references.spa.fl_str_mv Aaseth, J., Hilt, B., & Bjørklund, G. (2018). Mercury exposure and health impacts in dental personnel. Environmental Research, 164(February), 65–69. https://doi.org/10.1016/j.envres.2018.02.019
Alatawi, R. A. S., Elsayed, N. H., & Mohamed, W. S. (2018). Influence of hydroxyapatite nanoparticles on the properties of glass ionomer cement. Journal of Materials Research and Technology, (x x), 6–11. https://doi.org/10.1016/j.jmrt.2018.01.010
Anusha, C., Sankar, R., Varunkumar, K., Sivasindhuja, G., & Ravikumar, V. (2017). Fourier transform-infrared spectroscopy as a diagnostic tool for mosquito coil smoke inhalation toxicity in Swiss Albino mice. Journal of Molecular Structure, 1149, 128–135. https://doi.org/10.1016/j.molstruc.2017.07.087
Askeland, D. R., & Phulé, P. P. (2004). Ciencia e ingeniería de los materiales. Retrieved from https://books.google.com/books?id=2kpDKWJ7eYIC&pgis=1
Bates, M. N. (2006). Mercury amalgam dental fillings: An epidemiologic assessment. International Journal of Hygiene and Environmental Health, 209(4), 309–316. https://doi.org/10.1016/j.ijheh.2005.11.006
Callahan, P. G., Stinville, J. C., Yao, E. R., Echlin, M. P., Titus, M. S., De Graef, M., … Pollock, T. M. (2018). Transmission scanning electron microscopy: Defect observations and image simulations. Ultramicroscopy, 186, 49–61. https://doi.org/10.1016/j.ultramic.2017.11.004
Chitra, J., Ghosh, M., & Mishra, H. N. (2017). Rapid quantification of cholesterol in dairy powders using Fourier transform near infrared spectroscopy and chemometrics. Food Control, 78, 342–349. https://doi.org/10.1016/j.foodcont.2016.10.008
Crisp, S., Kent, B. E., Lewis, B. G., Ferner, A. J., & Wilson, A. D. (1980). Glass-ionomer Cement Formulations. II. The Synthesis of NovelPolycarboxylic Acids. J Dent Res, 59(6), 1055–1063. https://doi.org/10.1177/00220345800590060801
Culbertson, B. M. (2001). Glass-ionomer dental restoratives. Progress in Polymer Science (Oxford), 26(4), 577–604. https://doi.org/10.1016/S0079-6700(01)00006-5
Dalen, K., Lygre, G. B., Kløve, H., Gjerdet, N. R., & Askevold, E. (2003). Memory functions in persons with dental amalgam. Journal of Dentistry, 31(7), 487–492. https://doi.org/10.1016/S0300-5712(03)00086-1
Djas, M., & Henczka, M. (2018). Reactive extraction of carboxylic acids using organic solvents and supercritical fluids: A review. Separation and Purification Technology, 201(January), 106–119. https://doi.org/10.1016/j.seppur.2018.02.010
Ferrand, C., Marc, F., Fritsch, P., & Cassand, P. (2000). Mutagenicity and genotoxicity of sorbic acid ± amine reaction products, 14, 423–428.
Fred W.Billmeyer, J. (2004). ciencia de los polímeros. (Reverté S:A, Ed.) (primera). Barcelona, España. Retrieved from https://books.google.es/books?hl=es&lr=&id=vL9QrpOKsQcC&oi=fnd&pg=PA1&dq=rela ted:77mSagbTbcgJ:scholar.google.com/&ots=yxLv8fvkEj&sig=LjNHxlzTndN1KY1JD rtbFrltoY#v=onepage&q&f=fals
Gratzl, G., Paulik, C., Hild, S., Guggenbichler, J. P., & Lackner, M. (2014). Antimicrobial activity of poly(acrylic acid) block copolymers. Materials Science and Engineering C, 38(1), 94–100. https://doi.org/10.1016/j.msec.2014.01.050
Gude, M., Schirner, R., Weck, D., Dohmen, E., & Andrich, M. (2016). Through-thickness compression testing of fabric reinforced composite materials: Adapted design of novel compression stamps. Polymer Testing, 56, 269–276. https://doi.org/10.1016/j.polymertesting.2016.10.024
Klement, T., & Büchs, J. (2013). Itaconic acid - A biotechnological process in change. Bioresource Technology, 135, 422–431. https://doi.org/10.1016/j.biortech.2012.11.141
Klement, T., & Büchs, J. (2013). Itaconic acid - A biotechnological process in change. Bioresource Technology, 135, 422–431. https://doi.org/10.1016/j.biortech.2012.11.141
Moheet, I. A., Luddin, N., Ab Rahman, I., Masudi, S. M., Kannan, T. P., & Abd Ghani, N. R. N. (2018). Evaluation of mechanical properties and bond strength of nano-hydroxyapatite silica added glass ionomer cement. Ceramics International, (March), 0–1. https://doi.org/10.1016/j.ceramint.2018.03.010
Moshaverinia, A., Roohpour, N., Ansari, S., Moshaverinia, M., Schricker, S., Darr, J. a., & Rehman, I. U. (2009). Effects of N-vinylpyrrolidone (NVP) containing polyelectrolytes on surface properties of conventional glass-ionomer cements (GIC). Dental Materials, 25(10), 1240–1247. https://doi.org/10.1016/j.dental.2009.05.006
Nicholson, J. W. (2016). Adhesion of glass-ionomer cements to teeth: A review. International Journal of Adhesion and Adhesives, 69, 33–38. https://doi.org/10.1016/j.ijadhadh.2016.03.012
Nisenbaum, A., Apelblat, A., & Manzurola, E. (2012). Volumetric properties of itaconic acid aqueous solutions. Journal of Chemical Thermodynamics, 47, 42–47. https://doi.org/10.1016/j.jct.2011.09.014
Pandey, H., Kumar, V., & Roy, B. K. (2014). Assessment of genotoxicity of some common food preservatives using Allium cepa L. as a test plant. Toxicology Reports, 1, 300–308. https://doi.org/10.1016/j.toxrep.2014.06.002
Petrescu, L., Fermeglia, M., & Cormos, C. C. (2016). Life Cycle Analysis applied to acrylic acid production process with different fuels for steam generation. Journal of Cleaner Production, 133(2016), 294–303. https://doi.org/10.1016/j.jclepro.2016.05.088
Pirok, B. W. J., Breuer, P., Hoppe, S. J. M., Chitty, M., Welch, E., Farkas, T., … Schoenmakers, 45 P. J. (2017). Size-exclusion chromatography using core-shell particles. Journal of Chromatography A, 1486, 96–102. https://doi.org/10.1016/j.chroma.2016.12.015
Sakthivel, M., Franklin, D. S., Sudarsan, S., Chitra, G., & Guhanathan, S. (2017). Investigation on Au-nano incorporated pH-sensitive (itaconic acid/acrylic acid/triethylene glycol) based polymeric biocompatible hydrogels. Materials Science and Engineering C, 75, 517–523. https://doi.org/10.1016/j.msec.2017.02.054
Schramm, G. (1994). A Practical Approach to Rheology and Rheometry. Rheology, 291. https://doi.org/10.1017/CBO9781107415324.004
Shimoyama, A., Fujisaka, A., & Obika, S. (2017). Evaluation of size-exclusion chromatography for the analysis of phosphorothioate oligonucleotides. Journal of Pharmaceutical and Biomedical Analysis, 136, 55–65. https://doi.org/10.1016/j.jpba.2016.12.036
Smith, William & Hashemi, J. (2006). Fundamentos de la ciencia e ingenieria de materiales. Retrieved from https://chirinossilvaroger.files.wordpress.com/2012/05/fundamentos-de-la ciencia-e-ingenieria-de-materiales-4ta-edicic3b3n-william-f-smi
Standards, I. (2003). म ा नक
Sun, L., Yan, Z., Duan, Y., Zhang, J., & Liu, B. (2018). Improvement of the mechanical, tribological and antibacterial properties of glass ionomer cements by fluorinated graphene. Dental Materials, 1–13. https://doi.org/10.1016/j.dental.2018.02.006
Wade, L. G. J. (2012). www.elsolucionario.org. (Pearson, Ed.) (septima). México.
William, D., & Callister, J. (1995). Introducción a la Ciencia e Ingeniería de los Materiales. Reverté,.
Winkler, C., Frick, B., Schroecksnadel, K., Schennach, H., & Fuchs, D. (2006). Food preservatives sodium sulfite and sorbic acid suppress mitogen-stimulated peripheral blood mononuclear cells. Food and Chemical Toxicology, 44(12), 2003–2007. https://doi.org/10.1016/j.fct.2006.06.019
Yamazaki, T., Brantley, W., Culbertson, B., Seghi, R., & Schricker, S. (2005). The measure of wear in N-vinyl pyrrolidinone (NVP) modifed glass-ionomer cements. Polymers for Advanced Technologies, 16(2–3), 113–116. https://doi.org/10.1002/pat.552
Yang, R. J., Liu, C. C., Wang, Y. N., Hou, H. H., & Fu, L. M. (2017). A comprehensive review of micro-distillation methods. Chemical Engineering Journal, 313, 1509–1520. https://doi.org/10.1016/j.cej.2016.11.041
Zahir, F., Rizwi, S. J., Haq, S. K., & Khan, R. H. (2005). Low dose mercury toxicity and human health. Environmental Toxicology and Pharmacology, 20(2), 351–360. https://doi.org/10.1016/j.etap.2005.03.007
Zhu, P., Chen, Y., Fang, J., Wang, Z., Xie, C., Hou, B., … Xu, F. (2016). Solubility and solution thermodynamics of thymol in six pure organic solvents. Journal of Chemical Thermodynamics, 92, 198–206. https://doi.org/10.1016/j.jct.2015.09.010
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spelling Castro Pinto, Germán Alfonso58f31ab4037bef2a91480f67b1da5588Cerón Barrera, Jorge Roberto52ff277bc8baf7ee27713bdfa56941bcSaavedra Figueroa, Jhon Jairo0de0e8f93b654c318d8b1e67c7dcbfcbUniversidad ECCI2023-01-12T21:47:54Z2023-01-12T21:47:54Z2018https://repositorio.ecci.edu.co/handle/001/3212El cemento dental de ionómero de vidrio es un material de restauración o calza dental, consta de dos componentes: un sólido que es un vidrio básico y un líquido que es un ácido policarboxílico, en este trabajo se desarrolló un componente líquido; realizando la síntesis y caracterización de un copolímero a partir de un ácido acrílico (AA) y ácido sórbico (AS) y utilizando como iniciador persulfato de amonio. El componente líquido se caracterizó mediante las técnicas cromatografía por exclusión de tamaños (SEC), espectroscopía infrarroja por transformada de Fourier (FTIR) y viscosidad. Posteriormente el componente líquido se mezcló con el componente vidrio de un cemento de ionómero de vidrio comercial marca Fuji II, para verificar sus propiedades mecánicas a compresión y se utilizó la técnica microscopía electrónica de barrido (SEM) para analizar su superficie de fractura.Glass ionomer dental cement is a restorative material or dental tracing, it consists of two components: a solid that is a basic glass and a liquid that is a polycarboxylic acid, in this work it is a liquid component; perform the synthesis and characterization of a copolymer of an acrylic acid (AA) and sorbic acid (AS) and use ammonium persulfate as initiator. The liquid component was characterized by the size exclusion (SEC), infrared Fourier transform spectroscopy (FTIR) and viscosity techniques. Subsequently, the liquid component was mixed with the commercial glass ionomer cement glass component of the Fuji II brand, to verify its mechanical properties under compression and the scanning electron microscopy (SEM) technique was used to analyze its fracture surface.Resumen 5 Abstract 6 Lista de abreviaturas 7 Contenido 8 Lista de imágenes 10 Lista de tablas 11 1.Introducción 12 1.2 Objetivos específicos fueron 13 2. Marco teórico 14 2.1. Generalidades de los polímeros 14 2.2. Monómero 14 2.3. Polímero 14 2.4. Polimerización por adición 14 2.5. Polimerización por radicales libres 14 2.5.2. Propagación 15 2.5.3. Terminación 15 2.6. Cemento ionómero de vidrio (GIC) 15 2.7. Ácido Acrílico (AA) 15 2.8. Ácido Itacónico (AI) 16 2.9. Ácido sórbico (AS) 17 2.10. Ácido carboxílico (AC) 17 2.11. Técnica de destilación al vacío 18 2.12. Técnicas instrumentales de caracterización 18 2.13. Espectroscopia infrarroja por transformada de Fourier (FTIR) 18 2.14. Cromatografía de exclusión por tamaños (SEC) 19 2.15. Viscosidad de polímeros –prueba de reología 19 2.16. Ensayo de compresión 19 2.17. Microscopia electrónica de barrido (SEM) 20 3. Antecedentes 20 4. Procedimiento experimental 21 4.1. Paso 1. Síntesis de copolímeros y poliácido 22 4.2. Paso 2. Deshidratación y purificación del poliácido 26 4.3. Paso 3. Caracterización con FTIR y cromatografía del poliácido y copolímeros. 28 4.4. Paso 4. Mezcla de ionómero de vidrio comercial Fuji II con el componente liquido ionómero de Vidrio 28 4.5. Paso 5. Caracterización del cemento dental con la técnica de viscosidad y prueba de compresión a las propiedades mecánicas 29 4.6. Paso 6. Caracterización del cemento dental utilizando la técnica (SEM) 29 5. Resultados y análisis de los resultados 29 5.1. Caracterización con la técnica (FTIR) del poliácido (AA-AI-AS) sintetizado 29 5.2. Caracterización del poliácido y copolímeros en sus propiedades mecánicas a la resistencia a compresión 34 5.3. Caracterización del cemento dental utilizando la técnica (SEM) 35 5.4. Caracterización del poliácido y copolímeros por medio de la técnica (SEC) 37 5.5. Caracterización de copolímeros y poliácido por medio de la técnica de viscosidad 40 6. Conclusiones 41 7. Bibliografía 43PregradoIngeniero en MecánicaIngeniería Mecánica46 p.application/pdfspaUniversidad ECCIColombiaFacultad de IngenieríasDerechos Reservados - Universidad ECCI, 2018info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Desarrollo del componente líquido de ionómero de vidrio a partir del poliácido del ácido acrílico y del ácido sórbico.Trabajo de grado - Pregradohttp://purl.org/coar/resource_type/c_46echttp://purl.org/coar/resource_type/c_7a1fTextinfo:eu-repo/semantics/bachelorThesishttps://purl.org/redcol/resource_type/WPhttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/version/c_dc82b40f9837b551Aaseth, J., Hilt, B., & Bjørklund, G. (2018). Mercury exposure and health impacts in dental personnel. Environmental Research, 164(February), 65–69. https://doi.org/10.1016/j.envres.2018.02.019Alatawi, R. A. S., Elsayed, N. H., & Mohamed, W. S. (2018). Influence of hydroxyapatite nanoparticles on the properties of glass ionomer cement. Journal of Materials Research and Technology, (x x), 6–11. https://doi.org/10.1016/j.jmrt.2018.01.010Anusha, C., Sankar, R., Varunkumar, K., Sivasindhuja, G., & Ravikumar, V. (2017). Fourier transform-infrared spectroscopy as a diagnostic tool for mosquito coil smoke inhalation toxicity in Swiss Albino mice. Journal of Molecular Structure, 1149, 128–135. https://doi.org/10.1016/j.molstruc.2017.07.087Askeland, D. R., & Phulé, P. P. (2004). Ciencia e ingeniería de los materiales. Retrieved from https://books.google.com/books?id=2kpDKWJ7eYIC&pgis=1Bates, M. N. (2006). Mercury amalgam dental fillings: An epidemiologic assessment. International Journal of Hygiene and Environmental Health, 209(4), 309–316. https://doi.org/10.1016/j.ijheh.2005.11.006Callahan, P. G., Stinville, J. C., Yao, E. R., Echlin, M. P., Titus, M. S., De Graef, M., … Pollock, T. M. (2018). Transmission scanning electron microscopy: Defect observations and image simulations. Ultramicroscopy, 186, 49–61. https://doi.org/10.1016/j.ultramic.2017.11.004Chitra, J., Ghosh, M., & Mishra, H. N. (2017). Rapid quantification of cholesterol in dairy powders using Fourier transform near infrared spectroscopy and chemometrics. Food Control, 78, 342–349. https://doi.org/10.1016/j.foodcont.2016.10.008Crisp, S., Kent, B. E., Lewis, B. G., Ferner, A. J., & Wilson, A. D. (1980). Glass-ionomer Cement Formulations. II. The Synthesis of NovelPolycarboxylic Acids. J Dent Res, 59(6), 1055–1063. https://doi.org/10.1177/00220345800590060801Culbertson, B. M. (2001). Glass-ionomer dental restoratives. Progress in Polymer Science (Oxford), 26(4), 577–604. https://doi.org/10.1016/S0079-6700(01)00006-5Dalen, K., Lygre, G. B., Kløve, H., Gjerdet, N. R., & Askevold, E. (2003). Memory functions in persons with dental amalgam. Journal of Dentistry, 31(7), 487–492. https://doi.org/10.1016/S0300-5712(03)00086-1Djas, M., & Henczka, M. (2018). Reactive extraction of carboxylic acids using organic solvents and supercritical fluids: A review. Separation and Purification Technology, 201(January), 106–119. https://doi.org/10.1016/j.seppur.2018.02.010Ferrand, C., Marc, F., Fritsch, P., & Cassand, P. (2000). Mutagenicity and genotoxicity of sorbic acid ± amine reaction products, 14, 423–428.Fred W.Billmeyer, J. (2004). ciencia de los polímeros. (Reverté S:A, Ed.) (primera). Barcelona, España. Retrieved from https://books.google.es/books?hl=es&lr=&id=vL9QrpOKsQcC&oi=fnd&pg=PA1&dq=rela ted:77mSagbTbcgJ:scholar.google.com/&ots=yxLv8fvkEj&sig=LjNHxlzTndN1KY1JD rtbFrltoY#v=onepage&q&f=falsGratzl, G., Paulik, C., Hild, S., Guggenbichler, J. P., & Lackner, M. (2014). Antimicrobial activity of poly(acrylic acid) block copolymers. Materials Science and Engineering C, 38(1), 94–100. https://doi.org/10.1016/j.msec.2014.01.050Gude, M., Schirner, R., Weck, D., Dohmen, E., & Andrich, M. (2016). Through-thickness compression testing of fabric reinforced composite materials: Adapted design of novel compression stamps. Polymer Testing, 56, 269–276. https://doi.org/10.1016/j.polymertesting.2016.10.024Klement, T., & Büchs, J. (2013). Itaconic acid - A biotechnological process in change. Bioresource Technology, 135, 422–431. https://doi.org/10.1016/j.biortech.2012.11.141Klement, T., & Büchs, J. (2013). Itaconic acid - A biotechnological process in change. Bioresource Technology, 135, 422–431. https://doi.org/10.1016/j.biortech.2012.11.141Moheet, I. A., Luddin, N., Ab Rahman, I., Masudi, S. M., Kannan, T. P., & Abd Ghani, N. R. N. (2018). Evaluation of mechanical properties and bond strength of nano-hydroxyapatite silica added glass ionomer cement. Ceramics International, (March), 0–1. https://doi.org/10.1016/j.ceramint.2018.03.010Moshaverinia, A., Roohpour, N., Ansari, S., Moshaverinia, M., Schricker, S., Darr, J. a., & Rehman, I. U. (2009). Effects of N-vinylpyrrolidone (NVP) containing polyelectrolytes on surface properties of conventional glass-ionomer cements (GIC). Dental Materials, 25(10), 1240–1247. https://doi.org/10.1016/j.dental.2009.05.006Nicholson, J. W. (2016). Adhesion of glass-ionomer cements to teeth: A review. International Journal of Adhesion and Adhesives, 69, 33–38. https://doi.org/10.1016/j.ijadhadh.2016.03.012Nisenbaum, A., Apelblat, A., & Manzurola, E. (2012). Volumetric properties of itaconic acid aqueous solutions. Journal of Chemical Thermodynamics, 47, 42–47. https://doi.org/10.1016/j.jct.2011.09.014Pandey, H., Kumar, V., & Roy, B. K. (2014). Assessment of genotoxicity of some common food preservatives using Allium cepa L. as a test plant. Toxicology Reports, 1, 300–308. https://doi.org/10.1016/j.toxrep.2014.06.002Petrescu, L., Fermeglia, M., & Cormos, C. C. (2016). Life Cycle Analysis applied to acrylic acid production process with different fuels for steam generation. Journal of Cleaner Production, 133(2016), 294–303. https://doi.org/10.1016/j.jclepro.2016.05.088Pirok, B. W. J., Breuer, P., Hoppe, S. J. M., Chitty, M., Welch, E., Farkas, T., … Schoenmakers, 45 P. J. (2017). Size-exclusion chromatography using core-shell particles. Journal of Chromatography A, 1486, 96–102. https://doi.org/10.1016/j.chroma.2016.12.015Sakthivel, M., Franklin, D. S., Sudarsan, S., Chitra, G., & Guhanathan, S. (2017). Investigation on Au-nano incorporated pH-sensitive (itaconic acid/acrylic acid/triethylene glycol) based polymeric biocompatible hydrogels. Materials Science and Engineering C, 75, 517–523. https://doi.org/10.1016/j.msec.2017.02.054Schramm, G. (1994). A Practical Approach to Rheology and Rheometry. Rheology, 291. https://doi.org/10.1017/CBO9781107415324.004Shimoyama, A., Fujisaka, A., & Obika, S. (2017). Evaluation of size-exclusion chromatography for the analysis of phosphorothioate oligonucleotides. Journal of Pharmaceutical and Biomedical Analysis, 136, 55–65. https://doi.org/10.1016/j.jpba.2016.12.036Smith, William & Hashemi, J. (2006). Fundamentos de la ciencia e ingenieria de materiales. Retrieved from https://chirinossilvaroger.files.wordpress.com/2012/05/fundamentos-de-la ciencia-e-ingenieria-de-materiales-4ta-edicic3b3n-william-f-smiStandards, I. (2003). म ा नकSun, L., Yan, Z., Duan, Y., Zhang, J., & Liu, B. (2018). Improvement of the mechanical, tribological and antibacterial properties of glass ionomer cements by fluorinated graphene. Dental Materials, 1–13. https://doi.org/10.1016/j.dental.2018.02.006Wade, L. G. J. (2012). www.elsolucionario.org. (Pearson, Ed.) (septima). México.William, D., & Callister, J. (1995). Introducción a la Ciencia e Ingeniería de los Materiales. Reverté,.Winkler, C., Frick, B., Schroecksnadel, K., Schennach, H., & Fuchs, D. (2006). Food preservatives sodium sulfite and sorbic acid suppress mitogen-stimulated peripheral blood mononuclear cells. Food and Chemical Toxicology, 44(12), 2003–2007. https://doi.org/10.1016/j.fct.2006.06.019Yamazaki, T., Brantley, W., Culbertson, B., Seghi, R., & Schricker, S. (2005). The measure of wear in N-vinyl pyrrolidinone (NVP) modifed glass-ionomer cements. Polymers for Advanced Technologies, 16(2–3), 113–116. https://doi.org/10.1002/pat.552Yang, R. J., Liu, C. C., Wang, Y. N., Hou, H. H., & Fu, L. M. (2017). A comprehensive review of micro-distillation methods. Chemical Engineering Journal, 313, 1509–1520. https://doi.org/10.1016/j.cej.2016.11.041Zahir, F., Rizwi, S. J., Haq, S. K., & Khan, R. H. (2005). Low dose mercury toxicity and human health. Environmental Toxicology and Pharmacology, 20(2), 351–360. https://doi.org/10.1016/j.etap.2005.03.007Zhu, P., Chen, Y., Fang, J., Wang, Z., Xie, C., Hou, B., … Xu, F. (2016). Solubility and solution thermodynamics of thymol in six pure organic solvents. 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Thumbnailimage/jpeg15050https://repositorio.ecci.edu.co/bitstream/001/3212/10/Cesi%c3%b3n%20de%20derechos.pdf.jpg5d31d6884fd49cdbb11f564ec67d236dMD510TEXTTHUMBNAIL001/3212oai:repositorio.ecci.edu.co:001/32122024-07-24 16:14:44.813Repositorio Digital Universidad ECCIrepositorio.institucional@ecci.edu.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