Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis
El presente documento de investigación tiene como objetivo principal dar a conocer ciertas consideraciones esenciales en el proceso de producción de polioles a base de aceites vegetales y aceite usado de cocina mediante el método de glicerolisis, a partir de la obtención de materia prima de recursos...
- Autores:
-
Díaz Holguín, Karol Dayana
- Tipo de recurso:
- Trabajo de grado de pregrado
- Fecha de publicación:
- 2017
- Institución:
- Universidad ECCI
- Repositorio:
- Repositorio Institucional ECCI
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.ecci.edu.co:001/1386
- Acceso en línea:
- https://repositorio.ecci.edu.co/handle/001/1386
- Palabra clave:
- Aceite Usado
Glicerina
Aceites Higuerilla
Poliol
Waste oil
Glycerin
Higuerilla oils
Polyol
- Rights
- openAccess
- License
- Derechos Reservados - Universidad ECCI, 2017
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dc.title.spa.fl_str_mv |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis |
title |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis |
spellingShingle |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis Aceite Usado Glicerina Aceites Higuerilla Poliol Waste oil Glycerin Higuerilla oils Polyol |
title_short |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis |
title_full |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis |
title_fullStr |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis |
title_full_unstemmed |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis |
title_sort |
Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisis |
dc.creator.fl_str_mv |
Díaz Holguín, Karol Dayana |
dc.contributor.advisor.none.fl_str_mv |
Malagón Romero, Dionisio Humberto Moreno, Diana Catalina |
dc.contributor.author.none.fl_str_mv |
Díaz Holguín, Karol Dayana |
dc.subject.proposal.spa.fl_str_mv |
Aceite Usado Glicerina Aceites Higuerilla Poliol |
topic |
Aceite Usado Glicerina Aceites Higuerilla Poliol Waste oil Glycerin Higuerilla oils Polyol |
dc.subject.proposal.eng.fl_str_mv |
Waste oil Glycerin Higuerilla oils Polyol |
description |
El presente documento de investigación tiene como objetivo principal dar a conocer ciertas consideraciones esenciales en el proceso de producción de polioles a base de aceites vegetales y aceite usado de cocina mediante el método de glicerolisis, a partir de la obtención de materia prima de recursos renovables. El método de glicerolisis como se evidencio es una reacción de transesterificación de triglicéridos utilizando glicerol como alcohol, obteniendo así monoglicéridos y diglicéridos. |
publishDate |
2017 |
dc.date.issued.none.fl_str_mv |
2017 |
dc.date.accessioned.none.fl_str_mv |
2021-08-27T17:55:10Z |
dc.date.available.none.fl_str_mv |
2021-08-27T17:55:10Z |
dc.type.spa.fl_str_mv |
Trabajo de grado - Pregrado |
dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_dc82b40f9837b551 |
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dc.type.content.spa.fl_str_mv |
Text |
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info:eu-repo/semantics/bachelorThesis |
dc.type.redcol.spa.fl_str_mv |
https://purl.org/redcol/resource_type/TP |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
format |
http://purl.org/coar/resource_type/c_7a1f |
dc.identifier.uri.none.fl_str_mv |
https://repositorio.ecci.edu.co/handle/001/1386 |
url |
https://repositorio.ecci.edu.co/handle/001/1386 |
dc.language.iso.spa.fl_str_mv |
spa |
language |
spa |
dc.relation.references.spa.fl_str_mv |
A. A. Apostolakou, I. K. (2009). Techno-economic analysis of a biodiesel production process from vegetable oils. Fuel Process. Technol., vol. 90, no. 7–8, pp. 1023–1031. A. Beatriz, Y. A. (2015). Glicerol: um breve histórico e aplicação em sínteses estereosseletivas. Quim. Nova, vol. 34, , no. 2, pp. 1–15. A. Gil, F. J. (2007). POLIURETANOS DEGRADABLES A PARTIR DE ACEITE DE HIGUERILLA . Sci. Tech., vol. 8, no. 36, pp. 1–6. A. Imasuen, F. I. (2014). Isolation and characterization of castor seed oil and its utilization potential in the production of polyurethane foam. Walailak J. Sci. Technol., vol. 11, no. 5, 421–427. A. Islam, H. R.-y. (2016). Glycerolysis of palm fatty acid distillate for biodiesel feedstock under different reactor conditions. FUEL, vol. 174, pp. 133–139. A. P. D. De Lima, E. M. (2013). Towards regioselective enzymatic hydrolysis and glycerolysis of tricaaprylin in miniemulsion and the direct preparation of polyurethane from the hydrolysis products. J. Mol. Catal. B Enzym., 127- 137. A. Shirke, B. D. (2015, vol. 57). Novel Applications of Castor Oil Based Polyurethanes: a Short Review. Polymer Science, 292-297,no 4. Agencia Iberoamericana de ciencia y Tecnología. (2011). Corpoica lanza primera variedad colombiana de higuerilla para clima frío moderado. Obtenido de http://www.dicyt.com/noticias/corpoica-lanza-primera-variedad-colombiana C. J. a. Mota, C. X. (2009). C. J. a. Mota, C. X. A. da Silva, and V. L. C. Gonçalves, “Gliceroquímica: novos produtos e processos a partir da glicerina de produção de biodiesel. Quim. Nova, vol. 32, no. 3, pp. 639–648. C. S. Sipaut, S. M. (2012). Synthesis and characterization of polyols from refined cooking oil for polyurethane foam formation . Cell. Polym, vol 31, 19-38. C. Santibáñez, M. T. (2011). Residual Glycerol from Biodiesel Manufacturing, Waste or Potential Source of Bioenergyno. A Review,” Chil. J. Agric. Res., vol. 71, no. 3, pp. 469–475. C. V. R. De Moura, a. S. (s.f.). Synthesis and characterization of polyesters from glycerol by-product of biodiesel production. J. Braz. Chem. Soc., vol. 23, no. 7, pp. 1226–1231 C. Varella, K. O. (2016). Crude glycerol by transesterification process from used cooking oils : Characterization and potentialities on hydrogen bioproduction. Int. J. energy, vol. 41, 14641–51. C. Zambiazi, R., Przybylski, R., Zambiazi, M., & Mendonça. (2007). Fatty acid composition of vegetable oils and fats. B.CEPPA, 111–120 C., M. C. (2004). El uso del aceite de palma en la producción de poliuretanos. Palmas, 422-427, vol. 25. Cardona Alzate, J. A.-D. (2010). Obtenida Como Coproducto En La Producción De Biodiésel * Na Produção De Biodiesel. Ing. Univ. Bogotá, vol. 14, no. 1, pp. 9–27. D. a. Echeverri, F. C. (2011). Glycerolysis of soybean oil with crude glycerol containing residual alkaline catalysts from biodiesel production. JAOCS, J. Am. Oil Chem. Soc., vol. 88, no. 4, pp. 551–557. D. a. Echeverri, L. a. (2015). Synthesis and copolymerization of thermosetting resins obtained from vegetable oils and biodiesel-derived crude glycerol. Eur. Polym. J., vol. 67, pp. 428–438 D. P. Cárdenas, C. P. (2006). Evaluación de la producción de 1,3-propanodiol por cepas nativas de Clostridium sp. mediante fermentación a partir de glicerol USP y glicerol industrial subproducto de la producción de biodiés. Rev. Col. Cienc. Quím. Farm, vol. 35, no. 1, pp. 120–137. Dogan, T. H. (2016). The testing of the effects of cooking conditions on the quality of biodiesel produced from waste cooking oils. Renewable Energy, 466-473, vol. 94. E. O. dos Santos, M. M. (2012). Evaluation of the Composition of Culture Medium for Yeast Biomass Production Using. Brazilian J. Microbiol., vol. 43, no. 2, pp. 432–440. E. Sharmin, F. Z. (2015). “Recent advances in vegetable oils based environment friendly coatings. Ind. Crops Prod, 215–229. E. Sharmin, F., Zafar, D., & Akram, M. A. (2015). Recent advances in vegetable oils based environment friendly coating. Ind. Crops Prod., vol. 76, 215–229. Echeverri, T. (20 de 04 de 2012). Aceite de cocina usado se recicla y sirve para hacer Biodiesel. EL TIEMPO, pág. 2. Obtenido de http://www.eltiempo.com/archivo/documento/MAM-5365455 Federación Nacional de Biocombustibles de Colombia. (02 de 10 de 2015). Producción de biodiesel en Colombia. Obtenido de Estadísticas sobre Biodiesel, 2014. : http://www.fedebiocombustibles.com/v3/estadistica mostrar_info-titulo-Biodiesel.htm Fernando, R. L. (2012). Espumas rigidas de poliuretano. Editorial Universidad de Antioquia, Medellín, p. 83. González, A. F. (2010). Production of monoglycerides from castor oil using crude and refined glycerin. . Study of the main variables of the process, Vitae, 1- 12. Gupta, M. K. (2012). Obtaining monoglycerides by esterification of glycerol with palmitic acid using some high activity preparations of Candida antarctica lipase B . Process Biochem., vol. 47, no 3, pp. 503–508. Hofer, R. (1997). Oleochemical Polyols-A New Raw Material source for polyurethane coatings and floorings. Formulation and production forum, 65- 72, no 869. Huertas, I. S. (2012). Obtención y caracterización de biodiesel a partir de aceite de semillas de Ricinus communis (higuerilla) modificadas genéticamente y cultivadas en el eje cafetero. Cafe de Pereira. J. Fu, Z. L. (2016). Cation exchange resin catalysed biodiesel production from used cooking oil (UCO):. Cation exchange resin catalInvestigation of impurities effect, 1058-1065, vol. 181. J. Pulido, P. F. ( Medellín, 2007). Synthesis and characterization of polyurethane elastomers from polyol-suspensions of castor oil and yucca starch. Rev. Fac. Ing. Univ. Antioquia de Colomb. , No. 39, 100-111 K. F. Mustafa, S. A. (2015). Experimental analysis of a porous burner operating on kerosene–vegetable cooking oil blends for thermophotovoltaic power generation. Energy Conversion and Management, 544-560, vol. 96. L. Freitas, A. V. (s.f.). Enzymatic synthesis of monoglycerides by esterification reaction using Penicillium camembertii lipase immobilized on epoxy SiO2- PVA composite. J. Mol. Catal. B Enzym., vol. 65. L. Freitas, P. C. (2009). An integrated approach to produce biodiesel and monoglycerides by enzymatic interestification of babassu oil (Orbinya sp) . Process Biochem., vol. 44, no. 10, pp. 1068–1074. Li, S. H. (2014). Polyols and polyurethane foams from base-catalyzed liquefaction of lignocellulosic biomass by crude glycerol . Effects of crude glycerol impurities ,Ind. Crop. Prod., vol. 57, pp. 188–194 M. Bernal, L. K.-R. (2013). Evaluating Colombian Clostridium spp. strains’ hydrogen production using glycerol as substrate. Electron. J. Biotechnol., vol. 16, no. 2, p. 6. M. Desroches, M. E. (2012). From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products. Polym. Rev., vol. 52, no. 1, pp. 38–79. M. F. Valero, J. E. (2009). Determinación de la densidad de entrecruzamiento de poliuretanos obtenidos a partir de aceite de ricino modificado por transesterificación. Polímeros Cienc. e Tecnol., vol. 19, no. 1, 14–21. M. I. Aranguren, J. F. (2012). Biodegradation of a vegetable oil based polyurethane and wood flour composites. Polym. Test., vol. 31, no. 1, pp. 7–15. M. M. Nobrega, J. B. (2012). Glycerol with different purity grades derived from biodiesel: Effect on the mechanical and viscoelastic properties of biodegradable strands and films. Mater. Sci. Eng. C, v M. Zan, A. S. (2015). Synthesis of Transesterified Palm Olein - Based Polyol and Rigid Polyurethanes from this Polyol. pp. 243–255. M. Zhang, H. P. (2014). Study of the mechanical, thermal properties and flame retardancy of rigid polyurethane foams prepared from modified castor-oil based polyols . nd. Crops Prod., vol. 59, 135–143. M. Zieleniewska, M. K. (2015). Preparation and characterisation of rigid polyurethane foams using a rapeseed oil-based polyol . Ind. Crops Prod., vol. 74, pp. 887–897. Mireza, K., & Ryszkowska, J. (2016). Polyurethane elastomers from polyols based on soybean oil with a different molar ration. Polymer Degradation and Stability, 1-11. Mizera , K., & Ryszkowska, J. (2016). Polyurethane elastomers from polyols based on soybean oil with a different molar ratio. Polymer Degradation and Stability, 1-11. Montoya, D. (2010). Bioprocesos aplicados a la valorización del glicerol residual en la producción de biodiésel Bioprocesses for adding value to residual glycerol in the production of biodiesel Introducción. 126–135. O. Valerio, T. H. (2015). Improved utilization of crude glycerol from biodiesel industries : Synthesis and characterization of sustainable biobased polyesters. Ind. Crop. Prod., vol. 78, , pp. 141–147 P. Mazo, L. a. (2009). Síntesis y caracterización de espumas flexibles de poliuretano obtenidas a partir de aceite de castor maleinizado. Polímeros Cienc. e Tecnol., vol. 19, no. 2, 149–154. P. Mazo, L. a. (2009). Síntesis y caracterización de espumas flexibles de poliuretano obtenidas a partir de aceite de castor maleinizado. Polímeros Cienc. e Tecnol., vol. 19, no. 2, pp. 149–154. P. S. Kong, M. K. (2016). Conversion of crude and pure glycerol into derivatives : A feasibility evaluation. Renew. Sustain. Energy Rev., vol. 63,, pp. 533–555. Petrovic, Z. (2008). Polyurethanes from Vegetable Oils . Polym. Rev., vol. 48, no. 1, pp. 109–155. Q. Li, H. W. (2016). Enhanced succinate production from glycerol by engineered Escherichia coli strains. Bioresour. Technol., vol. 218,, pp. 217–223, R. de Vasconcelos Vieira Lopes, N. P. (2013). Synthesis of polyols and polyurethanes from vegetable oils–kinetic and characterization. J. Polym. Res., vol. 20, no. 9. R. Hofer, P. D. (1997). Oleochemical Polyols-A New Raw Material source for polyurethane coatings and floorings. Formulation and production forum, vol. 69, 65-72, no 869. R. Hofer, P. D.--.-a. (1997). Oleochemical Polyols--A New Raw Material Source for Polyurethane Coatings and Floorings. no. 869, pp. 65–72. R. Tanaka, S. H. (2008). Preparation and characterization of polyurethane foams using a palm oil-based polyol . Bioresour. Technol., vol. 99, no. 9, pp. 3810– 3816 S. Anandan, G. K. (2005). Effect of different physical and chemical treatments on detoxification of ricin in castor cake. Anim. Feed Sci. Technol, no. 1–2, 159– 168 S. Benítez. (2013). Productividad animal de bovinos estabulados suplementados con glicerina cruda S. Gryglewicz, W. P. (2003.). Preparation of polyol esters based on vegetable and animal fats . Bioresour. Technol., vol. 87, no. 1, pp. 35–39. S. M. Cardona, R. G. (2010). S. M. Cardona, R. González, A. Franco, F. Cardeño, and L. A. Ríos, “Production of monoglycerides from castor oil using crude and refined glycerin. Study of the main variables of the process . Vitae, vol. 17, no. 2, pp. 1–12. S. Marx. (2016). Glycerol-free biodiesel production through transesteri fi cation . Fuel Process. Technol., vol. 151, 139–147. S. Miao, P. W. (2014). Vegetable-oil-based polymers as future polymeric biomaterials . Acta Biomater., vol. 10, no. 4, pp. 1692–1704 Skopal, M. H. (2010). Treatment of glycerol phase formed by biodiesel production,. Bioresour. Technol vol. 101, no. 9, pp. 3242–3245. T. O. Akande, A. A. (2011). Toxicity and Nutritive Assessment of Castor (Ricinus cummunis) Oil and Processed Cake in Rat Diet . Asian J. Anim. Sci, no. 5, pp. 330–339. Tippawan, T. T. (2016). Using glycerol for hydrogen production via sorption enhanced chemical looping reforming. Energy Convers. Manag., vol. 124, pp. 325–332. X. Kong, G. L. (2013). Preparation and characterization of high-solid polyurethane coating systems based on vegetable oil derived polyols. Prog. Org. Coatings, no. 9, 1151–1160,. X. Luo, X. G. (2016). Value-added processing of crude glycerol into chemicals and polymers. Bioresour. Technol., vol. 215, pp. 144–154. Y, p., D. E. P. A., P., H. , M., & A. Y., E. (2006). PREPARACIÓN Y CARACTERIZACIÓN DE POllURETANOS A PARTIR DE ACEITE DE HIGUERlllA MODIFICADO. AlMIDÓN Y ESTIRENO. Y. Dang, X. L. (2016). Value-added conversion of waste cooking oil and post consumer PET bottles into biodiesel and polyurethane foams. Waste Management, 360-366,vol. 52. Yamin, Z. A.-H. (2014). Parametric study of the alkali catalyzed transesterification of waste frying oil for Biodiesel production. Energy Convers. Manag., vol. 79, 246–254. Z. Gao, Y. M. (2016). Effect of crude glycerol impurities on lipid preparation by Rhodosporidium toruloides yeast 32489 . Bioresour. Technol., vol. 218, pp. 373–379. |
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Derechos Reservados - Universidad ECCI, 2017 |
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Malagón Romero, Dionisio Humberto9cbdd5ec3b5873756502e576a3a302eeMoreno, Diana Catalina2c8ad2fb31f3505d61c9ac82af2d5b82Díaz Holguín, Karol Dayanae2103d795a803cecd978f08b051fed222021-08-27T17:55:10Z2021-08-27T17:55:10Z2017https://repositorio.ecci.edu.co/handle/001/1386El presente documento de investigación tiene como objetivo principal dar a conocer ciertas consideraciones esenciales en el proceso de producción de polioles a base de aceites vegetales y aceite usado de cocina mediante el método de glicerolisis, a partir de la obtención de materia prima de recursos renovables. El método de glicerolisis como se evidencio es una reacción de transesterificación de triglicéridos utilizando glicerol como alcohol, obteniendo así monoglicéridos y diglicéridos.1 Lista de tablas 2 Lista de graficas 3 Lista de figuras 4 Resumen 5 Abstract 5.1 Palabras claves 6 Introducción 7 Titulo 8 Problema de investigacion A. Descripción del problema B. Formulación del problema 9 Objetivos de la investigacion A. Objetivo general B. Objetivos específicos 10 Justificación 11 Delimitación de la investigacion 12 Marco de referencia de la investigacion A. Aceites vegetales B. Aceite usado de cocina C. Aceite de higuerilla o aceite de castor D. Glicerol E. Glicerólisis F. Poliol 13 Tipo de investigacion 14 Diseño metodológico A Síntesis poliol B Caracterización de polioles 15 Resultados diseño experimental A Polioles obtenidos B Caracterización por infrarrojo 16 Conclusiones 17 Referencias 18 Anexos 18.1 Protocolos 18.2 Caracterización por infrarrojoPregradoTecnólogo en Gestión de Procesos IndustrialesIngeniería Industrial46 p.application/pdfspaUniversidad ECCIColombiaFacultad de IngenieríasDerechos Reservados - Universidad ECCI, 2017info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Estandarización del proceso de obtención de polioles a partir de aceites vegetales mediante glicerólisisTrabajo de grado - Pregradohttp://purl.org/coar/resource_type/c_7a1fTextinfo:eu-repo/semantics/bachelorThesishttps://purl.org/redcol/resource_type/TPhttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/version/c_dc82b40f9837b551A. A. Apostolakou, I. K. (2009). Techno-economic analysis of a biodiesel production process from vegetable oils. Fuel Process. Technol., vol. 90, no. 7–8, pp. 1023–1031.A. Beatriz, Y. A. (2015). Glicerol: um breve histórico e aplicação em sínteses estereosseletivas. Quim. Nova, vol. 34, , no. 2, pp. 1–15.A. Gil, F. J. (2007). POLIURETANOS DEGRADABLES A PARTIR DE ACEITE DE HIGUERILLA . Sci. Tech., vol. 8, no. 36, pp. 1–6.A. Imasuen, F. I. (2014). Isolation and characterization of castor seed oil and its utilization potential in the production of polyurethane foam. Walailak J. Sci. Technol., vol. 11, no. 5, 421–427.A. Islam, H. R.-y. (2016). Glycerolysis of palm fatty acid distillate for biodiesel feedstock under different reactor conditions. FUEL, vol. 174, pp. 133–139.A. P. D. De Lima, E. M. (2013). Towards regioselective enzymatic hydrolysis and glycerolysis of tricaaprylin in miniemulsion and the direct preparation of polyurethane from the hydrolysis products. J. Mol. Catal. B Enzym., 127- 137.A. Shirke, B. D. (2015, vol. 57). Novel Applications of Castor Oil Based Polyurethanes: a Short Review. Polymer Science, 292-297,no 4.Agencia Iberoamericana de ciencia y Tecnología. (2011). Corpoica lanza primera variedad colombiana de higuerilla para clima frío moderado. Obtenido de http://www.dicyt.com/noticias/corpoica-lanza-primera-variedad-colombianaC. J. a. Mota, C. X. (2009). C. J. a. Mota, C. X. A. da Silva, and V. L. C. Gonçalves, “Gliceroquímica: novos produtos e processos a partir da glicerina de produção de biodiesel. Quim. Nova, vol. 32, no. 3, pp. 639–648.C. S. Sipaut, S. M. (2012). Synthesis and characterization of polyols from refined cooking oil for polyurethane foam formation . Cell. Polym, vol 31, 19-38.C. Santibáñez, M. T. (2011). Residual Glycerol from Biodiesel Manufacturing, Waste or Potential Source of Bioenergyno. A Review,” Chil. J. Agric. Res., vol. 71, no. 3, pp. 469–475.C. V. R. De Moura, a. S. (s.f.). Synthesis and characterization of polyesters from glycerol by-product of biodiesel production. J. Braz. Chem. Soc., vol. 23, no. 7, pp. 1226–1231C. Varella, K. O. (2016). Crude glycerol by transesterification process from used cooking oils : Characterization and potentialities on hydrogen bioproduction. Int. J. energy, vol. 41, 14641–51.C. Zambiazi, R., Przybylski, R., Zambiazi, M., & Mendonça. (2007). Fatty acid composition of vegetable oils and fats. B.CEPPA, 111–120C., M. C. (2004). El uso del aceite de palma en la producción de poliuretanos. Palmas, 422-427, vol. 25.Cardona Alzate, J. A.-D. (2010). Obtenida Como Coproducto En La Producción De Biodiésel * Na Produção De Biodiesel. Ing. Univ. Bogotá, vol. 14, no. 1, pp. 9–27.D. a. Echeverri, F. C. (2011). Glycerolysis of soybean oil with crude glycerol containing residual alkaline catalysts from biodiesel production. JAOCS, J. Am. Oil Chem. Soc., vol. 88, no. 4, pp. 551–557.D. a. Echeverri, L. a. (2015). Synthesis and copolymerization of thermosetting resins obtained from vegetable oils and biodiesel-derived crude glycerol. Eur. Polym. J., vol. 67, pp. 428–438D. P. Cárdenas, C. P. (2006). Evaluación de la producción de 1,3-propanodiol por cepas nativas de Clostridium sp. mediante fermentación a partir de glicerol USP y glicerol industrial subproducto de la producción de biodiés. Rev. Col. Cienc. Quím. Farm, vol. 35, no. 1, pp. 120–137.Dogan, T. H. (2016). The testing of the effects of cooking conditions on the quality of biodiesel produced from waste cooking oils. Renewable Energy, 466-473, vol. 94.E. O. dos Santos, M. M. (2012). Evaluation of the Composition of Culture Medium for Yeast Biomass Production Using. Brazilian J. Microbiol., vol. 43, no. 2, pp. 432–440.E. Sharmin, F. Z. (2015). “Recent advances in vegetable oils based environment friendly coatings. Ind. Crops Prod, 215–229.E. Sharmin, F., Zafar, D., & Akram, M. A. (2015). Recent advances in vegetable oils based environment friendly coating. Ind. Crops Prod., vol. 76, 215–229.Echeverri, T. (20 de 04 de 2012). Aceite de cocina usado se recicla y sirve para hacer Biodiesel. EL TIEMPO, pág. 2. Obtenido de http://www.eltiempo.com/archivo/documento/MAM-5365455Federación Nacional de Biocombustibles de Colombia. (02 de 10 de 2015). Producción de biodiesel en Colombia. Obtenido de Estadísticas sobre Biodiesel, 2014. : http://www.fedebiocombustibles.com/v3/estadistica mostrar_info-titulo-Biodiesel.htmFernando, R. L. (2012). Espumas rigidas de poliuretano. Editorial Universidad de Antioquia, Medellín, p. 83.González, A. F. (2010). Production of monoglycerides from castor oil using crude and refined glycerin. . Study of the main variables of the process, Vitae, 1- 12.Gupta, M. K. (2012). Obtaining monoglycerides by esterification of glycerol with palmitic acid using some high activity preparations of Candida antarctica lipase B . Process Biochem., vol. 47, no 3, pp. 503–508.Hofer, R. (1997). Oleochemical Polyols-A New Raw Material source for polyurethane coatings and floorings. Formulation and production forum, 65- 72, no 869.Huertas, I. S. (2012). Obtención y caracterización de biodiesel a partir de aceite de semillas de Ricinus communis (higuerilla) modificadas genéticamente y cultivadas en el eje cafetero. Cafe de Pereira.J. Fu, Z. L. (2016). Cation exchange resin catalysed biodiesel production from used cooking oil (UCO):. Cation exchange resin catalInvestigation of impurities effect, 1058-1065, vol. 181.J. Pulido, P. F. ( Medellín, 2007). Synthesis and characterization of polyurethane elastomers from polyol-suspensions of castor oil and yucca starch. Rev. Fac. Ing. Univ. Antioquia de Colomb. , No. 39, 100-111K. F. Mustafa, S. A. (2015). Experimental analysis of a porous burner operating on kerosene–vegetable cooking oil blends for thermophotovoltaic power generation. Energy Conversion and Management, 544-560, vol. 96.L. Freitas, A. V. (s.f.). Enzymatic synthesis of monoglycerides by esterification reaction using Penicillium camembertii lipase immobilized on epoxy SiO2- PVA composite. J. Mol. Catal. B Enzym., vol. 65.L. Freitas, P. C. (2009). An integrated approach to produce biodiesel and monoglycerides by enzymatic interestification of babassu oil (Orbinya sp) . Process Biochem., vol. 44, no. 10, pp. 1068–1074.Li, S. H. (2014). Polyols and polyurethane foams from base-catalyzed liquefaction of lignocellulosic biomass by crude glycerol . Effects of crude glycerol impurities ,Ind. Crop. Prod., vol. 57, pp. 188–194M. Bernal, L. K.-R. (2013). Evaluating Colombian Clostridium spp. strains’ hydrogen production using glycerol as substrate. Electron. J. Biotechnol., vol. 16, no. 2, p. 6.M. Desroches, M. E. (2012). From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products. Polym. Rev., vol. 52, no. 1, pp. 38–79.M. F. Valero, J. E. (2009). Determinación de la densidad de entrecruzamiento de poliuretanos obtenidos a partir de aceite de ricino modificado por transesterificación. Polímeros Cienc. e Tecnol., vol. 19, no. 1, 14–21.M. I. Aranguren, J. F. (2012). Biodegradation of a vegetable oil based polyurethane and wood flour composites. Polym. Test., vol. 31, no. 1, pp. 7–15.M. M. Nobrega, J. B. (2012). Glycerol with different purity grades derived from biodiesel: Effect on the mechanical and viscoelastic properties of biodegradable strands and films. Mater. Sci. Eng. C, vM. Zan, A. S. (2015). Synthesis of Transesterified Palm Olein - Based Polyol and Rigid Polyurethanes from this Polyol. pp. 243–255.M. Zhang, H. P. (2014). Study of the mechanical, thermal properties and flame retardancy of rigid polyurethane foams prepared from modified castor-oil based polyols . nd. Crops Prod., vol. 59, 135–143.M. Zieleniewska, M. K. (2015). Preparation and characterisation of rigid polyurethane foams using a rapeseed oil-based polyol . Ind. Crops Prod., vol. 74, pp. 887–897.Mireza, K., & Ryszkowska, J. (2016). Polyurethane elastomers from polyols based on soybean oil with a different molar ration. Polymer Degradation and Stability, 1-11.Mizera , K., & Ryszkowska, J. (2016). Polyurethane elastomers from polyols based on soybean oil with a different molar ratio. Polymer Degradation and Stability, 1-11.Montoya, D. (2010). Bioprocesos aplicados a la valorización del glicerol residual en la producción de biodiésel Bioprocesses for adding value to residual glycerol in the production of biodiesel Introducción. 126–135.O. Valerio, T. H. (2015). Improved utilization of crude glycerol from biodiesel industries : Synthesis and characterization of sustainable biobased polyesters. Ind. Crop. Prod., vol. 78, , pp. 141–147P. Mazo, L. a. (2009). Síntesis y caracterización de espumas flexibles de poliuretano obtenidas a partir de aceite de castor maleinizado. Polímeros Cienc. e Tecnol., vol. 19, no. 2, 149–154.P. Mazo, L. a. (2009). Síntesis y caracterización de espumas flexibles de poliuretano obtenidas a partir de aceite de castor maleinizado. Polímeros Cienc. e Tecnol., vol. 19, no. 2, pp. 149–154.P. S. Kong, M. K. (2016). Conversion of crude and pure glycerol into derivatives : A feasibility evaluation. Renew. Sustain. Energy Rev., vol. 63,, pp. 533–555.Petrovic, Z. (2008). Polyurethanes from Vegetable Oils . Polym. Rev., vol. 48, no. 1, pp. 109–155.Q. Li, H. W. (2016). Enhanced succinate production from glycerol by engineered Escherichia coli strains. Bioresour. Technol., vol. 218,, pp. 217–223,R. de Vasconcelos Vieira Lopes, N. P. (2013). Synthesis of polyols and polyurethanes from vegetable oils–kinetic and characterization. J. Polym. Res., vol. 20, no. 9.R. Hofer, P. D. (1997). Oleochemical Polyols-A New Raw Material source for polyurethane coatings and floorings. Formulation and production forum, vol. 69, 65-72, no 869.R. Hofer, P. D.--.-a. (1997). Oleochemical Polyols--A New Raw Material Source for Polyurethane Coatings and Floorings. no. 869, pp. 65–72.R. Tanaka, S. H. (2008). Preparation and characterization of polyurethane foams using a palm oil-based polyol . Bioresour. Technol., vol. 99, no. 9, pp. 3810– 3816S. Anandan, G. K. (2005). Effect of different physical and chemical treatments on detoxification of ricin in castor cake. Anim. Feed Sci. Technol, no. 1–2, 159– 168S. Benítez. (2013). Productividad animal de bovinos estabulados suplementados con glicerina crudaS. Gryglewicz, W. P. (2003.). Preparation of polyol esters based on vegetable and animal fats . Bioresour. Technol., vol. 87, no. 1, pp. 35–39.S. M. Cardona, R. G. (2010). S. M. Cardona, R. González, A. Franco, F. Cardeño, and L. A. Ríos, “Production of monoglycerides from castor oil using crude and refined glycerin. Study of the main variables of the process . Vitae, vol. 17, no. 2, pp. 1–12.S. Marx. (2016). Glycerol-free biodiesel production through transesteri fi cation . Fuel Process. Technol., vol. 151, 139–147.S. Miao, P. W. (2014). Vegetable-oil-based polymers as future polymeric biomaterials . Acta Biomater., vol. 10, no. 4, pp. 1692–1704Skopal, M. H. (2010). Treatment of glycerol phase formed by biodiesel production,. Bioresour. Technol vol. 101, no. 9, pp. 3242–3245.T. O. Akande, A. A. (2011). Toxicity and Nutritive Assessment of Castor (Ricinus cummunis) Oil and Processed Cake in Rat Diet . Asian J. Anim. Sci, no. 5, pp. 330–339.Tippawan, T. T. (2016). Using glycerol for hydrogen production via sorption enhanced chemical looping reforming. Energy Convers. Manag., vol. 124, pp. 325–332.X. Kong, G. L. (2013). Preparation and characterization of high-solid polyurethane coating systems based on vegetable oil derived polyols. Prog. Org. Coatings, no. 9, 1151–1160,.X. Luo, X. G. (2016). Value-added processing of crude glycerol into chemicals and polymers. Bioresour. Technol., vol. 215, pp. 144–154.Y, p., D. E. P. A., P., H. , M., & A. Y., E. (2006). PREPARACIÓN Y CARACTERIZACIÓN DE POllURETANOS A PARTIR DE ACEITE DE HIGUERlllA MODIFICADO. AlMIDÓN Y ESTIRENO.Y. Dang, X. L. (2016). Value-added conversion of waste cooking oil and post consumer PET bottles into biodiesel and polyurethane foams. Waste Management, 360-366,vol. 52.Yamin, Z. A.-H. (2014). Parametric study of the alkali catalyzed transesterification of waste frying oil for Biodiesel production. Energy Convers. Manag., vol. 79, 246–254.Z. Gao, Y. M. (2016). Effect of crude glycerol impurities on lipid preparation by Rhodosporidium toruloides yeast 32489 . Bioresour. 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ECCIrepositorio.institucional@ecci.edu.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