Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K

Artículo científico

Autores:
Muñoz, María M.
Rodríguez, Carlos J.
Delgado, Daniel Ricardo
Peña, María A.
Jouyban, Abolghasem
Martínez, Fleming
Tipo de recurso:
Article of journal
Fecha de publicación:
2015
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
Idioma:
OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/971
Acceso en línea:
https://hdl.handle.net/20.500.12494/971
Palabra clave:
Sodium sulfonamides Propylene glycol Solubility Apparent specific volume Jouyban–Acree model
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closedAccess
License
Licencia CC
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network_name_str Repositorio UCC
repository_id_str
dc.title.spa.fl_str_mv Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
title Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
spellingShingle Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
Sodium sulfonamides Propylene glycol Solubility Apparent specific volume Jouyban–Acree model
title_short Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
title_full Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
title_fullStr Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
title_full_unstemmed Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
title_sort Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
dc.creator.fl_str_mv Muñoz, María M.
Rodríguez, Carlos J.
Delgado, Daniel Ricardo
Peña, María A.
Jouyban, Abolghasem
Martínez, Fleming
dc.contributor.advisor.none.fl_str_mv Delgado, Daniel Ricardo
dc.contributor.author.none.fl_str_mv Muñoz, María M.
Rodríguez, Carlos J.
Delgado, Daniel Ricardo
Peña, María A.
Jouyban, Abolghasem
Martínez, Fleming
dc.subject.spa.fl_str_mv Sodium sulfonamides Propylene glycol Solubility Apparent specific volume Jouyban–Acree model
topic Sodium sulfonamides Propylene glycol Solubility Apparent specific volume Jouyban–Acree model
description Artículo científico
publishDate 2015
dc.date.issued.none.fl_str_mv 2015-07-05
dc.date.accessioned.none.fl_str_mv 2017-08-09T01:10:16Z
dc.date.available.none.fl_str_mv 2017-08-09T01:10:16Z
dc.type.none.fl_str_mv Artículo
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dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12494/971
dc.identifier.bibliographicCitation.spa.fl_str_mv M.M. Muñoz, C.J. Rodríguez, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez. Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K. Journal of Molecular Liquids 211 (2015) 192–196
url https://hdl.handle.net/20.500.12494/971
identifier_str_mv M.M. Muñoz, C.J. Rodríguez, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez. Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K. Journal of Molecular Liquids 211 (2015) 192–196
dc.relation.isversionof.spa.fl_str_mv http://dx.doi.org/10.1016/j.molliq.2015.07.016
dc.rights.cc.none.fl_str_mv Licencia CC
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rights_invalid_str_mv Licencia CC
http://purl.org/coar/access_right/c_14cb
eu_rights_str_mv closedAccess
dc.publisher.spa.fl_str_mv Universidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000
dc.publisher.program.spa.fl_str_mv Ingeniería Industrial
dc.publisher.place.spa.fl_str_mv Neiva
institution Universidad Cooperativa de Colombia
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spelling Delgado, Daniel RicardoMuñoz, María M.Rodríguez, Carlos J.Delgado, Daniel RicardoPeña, María A.Jouyban, AbolghasemMartínez, Fleming2017-08-09T01:10:16Z2017-08-09T01:10:16Z2015-07-05https://hdl.handle.net/20.500.12494/971M.M. Muñoz, C.J. Rodríguez, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez. Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K. Journal of Molecular Liquids 211 (2015) 192–196Artículo científicoEquilibrium solubility of sodiumsulfadiazine (Na.SDZ), sodiumsulfamerazine (Na.SMR), and sodiumsulfamethazine (Na.SMT),was determined in aqueous binary mixtures of propylene glycol (PG) at 298.15 K. If the solubility values expressed in both concentration scales are considered, i.e. mole fraction and molarity, in water-rich mixtures the solubility decrease as: Na.SDZ N Na.SMT N Na.SMR, whereas, in PG-rich mixtures the observed order is: Na.SMT N Na.SDZ N Na.SMR. In all cases the solubility in neat water is higher than those in neat PG. Correlation of the solubility data obtainedwasmade bymeans of the Jouyban–Acreemodel for all the sodiumsulfonamides. Otherwise, apparent specific volumes (ϕVsp) of sodiumsulfonamides at saturationwere also calculated in all the mixtures. The average ϕV sp values are as follows: 0.663 cm3 g−1 for Na.SDZ, 0.723 cm3 g−1 for Na.SMR,and 0.740 cm3 g−1 for Na.SMT, with a variation lower than 5.0% in each case.1. Introduction, 2. Experimental, 2.1. Reagents and materials, 2.2. Solvent mixture preparation, 2.3. Solubility determinations, 3. Results and discussion, 3.1. Experimental solubility of sodium sulfonamides, 3.2. Solubility calculations with the Jouyban–Acree model, 4. Conclusions, Acknowledgments,m, References.danielr.delgado@campusucc.edu.coUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000Ingeniería IndustrialNeivahttp://dx.doi.org/10.1016/j.molliq.2015.07.016Sodium sulfonamides Propylene glycol Solubility Apparent specific volume Jouyban–Acree modelSolubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 KArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionLicencia CCinfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbPublicationTHUMBNAIL2015_Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K.pdf.jpg2015_Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K.pdf.jpgIM Thumbnailimage/jpeg19657https://repository.ucc.edu.co/bitstreams/38d105da-8a31-4ae2-b353-b1a930633850/download93784e859a1aa9174c82e1762af559fbMD54ORIGINAL2015_Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K.pdf2015_Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K.pdfapplication/pdf562484https://repository.ucc.edu.co/bitstreams/27cbca05-4b41-4746-ba20-9b8e1350eb25/downloaddd287cd55730718165e1cca9085284faMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repository.ucc.edu.co/bitstreams/f75872e3-384f-444e-9d09-0a40f237c37d/download8a4605be74aa9ea9d79846c1fba20a33MD52TEXT2015_Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K.pdf.txt2015_Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K.pdf.txtExtracted texttext/plain28245https://repository.ucc.edu.co/bitstreams/10c428d5-9522-4027-83c4-49551110fe00/download536887d05af3866654c6e20bd0ae3219MD5320.500.12494/971oai:repository.ucc.edu.co:20.500.12494/9712024-08-10 20:59:14.083open.accesshttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.comTk9URTogUExBQ0UgWU9VUiBPV04gTElDRU5TRSBIRVJFClRoaXMgc2FtcGxlIGxpY2Vuc2UgaXMgcHJvdmlkZWQgZm9yIGluZm9ybWF0aW9uYWwgcHVycG9zZXMgb25seS4KCk5PTi1FWENMVVNJVkUgRElTVFJJQlVUSU9OIExJQ0VOU0UKCkJ5IHNpZ25pbmcgYW5kIHN1Ym1pdHRpbmcgdGhpcyBsaWNlbnNlLCB5b3UgKHRoZSBhdXRob3Iocykgb3IgY29weXJpZ2h0Cm93bmVyKSBncmFudHMgdG8gRFNwYWNlIFVuaXZlcnNpdHkgKERTVSkgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgdG8gcmVwcm9kdWNlLAp0cmFuc2xhdGUgKGFzIGRlZmluZWQgYmVsb3cpLCBhbmQvb3IgZGlzdHJpYnV0ZSB5b3VyIHN1Ym1pc3Npb24gKGluY2x1ZGluZwp0aGUgYWJzdHJhY3QpIHdvcmxkd2lkZSBpbiBwcmludCBhbmQgZWxlY3Ryb25pYyBmb3JtYXQgYW5kIGluIGFueSBtZWRpdW0sCmluY2x1ZGluZyBidXQgbm90IGxpbWl0ZWQgdG8gYXVkaW8gb3IgdmlkZW8uCgpZb3UgYWdyZWUgdGhhdCBEU1UgbWF5LCB3aXRob3V0IGNoYW5naW5nIHRoZSBjb250ZW50LCB0cmFuc2xhdGUgdGhlCnN1Ym1pc3Npb24gdG8gYW55IG1lZGl1bSBvciBmb3JtYXQgZm9yIHRoZSBwdXJwb3NlIG9mIHByZXNlcnZhdGlvbi4KCllvdSBhbHNvIGFncmVlIHRoYXQgRFNVIG1heSBrZWVwIG1vcmUgdGhhbiBvbmUgY29weSBvZiB0aGlzIHN1Ym1pc3Npb24gZm9yCnB1cnBvc2VzIG9mIHNlY3VyaXR5LCBiYWNrLXVwIGFuZCBwcmVzZXJ2YXRpb24uCgpZb3UgcmVwcmVzZW50IHRoYXQgdGhlIHN1Ym1pc3Npb24gaXMgeW91ciBvcmlnaW5hbCB3b3JrLCBhbmQgdGhhdCB5b3UgaGF2ZQp0aGUgcmlnaHQgdG8gZ3JhbnQgdGhlIHJpZ2h0cyBjb250YWluZWQgaW4gdGhpcyBsaWNlbnNlLiBZb3UgYWxzbyByZXByZXNlbnQKdGhhdCB5b3VyIHN1Ym1pc3Npb24gZG9lcyBub3QsIHRvIHRoZSBiZXN0IG9mIHlvdXIga25vd2xlZGdlLCBpbmZyaW5nZSB1cG9uCmFueW9uZSdzIGNvcHlyaWdodC4KCklmIHRoZSBzdWJtaXNzaW9uIGNvbnRhaW5zIG1hdGVyaWFsIGZvciB3aGljaCB5b3UgZG8gbm90IGhvbGQgY29weXJpZ2h0LAp5b3UgcmVwcmVzZW50IHRoYXQgeW91IGhhdmUgb2J0YWluZWQgdGhlIHVucmVzdHJpY3RlZCBwZXJtaXNzaW9uIG9mIHRoZQpjb3B5cmlnaHQgb3duZXIgdG8gZ3JhbnQgRFNVIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdApzdWNoIHRoaXJkLXBhcnR5IG93bmVkIG1hdGVyaWFsIGlzIGNsZWFybHkgaWRlbnRpZmllZCBhbmQgYWNrbm93bGVkZ2VkCndpdGhpbiB0aGUgdGV4dCBvciBjb250ZW50IG9mIHRoZSBzdWJtaXNzaW9uLgoKSUYgVEhFIFNVQk1JU1NJT04gSVMgQkFTRUQgVVBPTiBXT1JLIFRIQVQgSEFTIEJFRU4gU1BPTlNPUkVEIE9SIFNVUFBPUlRFRApCWSBBTiBBR0VOQ1kgT1IgT1JHQU5JWkFUSU9OIE9USEVSIFRIQU4gRFNVLCBZT1UgUkVQUkVTRU5UIFRIQVQgWU9VIEhBVkUKRlVMRklMTEVEIEFOWSBSSUdIVCBPRiBSRVZJRVcgT1IgT1RIRVIgT0JMSUdBVElPTlMgUkVRVUlSRUQgQlkgU1VDSApDT05UUkFDVCBPUiBBR1JFRU1FTlQuCgpEU1Ugd2lsbCBjbGVhcmx5IGlkZW50aWZ5IHlvdXIgbmFtZShzKSBhcyB0aGUgYXV0aG9yKHMpIG9yIG93bmVyKHMpIG9mIHRoZQpzdWJtaXNzaW9uLCBhbmQgd2lsbCBub3QgbWFrZSBhbnkgYWx0ZXJhdGlvbiwgb3RoZXIgdGhhbiBhcyBhbGxvd2VkIGJ5IHRoaXMKbGljZW5zZSwgdG8geW91ciBzdWJtaXNzaW9uLgo=

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