Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures

The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of co...

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Autores:
Delgado, Daniel ricardo
Mogollon Waltero, Edgar mauricio
Ortiz C.P.
Peña M.Á.
Almanza O.A.
Martínez F.
Jouyban A.
Tipo de recurso:
Article of journal
Fecha de publicación:
2023
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
Idioma:
OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/50452
Acceso en línea:
https://doi.org/10.1016/j.molliq.2018.09.026
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053028646&doi=10.1016%2fj.molliq.2018.09.026&partnerID=40&md5=9a5e815f52257c540d4ce0c9423a0b37
https://hdl.handle.net/20.500.12494/50452
Palabra clave:
1 ,4-DIOXANE
DISSOLUTION
DISSOLUTION MECHANISM
ENTHALPY
ENTHALPY-ENTROPY COMPENSATION
ENTROPY
EQUILIBRIUM SOLUBILITIES
JOUYBAN-ACREE MODEL
MIXTURES
SOLUBILITY
THERMODYNAMIC QUANTITIES
TRICLOCARBAN
VAN'T HOFF EQUATION
Rights
openAccess
License
http://purl.org/coar/access_right/c_abf2
id COOPER2_f89d148733925afda973f80b5e6fcf6e
oai_identifier_str oai:repository.ucc.edu.co:20.500.12494/50452
network_acronym_str COOPER2
network_name_str Repositorio UCC
repository_id_str
spelling Delgado, Daniel ricardoMogollon Waltero, Edgar mauricioOrtiz C.P.Peña M.Á.Almanza O.A.Martínez F.Jouyban A.2023-05-24T16:26:14Z2023-05-24T16:26:14Z01/01/2018https://doi.org/10.1016/j.molliq.2018.09.026https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053028646&doi=10.1016%2fj.molliq.2018.09.026&partnerID=40&md5=9a5e815f52257c540d4ce0c9423a0b3701677322https://hdl.handle.net/20.500.12494/50452Delgado Daniel ricardo,Mogollon Waltero Edgar mauricio,Ortiz C.P.,Peña M.Á.,Almanza O.A.,Martínez F.,Jouyban A..Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures.J MOL LIQ. 2018. 271.:p. 522-529The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition. © 2018 Elsevier B.V.0000-0002-4835-9739danielr.delgado@campusucc.edu.coedgar.mogollonw@campusucc.edu.co522-529Elsevier1 ,4-DIOXANEDISSOLUTIONDISSOLUTION MECHANISMENTHALPYENTHALPY-ENTROPY COMPENSATIONENTROPYEQUILIBRIUM SOLUBILITIESJOUYBAN-ACREE MODELMIXTURESSOLUBILITYTHERMODYNAMIC QUANTITIESTRICLOCARBANVAN'T HOFF EQUATIONEnthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixturesArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionJ MOL LIQinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Publication20.500.12494/50452oai:repository.ucc.edu.co:20.500.12494/504522024-08-20 16:17:26.501metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com
dc.title.spa.fl_str_mv Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
spellingShingle Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
1 ,4-DIOXANE
DISSOLUTION
DISSOLUTION MECHANISM
ENTHALPY
ENTHALPY-ENTROPY COMPENSATION
ENTROPY
EQUILIBRIUM SOLUBILITIES
JOUYBAN-ACREE MODEL
MIXTURES
SOLUBILITY
THERMODYNAMIC QUANTITIES
TRICLOCARBAN
VAN'T HOFF EQUATION
title_short Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_full Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_fullStr Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_full_unstemmed Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_sort Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
dc.creator.fl_str_mv Delgado, Daniel ricardo
Mogollon Waltero, Edgar mauricio
Ortiz C.P.
Peña M.Á.
Almanza O.A.
Martínez F.
Jouyban A.
dc.contributor.author.none.fl_str_mv Delgado, Daniel ricardo
Mogollon Waltero, Edgar mauricio
Ortiz C.P.
Peña M.Á.
Almanza O.A.
Martínez F.
Jouyban A.
dc.subject.spa.fl_str_mv 1 ,4-DIOXANE
DISSOLUTION
DISSOLUTION MECHANISM
ENTHALPY
ENTHALPY-ENTROPY COMPENSATION
ENTROPY
EQUILIBRIUM SOLUBILITIES
JOUYBAN-ACREE MODEL
MIXTURES
SOLUBILITY
THERMODYNAMIC QUANTITIES
TRICLOCARBAN
VAN'T HOFF EQUATION
topic 1 ,4-DIOXANE
DISSOLUTION
DISSOLUTION MECHANISM
ENTHALPY
ENTHALPY-ENTROPY COMPENSATION
ENTROPY
EQUILIBRIUM SOLUBILITIES
JOUYBAN-ACREE MODEL
MIXTURES
SOLUBILITY
THERMODYNAMIC QUANTITIES
TRICLOCARBAN
VAN'T HOFF EQUATION
description The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition. © 2018 Elsevier B.V.
publishDate 2023
dc.date.issued.none.fl_str_mv 01/01/2018
dc.date.accessioned.none.fl_str_mv 2023-05-24T16:26:14Z
dc.date.available.none.fl_str_mv 2023-05-24T16:26:14Z
dc.type.none.fl_str_mv Artículo
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.none.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.none.fl_str_mv info:eu-repo/semantics/publishedVersion
format http://purl.org/coar/resource_type/c_6501
status_str publishedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1016/j.molliq.2018.09.026
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053028646&doi=10.1016%2fj.molliq.2018.09.026&partnerID=40&md5=9a5e815f52257c540d4ce0c9423a0b37
dc.identifier.issn.spa.fl_str_mv 01677322
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12494/50452
dc.identifier.bibliographicCitation.spa.fl_str_mv Delgado Daniel ricardo,Mogollon Waltero Edgar mauricio,Ortiz C.P.,Peña M.Á.,Almanza O.A.,Martínez F.,Jouyban A..Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures.J MOL LIQ. 2018. 271.:p. 522-529
url https://doi.org/10.1016/j.molliq.2018.09.026
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053028646&doi=10.1016%2fj.molliq.2018.09.026&partnerID=40&md5=9a5e815f52257c540d4ce0c9423a0b37
https://hdl.handle.net/20.500.12494/50452
identifier_str_mv 01677322
Delgado Daniel ricardo,Mogollon Waltero Edgar mauricio,Ortiz C.P.,Peña M.Á.,Almanza O.A.,Martínez F.,Jouyban A..Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures.J MOL LIQ. 2018. 271.:p. 522-529
dc.relation.ispartofjournal.spa.fl_str_mv J MOL LIQ
dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.coar.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
rights_invalid_str_mv http://purl.org/coar/access_right/c_abf2
dc.format.extent.spa.fl_str_mv 522-529
dc.publisher.spa.fl_str_mv Elsevier
institution Universidad Cooperativa de Colombia
repository.name.fl_str_mv Repositorio Institucional Universidad Cooperativa de Colombia
repository.mail.fl_str_mv bdigital@metabiblioteca.com
_version_ 1814246755505537024

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