Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K

Extended Hildebrand solubility approach (EHSA) was applied in this research to analyse the equilibrium solubility of sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K. Reported experimental solubilities and some fusion properties of these dru...

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Autores:
Delgado, Daniel Ricardo
Peña, María Á.
Martínez, Fleming
Tipo de recurso:
Article of journal
Fecha de publicación:
2018
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
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OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/4598
Acceso en línea:
https://hdl.handle.net/20.500.12494/4598
Palabra clave:
Sulphonamides
1-propanol
Binary mixtures
Extended Hildebrand solubility approach
EHSA
Hildebrand solubility parameter
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closedAccess
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Licencia CC
id COOPER2_f41a7aea76cb4676d24e6565f8da6ead
oai_identifier_str oai:repository.ucc.edu.co:20.500.12494/4598
network_acronym_str COOPER2
network_name_str Repositorio UCC
repository_id_str
spelling Delgado, Daniel RicardoPeña, María Á.Martínez, Fleming2018-06-29T12:34:05Z2020-01-012018-06-29T12:34:05Z2018https://hdl.handle.net/20.500.12494/4598Delgado, D. R., Peña, M. Á., & Martínez, F. (2018). Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K. Physics and Chemistry of Liquids, 56(2), 176-188. https://doi.org/10.1080/00319104.2017.1317779Extended Hildebrand solubility approach (EHSA) was applied in this research to analyse the equilibrium solubility of sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K. Reported experimental solubilities and some fusion properties of these drugs were used for EHSA calculations. A good predictive character of EHSA (with mean deviations lower than 4.0%) was found by using regular polynomials in order five when correlating the interaction parameter (W) and the Hildebrand solubility parameter of solvent mixtures free of drug (δ1+2). Nevertheless, the predictive character of EHSA was almost the same as obtained when logarithmic drug solubilities (log x3) were correlated with δ1+2 by using a fifth-degree regular polynomial.danielr.delgado@campusucc.edu.cofmartinezr@unal.edu.coUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, NeivaIngeniería IndustrialNeivahttps://doi.org/10.1080/00319104.2017.1317779Sulphonamides1-propanolBinary mixturesExtended Hildebrand solubility approachEHSAHildebrand solubility parameterExtended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 KArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionLicencia CCinfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbhttps://orcid.org/0000-0002-4835-9739Publication20.500.12494/4598oai:repository.ucc.edu.co:20.500.12494/45982024-08-10 20:59:02.832metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com
dc.title.spa.fl_str_mv Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
title Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
spellingShingle Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
Sulphonamides
1-propanol
Binary mixtures
Extended Hildebrand solubility approach
EHSA
Hildebrand solubility parameter
title_short Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
title_full Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
title_fullStr Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
title_full_unstemmed Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
title_sort Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K
dc.creator.fl_str_mv Delgado, Daniel Ricardo
Peña, María Á.
Martínez, Fleming
dc.contributor.author.none.fl_str_mv Delgado, Daniel Ricardo
Peña, María Á.
Martínez, Fleming
dc.subject.spa.fl_str_mv Sulphonamides
1-propanol
Binary mixtures
Extended Hildebrand solubility approach
EHSA
Hildebrand solubility parameter
topic Sulphonamides
1-propanol
Binary mixtures
Extended Hildebrand solubility approach
EHSA
Hildebrand solubility parameter
description Extended Hildebrand solubility approach (EHSA) was applied in this research to analyse the equilibrium solubility of sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K. Reported experimental solubilities and some fusion properties of these drugs were used for EHSA calculations. A good predictive character of EHSA (with mean deviations lower than 4.0%) was found by using regular polynomials in order five when correlating the interaction parameter (W) and the Hildebrand solubility parameter of solvent mixtures free of drug (δ1+2). Nevertheless, the predictive character of EHSA was almost the same as obtained when logarithmic drug solubilities (log x3) were correlated with δ1+2 by using a fifth-degree regular polynomial.
publishDate 2018
dc.date.accessioned.none.fl_str_mv 2018-06-29T12:34:05Z
dc.date.available.none.fl_str_mv 2018-06-29T12:34:05Z
2020-01-01
dc.date.issued.none.fl_str_mv 2018
dc.type.none.fl_str_mv Artículo
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/article
dc.type.version.none.fl_str_mv info:eu-repo/semantics/publishedVersion
format http://purl.org/coar/resource_type/c_6501
status_str publishedVersion
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12494/4598
dc.identifier.bibliographicCitation.spa.fl_str_mv Delgado, D. R., Peña, M. Á., & Martínez, F. (2018). Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K. Physics and Chemistry of Liquids, 56(2), 176-188. https://doi.org/10.1080/00319104.2017.1317779
url https://hdl.handle.net/20.500.12494/4598
identifier_str_mv Delgado, D. R., Peña, M. Á., & Martínez, F. (2018). Extended Hildebrand solubility approach applied to sulphadiazine, sulphamerazine and sulphamethazine in some {1-propanol (1) + water (2)} mixtures at 298.15 K. Physics and Chemistry of Liquids, 56(2), 176-188. https://doi.org/10.1080/00319104.2017.1317779
dc.relation.isversionof.spa.fl_str_mv https://doi.org/10.1080/00319104.2017.1317779
dc.rights.cc.none.fl_str_mv Licencia CC
dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/closedAccess
dc.rights.coar.none.fl_str_mv http://purl.org/coar/access_right/c_14cb
rights_invalid_str_mv Licencia CC
http://purl.org/coar/access_right/c_14cb
eu_rights_str_mv closedAccess
dc.publisher.spa.fl_str_mv Universidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, Neiva
dc.publisher.program.spa.fl_str_mv Ingeniería Industrial
dc.publisher.place.spa.fl_str_mv Neiva
institution Universidad Cooperativa de Colombia
repository.name.fl_str_mv Repositorio Institucional Universidad Cooperativa de Colombia
repository.mail.fl_str_mv bdigital@metabiblioteca.com
_version_ 1818158413601832960

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