Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification

To overcome the low equilibrium conversion in the direct synthesis of diethyl carbonate from ethanol and CO 2 under moderate reaction conditions, the reaction was conducted in a membrane reactor packed with pelletized Cu-Ni:3-1 supported on activated carbon. A SiO 2 /?-Al 2 O 3 commercial membrane a...

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Autores:: Arbeláez Pérez, Oscar Felipe
Hernandez Aguirre, Enio
González L.-M.
Bustamante F.
Villa A.-L.

Tipo de recurso:: Article of journal

Fecha de publicación:: 2023

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

Idioma:

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network_acronym_str	COOPER2
network_name_str	Repositorio UCC
repository_id_str
spelling	Arbeláez Pérez, Oscar FelipeHernandez Aguirre, EnioGonzález L.-M.Bustamante F.Villa A.-L.2023-05-24T16:30:12Z2023-05-24T16:30:12Z14/03/2019https://doi.org/10.1002/ceat.201800456https://www.scopus.com/inward/record.uri?eid=2-s2.0-85063934736&doi=10.1002%2fceat.201800456&partnerID=40&md5=2452389a72c02f542f6afb65a00fb8b509307516https://hdl.handle.net/20.500.12494/50889Arbelaez Perez Oscar felipe,Hernandez Aguirre Enio,González L.-M.,Bustamante F.,Villa A.-L..Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification.Chemical Engineering and Technology. 2019. 42. (5):p. 1135-1143To overcome the low equilibrium conversion in the direct synthesis of diethyl carbonate from ethanol and CO 2 under moderate reaction conditions, the reaction was conducted in a membrane reactor packed with pelletized Cu-Ni:3-1 supported on activated carbon. A SiO 2 /?-Al 2 O 3 commercial membrane and zeolite A membranes synthesized on commercial Al 2 O 3 supports were evaluated in the membrane reactor. Although characterization of the membranes by X-ray diffraction confirmed the presence of a zeolite A layer on the supports, gas permeation and permselectivity tests of ethanol and water evidenced some defects of the synthesized membranes. An increase in conversion with respect to a conventional packed-bed reactor was observed in the membrane reactors prepared on Al 2 O 3 , but equilibrium conversion was not attained. However, with the commercial membrane, the ethanol conversion was higher than the equilibrium conversion. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimOscar.Arbelaez@campusucc.edu.co1135-1143Wiley - V C H Verlag GmbbH & Co.ACTIVATED CARBONALUMINAALUMINUM OXIDEBIOREACTORSCARBON DIOXIDECARBONATIONCATALYTIC MEMBRANE REACTORSCOMMERCIAL MEMBRANESDIETHYL CARBONATESEQUILIBRIUM CONVERSIONETHANOLETHANOL CONVERSIONGAS PERMEABLE MEMBRANESPACKED BED REACTORPACKED BEDSPELLETIZINGPROCESS INTENSIFICATIONREACTION CONDITIONSSILICAZEOLITESEnhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process IntensificationArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionChemical Engineering and Technologyinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Publication20.500.12494/50889oai:repository.ucc.edu.co:20.500.12494/508892024-08-20 16:21:53.456metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com
dc.title.spa.fl_str_mv	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
spellingShingle	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification ACTIVATED CARBON ALUMINA ALUMINUM OXIDE BIOREACTORS CARBON DIOXIDE CARBONATION CATALYTIC MEMBRANE REACTORS COMMERCIAL MEMBRANES DIETHYL CARBONATES EQUILIBRIUM CONVERSION ETHANOL ETHANOL CONVERSION GAS PERMEABLE MEMBRANES PACKED BED REACTOR PACKED BEDS PELLETIZING PROCESS INTENSIFICATION REACTION CONDITIONS SILICA ZEOLITES
title_short	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_full	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_fullStr	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_full_unstemmed	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_sort	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
dc.creator.fl_str_mv	Arbeláez Pérez, Oscar Felipe Hernandez Aguirre, Enio González L.-M. Bustamante F. Villa A.-L.
dc.contributor.author.none.fl_str_mv	Arbeláez Pérez, Oscar Felipe Hernandez Aguirre, Enio González L.-M. Bustamante F. Villa A.-L.
dc.subject.spa.fl_str_mv	ACTIVATED CARBON ALUMINA ALUMINUM OXIDE BIOREACTORS CARBON DIOXIDE CARBONATION CATALYTIC MEMBRANE REACTORS COMMERCIAL MEMBRANES DIETHYL CARBONATES EQUILIBRIUM CONVERSION ETHANOL ETHANOL CONVERSION GAS PERMEABLE MEMBRANES PACKED BED REACTOR PACKED BEDS PELLETIZING PROCESS INTENSIFICATION REACTION CONDITIONS SILICA ZEOLITES
topic	ACTIVATED CARBON ALUMINA ALUMINUM OXIDE BIOREACTORS CARBON DIOXIDE CARBONATION CATALYTIC MEMBRANE REACTORS COMMERCIAL MEMBRANES DIETHYL CARBONATES EQUILIBRIUM CONVERSION ETHANOL ETHANOL CONVERSION GAS PERMEABLE MEMBRANES PACKED BED REACTOR PACKED BEDS PELLETIZING PROCESS INTENSIFICATION REACTION CONDITIONS SILICA ZEOLITES
description	To overcome the low equilibrium conversion in the direct synthesis of diethyl carbonate from ethanol and CO 2 under moderate reaction conditions, the reaction was conducted in a membrane reactor packed with pelletized Cu-Ni:3-1 supported on activated carbon. A SiO 2 /?-Al 2 O 3 commercial membrane and zeolite A membranes synthesized on commercial Al 2 O 3 supports were evaluated in the membrane reactor. Although characterization of the membranes by X-ray diffraction confirmed the presence of a zeolite A layer on the supports, gas permeation and permselectivity tests of ethanol and water evidenced some defects of the synthesized membranes. An increase in conversion with respect to a conventional packed-bed reactor was observed in the membrane reactors prepared on Al 2 O 3 , but equilibrium conversion was not attained. However, with the commercial membrane, the ethanol conversion was higher than the equilibrium conversion. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
publishDate	2023
dc.date.issued.none.fl_str_mv	14/03/2019
dc.date.accessioned.none.fl_str_mv	2023-05-24T16:30:12Z
dc.date.available.none.fl_str_mv	2023-05-24T16:30:12Z
dc.type.none.fl_str_mv	Artículo
dc.type.coar.fl_str_mv	http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv	http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv	http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv	info:eu-repo/semantics/article
dc.type.redcol.none.fl_str_mv	http://purl.org/redcol/resource_type/ART
dc.type.version.none.fl_str_mv	info:eu-repo/semantics/publishedVersion
format	http://purl.org/coar/resource_type/c_6501
status_str	publishedVersion
dc.identifier.none.fl_str_mv	https://doi.org/10.1002/ceat.201800456 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85063934736&doi=10.1002%2fceat.201800456&partnerID=40&md5=2452389a72c02f542f6afb65a00fb8b5
dc.identifier.issn.spa.fl_str_mv	09307516
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12494/50889
dc.identifier.bibliographicCitation.spa.fl_str_mv	Arbelaez Perez Oscar felipe,Hernandez Aguirre Enio,González L.-M.,Bustamante F.,Villa A.-L..Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification.Chemical Engineering and Technology. 2019. 42. (5):p. 1135-1143
url	https://doi.org/10.1002/ceat.201800456 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85063934736&doi=10.1002%2fceat.201800456&partnerID=40&md5=2452389a72c02f542f6afb65a00fb8b5 https://hdl.handle.net/20.500.12494/50889
identifier_str_mv	09307516 Arbelaez Perez Oscar felipe,Hernandez Aguirre Enio,González L.-M.,Bustamante F.,Villa A.-L..Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification.Chemical Engineering and Technology. 2019. 42. (5):p. 1135-1143
dc.relation.ispartofjournal.spa.fl_str_mv	Chemical Engineering and Technology
dc.rights.accessrights.none.fl_str_mv	info:eu-repo/semantics/openAccess
dc.rights.coar.none.fl_str_mv	http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv	openAccess
rights_invalid_str_mv	http://purl.org/coar/access_right/c_abf2
dc.format.extent.spa.fl_str_mv	1135-1143
dc.publisher.spa.fl_str_mv	Wiley - V C H Verlag GmbbH & Co.
institution	Universidad Cooperativa de Colombia
repository.name.fl_str_mv	Repositorio Institucional Universidad Cooperativa de Colombia
repository.mail.fl_str_mv	bdigital@metabiblioteca.com
_version_	1814247195889631232

Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification

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