Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K
Articulo Científico
- Autores:
-
Cárdenas, Zaira J.
Jiménez, Daniel M.
Delgado, Daniel Ricardo
Almanza Montero, Ovidio Amado
Jouyban, Abolghasem
Martínez, Fleming
Acree Jr, William Eugene
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2017
- Institución:
- Universidad Cooperativa de Colombia
- Repositorio:
- Repositorio UCC
- Idioma:
- OAI Identifier:
- oai:repository.ucc.edu.co:20.500.12494/981
- Acceso en línea:
- https://hdl.handle.net/20.500.12494/981
- Palabra clave:
- Parabens Solubility Methanol + water mixtures Jouyban-Acree model Inverse Kirkwood-Buff integrals Preferential solvation
- Rights
- closedAccess
- License
- Licencia CC
| id |
COOPER2_cecb8a81331c320a2cae65a9508e501a |
|---|---|
| oai_identifier_str |
oai:repository.ucc.edu.co:20.500.12494/981 |
| network_acronym_str |
COOPER2 |
| network_name_str |
Repositorio UCC |
| repository_id_str |
|
| dc.title.spa.fl_str_mv |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K |
| title |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K |
| spellingShingle |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K Parabens Solubility Methanol + water mixtures Jouyban-Acree model Inverse Kirkwood-Buff integrals Preferential solvation |
| title_short |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K |
| title_full |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K |
| title_fullStr |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K |
| title_full_unstemmed |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K |
| title_sort |
Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K |
| dc.creator.fl_str_mv |
Cárdenas, Zaira J. Jiménez, Daniel M. Delgado, Daniel Ricardo Almanza Montero, Ovidio Amado Jouyban, Abolghasem Martínez, Fleming Acree Jr, William Eugene |
| dc.contributor.advisor.none.fl_str_mv |
Delgado, Daniel Ricardo |
| dc.contributor.author.none.fl_str_mv |
Cárdenas, Zaira J. Jiménez, Daniel M. Delgado, Daniel Ricardo Almanza Montero, Ovidio Amado Jouyban, Abolghasem Martínez, Fleming Acree Jr, William Eugene |
| dc.subject.spa.fl_str_mv |
Parabens Solubility Methanol + water mixtures Jouyban-Acree model Inverse Kirkwood-Buff integrals Preferential solvation |
| topic |
Parabens Solubility Methanol + water mixtures Jouyban-Acree model Inverse Kirkwood-Buff integrals Preferential solvation |
| description |
Articulo Científico |
| publishDate |
2017 |
| dc.date.accessioned.none.fl_str_mv |
2017-08-09T20:48:52Z |
| dc.date.available.none.fl_str_mv |
2017-08-09T20:48:52Z |
| dc.date.issued.none.fl_str_mv |
2017-01-09 |
| dc.type.none.fl_str_mv |
Artículo |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coar.none.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
| dc.type.coarversion.none.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.driver.none.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.version.none.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| format |
http://purl.org/coar/resource_type/c_6501 |
| status_str |
publishedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/20.500.12494/981 |
| dc.identifier.bibliographicCitation.spa.fl_str_mv |
Zaira J. Cárdenas, Daniel M. Jiménez, Daniel R. Delgado, Ovidio A. Almanza, Abolghasem Jouyban, Fleming Martínez, William E. Acree Jr. Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K. J. Chem. Thermodynamics 108 (2017) 26–37 |
| url |
https://hdl.handle.net/20.500.12494/981 |
| identifier_str_mv |
Zaira J. Cárdenas, Daniel M. Jiménez, Daniel R. Delgado, Ovidio A. Almanza, Abolghasem Jouyban, Fleming Martínez, William E. Acree Jr. Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K. J. Chem. Thermodynamics 108 (2017) 26–37 |
| dc.relation.isversionof.spa.fl_str_mv |
http://www.sciencedirect.com/science/article/pii/S0021961417300058 |
| dc.rights.cc.none.fl_str_mv |
Licencia CC |
| dc.rights.accessrights.none.fl_str_mv |
info:eu-repo/semantics/closedAccess |
| dc.rights.coar.none.fl_str_mv |
http://purl.org/coar/access_right/c_14cb |
| rights_invalid_str_mv |
Licencia CC http://purl.org/coar/access_right/c_14cb |
| eu_rights_str_mv |
closedAccess |
| dc.publisher.spa.fl_str_mv |
Universidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000 |
| dc.publisher.program.spa.fl_str_mv |
Ingeniería Industrial |
| dc.publisher.place.spa.fl_str_mv |
Neiva |
| institution |
Universidad Cooperativa de Colombia |
| bitstream.url.fl_str_mv |
https://repository.ucc.edu.co/bitstreams/6418a30d-fd57-4209-b9a3-98910b4f871b/download https://repository.ucc.edu.co/bitstreams/efef79c9-2f45-45c6-9b70-7d5ec6cb87f9/download https://repository.ucc.edu.co/bitstreams/3c975a8c-9c27-41a0-9e18-4bb889e976ef/download https://repository.ucc.edu.co/bitstreams/f78a248c-67a4-4dbb-b6fb-57b73d31adf4/download |
| bitstream.checksum.fl_str_mv |
bba3b6ac1f76c91198718b175a5e1e71 4964561dc45916d1c9e8ecf22dd18746 997c6e27b33dd1bbb0ecedddb38b09e7 de761e1f2d941a1706625b603088b857 |
| bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 MD5 |
| repository.name.fl_str_mv |
Repositorio Institucional Universidad Cooperativa de Colombia |
| repository.mail.fl_str_mv |
bdigital@metabiblioteca.com |
| _version_ |
1814246698647552000 |
| spelling |
Delgado, Daniel RicardoCárdenas, Zaira J.Jiménez, Daniel M.Delgado, Daniel RicardoAlmanza Montero, Ovidio AmadoJouyban, AbolghasemMartínez, FlemingAcree Jr, William Eugene2017-08-09T20:48:52Z2017-08-09T20:48:52Z2017-01-09https://hdl.handle.net/20.500.12494/981Zaira J. Cárdenas, Daniel M. Jiménez, Daniel R. Delgado, Ovidio A. Almanza, Abolghasem Jouyban, Fleming Martínez, William E. Acree Jr. Solubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 K. J. Chem. Thermodynamics 108 (2017) 26–37Articulo CientíficoMethyl, ethyl and propyl parabens equilibrium solubility was determined in (methanol + water) binary mixtures at 298.15K. The mole fraction solubility of these compounds increased in 503 (from 2.40 10 4 to 0.121), 1377 (from 9.86 10 5 to 0.136) and 4597 (from 3.73 10 5 to 0.171) times when passing from neat water to neat methanol, for methyl, ethyl and propyl parabens, respectively. All these solubility values were correlated with the Jouyban-Acree model. Preferential solvation parameters by methanol (dx1,3) of these parabens were derived from their thermodynamic solution properties using the inverse Kirkwood-Buff integrals (IKBI) method. For all compounds dx1,3 values are negative in water-rich mixtures but positive in mixtures with methanol mole fraction greater than 0.32. It is conjec- turable that in the former case the hydrophobic hydration around non-polar groups of parabens plays a relevant role in the solvation. Besides, the preferential solvation of these solutes by methanol in mixtures of similar co-solvent compositions and in methanol-rich mixtures could be explained in terms of the higher basic behaviour of methanol.1. Introduction, 2. Experimental, 3. Results and discussion, 4. Conclusions, Referencesdanielr.delgado@campusucc.edu.coUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000Ingeniería IndustrialNeivahttp://www.sciencedirect.com/science/article/pii/S0021961417300058Parabens Solubility Methanol + water mixtures Jouyban-Acree model Inverse Kirkwood-Buff integrals Preferential solvationSolubility and preferential solvation of some n-alkyl-parabens in methanol + water mixtures at 298.15 KArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionLicencia CCinfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbPublicationORIGINAL2017_MP-EP-PP-MeOH+W-JCT-2017-Def.pdf2017_MP-EP-PP-MeOH+W-JCT-2017-Def.pdfapplication/pdf1406554https://repository.ucc.edu.co/bitstreams/6418a30d-fd57-4209-b9a3-98910b4f871b/downloadbba3b6ac1f76c91198718b175a5e1e71MD51TEXT2017_MP-EP-PP-MeOH+W-JCT-2017-Def.pdf.txt2017_MP-EP-PP-MeOH+W-JCT-2017-Def.pdf.txtExtracted texttext/plain57677https://repository.ucc.edu.co/bitstreams/efef79c9-2f45-45c6-9b70-7d5ec6cb87f9/download4964561dc45916d1c9e8ecf22dd18746MD53THUMBNAIL2017_MP-EP-PP-MeOH+W-JCT-2017-Def.pdf.jpg2017_MP-EP-PP-MeOH+W-JCT-2017-Def.pdf.jpgIM Thumbnailimage/jpeg19960https://repository.ucc.edu.co/bitstreams/3c975a8c-9c27-41a0-9e18-4bb889e976ef/download997c6e27b33dd1bbb0ecedddb38b09e7MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-84587https://repository.ucc.edu.co/bitstreams/f78a248c-67a4-4dbb-b6fb-57b73d31adf4/downloadde761e1f2d941a1706625b603088b857MD5220.500.12494/981oai:repository.ucc.edu.co:20.500.12494/9812024-08-10 17:55:20.426open.accesshttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.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 |