Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K
Equilibrium solubility of sodium sulfadiazine (Na.SDZ), sodium sulfamerazine (Na.SMR), and sodium sulfamethazine (Na.SMT), was determined in aqueous binary mixtures of propylene glycol (PG) at 298.15 K. If the solubility values expressed in both concentration scales are considered, i.e. mole fractio...
- Autores:
-
Muñoz M.M.
Rodríguez C.J.
Delgado, Daniel Ricardo
Peña M.Á.
Jouyban A.
Martínez F.
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2015
- Institución:
- Universidad Cooperativa de Colombia
- Repositorio:
- Repositorio UCC
- Idioma:
- OAI Identifier:
- oai:repository.ucc.edu.co:20.500.12494/41534
- Acceso en línea:
- https://doi.org/10.1038/s41598-021-91783-2
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061485973&doi=10.4067%2fS0718-07642018000600307&partnerID=40&md5=c4b6c9d4bd959dbdb5b5ed8a8425ad3a
https://hdl.handle.net/20.500.12494/41534
- Palabra clave:
- Sodium sulfonamidesPropylene glycolSolubilityApparent specific volumeJouyban–Acree model
- Rights
- closedAccess
- License
- http://purl.org/coar/access_right/c_14cb
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Muñoz M.M.Rodríguez C.J.Delgado, Daniel RicardoPeña M.Á.Jouyban A.Martínez F.2021-12-16T22:15:35Z2021-12-16T22:15:35Z2015https://doi.org/10.1038/s41598-021-91783-2https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061485973&doi=10.4067%2fS0718-07642018000600307&partnerID=40&md5=c4b6c9d4bd959dbdb5b5ed8a8425ad3a01677322https://hdl.handle.net/20.500.12494/41534Muñoz MM,Rodríguez CJ,Delgado DR,Peña MÁ,Jouyban A,Martínez F. Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K. J MOL LIQ. 2015. 211. p. 192-196. .Equilibrium solubility of sodium sulfadiazine (Na.SDZ), sodium sulfamerazine (Na.SMR), and sodium sulfamethazine (Na.SMT), was determined in aqueous binary mixtures of propylene glycol (PG) at 298.15 K. If the solubility values expressed in both concentration scales are considered, i.e. mole fraction and molarity, in water-rich mixtures the solubility decrease as: Na.SDZ > Na.SMT > Na.SMR, whereas, in PG-rich mixtures the observed order is: Na.SMT > Na.SDZ > Na.SMR. In all cases the solubility in neat water is higher than those in neat PG. Correlation of the solubility data obtained was made by means of the Jouyban-Acree model for all the sodium sulfonamides. Otherwise, apparent specific volumes (F<inf>V</inf>sp) of sodium sulfonamides at saturation were also calculated in all the mixtures. The average F<inf>V</inf>sp values are as follows: 0.663 cm3 g- 1 for Na.SDZ, 0.723 cm3 g- 1 for Na.SMR, and 0.740 cm3 g- 1 for Na.SMT, with a variation lower than 5.0% in each case. © 2015 Elsevier B.V. All rights reserved.0000-0002-4835-9739danielr.delgado@campusucc.edu.co196-192ElsevierSodium sulfonamidesPropylene glycolSolubilityApparent specific volumeJouyban–Acree modelSolubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 KArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionJ MOL LIQinfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbPublication20.500.12494/41534oai:repository.ucc.edu.co:20.500.12494/415342024-08-20 16:15:50.148metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com |
| dc.title.spa.fl_str_mv |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K |
| title |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K |
| spellingShingle |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K Sodium sulfonamidesPropylene glycolSolubilityApparent specific volumeJouyban–Acree model |
| title_short |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K |
| title_full |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K |
| title_fullStr |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K |
| title_full_unstemmed |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K |
| title_sort |
Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K |
| dc.creator.fl_str_mv |
Muñoz M.M. Rodríguez C.J. Delgado, Daniel Ricardo Peña M.Á. Jouyban A. Martínez F. |
| dc.contributor.author.none.fl_str_mv |
Muñoz M.M. Rodríguez C.J. Delgado, Daniel Ricardo Peña M.Á. Jouyban A. Martínez F. |
| dc.subject.spa.fl_str_mv |
Sodium sulfonamidesPropylene glycolSolubilityApparent specific volumeJouyban–Acree model |
| topic |
Sodium sulfonamidesPropylene glycolSolubilityApparent specific volumeJouyban–Acree model |
| description |
Equilibrium solubility of sodium sulfadiazine (Na.SDZ), sodium sulfamerazine (Na.SMR), and sodium sulfamethazine (Na.SMT), was determined in aqueous binary mixtures of propylene glycol (PG) at 298.15 K. If the solubility values expressed in both concentration scales are considered, i.e. mole fraction and molarity, in water-rich mixtures the solubility decrease as: Na.SDZ > Na.SMT > Na.SMR, whereas, in PG-rich mixtures the observed order is: Na.SMT > Na.SDZ > Na.SMR. In all cases the solubility in neat water is higher than those in neat PG. Correlation of the solubility data obtained was made by means of the Jouyban-Acree model for all the sodium sulfonamides. Otherwise, apparent specific volumes (F<inf>V</inf>sp) of sodium sulfonamides at saturation were also calculated in all the mixtures. The average F<inf>V</inf>sp values are as follows: 0.663 cm3 g- 1 for Na.SDZ, 0.723 cm3 g- 1 for Na.SMR, and 0.740 cm3 g- 1 for Na.SMT, with a variation lower than 5.0% in each case. © 2015 Elsevier B.V. All rights reserved. |
| publishDate |
2015 |
| dc.date.issued.none.fl_str_mv |
2015 |
| dc.date.accessioned.none.fl_str_mv |
2021-12-16T22:15:35Z |
| dc.date.available.none.fl_str_mv |
2021-12-16T22:15:35Z |
| dc.type.none.fl_str_mv |
Artículo |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coar.none.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/article |
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http://purl.org/redcol/resource_type/ART |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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publishedVersion |
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https://doi.org/10.1038/s41598-021-91783-2 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061485973&doi=10.4067%2fS0718-07642018000600307&partnerID=40&md5=c4b6c9d4bd959dbdb5b5ed8a8425ad3a |
| dc.identifier.issn.spa.fl_str_mv |
01677322 |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/20.500.12494/41534 |
| dc.identifier.bibliographicCitation.spa.fl_str_mv |
Muñoz MM,Rodríguez CJ,Delgado DR,Peña MÁ,Jouyban A,Martínez F. Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K. J MOL LIQ. 2015. 211. p. 192-196. . |
| url |
https://doi.org/10.1038/s41598-021-91783-2 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061485973&doi=10.4067%2fS0718-07642018000600307&partnerID=40&md5=c4b6c9d4bd959dbdb5b5ed8a8425ad3a https://hdl.handle.net/20.500.12494/41534 |
| identifier_str_mv |
01677322 Muñoz MM,Rodríguez CJ,Delgado DR,Peña MÁ,Jouyban A,Martínez F. Solubility and saturation apparent specific volume of some sodium sulfonamides in propylene glycol + water mixtures at 298.15 K. J MOL LIQ. 2015. 211. p. 192-196. . |
| dc.relation.ispartofjournal.spa.fl_str_mv |
J MOL LIQ |
| dc.rights.accessrights.none.fl_str_mv |
info:eu-repo/semantics/closedAccess |
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http://purl.org/coar/access_right/c_14cb |
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closedAccess |
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http://purl.org/coar/access_right/c_14cb |
| dc.format.extent.spa.fl_str_mv |
196-192 |
| dc.publisher.spa.fl_str_mv |
Elsevier |
| institution |
Universidad Cooperativa de Colombia |
| repository.name.fl_str_mv |
Repositorio Institucional Universidad Cooperativa de Colombia |
| repository.mail.fl_str_mv |
bdigital@metabiblioteca.com |
| _version_ |
1818158462900633600 |