Chemical composition of spilanthes americana extract

Spilanthes Americana flower has been commonly used in the treatment of   recurrent herpes labialis through the fraction of the flower extract on yellowish oil, which has often been diluted in vaseline or alcohol. The objective was  identify and compare the chemical composition of the flowerhead and...

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Autores:
Zuluaga-López, Oscar Hernán
Tipo de recurso:
Article of journal
Fecha de publicación:
2017
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
Idioma:
eng
OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/9727
Acceso en línea:
https://revistas.ucc.edu.co/index.php/od/article/view/1657
https://hdl.handle.net/20.500.12494/9727
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openAccess
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Derechos de autor 2017 Revista Nacional de Odontología
id COOPER2_a89fd6681022a1ba9c66d4e6e3966a8f
oai_identifier_str oai:repository.ucc.edu.co:20.500.12494/9727
network_acronym_str COOPER2
network_name_str Repositorio UCC
repository_id_str
dc.title.eng.fl_str_mv Chemical composition of spilanthes americana extract
dc.title.spa.fl_str_mv Composición química del extracto de spilanthes americana
dc.title.por.fl_str_mv Composição Química do Extrato de Spilanthes americana
title Chemical composition of spilanthes americana extract
spellingShingle Chemical composition of spilanthes americana extract
title_short Chemical composition of spilanthes americana extract
title_full Chemical composition of spilanthes americana extract
title_fullStr Chemical composition of spilanthes americana extract
title_full_unstemmed Chemical composition of spilanthes americana extract
title_sort Chemical composition of spilanthes americana extract
dc.creator.fl_str_mv Zuluaga-López, Oscar Hernán
dc.contributor.author.none.fl_str_mv Zuluaga-López, Oscar Hernán
description Spilanthes Americana flower has been commonly used in the treatment of   recurrent herpes labialis through the fraction of the flower extract on yellowish oil, which has often been diluted in vaseline or alcohol. The objective was  identify and compare the chemical composition of the flowerhead and the extract of Spilanthes americana flower diluted in vaseline and alcohol. Methods: A descriptive study was carried out to make the chemical identification of the flower head of Spilanthes americana and the extract diluted in vaseline and alcohol, which was subjected to the process of Infrared Spectroscopy by Fourier Transform. Results: Characteristic functional groups of spilanthol were identified in the flowerhead of Spilanthes americana and the extract diluted in vaseline and alcohol, which correspond to the chemical formula N-isobutyl-2,6,8-decatrienamide such as linear aliphatic hydrocarbon, gem-dimethyl group, carbonyl group and disubstituted unsaturated alkenes. The analysis permitted the identification of different functional groups in different samples. In the pure sample of Spilanthes Americana, the presence of a secondary amine, a nitro group, an ester, a nitrite and nitrate and sulfur in the form of aromatic sulfonamide was determined.  In the spectra of the sample of the pure solid and the extract diluted in vaseline, disubstituted unsaturated alkenes with isomery trans were observed, while in the extract diluted in alcohol a configuration cis was found. Conclusion: The spectroscopic analysis evidenced the presence of characteristic functional groups of compound spilanthol, which modified the trans isomery of the pure sample and the one diluted in vaseline cis in the extract prepared in alcohol. Finally, common compounds to the three sulfur samples and an organic ester functional group were found. 
publishDate 2017
dc.date.accessioned.none.fl_str_mv 2019-05-14T21:13:03Z
dc.date.available.none.fl_str_mv 2019-05-14T21:13:03Z
dc.date.none.fl_str_mv 2017-02-06
dc.type.none.fl_str_mv Artículo
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
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dc.type.driver.none.fl_str_mv info:eu-repo/semantics/article
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status_str publishedVersion
dc.identifier.none.fl_str_mv https://revistas.ucc.edu.co/index.php/od/article/view/1657
10.16925/od.v12i24.1657
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12494/9727
url https://revistas.ucc.edu.co/index.php/od/article/view/1657
https://hdl.handle.net/20.500.12494/9727
identifier_str_mv 10.16925/od.v12i24.1657
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv https://revistas.ucc.edu.co/index.php/od/article/view/1657/2013
dc.rights.none.fl_str_mv Derechos de autor 2017 Revista Nacional de Odontología
http://creativecommons.org/licenses/by-nc-nd/4.0
dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.coar.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
rights_invalid_str_mv Derechos de autor 2017 Revista Nacional de Odontología
http://creativecommons.org/licenses/by-nc-nd/4.0
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eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Universidad Cooperativa de Colombia
dc.source.eng.fl_str_mv Revista Nacional de Odontología; Vol 13 No 24 (2017)
dc.source.spa.fl_str_mv Revista Nacional de Odontología; Vol. 13 Núm. 24 (2017)
dc.source.por.fl_str_mv Revista Nacional de Odontología; v. 13 n. 24 (2017)
dc.source.none.fl_str_mv 2357-4607
1900-3080
institution Universidad Cooperativa de Colombia
repository.name.fl_str_mv Repositorio Institucional Universidad Cooperativa de Colombia
repository.mail.fl_str_mv bdigital@metabiblioteca.com
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spelling Zuluaga-López, Oscar Hernán2017-02-062019-05-14T21:13:03Z2019-05-14T21:13:03Zhttps://revistas.ucc.edu.co/index.php/od/article/view/165710.16925/od.v12i24.1657https://hdl.handle.net/20.500.12494/9727Spilanthes Americana flower has been commonly used in the treatment of   recurrent herpes labialis through the fraction of the flower extract on yellowish oil, which has often been diluted in vaseline or alcohol. The objective was  identify and compare the chemical composition of the flowerhead and the extract of Spilanthes americana flower diluted in vaseline and alcohol. Methods: A descriptive study was carried out to make the chemical identification of the flower head of Spilanthes americana and the extract diluted in vaseline and alcohol, which was subjected to the process of Infrared Spectroscopy by Fourier Transform. Results: Characteristic functional groups of spilanthol were identified in the flowerhead of Spilanthes americana and the extract diluted in vaseline and alcohol, which correspond to the chemical formula N-isobutyl-2,6,8-decatrienamide such as linear aliphatic hydrocarbon, gem-dimethyl group, carbonyl group and disubstituted unsaturated alkenes. The analysis permitted the identification of different functional groups in different samples. In the pure sample of Spilanthes Americana, the presence of a secondary amine, a nitro group, an ester, a nitrite and nitrate and sulfur in the form of aromatic sulfonamide was determined.  In the spectra of the sample of the pure solid and the extract diluted in vaseline, disubstituted unsaturated alkenes with isomery trans were observed, while in the extract diluted in alcohol a configuration cis was found. Conclusion: The spectroscopic analysis evidenced the presence of characteristic functional groups of compound spilanthol, which modified the trans isomery of the pure sample and the one diluted in vaseline cis in the extract prepared in alcohol. Finally, common compounds to the three sulfur samples and an organic ester functional group were found. la flor del Spilanthes Americano ha sido comúnmente utilizada para el tratamiento del herpes labial recurrente mediante el uso del extracto de la flor en aceite amarillo, diluido en vaselina o alcohol. Objetivo: identificar y comparar los componentes químicos de la cabezuela de la flor con su diluido en alcohol y vaselina. Método: estudio descriptivo que identificó los componentes químicos de la cabezuela de la flor de Spilanthes americano, y del extracto diluido en vaselina y alcohol, mediante la aplicación de proceso de Espectroscopia Infrarroja Transformada de Fourier. Resultados: se identificaron grupos funcionales comunes a la cabezuela de la flor y a los diluidos en ambos vehículos como los grupos característicos del spilantol (N-isobutil-2,6,8-decatrienamida),compuestos químicos de hidrocarburos alifáticos lineales, gem dimetil, grupos carbonilos, y alquenos insaturados disustituidos. En el Spilanthes americano puro se encontró una amina secundaria, un grupo nitro, un ester, un nitrito y nitrato y azufre en forma de sulfonamida aromática. En los espectros de la muestra del sólido puro y el extracto diluido en vaselina se observaron alquenos insaturados disustituídos con isomería tipo trans, mientras que en el extracto diluido en alcohol se encontró una configuración tipo cis. Conclusiones: el análisis espectroscópico evidenció la presencia de grupos funcionales característicos del compuesto Spilantol, el cual cambió el tipo de isomería trans de la muestra pura y diluida en vaselina a cis en el extracto preparado en alcohol. Se encontraron como compuestos comunes a las 3 muestras azufre, y un grupo funcional orgánico tipo éster.  Introdução: A flor da Spilanthes americana vem sendo comumente utilizada notratamento de herpes labial recorrente mediante o uso da fração do extrato da flor em óleo amarelo, o qual é frequentemente diluído em vaselina ou álcool. Objetivo: Identificar e comparar a composição química dos capítulos da flor de Spilanthes americana e do extrato diluído em vaselina ou álcool. Métodos: Um estudo descritivo foi conduzido para gerar a identificação química dos capítulos da flor de Spilanthes americana e do extrato diluído em vaselina ou álcool, o qual foi submetido à Espectroscopia no Infravermelho por Transformada de Fourier. Resultados: Grupos funcionais característicos de espilantol (N-isobutil- -2,6,8-decatrienamida) tais como hidrocarboneto alifático linear, grupo gem-dimetil, grupo carbonila e alcenos insaturados dissubstituídos foram identificados nos capítulos da flor de Spilanthes americana e do extrato diluído em vaselina ou álcool. A análise possibilitou a identificação de vários grupos funcionais em diferentes amostras. Na amostra pura deSpilanthes americana, a presença de uma amina secundária, um grupo nitro, um éster, um nitrito, um nitrato e enxofre na forma de sulfonamida aromática foi determinada. Nos espectros das amostras do sólido puro e do extrato diluído em vaselina foram observados alcenos insaturados dissubstituídos com isomeria do tipo trans, enquanto no extrato diluído em álcool encontrou-se uma configuração do tipo cis. Conclusão: A análise espectroscópica evidenciou a presença de grupos funcionais característicos do espilantol, o qual alterou a isomeria trans das amostras pura e diluída em vaselina para cis no extrato preparado em álcool. Por fim, enxofre e um grupo funcional orgânico tipo éster foram encontrados como compostos comuns para as três amostras.application/pdfengUniversidad Cooperativa de Colombiahttps://revistas.ucc.edu.co/index.php/od/article/view/1657/2013Derechos de autor 2017 Revista Nacional de Odontologíahttp://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Revista Nacional de Odontología; Vol 13 No 24 (2017)Revista Nacional de Odontología; Vol. 13 Núm. 24 (2017)Revista Nacional de Odontología; v. 13 n. 24 (2017)2357-46071900-3080Chemical composition of spilanthes americana extractComposición química del extracto de spilanthes americanaComposição Química do Extrato de Spilanthes americanaArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionPublication20.500.12494/9727oai:repository.ucc.edu.co:20.500.12494/97272024-07-16 13:33:55.328metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com