Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures

Artículo publicado en acceso abierto en la revista: Revista Colombiana de Química. ISSN Impreso: 0120-2804. ISSN En línea: 2357-3791. Universidad Nacional de Colombia. Bogotá, Colombia.

Autores:
Delgado, Daniel Ricardo
Peña, María A.
Martínez, Fleming
Tipo de recurso:
Article of journal
Fecha de publicación:
2016
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
Idioma:
OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/1098
Acceso en línea:
https://hdl.handle.net/20.500.12494/1098
Palabra clave:
Hildebrand solubility approach
Binary mixtures
Hildebrand solubility parameter
Sulfonamides
Ethanol
Rights
openAccess
License
Licencia CC
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repository_id_str
dc.title.eng.fl_str_mv Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
title Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
spellingShingle Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
Hildebrand solubility approach
Binary mixtures
Hildebrand solubility parameter
Sulfonamides
Ethanol
title_short Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
title_full Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
title_fullStr Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
title_full_unstemmed Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
title_sort Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures
dc.creator.fl_str_mv Delgado, Daniel Ricardo
Peña, María A.
Martínez, Fleming
dc.contributor.author.none.fl_str_mv Delgado, Daniel Ricardo
Peña, María A.
Martínez, Fleming
dc.subject.spa.fl_str_mv Hildebrand solubility approach
Binary mixtures
Hildebrand solubility parameter
Sulfonamides
Ethanol
topic Hildebrand solubility approach
Binary mixtures
Hildebrand solubility parameter
Sulfonamides
Ethanol
description Artículo publicado en acceso abierto en la revista: Revista Colombiana de Química. ISSN Impreso: 0120-2804. ISSN En línea: 2357-3791. Universidad Nacional de Colombia. Bogotá, Colombia.
publishDate 2016
dc.date.issued.none.fl_str_mv 2016
dc.date.accessioned.none.fl_str_mv 2017-08-14T17:03:39Z
dc.date.available.none.fl_str_mv 2017-08-14T17:03:39Z
dc.type.none.fl_str_mv Artículo
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dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12494/1098
dc.identifier.bibliographicCitation.spa.fl_str_mv Delgado, D. R., Peña, M., & Martínez, F. (2016). Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures. Revista Colombiana de Química, 45(1), 34-43. doi:https://doi.org/10.15446/rev.colomb.quim.v45n1.57201
url https://hdl.handle.net/20.500.12494/1098
identifier_str_mv Delgado, D. R., Peña, M., & Martínez, F. (2016). Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures. Revista Colombiana de Química, 45(1), 34-43. doi:https://doi.org/10.15446/rev.colomb.quim.v45n1.57201
dc.relation.isversionof.spa.fl_str_mv http://dx.doi.org/10.15446/rev.colomb.quim.v45n1.57201
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rights_invalid_str_mv Licencia CC
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eu_rights_str_mv openAccess
dc.publisher.spa.fl_str_mv Universidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000
dc.publisher.program.spa.fl_str_mv Ingeniería Industrial
dc.publisher.place.spa.fl_str_mv Neiva
institution Universidad Cooperativa de Colombia
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spelling Delgado, Daniel RicardoPeña, María A.Martínez, Fleming2017-08-14T17:03:39Z2017-08-14T17:03:39Z2016https://hdl.handle.net/20.500.12494/1098Delgado, D. R., Peña, M., & Martínez, F. (2016). Extended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixtures. Revista Colombiana de Química, 45(1), 34-43. doi:https://doi.org/10.15446/rev.colomb.quim.v45n1.57201Artículo publicado en acceso abierto en la revista: Revista Colombiana de Química. ISSN Impreso: 0120-2804. ISSN En línea: 2357-3791. Universidad Nacional de Colombia. Bogotá, Colombia.Extended Hildebrand Solubility Approach (EHSA) was applied to evaluate the solubility of sulfadiazine, sulfamerazine, and sulfamethazine in some ethanol + water mixtures at 298.15 K. Reported experimental equilibrium solubilities and some fusion properties of these drugs were used for the calculations. In particular, a good predictive character of EHSA (with mean deviations lower than 3.0%) has been found by using regular polynomials in order four correlating the interaction parameter W with the Hildebrand solubility parameter of solvent mixtures without drug. However, the predictive character of EHSA was the same as that obtained by direct correlation of drug solubilities with the same descriptor of polarity of the cosolvent mixtures.danielr.delgado@campusucc.edu.cofmartinezr@unal.edu.coUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000Ingeniería IndustrialNeivahttp://dx.doi.org/10.15446/rev.colomb.quim.v45n1.57201Hildebrand solubility approachBinary mixturesHildebrand solubility parameterSulfonamidesEthanolExtended Hildebrand solubility approach applied to some structurally related sulfonamides in ethanol + water mixturesArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionLicencia CCinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2PublicationTEXT2016_Extended Hildebrand solubility approach.pdf.txt2016_Extended Hildebrand solubility approach.pdf.txtExtracted texttext/plain44783https://repository.ucc.edu.co/bitstreams/2093817b-4f3f-45f7-a623-22c974587210/download7eafff0f555705ab0775470d7aeda815MD53THUMBNAIL2016_Extended Hildebrand solubility approach.pdf.jpg2016_Extended Hildebrand solubility approach.pdf.jpgIM Thumbnailimage/jpeg7355https://repository.ucc.edu.co/bitstreams/90b8c075-8f13-403b-96d1-a909f6e279cf/downloaddc2f4c823bf63e3f0290d352fe2fbb67MD54ORIGINAL2016_Extended Hildebrand solubility approach.pdf2016_Extended Hildebrand solubility approach.pdfArchivo únicoapplication/pdf2005758https://repository.ucc.edu.co/bitstreams/1cb8ecf6-0987-47ad-96ac-8f1c93cb7a38/download8b3ed032c4fef3279910b78f2585836aMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repository.ucc.edu.co/bitstreams/a2b39ea1-f5f5-4df2-8a70-802e72f3af04/download8a4605be74aa9ea9d79846c1fba20a33MD5220.500.12494/1098oai:repository.ucc.edu.co:20.500.12494/10982024-08-10 21:00:32.784open.accesshttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.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