Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts

El oro es un metal precioso muy inerte y resistente a la oxidación del aire en comparación con otros debido a su alto potencial de electrodo, primera energía de ionización y fuerte unión metálica. Sin embargo, cuando el oro se dispersa en forma de nanopartículas en diferentes soportes, alcanza propi...

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Autores:: Arbeláez Pérez, Oscar Felipe
Villa Holguín, Aida Luz
Becerra, Jaime Andres

Tipo de recurso:: Article of journal

Fecha de publicación:: 2020

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

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id	COOPER2_820f3922ca28264424f6aca6fc6697ca
oai_identifier_str	oai:repository.ucc.edu.co:20.500.12494/33440
network_acronym_str	COOPER2
network_name_str	Repositorio UCC
repository_id_str
dc.title.spa.fl_str_mv	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts
title	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts
spellingShingle	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts Oro, Monoterpenos Catalizadores Heterogeneos, Oxidación Isomerización Hidrogeación Aminación Gold monoterpenes heterogeneous catalysts oxidation isomerization hydrogenation amination
title_short	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts
title_full	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts
title_fullStr	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts
title_full_unstemmed	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts
title_sort	Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts
dc.creator.fl_str_mv	Arbeláez Pérez, Oscar Felipe Villa Holguín, Aida Luz Becerra, Jaime Andres
dc.contributor.author.none.fl_str_mv	Arbeláez Pérez, Oscar Felipe Villa Holguín, Aida Luz Becerra, Jaime Andres
dc.subject.spa.fl_str_mv	Oro, Monoterpenos Catalizadores Heterogeneos, Oxidación Isomerización Hidrogeación Aminación
topic	Oro, Monoterpenos Catalizadores Heterogeneos, Oxidación Isomerización Hidrogeación Aminación Gold monoterpenes heterogeneous catalysts oxidation isomerization hydrogenation amination
dc.subject.other.spa.fl_str_mv	Gold monoterpenes heterogeneous catalysts oxidation isomerization hydrogenation amination
description	El oro es un metal precioso muy inerte y resistente a la oxidación del aire en comparación con otros debido a su alto potencial de electrodo, primera energía de ionización y fuerte unión metálica. Sin embargo, cuando el oro se dispersa en forma de nanopartículas en diferentes soportes, alcanza propiedades catalíticas excepcionales, lo que promueve el desarrollo de materiales a base de oro catalíticamente activos en reacciones orgánicas. La principal ventaja de los procesos catalíticos heterogéneos frente a los homogéneos es la fácil separación del catalizador facilitando la recuperación, reciclaje y reducción de la cantidad de subproductos. Algunos catalizadores de oro heterogéneos tienen actividad en las transformaciones de monoterpenos y monoterpenoides, compuestos orgánicos naturales extraídos de plantas cuyas transformaciones producen sustancias con aplicaciones en química fina, farmacéutica, cosmética, agricultura, polímeros e industrias alimentarias. Esta revisión describe los logros de algunas transformaciones de monoterpenos y monoterpenoides informadas de 2002 a 2018 mediante oxidación, hidrogenación, isomerización y aminación sobre catalizadores heterogéneos a base de oro.
publishDate	2020
dc.date.available.none.fl_str_mv	2020-01 2021-02-18T20:08:04Z
dc.date.issued.none.fl_str_mv	2020-04-26
dc.date.accessioned.none.fl_str_mv	2021-02-18T20:08:04Z
dc.type.none.fl_str_mv	Artículo
dc.type.coar.fl_str_mv	http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv	http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv	http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv	info:eu-repo/semantics/article
dc.type.version.none.fl_str_mv	info:eu-repo/semantics/publishedVersion
format	http://purl.org/coar/resource_type/c_6501
status_str	publishedVersion
dc.identifier.issn.spa.fl_str_mv	1678-4383
dc.identifier.uri.spa.fl_str_mv	https://doi.org/10.1007/s43153-020-00013-1
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12494/33440
dc.identifier.bibliographicCitation.spa.fl_str_mv	Becerra, J. A., Arbeláez, Ó. F. y Villa, A. L. (2020). Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts. Brazilian Journal of Chemical Engineering, 37(1), 1–62. http://doi.org/10.1007/s43153-020-00013-1
identifier_str_mv	1678-4383 Becerra, J. A., Arbeláez, Ó. F. y Villa, A. L. (2020). Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts. Brazilian Journal of Chemical Engineering, 37(1), 1–62. http://doi.org/10.1007/s43153-020-00013-1
url	https://doi.org/10.1007/s43153-020-00013-1 https://hdl.handle.net/20.500.12494/33440
dc.relation.isversionof.spa.fl_str_mv	https://bbibliograficas.ucc.edu.co:2201/article/10.1007/s43153-020-00013-1
dc.relation.ispartofjournal.spa.fl_str_mv	Brazilian Journal of Chemical Engineering
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spelling	Arbeláez Pérez, Oscar FelipeVilla Holguín, Aida LuzBecerra, Jaime Andres372021-02-18T20:08:04Z2021-02-18T20:08:04Z2020-012020-04-261678-4383https://doi.org/10.1007/s43153-020-00013-1https://hdl.handle.net/20.500.12494/33440Becerra, J. A., Arbeláez, Ó. F. y Villa, A. L. (2020). Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts. Brazilian Journal of Chemical Engineering, 37(1), 1–62. http://doi.org/10.1007/s43153-020-00013-1El oro es un metal precioso muy inerte y resistente a la oxidación del aire en comparación con otros debido a su alto potencial de electrodo, primera energía de ionización y fuerte unión metálica. Sin embargo, cuando el oro se dispersa en forma de nanopartículas en diferentes soportes, alcanza propiedades catalíticas excepcionales, lo que promueve el desarrollo de materiales a base de oro catalíticamente activos en reacciones orgánicas. La principal ventaja de los procesos catalíticos heterogéneos frente a los homogéneos es la fácil separación del catalizador facilitando la recuperación, reciclaje y reducción de la cantidad de subproductos. Algunos catalizadores de oro heterogéneos tienen actividad en las transformaciones de monoterpenos y monoterpenoides, compuestos orgánicos naturales extraídos de plantas cuyas transformaciones producen sustancias con aplicaciones en química fina, farmacéutica, cosmética, agricultura, polímeros e industrias alimentarias. Esta revisión describe los logros de algunas transformaciones de monoterpenos y monoterpenoides informadas de 2002 a 2018 mediante oxidación, hidrogenación, isomerización y aminación sobre catalizadores heterogéneos a base de oro.Gold is a precious metal very inert and resistant to air oxidation compared with others due to its high electrode potential, first ionization energy and strong metallic bonding. However, when gold is dispersed as nanoparticles onto different supports it attains exceptional catalytic properties, promoting the development of gold-based materials catalytically active in organic reactions. The main advantage of heterogeneous catalytic processes against the homogeneous ones is the easy separation of catalyst facilitating recovering, recycling and reducing the amount of byproducts. Some heterogeneous gold catalysts have activity in the transformations of monoterpenes and monoterpenoids, natural organic compounds extracted from plants whose transformations produce substances with applications in fine chemicals, pharmaceuticals, cosmetics, agriculture, polymers and food industries. This review describes the achievements of some transformations of monoterpenes and monoterpenoids reported from 2002 to 2018 through oxidation, hydrogenation, isomerization and amination over gold-based heterogeneous catalysts.https://scienti.colciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001125974http://scienti.colciencias.gov.co:8081/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000087785https://orcid.org/0000-0001-8592-5333https://orcid.org/0000-0002-3770-3223http://orcid.org/0000-0003-0774-876Xoscar.arbelaez@campusucc.edu.coaida.villa@udea.edu.coiq.jymchala@gmail.com57 p.Universidad Cooperativa de Colombia, Facultad de ingenierías, Ingeniería civil, Medellín.Ingeniería CivilMedellínhttps://bbibliograficas.ucc.edu.co:2201/article/10.1007/s43153-020-00013-1Brazilian Journal of Chemical EngineeringAbad A, Almela C, Corma A, García H (2006) Unique gold chemoselectivity for the aerobic oxidation of allylic alcohols. 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Catalysis Today 164(1):28–33Oro,MonoterpenosCatalizadoresHeterogeneos,OxidaciónIsomerizaciónHidrogeaciónAminaciónGoldmonoterpenesheterogeneous catalystsoxidationisomerizationhydrogenationaminationTransformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalystsArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionAtribucióninfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbPublicationLICENSElicense.txtlicense.txttext/plain; charset=utf-84334https://repository.ucc.edu.co/bitstreams/539be0d7-05b8-4f0d-803e-8c6031e9e48a/download3bce4f7ab09dfc588f126e1e36e98a45MD5220.500.12494/33440oai:repository.ucc.edu.co:20.500.12494/334402024-08-10 20:59:21.822metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de 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

Transformation of monoterpenes and monoterpenoids using gold-based heterogeneous catalysts

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