Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K

The equilibrium solubility and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K was reported. Mole fraction solubility varies continuously from 2.85 × 10–9 in neat water to 2.39 × 10–3 in neat 1,4-dioxane. Solubility behaviour was adequately correlated by...

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Autores:
Gaviria Castillo, Ana Carolina
Artunduaga Tole, Jesús Daniel
Rodríguez Rubiano, Juan Diego
Zuñiga Andrade, Jairo Alberto
Delgado, Daniel Ricardo
Jouyban, Abolghasem
Martínez, Fleming
Tipo de recurso:
Article of journal
Fecha de publicación:
2017
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
Idioma:
OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/4650
Acceso en línea:
https://hdl.handle.net/20.500.12494/4650
Palabra clave:
Triclocarban
{14-dioxane (1) + water (2)} mixtures
Solubility
Jouyban-acree model
Preferential solvation
Ikbi
Rights
closedAccess
License
Licencia CC
id COOPER2_78655711d27f9c915380a689f081e3fc
oai_identifier_str oai:repository.ucc.edu.co:20.500.12494/4650
network_acronym_str COOPER2
network_name_str Repositorio UCC
repository_id_str
spelling Gaviria Castillo, Ana CarolinaArtunduaga Tole, Jesús DanielRodríguez Rubiano, Juan DiegoZuñiga Andrade, Jairo AlbertoDelgado, Daniel RicardoJouyban, AbolghasemMartínez, Fleming2018-07-03T13:05:49Z2018-07-03T13:05:49Z2017https://hdl.handle.net/20.500.12494/4650Gaviria, A. C., Artunduaga, J. D., Rodríguez, J. D., Zuñiga, J. A., Delgado, D. R., Jouyban, A., & Martínez, F. (2017). Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K. Physics and Chemistry of Liquids, 1–12. https://doi.org/10.1080/00319104.2017.1416613The equilibrium solubility and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K was reported. Mole fraction solubility varies continuously from 2.85 × 10–9 in neat water to 2.39 × 10–3 in neat 1,4-dioxane. Solubility behaviour was adequately correlated by means of the Jouyban-Acree model. Based on the inverse Kirkwood-Buff integrals, preferential solvation parameters were calculated. Triclocarban is preferentially solvated by water in water-rich mixtures (0.00 < x1 < 0.18) and also in 1,4-dioxane-rich mixtures (0.78 < x1 < 1.00) but preferentially solvated by 1,4-dioxane in mixtures with similar solvent compositions.ana.gaviriaca@campusucc.edu.cojesus.artunduagat@campusucc.edu.codanielr.delgado@campusucc.edu.cofmartinezr@unal.edu.coUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, NeivaIngeniería IndustrialNeivahttps://doi.org/10.1080/00319104.2017.1416613Triclocarban{14-dioxane (1) + water (2)} mixturesSolubilityJouyban-acree modelPreferential solvationIkbiSolution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 KArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionLicencia CCinfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbhttps://orcid.org/0000-0002-4835-9739Publication20.500.12494/4650oai:repository.ucc.edu.co:20.500.12494/46502024-08-10 20:59:04.699metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com
dc.title.spa.fl_str_mv Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
title Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
spellingShingle Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
Triclocarban
{14-dioxane (1) + water (2)} mixtures
Solubility
Jouyban-acree model
Preferential solvation
Ikbi
title_short Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
title_full Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
title_fullStr Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
title_full_unstemmed Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
title_sort Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K
dc.creator.fl_str_mv Gaviria Castillo, Ana Carolina
Artunduaga Tole, Jesús Daniel
Rodríguez Rubiano, Juan Diego
Zuñiga Andrade, Jairo Alberto
Delgado, Daniel Ricardo
Jouyban, Abolghasem
Martínez, Fleming
dc.contributor.author.none.fl_str_mv Gaviria Castillo, Ana Carolina
Artunduaga Tole, Jesús Daniel
Rodríguez Rubiano, Juan Diego
Zuñiga Andrade, Jairo Alberto
Delgado, Daniel Ricardo
Jouyban, Abolghasem
Martínez, Fleming
dc.subject.spa.fl_str_mv Triclocarban
{14-dioxane (1) + water (2)} mixtures
Solubility
Jouyban-acree model
Preferential solvation
Ikbi
topic Triclocarban
{14-dioxane (1) + water (2)} mixtures
Solubility
Jouyban-acree model
Preferential solvation
Ikbi
description The equilibrium solubility and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K was reported. Mole fraction solubility varies continuously from 2.85 × 10–9 in neat water to 2.39 × 10–3 in neat 1,4-dioxane. Solubility behaviour was adequately correlated by means of the Jouyban-Acree model. Based on the inverse Kirkwood-Buff integrals, preferential solvation parameters were calculated. Triclocarban is preferentially solvated by water in water-rich mixtures (0.00 < x1 < 0.18) and also in 1,4-dioxane-rich mixtures (0.78 < x1 < 1.00) but preferentially solvated by 1,4-dioxane in mixtures with similar solvent compositions.
publishDate 2017
dc.date.issued.none.fl_str_mv 2017
dc.date.accessioned.none.fl_str_mv 2018-07-03T13:05:49Z
dc.date.available.none.fl_str_mv 2018-07-03T13:05:49Z
dc.type.none.fl_str_mv Artículo
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/article
dc.type.version.none.fl_str_mv info:eu-repo/semantics/publishedVersion
format http://purl.org/coar/resource_type/c_6501
status_str publishedVersion
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12494/4650
dc.identifier.bibliographicCitation.spa.fl_str_mv Gaviria, A. C., Artunduaga, J. D., Rodríguez, J. D., Zuñiga, J. A., Delgado, D. R., Jouyban, A., & Martínez, F. (2017). Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K. Physics and Chemistry of Liquids, 1–12. https://doi.org/10.1080/00319104.2017.1416613
url https://hdl.handle.net/20.500.12494/4650
identifier_str_mv Gaviria, A. C., Artunduaga, J. D., Rodríguez, J. D., Zuñiga, J. A., Delgado, D. R., Jouyban, A., & Martínez, F. (2017). Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K. Physics and Chemistry of Liquids, 1–12. https://doi.org/10.1080/00319104.2017.1416613
dc.relation.isversionof.spa.fl_str_mv https://doi.org/10.1080/00319104.2017.1416613
dc.rights.cc.none.fl_str_mv Licencia CC
dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/closedAccess
dc.rights.coar.none.fl_str_mv http://purl.org/coar/access_right/c_14cb
rights_invalid_str_mv Licencia CC
http://purl.org/coar/access_right/c_14cb
eu_rights_str_mv closedAccess
dc.publisher.spa.fl_str_mv Universidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, Neiva
dc.publisher.program.spa.fl_str_mv Ingeniería Industrial
dc.publisher.place.spa.fl_str_mv Neiva
institution Universidad Cooperativa de Colombia
repository.name.fl_str_mv Repositorio Institucional Universidad Cooperativa de Colombia
repository.mail.fl_str_mv bdigital@metabiblioteca.com
_version_ 1814246758523338752

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