Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures

The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of co...

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Autores:: Delgado, Daniel Ricardo
Mogollon Waltero, Edgar Mauricio
Ortiz C.P.
Peña M.Á.
Almanza O.A.
Martínez F.
Jouyban A.

Tipo de recurso:: Article of journal

Fecha de publicación:: 2018

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

Idioma:

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network_acronym_str	COOPER2
network_name_str	Repositorio UCC
repository_id_str
spelling	Delgado, Daniel RicardoMogollon Waltero, Edgar MauricioOrtiz C.P.Peña M.Á.Almanza O.A.Martínez F.Jouyban A.2021-12-16T22:15:36Z2021-12-16T22:15:36Z2018https://doi.org/10.1080/00319104.2013.842474https://revia.areandina.edu.co/index.php/IA/article/view/94501677322https://hdl.handle.net/20.500.12494/41541Delgado DR,Mogollon EM,Ortiz CP,Peña MÁ,Almanza OA,Martínez F,Jouyban A. Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures. J MOL LIQ. 2018. 271. p. 522-529. .The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition. © 2018 Elsevier B.V.0000-0002-4835-9739danielr.delgado@campusucc.edu.co529-522ElsevierDissolutionEnthalpyEntropySolubility1 ,4-DioxaneDissolution mechanismEnthalpy-entropy compensationEquilibrium solubilitiesJouyban-Acree modelThermodynamic quantitiesTriclocarbanVan't Hoff equationMixturesEnthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixturesArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionJ MOL LIQinfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbPublication20.500.12494/41541oai:repository.ucc.edu.co:20.500.12494/415412024-08-20 16:23:03.138metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com
dc.title.spa.fl_str_mv	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
spellingShingle	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures Dissolution Enthalpy Entropy Solubility 1 ,4-Dioxane Dissolution mechanism Enthalpy-entropy compensation Equilibrium solubilities Jouyban-Acree model Thermodynamic quantities Triclocarban Van't Hoff equation Mixtures
title_short	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_full	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_fullStr	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_full_unstemmed	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
title_sort	Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures
dc.creator.fl_str_mv	Delgado, Daniel Ricardo Mogollon Waltero, Edgar Mauricio Ortiz C.P. Peña M.Á. Almanza O.A. Martínez F. Jouyban A.
dc.contributor.author.none.fl_str_mv	Delgado, Daniel Ricardo Mogollon Waltero, Edgar Mauricio Ortiz C.P. Peña M.Á. Almanza O.A. Martínez F. Jouyban A.
dc.subject.spa.fl_str_mv	Dissolution Enthalpy Entropy Solubility 1 ,4-Dioxane Dissolution mechanism Enthalpy-entropy compensation Equilibrium solubilities Jouyban-Acree model Thermodynamic quantities Triclocarban Van't Hoff equation Mixtures
topic	Dissolution Enthalpy Entropy Solubility 1 ,4-Dioxane Dissolution mechanism Enthalpy-entropy compensation Equilibrium solubilities Jouyban-Acree model Thermodynamic quantities Triclocarban Van't Hoff equation Mixtures
description	The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition. © 2018 Elsevier B.V.
publishDate	2018
dc.date.issued.none.fl_str_mv	2018
dc.date.accessioned.none.fl_str_mv	2021-12-16T22:15:36Z
dc.date.available.none.fl_str_mv	2021-12-16T22:15:36Z
dc.type.none.fl_str_mv	Artículo
dc.type.coar.fl_str_mv	http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv	http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv	http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv	info:eu-repo/semantics/article
dc.type.redcol.none.fl_str_mv	http://purl.org/redcol/resource_type/ART
dc.type.version.none.fl_str_mv	info:eu-repo/semantics/publishedVersion
format	http://purl.org/coar/resource_type/c_6501
status_str	publishedVersion
dc.identifier.none.fl_str_mv	https://doi.org/10.1080/00319104.2013.842474 https://revia.areandina.edu.co/index.php/IA/article/view/945
dc.identifier.issn.spa.fl_str_mv	01677322
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12494/41541
dc.identifier.bibliographicCitation.spa.fl_str_mv	Delgado DR,Mogollon EM,Ortiz CP,Peña MÁ,Almanza OA,Martínez F,Jouyban A. Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures. J MOL LIQ. 2018. 271. p. 522-529. .
url	https://doi.org/10.1080/00319104.2013.842474 https://revia.areandina.edu.co/index.php/IA/article/view/945 https://hdl.handle.net/20.500.12494/41541
identifier_str_mv	01677322 Delgado DR,Mogollon EM,Ortiz CP,Peña MÁ,Almanza OA,Martínez F,Jouyban A. Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures. J MOL LIQ. 2018. 271. p. 522-529. .
dc.relation.ispartofjournal.spa.fl_str_mv	J MOL LIQ
dc.rights.accessrights.none.fl_str_mv	info:eu-repo/semantics/closedAccess
dc.rights.coar.none.fl_str_mv	http://purl.org/coar/access_right/c_14cb
eu_rights_str_mv	closedAccess
rights_invalid_str_mv	http://purl.org/coar/access_right/c_14cb
dc.format.extent.spa.fl_str_mv	529-522
dc.publisher.spa.fl_str_mv	Elsevier
institution	Universidad Cooperativa de Colombia
repository.name.fl_str_mv	Repositorio Institucional Universidad Cooperativa de Colombia
repository.mail.fl_str_mv	bdigital@metabiblioteca.com
_version_	1814247311656615936

Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1)?+?water (2)} mixtures

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