Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification

To overcome the low equilibrium conversion in the direct synthesis of diethyl carbonate from ethanol and CO 2 under moderate reaction conditions, the reaction was conducted in a membrane reactor packed with pelletized Cu-Ni:3-1 supported on activated carbon. A SiO 2 /?-Al 2 O 3 commercial membrane a...

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Autores:: Arbeláez Pérez, Oscar Felipe
Hernandez Aguirre, Enio Armando
González L.-M.
Bustamante F.
Villa A.-L.

Tipo de recurso:: Article of journal

Fecha de publicación:: 2019

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

Idioma:

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repository_id_str
spelling	Arbeláez Pérez, Oscar FelipeHernandez Aguirre, Enio ArmandoGonzález L.-M.Bustamante F.Villa A.-L.2021-12-16T22:15:28Z2021-12-16T22:15:28Z2019https://doi.org/10.1002/jbm.b.31976https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068720695&doi=10.3390%2fv11070582&partnerID=40&md5=2714f3155c5733d05b7c2a5079457ba209307516https://hdl.handle.net/20.500.12494/41372Arbeláez O,Hernández E,González L-M,Bustamante F,Villa A-L. Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification. Chem Eng Technol. 2019. 04. (5):p. 1135-1143. .To overcome the low equilibrium conversion in the direct synthesis of diethyl carbonate from ethanol and CO 2 under moderate reaction conditions, the reaction was conducted in a membrane reactor packed with pelletized Cu-Ni:3-1 supported on activated carbon. A SiO 2 /?-Al 2 O 3 commercial membrane and zeolite A membranes synthesized on commercial Al 2 O 3 supports were evaluated in the membrane reactor. Although characterization of the membranes by X-ray diffraction confirmed the presence of a zeolite A layer on the supports, gas permeation and permselectivity tests of ethanol and water evidenced some defects of the synthesized membranes. An increase in conversion with respect to a conventional packed-bed reactor was observed in the membrane reactors prepared on Al 2 O 3 , but equilibrium conversion was not attained. However, with the commercial membrane, the ethanol conversion was higher than the equilibrium conversion. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimenio.hernandez@campusucc.edu.co1143-1135Wiley - V C H Verlag GmbbH & Co.Activated carbonAluminaAluminum oxideBioreactorsCarbon dioxideCarbonationEthanolPacked bedsPelletizingSilicaZeolitesCatalytic membrane reactorsCommercial membranesDiethyl carbonatesEquilibrium conversionEthanol conversionPacked bed reactorProcess intensificationReaction conditionsGas permeable membranesEnhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process IntensificationArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionChemical Engineering and Technologyinfo:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbPublication20.500.12494/41372oai:repository.ucc.edu.co:20.500.12494/413722024-08-20 16:15:54.816metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de Colombiabdigital@metabiblioteca.com
dc.title.spa.fl_str_mv	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
spellingShingle	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification Activated carbon Alumina Aluminum oxide Bioreactors Carbon dioxide Carbonation Ethanol Packed beds Pelletizing Silica Zeolites Catalytic membrane reactors Commercial membranes Diethyl carbonates Equilibrium conversion Ethanol conversion Packed bed reactor Process intensification Reaction conditions Gas permeable membranes
title_short	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_full	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_fullStr	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_full_unstemmed	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
title_sort	Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification
dc.creator.fl_str_mv	Arbeláez Pérez, Oscar Felipe Hernandez Aguirre, Enio Armando González L.-M. Bustamante F. Villa A.-L.
dc.contributor.author.none.fl_str_mv	Arbeláez Pérez, Oscar Felipe Hernandez Aguirre, Enio Armando González L.-M. Bustamante F. Villa A.-L.
dc.subject.spa.fl_str_mv	Activated carbon Alumina Aluminum oxide Bioreactors Carbon dioxide Carbonation Ethanol Packed beds Pelletizing Silica Zeolites Catalytic membrane reactors Commercial membranes Diethyl carbonates Equilibrium conversion Ethanol conversion Packed bed reactor Process intensification Reaction conditions Gas permeable membranes
topic	Activated carbon Alumina Aluminum oxide Bioreactors Carbon dioxide Carbonation Ethanol Packed beds Pelletizing Silica Zeolites Catalytic membrane reactors Commercial membranes Diethyl carbonates Equilibrium conversion Ethanol conversion Packed bed reactor Process intensification Reaction conditions Gas permeable membranes
description	To overcome the low equilibrium conversion in the direct synthesis of diethyl carbonate from ethanol and CO 2 under moderate reaction conditions, the reaction was conducted in a membrane reactor packed with pelletized Cu-Ni:3-1 supported on activated carbon. A SiO 2 /?-Al 2 O 3 commercial membrane and zeolite A membranes synthesized on commercial Al 2 O 3 supports were evaluated in the membrane reactor. Although characterization of the membranes by X-ray diffraction confirmed the presence of a zeolite A layer on the supports, gas permeation and permselectivity tests of ethanol and water evidenced some defects of the synthesized membranes. An increase in conversion with respect to a conventional packed-bed reactor was observed in the membrane reactors prepared on Al 2 O 3 , but equilibrium conversion was not attained. However, with the commercial membrane, the ethanol conversion was higher than the equilibrium conversion. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
publishDate	2019
dc.date.issued.none.fl_str_mv	2019
dc.date.accessioned.none.fl_str_mv	2021-12-16T22:15:28Z
dc.date.available.none.fl_str_mv	2021-12-16T22:15:28Z
dc.type.none.fl_str_mv	Artículo
dc.type.coar.fl_str_mv	http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv	http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv	http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv	info:eu-repo/semantics/article
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dc.type.version.none.fl_str_mv	info:eu-repo/semantics/publishedVersion
format	http://purl.org/coar/resource_type/c_6501
status_str	publishedVersion
dc.identifier.none.fl_str_mv	https://doi.org/10.1002/jbm.b.31976 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068720695&doi=10.3390%2fv11070582&partnerID=40&md5=2714f3155c5733d05b7c2a5079457ba2
dc.identifier.issn.spa.fl_str_mv	09307516
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12494/41372
dc.identifier.bibliographicCitation.spa.fl_str_mv	Arbeláez O,Hernández E,González L-M,Bustamante F,Villa A-L. Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification. Chem Eng Technol. 2019. 04. (5):p. 1135-1143. .
url	https://doi.org/10.1002/jbm.b.31976 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068720695&doi=10.3390%2fv11070582&partnerID=40&md5=2714f3155c5733d05b7c2a5079457ba2 https://hdl.handle.net/20.500.12494/41372
identifier_str_mv	09307516 Arbeláez O,Hernández E,González L-M,Bustamante F,Villa A-L. Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification. Chem Eng Technol. 2019. 04. (5):p. 1135-1143. .
dc.relation.ispartofjournal.spa.fl_str_mv	Chemical Engineering and Technology
dc.rights.accessrights.none.fl_str_mv	info:eu-repo/semantics/closedAccess
dc.rights.coar.none.fl_str_mv	http://purl.org/coar/access_right/c_14cb
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rights_invalid_str_mv	http://purl.org/coar/access_right/c_14cb
dc.format.extent.spa.fl_str_mv	1143-1135
dc.publisher.spa.fl_str_mv	Wiley - V C H Verlag GmbbH & Co.
institution	Universidad Cooperativa de Colombia
repository.name.fl_str_mv	Repositorio Institucional Universidad Cooperativa de Colombia
repository.mail.fl_str_mv	bdigital@metabiblioteca.com
_version_	1814246579005030400

Enhanced Conversion in the Direct Synthesis of Diethyl Carbonate from Ethanol and CO 2 by Process Intensification

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