Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures

Articulo de investigación

Autores:
Areiza Aldana, Grecia Angeline del Mar
Cuellar Lozano, Aleida
Peña Carmona, Nasly Alexandra
Caviedes Rubio, Diego Iván
Mehrdad, Abbas
Hossein Miri, Amir
Rodríguez Rodríguez, Gerson Andrés
Delgado, Daniel Ricardo
Tipo de recurso:
Article of journal
Fecha de publicación:
2016
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
Idioma:
OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/1016
Acceso en línea:
https://hdl.handle.net/20.500.12494/1016
Palabra clave:
3-Chloro-N-phenylphthalimide
solubility
solution thermodynamics
activity coeficients
preferential solvation
Rights
openAccess
License
Licencia CC
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repository_id_str
dc.title.spa.fl_str_mv Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
title Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
spellingShingle Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
3-Chloro-N-phenylphthalimide
solubility
solution thermodynamics
activity coeficients
preferential solvation
title_short Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
title_full Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
title_fullStr Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
title_full_unstemmed Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
title_sort Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
dc.creator.fl_str_mv Areiza Aldana, Grecia Angeline del Mar
Cuellar Lozano, Aleida
Peña Carmona, Nasly Alexandra
Caviedes Rubio, Diego Iván
Mehrdad, Abbas
Hossein Miri, Amir
Rodríguez Rodríguez, Gerson Andrés
Delgado, Daniel Ricardo
dc.contributor.advisor.none.fl_str_mv Delgado, Daniel Ricardo
dc.contributor.author.none.fl_str_mv Areiza Aldana, Grecia Angeline del Mar
Cuellar Lozano, Aleida
Peña Carmona, Nasly Alexandra
Caviedes Rubio, Diego Iván
Mehrdad, Abbas
Hossein Miri, Amir
Rodríguez Rodríguez, Gerson Andrés
Delgado, Daniel Ricardo
dc.subject.spa.fl_str_mv 3-Chloro-N-phenylphthalimide
solubility
solution thermodynamics
activity coeficients
preferential solvation
topic 3-Chloro-N-phenylphthalimide
solubility
solution thermodynamics
activity coeficients
preferential solvation
description Articulo de investigación
publishDate 2016
dc.date.issued.none.fl_str_mv 2016-06-23
dc.date.accessioned.none.fl_str_mv 2017-08-10T20:30:58Z
dc.date.available.none.fl_str_mv 2017-08-10T20:30:58Z
dc.type.none.fl_str_mv Artículo
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dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12494/1016
dc.identifier.bibliographicCitation.spa.fl_str_mv Grecia Angeline del Mar Areiza Aldana, Aleida Cuellar Lozano, Nasly Alexandra Peña Carmona, Diego Iván Caviedes Rubio, Abbas Mehrdad, Amir Hossein Miri, Gerson Andrés Rodríguez Rodríguez, Daniel Ricardo Delgado. Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures. Rev. Colomb. Cienc. Quím. Farm., Vol. 45(2), 256-274, 2016
url https://hdl.handle.net/20.500.12494/1016
identifier_str_mv Grecia Angeline del Mar Areiza Aldana, Aleida Cuellar Lozano, Nasly Alexandra Peña Carmona, Diego Iván Caviedes Rubio, Abbas Mehrdad, Amir Hossein Miri, Gerson Andrés Rodríguez Rodríguez, Daniel Ricardo Delgado. Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures. Rev. Colomb. Cienc. Quím. Farm., Vol. 45(2), 256-274, 2016
dc.relation.isversionof.spa.fl_str_mv http://www.scielo.org.co/scielo.php?script=sci_arttext&pid=S0034-74182016000200006
dc.rights.cc.none.fl_str_mv Licencia CC
dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/openAccess
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rights_invalid_str_mv Licencia CC
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.publisher.spa.fl_str_mv Universidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000
dc.publisher.program.spa.fl_str_mv Ingeniería Industrial
dc.publisher.place.spa.fl_str_mv Neiva
institution Universidad Cooperativa de Colombia
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repository.name.fl_str_mv Repositorio Institucional Universidad Cooperativa de Colombia
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spelling Delgado, Daniel RicardoAreiza Aldana, Grecia Angeline del MarCuellar Lozano, AleidaPeña Carmona, Nasly AlexandraCaviedes Rubio, Diego IvánMehrdad, AbbasHossein Miri, AmirRodríguez Rodríguez, Gerson AndrésDelgado, Daniel Ricardo2017-08-10T20:30:58Z2017-08-10T20:30:58Z2016-06-23https://hdl.handle.net/20.500.12494/1016Grecia Angeline del Mar Areiza Aldana, Aleida Cuellar Lozano, Nasly Alexandra Peña Carmona, Diego Iván Caviedes Rubio, Abbas Mehrdad, Amir Hossein Miri, Gerson Andrés Rodríguez Rodríguez, Daniel Ricardo Delgado. Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures. Rev. Colomb. Cienc. Quím. Farm., Vol. 45(2), 256-274, 2016Articulo de investigaciónThe thermodynamic properties of the 3-chloro-N-phenyl-phthalimide in acetone + methanol cosolvent mixtures were obtained from solubility data report in literature. The solubility was higher in near acetone and lower in pure methanol at all temperatures studied. A non-linear plot of ∆solnH° vs. ∆solnG° shows a negative slope from pure acetone up to x1 = 0.691. Beyond this composition, a variable positive slope is obtained with the exception of mixtures with x1 = 0.121, x1 = 0.272 and x1 = 0.356 which is a not common trend in these systems. The preferential solvation of 3-chloro-N-phenyl-phthalimide by the components of the solvents was estimated by means of the inverse Kirkwood–Buff integral method, showing the 3-chloro-Nphenyl-phthalimide is preferential solvated by methanol in more polar mixtures and by acetone in less polar ones.Introduction. Theoretical. Results and discussion. Conclusions. Disclosure statement. Referencesdanielr.delgado@campusucc.edu.coUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Programa de Ingeniería Industrial, Neiva, Colombia, 00000Ingeniería IndustrialNeivahttp://www.scielo.org.co/scielo.php?script=sci_arttext&pid=S0034-741820160002000063-Chloro-N-phenylphthalimidesolubilitysolution thermodynamicsactivity coeficientspreferential solvationSolution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixturesArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionLicencia CCinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2PublicationLICENSElicense.txtlicense.txttext/plain; charset=utf-84587https://repository.ucc.edu.co/bitstreams/4f8a7cae-4f2c-4c59-b902-b6e5f62801b2/downloadde761e1f2d941a1706625b603088b857MD52TEXT2016_Solution 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