Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation
Equilibrium solubility of triclocarban (TCC) expressed in mole fraction in 1,4-dioxane and cyclohexane, as well, as in 19 {cyclohexane (1) + 1,4-dioxane (2)} mixtures, was determined at seven temperatures from T = (288.15 to 318.15) K. Logarithmic TCC solubility in these cosolvent mixtures was adequ...
- Autores:
-
Delgado, Daniel Ricardo
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2022
- Institución:
- Universidad Cooperativa de Colombia
- Repositorio:
- Repositorio UCC
- Idioma:
- eng
- OAI Identifier:
- oai:repository.ucc.edu.co:20.500.12494/55525
- Acceso en línea:
- https://hdl.handle.net/20.500.12494/55525
- Palabra clave:
- Triclocarban
Solibility
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by/4.0/
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Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| dc.title.translated.none.fl_str_mv |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| title |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| spellingShingle |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation Triclocarban Solibility |
| title_short |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| title_full |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| title_fullStr |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| title_full_unstemmed |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| title_sort |
Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation |
| dc.creator.fl_str_mv |
Delgado, Daniel Ricardo |
| dc.contributor.author.none.fl_str_mv |
Delgado, Daniel Ricardo |
| dc.contributor.researchgroup.none.fl_str_mv |
Grupo de Investigación de Ingenierías UCC-Neiva |
| dc.subject.proposal.none.fl_str_mv |
Triclocarban Solibility |
| topic |
Triclocarban Solibility |
| description |
Equilibrium solubility of triclocarban (TCC) expressed in mole fraction in 1,4-dioxane and cyclohexane, as well, as in 19 {cyclohexane (1) + 1,4-dioxane (2)} mixtures, was determined at seven temperatures from T = (288.15 to 318.15) K. Logarithmic TCC solubility in these cosolvent mixtures was adequately correlated with a lineal bivariate equation as function of both the mixtures composition and temperature. Apparent thermodynamic quantities for the dissolution and mixing processes were computed by means of the van’t Hoff and Gibbs equations observing endothermal and entropy-driven dissolution processes in all cases. The enthalpy–entropy compensation plot of apparent enthalpy vs. apparent Gibbs energy was linear exhibiting positive slope implying enthalpy-driving for TCC transfer from cyclohexane to 1,4-dioxane. Ultimately, by using the inverse Kirkwood–Buff integrals it is observed that TCC is preferentially solvated by cyclohexane molecules in 1,4-dioxane-rich mixtures but preferentially solvated by 1,4-dioxane molecules in cyclohexane-rich mixtures. |
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2022 |
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2022-10-11 |
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2024-05-06T20:42:04Z |
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2024-05-06T20:42:04Z |
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Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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http://purl.org/coar/resource_type/c_6501 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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Agredo-Collazos, J.J., Ortiz, C.P., Cerquera, N.E. et al. Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation. J Solution Chem 51, 1603–1625 (2022). https://doi.org/10.1007/s10953-022-01209-4 |
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1572-8927 |
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https://hdl.handle.net/20.500.12494/55525 |
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doi.org/10.1007/s10953-022-01209-4 |
| dc.identifier.eissn.none.fl_str_mv |
0095-9782 |
| identifier_str_mv |
Agredo-Collazos, J.J., Ortiz, C.P., Cerquera, N.E. et al. Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation. J Solution Chem 51, 1603–1625 (2022). https://doi.org/10.1007/s10953-022-01209-4 1572-8927 doi.org/10.1007/s10953-022-01209-4 0095-9782 |
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https://hdl.handle.net/20.500.12494/55525 |
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eng |
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eng |
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1625 |
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1603 |
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51 |
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Journal of Solution Chemistry |
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Budavari, S., O’Neil, M.J., Smith, A., Heckelman, P.E., Obenchain, J.R., Jr., Gallipeau, J.A.R., D’Arecea, M.A.: The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals, 13th edn. Merck & Co., Inc., Whitehouse Station, NJ (2001) Khan, R., Zeb, A., Roy, N., Magar, R.T., Kim, H.J., Lee, K.W., Lee, S.-W.: Biochemical and structural basis of triclosan resistance in a novel enoyl-acyl carrier protein reductase. Antimicrob. Agents Chemother. 62, e00648-e718 (2018) Zhu, L., Bi, H., Ma, J., Hu, Z., Zhang, W., Cronan, J.E., Wang, H.: The two functional enoylacyl carrier protein reductases of enterococcus faecalis do not mediate triclosan resistance. MBio 4, e00613 (2013) |
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Attribution 4.0 International |
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pdf |
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Universidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Civil, Neiva |
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Neiva |
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Universidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Civil, Neiva |
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https://link.springer.com/article/10.1007/s10953-022-01209-4 |
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Delgado, Daniel RicardoGrupo de Investigación de Ingenierías UCC-Neiva2024-05-06T20:42:04Z2024-05-06T20:42:04Z2022-10-11Agredo-Collazos, J.J., Ortiz, C.P., Cerquera, N.E. et al. Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation. J Solution Chem 51, 1603–1625 (2022). https://doi.org/10.1007/s10953-022-01209-41572-8927https://hdl.handle.net/20.500.12494/55525doi.org/10.1007/s10953-022-01209-40095-9782Equilibrium solubility of triclocarban (TCC) expressed in mole fraction in 1,4-dioxane and cyclohexane, as well, as in 19 {cyclohexane (1) + 1,4-dioxane (2)} mixtures, was determined at seven temperatures from T = (288.15 to 318.15) K. Logarithmic TCC solubility in these cosolvent mixtures was adequately correlated with a lineal bivariate equation as function of both the mixtures composition and temperature. Apparent thermodynamic quantities for the dissolution and mixing processes were computed by means of the van’t Hoff and Gibbs equations observing endothermal and entropy-driven dissolution processes in all cases. The enthalpy–entropy compensation plot of apparent enthalpy vs. apparent Gibbs energy was linear exhibiting positive slope implying enthalpy-driving for TCC transfer from cyclohexane to 1,4-dioxane. Ultimately, by using the inverse Kirkwood–Buff integrals it is observed that TCC is preferentially solvated by cyclohexane molecules in 1,4-dioxane-rich mixtures but preferentially solvated by 1,4-dioxane molecules in cyclohexane-rich mixtures.Energias, agua y medio ambientepdfapplication/pdfengUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Civil, NeivaNeivahttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessAttribution 4.0 Internationalhttp://purl.org/coar/access_right/c_abf2https://link.springer.com/article/10.1007/s10953-022-01209-4Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential SolvationEquilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential SolvationArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion1625160351Journal of Solution ChemistryBudavari, S., O’Neil, M.J., Smith, A., Heckelman, P.E., Obenchain, J.R., Jr., Gallipeau, J.A.R., D’Arecea, M.A.: The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals, 13th edn. Merck & Co., Inc., Whitehouse Station, NJ (2001)Khan, R., Zeb, A., Roy, N., Magar, R.T., Kim, H.J., Lee, K.W., Lee, S.-W.: Biochemical and structural basis of triclosan resistance in a novel enoyl-acyl carrier protein reductase. Antimicrob. Agents Chemother. 62, e00648-e718 (2018)Zhu, L., Bi, H., Ma, J., Hu, Z., Zhang, W., Cronan, J.E., Wang, H.: The two functional enoylacyl carrier protein reductases of enterococcus faecalis do not mediate triclosan resistance. MBio 4, e00613 (2013)TriclocarbanSolibilityPublication3171Estudio termodinámico de la solubilidad de la isoniacida en sistemas acuosos polietilenglicol 200, 300, 400 y 600 e implementación de algoritmos de machine learning para la predicción de la solubilidad.ORIGINALEquilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures Determination, Correlation, Thermodynamics and Preferential Solvation.pdfEquilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures Determination, Correlation, Thermodynamics and Preferential Solvation.pdfapplication/pdf2043522https://repository.ucc.edu.co/bitstreams/52bf45cd-dd53-4f11-9d5c-dd8770200101/download5f4cd321040f935bdadabae57b73285bMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8908https://repository.ucc.edu.co/bitstreams/f282e2a6-be88-4617-a7c5-8defa44cdf52/download0175ea4a2d4caec4bbcc37e300941108MD52LICENSElicense.txtlicense.txttext/plain; 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