Solution thermodynamics and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K

The equilibrium solubility and preferential solvation of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 298.15 K was reported. Mole fraction solubility varies continuously from 2.85 × 10–9 in neat water to 2.39 × 10–3 in neat 1,4-dioxane. Solubility behaviour was adequately correlated by means of the Jouyban-Acree model. Based on the inverse Kirkwood-Buff integrals, preferential solvation parameters were calculated. Triclocarban is preferentially solvated by water in water-rich mixtures (0.00 < x1 < 0.18) and also in 1,4-dioxane-rich mixtures (0.78 < x1 < 1.00) but preferentially solvated by 1,4-dioxane in mixtures with similar solvent compositions. © 2017 Informa UK Limited, trading as Taylor & Francis Group

• Autores: Gaviria-Castillo A.C.; Artunduaga-Tole J.D.; Rodríguez-Rubiano J.D.; Zuñiga-Andrade J.A.; Delgado, Daniel ricardo; Jouyban A.; Martínez F.
• Tipo de recurso: Article of journal
• Fecha de publicación: 2023
• Institución: Universidad Cooperativa de Colombia
• Repositorio: Repositorio UCC
• OAI Identifier: oai:repository.ucc.edu.co:20.500.12494/50341
• Acceso en línea: https://doi.org/10.1080/00319104.2017.1416613; https://www.scopus.com/inward/record.uri?eid=2-s2.0-85041353886&doi=10.1080%2f00319104.2017.1416613&partnerID=40&md5=edc2ac8d735e4be979fd0c38c62138c0; https://hdl.handle.net/20.500.12494/50341
• Palabra clave: EQUILIBRIUM SOLUBILITIES; IKBI; JOUYBAN-ACREE MODEL; KIRKWOOD-BUFF INTEGRALS; MIXTURES; PREFERENTIAL SOLVATION; SOLUBILITY; SOLUTION THERMODYNAMICS; SOLVATION; SOLVENT COMPOSITION; THERMODYNAMICS; TRICLOCARBAN
• Rights: openAccess
• License: http://purl.org/coar/access_right/c_abf2