Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures

La solubilidad de sulfametazina (SMT) en mezclas de codisolvente de etilenglicol (EG) + agua (W) se determinó a nueve temperaturas (278.15, 283.15, 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 y 318.15 K) por medio de la agitación método. A partir de los datos de solubilidad, se calcularon las fun...

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Autores:
Aydi, Abdelkarim
Ortiz, Claudia Patricia
Caviedes Rubio, Diego Iván
Ayadi, Cherifa
Hbaieb, Souhaira
Delgado, Daniel Ricardo
Tipo de recurso:
Article of journal
Fecha de publicación:
2021
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
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oai:repository.ucc.edu.co:20.500.12494/32654
Acceso en línea:
https://doi.org/10.1016/j.jtice.2020.12.031
https://hdl.handle.net/20.500.12494/32654
Palabra clave:
Sulfametazina
Solubilidad
Solvatación preferencial
van´t Hoff
Termodinámica de soluciones
Sulfamethazine
Solubility
Preferential solvation
van´t Hoff
Solution thermodynamics
Rights
embargoedAccess
License
Atribución – Sin Derivar
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oai_identifier_str oai:repository.ucc.edu.co:20.500.12494/32654
network_acronym_str COOPER2
network_name_str Repositorio UCC
repository_id_str
dc.title.spa.fl_str_mv Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
title Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
spellingShingle Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
Sulfametazina
Solubilidad
Solvatación preferencial
van´t Hoff
Termodinámica de soluciones
Sulfamethazine
Solubility
Preferential solvation
van´t Hoff
Solution thermodynamics
title_short Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
title_full Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
title_fullStr Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
title_full_unstemmed Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
title_sort Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures
dc.creator.fl_str_mv Aydi, Abdelkarim
Ortiz, Claudia Patricia
Caviedes Rubio, Diego Iván
Ayadi, Cherifa
Hbaieb, Souhaira
Delgado, Daniel Ricardo
dc.contributor.author.none.fl_str_mv Aydi, Abdelkarim
Ortiz, Claudia Patricia
Caviedes Rubio, Diego Iván
Ayadi, Cherifa
Hbaieb, Souhaira
Delgado, Daniel Ricardo
dc.subject.spa.fl_str_mv Sulfametazina
Solubilidad
Solvatación preferencial
van´t Hoff
Termodinámica de soluciones
topic Sulfametazina
Solubilidad
Solvatación preferencial
van´t Hoff
Termodinámica de soluciones
Sulfamethazine
Solubility
Preferential solvation
van´t Hoff
Solution thermodynamics
dc.subject.other.spa.fl_str_mv Sulfamethazine
Solubility
Preferential solvation
van´t Hoff
Solution thermodynamics
description La solubilidad de sulfametazina (SMT) en mezclas de codisolvente de etilenglicol (EG) + agua (W) se determinó a nueve temperaturas (278.15, 283.15, 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 y 318.15 K) por medio de la agitación método. A partir de los datos de solubilidad, se calcularon las funciones termodinámicas de solución, transferencia y mezcla utilizando las ecuaciones de Gibbs y van´t Hoff. Por otro lado, los parámetros de solvatación preferencial de SMT se determinaron mediante el método de las integrales inversas de Kirkwood-Buff (IKBI). En términos generales, la solubilidad del SMT se ve favorecida por el aumento de temperatura y la disminución de la polaridad del sistema codisolvente, por lo que la máxima solubilidad se alcanza en EG puro a 318.15 K y la mínima en agua pura a 278.15 K. Energía de Gibbs es positivo en todos los casos, con una mayor contribución del componente energético (entalpía de la solución). En cuanto a la compensación entalpía-entrópica, el proceso es impulsado en todos los casos por la entalpía de la solución. Finalmente, SMT se solvata preferentemente con agua en mezclas con mayor polaridad y con EG en mezclas menos polares.
publishDate 2021
dc.date.accessioned.none.fl_str_mv 2021-01-19T21:58:48Z
dc.date.available.none.fl_str_mv 2021-01-19T21:58:48Z
2022-12-31
dc.date.issued.none.fl_str_mv 2021-01-04
dc.type.none.fl_str_mv Artículo
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dc.identifier.bibliographicCitation.spa.fl_str_mv Abdelkarim, A., Ortiz, C. P., Caviedes-Rubio, D. I. Ayadi, C., Hbaieb S. y Ricardo Delgado, D. (2021). Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures. Journal of the Taiwan Institute of Chemical Engineers. https://doi.org/10.1016/j.jtice.2020.12.031
identifier_str_mv 18761070
Abdelkarim, A., Ortiz, C. P., Caviedes-Rubio, D. I. Ayadi, C., Hbaieb S. y Ricardo Delgado, D. (2021). Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures. Journal of the Taiwan Institute of Chemical Engineers. https://doi.org/10.1016/j.jtice.2020.12.031
url https://doi.org/10.1016/j.jtice.2020.12.031
https://hdl.handle.net/20.500.12494/32654
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dc.relation.ispartofjournal.spa.fl_str_mv Journal of the Taiwan Institute of Chemical Engineers
dc.relation.references.spa.fl_str_mv L.H. Sophian, D.L. Piper, G.H. Schneller The Sulfapyrimidines: sulfadiazine, sulfamerazine, sulfamethazine Literary Licens. (2012)
J.E. Riviere, M.G. Papich Veterinary pharmacology and therapeutics (10th ed.) (2017)
J.H. Blanco-Márquez, D.I. Caviedes Rubio, C.P. Ortiz, N.E. Cerquera, F. Martínez, D.R Delgado Thermodynamic analysis and preferential solvation of sulfamethazine in acetonitrile + water cosolvent mixtures Fluid Phase Equilib, 505 (2020), Article 112361 10.1016/j.fluid.2019.112361
B. Aday, P. Sola, F. Çolak, M. Kaya Synthesis of novel sulfonamide analogs containing sulfamerazine/sulfaguanidine and their biological activities J Enzym Inhib Med Chem, 31 (2016), pp. 1005-1010 10.3109/14756366.2015.1079183
A.N. Martin, P. Bustamante Physical pharmacy: physical chemical principles in the pharmaceutical sciences (4th ed.), Lippincott Williams & Wilking, Philadelphia (1993)
S.H. Yalkowsky Solubility and solubilization in aqueous media American Chemical Society, New York (1999)
S.H. Yalkowsky, Y. He, P. Jain Handbook of aqueous solubility data (2nd ed.), CRC Press, Boca Raton (2016) 10.1201/ebk1439802458
A. Jouyban, W.E. Acree, F. Martínez Preferential solvation of apremilast in some (Transcutol® + water) mixtures J Mol Liq, 316 (2020), Article 113905 10.1016/j.molliq.2020.113905
M. Barzegar-Jalali, S.N. Mirheydari, F. Martinez, A. Jouyban Lamotrigine solubility in 1-propanol + water mixtures at different temperatures: experimental data and mathematical modelling Phys Chem Liq, 58 (2020), pp. 432-445 10.1080/00319104.2019.1600141
A.M. Romero-Nieto, D.I. Caviedes-Rubio, J. Polania-Orozco, N.E. Cerquera, D.R. Delgado Temperature and cosolvent composition effects in the solubility of methylparaben in acetonitrile + water mixtures Phys Chem Liq (2019) 10.1080/00319104.2019.1636379
T. Higuchi, K.A. Connors Phase-solubility techniques Adv Anal Inst, 4 (1965), pp. 117-212
D.R. Delgado, O.A. Almanza, F. Martínez, M.A. Peña, A. Jouyban, W.E. Acree Solution thermodynamics and preferential solvation of sulfamethazine in (methanol + water) mixtures J Chem Thermodyn, 97 (2016), pp. 264-276 10.1016/J.JCT.2016.02.002
D.R. Delgado, F. Martínez Solubility and solution thermodynamics of sulfamerazine and sulfamethazine in some ethanol+water mixtures Fluid Phase Equilib, 360 (2013), pp. 88-96 10.1016/j.fluid.2013.09.018
D.R. Delgado, F. Martínez Solubility and solution thermodynamics of some sulfonamides in 1-propanol + water mixtures J Solut Chem, 43 (2014), pp. 836-852 10.1007/s10953-014-0169-0
M. Del Mar Muñoz, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez Solubility and preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in propylene glycol + water mixtures at 298.15K J Mol Liq, 204 (2015), pp. 132-136 10.1016/j.molliq.2015.01.047
A. Barton CRC handbook of solubility parameters and other cohesion parameters (2nd), CRC Press LLC, Boca Raton (FL) (1991)
L. Maury, J. Rambaud, B. Pauvert, Y. Lasserre, G. Bergé, M. Audran Physicochemical and structural study of sulfamethazine J Pharm Sci, 74 (1985), pp. 422-426 10.1002/JPS.2600740411
M. Sorrenti, G.P. Bettinetti, A. Negri Thermoanalytical characterization ofpseudopolymorphs of sulphadimidine and sulphadimidine–trimethoprim molecular complexes Thermochim Acta, 321 (1998), pp. 67-72 10.1016/S0040-6031(98)00441-9
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Elsevier B.V.
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dc.publisher.place.spa.fl_str_mv Neiva
institution Universidad Cooperativa de Colombia
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spelling Aydi, AbdelkarimOrtiz, Claudia PatriciaCaviedes Rubio, Diego IvánAyadi, CherifaHbaieb, SouhairaDelgado, Daniel Ricardo12021-01-19T21:58:48Z2022-12-312021-01-19T21:58:48Z2021-01-0418761070https://doi.org/10.1016/j.jtice.2020.12.031https://hdl.handle.net/20.500.12494/32654Abdelkarim, A., Ortiz, C. P., Caviedes-Rubio, D. I. Ayadi, C., Hbaieb S. y Ricardo Delgado, D. (2021). Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures. Journal of the Taiwan Institute of Chemical Engineers. https://doi.org/10.1016/j.jtice.2020.12.031La solubilidad de sulfametazina (SMT) en mezclas de codisolvente de etilenglicol (EG) + agua (W) se determinó a nueve temperaturas (278.15, 283.15, 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 y 318.15 K) por medio de la agitación método. A partir de los datos de solubilidad, se calcularon las funciones termodinámicas de solución, transferencia y mezcla utilizando las ecuaciones de Gibbs y van´t Hoff. Por otro lado, los parámetros de solvatación preferencial de SMT se determinaron mediante el método de las integrales inversas de Kirkwood-Buff (IKBI). En términos generales, la solubilidad del SMT se ve favorecida por el aumento de temperatura y la disminución de la polaridad del sistema codisolvente, por lo que la máxima solubilidad se alcanza en EG puro a 318.15 K y la mínima en agua pura a 278.15 K. Energía de Gibbs es positivo en todos los casos, con una mayor contribución del componente energético (entalpía de la solución). En cuanto a la compensación entalpía-entrópica, el proceso es impulsado en todos los casos por la entalpía de la solución. Finalmente, SMT se solvata preferentemente con agua en mezclas con mayor polaridad y con EG en mezclas menos polares.The solubility of sulfamethazine (SMT) in ethylene glycol (EG) + water (W) cosolvent mixtures was determined at nine temperatures (278.15, 283.15, 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15 K) by means of the stirring method. From the solubility data, the thermodynamic functions of solution, transfer and mixing were calculated using the Gibbs and van´t Hoff equations. On the other hand, the preferential solvation parameters of SMT were determined by means of the method of the inverse integrals of Kirkwood-Buff (IKBI). In general terms, the solubility of SMT is favored by the increase in temperature and the decrease in the polarity of the cosolvent system, thus the maximum solubility is reached in pure EG at 318.15 K and the minimum in pure water at 278.15 K. Gibbs energy is positive in all cases, with a higher contribution from the energy component (enthalpy of solution). Regarding enthalpy-entropic compensation, the process is driven in all cases by the enthalpy of solution. Finally, SMT is preferentially solvated by water in mixtures with higher polarity and by EG in less polar mixtures.Highlights. -- Abstract. -- Graphical abstract. -- Keywords. -- 1. Introduction. -- 2. Materials and methods. -- 3. Results. -- 4. Conclusions. -- Declaration of Competing Interest. -- Acknowledgments. -- References.http://scienti.colciencias.gov.co:8081/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001402116https://orcid.org/0000-0002-4835-9739https://scienti.minciencias.gov.co/gruplac/jsp/visualiza/visualizagr.jsp?nro=00000000004151danielr.delgado@campusucc.edu.cohttps://scholar.google.es/citations?user=OW0mejcAAAAJ&hl=es10Universidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, NeivaElsevier B.V.Ingeniería IndustrialNeivahttps://bbibliograficas.ucc.edu.co:2152/science/article/pii/S1876107020304405#!Journal of the Taiwan Institute of Chemical EngineersL.H. Sophian, D.L. Piper, G.H. Schneller The Sulfapyrimidines: sulfadiazine, sulfamerazine, sulfamethazine Literary Licens. (2012)J.E. Riviere, M.G. Papich Veterinary pharmacology and therapeutics (10th ed.) (2017)J.H. Blanco-Márquez, D.I. Caviedes Rubio, C.P. Ortiz, N.E. Cerquera, F. Martínez, D.R Delgado Thermodynamic analysis and preferential solvation of sulfamethazine in acetonitrile + water cosolvent mixtures Fluid Phase Equilib, 505 (2020), Article 112361 10.1016/j.fluid.2019.112361B. Aday, P. Sola, F. Çolak, M. Kaya Synthesis of novel sulfonamide analogs containing sulfamerazine/sulfaguanidine and their biological activities J Enzym Inhib Med Chem, 31 (2016), pp. 1005-1010 10.3109/14756366.2015.1079183A.N. Martin, P. Bustamante Physical pharmacy: physical chemical principles in the pharmaceutical sciences (4th ed.), Lippincott Williams & Wilking, Philadelphia (1993)S.H. Yalkowsky Solubility and solubilization in aqueous media American Chemical Society, New York (1999)S.H. Yalkowsky, Y. He, P. Jain Handbook of aqueous solubility data (2nd ed.), CRC Press, Boca Raton (2016) 10.1201/ebk1439802458A. Jouyban, W.E. Acree, F. Martínez Preferential solvation of apremilast in some (Transcutol® + water) mixtures J Mol Liq, 316 (2020), Article 113905 10.1016/j.molliq.2020.113905M. Barzegar-Jalali, S.N. Mirheydari, F. Martinez, A. Jouyban Lamotrigine solubility in 1-propanol + water mixtures at different temperatures: experimental data and mathematical modelling Phys Chem Liq, 58 (2020), pp. 432-445 10.1080/00319104.2019.1600141A.M. Romero-Nieto, D.I. Caviedes-Rubio, J. Polania-Orozco, N.E. Cerquera, D.R. Delgado Temperature and cosolvent composition effects in the solubility of methylparaben in acetonitrile + water mixtures Phys Chem Liq (2019) 10.1080/00319104.2019.1636379T. Higuchi, K.A. Connors Phase-solubility techniques Adv Anal Inst, 4 (1965), pp. 117-212D.R. Delgado, O.A. Almanza, F. Martínez, M.A. Peña, A. Jouyban, W.E. Acree Solution thermodynamics and preferential solvation of sulfamethazine in (methanol + water) mixtures J Chem Thermodyn, 97 (2016), pp. 264-276 10.1016/J.JCT.2016.02.002D.R. Delgado, F. Martínez Solubility and solution thermodynamics of sulfamerazine and sulfamethazine in some ethanol+water mixtures Fluid Phase Equilib, 360 (2013), pp. 88-96 10.1016/j.fluid.2013.09.018D.R. Delgado, F. Martínez Solubility and solution thermodynamics of some sulfonamides in 1-propanol + water mixtures J Solut Chem, 43 (2014), pp. 836-852 10.1007/s10953-014-0169-0M. Del Mar Muñoz, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez Solubility and preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in propylene glycol + water mixtures at 298.15K J Mol Liq, 204 (2015), pp. 132-136 10.1016/j.molliq.2015.01.047A. Barton CRC handbook of solubility parameters and other cohesion parameters (2nd), CRC Press LLC, Boca Raton (FL) (1991)L. Maury, J. Rambaud, B. Pauvert, Y. Lasserre, G. Bergé, M. Audran Physicochemical and structural study of sulfamethazine J Pharm Sci, 74 (1985), pp. 422-426 10.1002/JPS.2600740411M. Sorrenti, G.P. Bettinetti, A. Negri Thermoanalytical characterization ofpseudopolymorphs of sulphadimidine and sulphadimidine–trimethoprim molecular complexes Thermochim Acta, 321 (1998), pp. 67-72 10.1016/S0040-6031(98)00441-9SulfametazinaSolubilidadSolvatación preferencialvan´t HoffTermodinámica de solucionesSulfamethazineSolubilityPreferential solvationvan´t HoffSolution thermodynamicsSolution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixturesArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionAtribución – Sin Derivarinfo:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfPublicationORIGINALJournal of the Taiwan Institute of Chemical Engineers.pdfJournal of the Taiwan Institute of Chemical Engineers.pdfArtículo científico 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