Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation

El aumento continuo de la demanda de mercancías y combustibles aumenta la necesidad de enfoques modernos para la producción en masa de productos químicos renovables derivados de materias primas abundantes, como la biomasa, así como para la contaminación de la remediación del agua y el suelo resultan...

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Autores:: Giannakoudakis, Dimitrios A.
Zormpa, Foteini F.
Margellou, Antigoni G.
Qayyum, Abdul
Colmenares Quintero, Ramón Fernando
Len, Christophe
Colmenares Quintero, Juan Carlos
Triantafyllidis, Konstantinos S.

Tipo de recurso:: Article of journal

Fecha de publicación:: 2022

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

Idioma:

id	COOPER2_14fa975b523b4afa802993a0cf69b44c
oai_identifier_str	oai:repository.ucc.edu.co:20.500.12494/52484
network_acronym_str	COOPER2
network_name_str	Repositorio UCC
repository_id_str
dc.title.spa.fl_str_mv	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation
title	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation
spellingShingle	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation Nanocatalizadores de carbono Catálisis heterogénea Fotocatálisis Sonocatálisis Sonofotocatálisis Hidrogenólisis de la lignina 5-hidroximetilfurfural (5-HMF) a 2,5-diformilfurano (DFF) Valorización de la biomasa Saneamiento de sustancias orgánicas peligrosas Carbon-based nanocatalysts Heterogeneous catalysis Photocatalysis Sonocatalysis Sonophotocatalysis lignin hydrogenolysis 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF) Biomass valorization Hazardous organics remediation
title_short	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation
title_full	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation
title_fullStr	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation
title_full_unstemmed	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation
title_sort	Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation
dc.creator.fl_str_mv	Giannakoudakis, Dimitrios A. Zormpa, Foteini F. Margellou, Antigoni G. Qayyum, Abdul Colmenares Quintero, Ramón Fernando Len, Christophe Colmenares Quintero, Juan Carlos Triantafyllidis, Konstantinos S.
dc.contributor.author.none.fl_str_mv	Giannakoudakis, Dimitrios A. Zormpa, Foteini F. Margellou, Antigoni G. Qayyum, Abdul Colmenares Quintero, Ramón Fernando Len, Christophe Colmenares Quintero, Juan Carlos Triantafyllidis, Konstantinos S.
dc.subject.none.fl_str_mv	Nanocatalizadores de carbono Catálisis heterogénea Fotocatálisis Sonocatálisis Sonofotocatálisis Hidrogenólisis de la lignina 5-hidroximetilfurfural (5-HMF) a 2,5-diformilfurano (DFF) Valorización de la biomasa Saneamiento de sustancias orgánicas peligrosas
topic	Nanocatalizadores de carbono Catálisis heterogénea Fotocatálisis Sonocatálisis Sonofotocatálisis Hidrogenólisis de la lignina 5-hidroximetilfurfural (5-HMF) a 2,5-diformilfurano (DFF) Valorización de la biomasa Saneamiento de sustancias orgánicas peligrosas Carbon-based nanocatalysts Heterogeneous catalysis Photocatalysis Sonocatalysis Sonophotocatalysis lignin hydrogenolysis 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF) Biomass valorization Hazardous organics remediation
dc.subject.other.none.fl_str_mv	Carbon-based nanocatalysts Heterogeneous catalysis Photocatalysis Sonocatalysis Sonophotocatalysis lignin hydrogenolysis 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF) Biomass valorization Hazardous organics remediation
description	El aumento continuo de la demanda de mercancías y combustibles aumenta la necesidad de enfoques modernos para la producción en masa de productos químicos renovables derivados de materias primas abundantes, como la biomasa, así como para la contaminación de la remediación del agua y el suelo resultante de la descarga antropogénica de compuestos orgánicos. Hacia estas direcciones y dentro del concepto de (bio)economía circular, el desarrollo de procesos catalíticos eficientes y sostenibles es de suma importancia. En este contexto, el diseño de nuevos catalizadores desempeña un papel fundamental, y los nanocatalizadores basados en el carbono (CnC) representan una de las clases de materiales más prometedoras. En esta revisión, se resume y discute una amplia gama de CnCs utilizados para la valorización de la biomasa hacia la producción de productos químicos valiosos, y para aplicaciones de remediación ambiental. Se hace hincapié, en particular, en la producción catalítica de 5-hidroximetilfurfural (5-HMF) a partir de residuos alimentarios ricos en celulosa o almidón, la hidrogenólisis de la lignina para obtener altos rendimientos de bioaceite enriquecido predominantemente en monómeros fenólicos alquilados y oxigenados, la oxidación parcial selectiva fotocatalítica, sonocatalítica o sonofotocatalítica de 5-HMF a 2,5-diformilfurano (DFF) y la descomposición de contaminantes orgánicos en matrices acuosas. Los materiales carbonosos utilizados como catalizadores independientes o como soportes de (nano)metales son varios tipos de carbones micro/mesoporosos activados, grafeno/grafito y sus homólogos modificados químicamente, como el óxido de grafito y el óxido de grafito reducido, los nanotubos de carbono, los puntos cuánticos de carbono, el nitruro de carbono grafítico y los fullerenos.
publishDate	2022
dc.date.issued.none.fl_str_mv	2022-05-14
dc.date.accessioned.none.fl_str_mv	2023-08-18T16:29:17Z
dc.date.available.none.fl_str_mv	2023-08-18T16:29:17Z
dc.type.none.fl_str_mv	Artículo
dc.type.coar.fl_str_mv	http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.none.fl_str_mv	http://purl.org/coar/resource_type/c_6501
dc.type.coarversion.none.fl_str_mv	http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.none.fl_str_mv	info:eu-repo/semantics/article
dc.type.version.none.fl_str_mv	info:eu-repo/semantics/publishedVersion
format	http://purl.org/coar/resource_type/c_6501
status_str	publishedVersion
dc.identifier.issn.none.fl_str_mv	20794991
dc.identifier.uri.spa.fl_str_mv	https://doi.org/10.3390/nano12101679
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12494/52484
dc.identifier.bibliographicCitation.none.fl_str_mv	Giannakoudakis, D.A.; Zormpa, F.F.; Margellou, A.G.; Qayyum, A.; Colmenares-Quintero, R.F.; Len, C.; Colmenares, J.C.; Triantafyllidis, K.S. Carbon-Based Nanocatalysts (CnCs) for Biomass Valorization and Hazardous Organics Remediation. Nanomaterials 2022, 12, 1679. https://doi.org/10.3390/nano12101679
identifier_str_mv	20794991 Giannakoudakis, D.A.; Zormpa, F.F.; Margellou, A.G.; Qayyum, A.; Colmenares-Quintero, R.F.; Len, C.; Colmenares, J.C.; Triantafyllidis, K.S. Carbon-Based Nanocatalysts (CnCs) for Biomass Valorization and Hazardous Organics Remediation. Nanomaterials 2022, 12, 1679. https://doi.org/10.3390/nano12101679
url	https://doi.org/10.3390/nano12101679 https://hdl.handle.net/20.500.12494/52484
dc.relation.isversionof.spa.fl_str_mv	https://www.mdpi.com/2079-4991/12/10/1679#cite
dc.relation.ispartofjournal.spa.fl_str_mv	Nanomaterials
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repository.mail.fl_str_mv	bdigital@metabiblioteca.com
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spelling	Giannakoudakis, Dimitrios A.Zormpa, Foteini F.Margellou, Antigoni G.Qayyum, AbdulColmenares Quintero, Ramón FernandoLen, ChristopheColmenares Quintero, Juan CarlosTriantafyllidis, Konstantinos S.122023-08-18T16:29:17Z2023-08-18T16:29:17Z2022-05-1420794991https://doi.org/10.3390/nano12101679https://hdl.handle.net/20.500.12494/52484Giannakoudakis, D.A.; Zormpa, F.F.; Margellou, A.G.; Qayyum, A.; Colmenares-Quintero, R.F.; Len, C.; Colmenares, J.C.; Triantafyllidis, K.S. Carbon-Based Nanocatalysts (CnCs) for Biomass Valorization and Hazardous Organics Remediation. Nanomaterials 2022, 12, 1679. https://doi.org/10.3390/nano12101679El aumento continuo de la demanda de mercancías y combustibles aumenta la necesidad de enfoques modernos para la producción en masa de productos químicos renovables derivados de materias primas abundantes, como la biomasa, así como para la contaminación de la remediación del agua y el suelo resultante de la descarga antropogénica de compuestos orgánicos. Hacia estas direcciones y dentro del concepto de (bio)economía circular, el desarrollo de procesos catalíticos eficientes y sostenibles es de suma importancia. En este contexto, el diseño de nuevos catalizadores desempeña un papel fundamental, y los nanocatalizadores basados en el carbono (CnC) representan una de las clases de materiales más prometedoras. En esta revisión, se resume y discute una amplia gama de CnCs utilizados para la valorización de la biomasa hacia la producción de productos químicos valiosos, y para aplicaciones de remediación ambiental. Se hace hincapié, en particular, en la producción catalítica de 5-hidroximetilfurfural (5-HMF) a partir de residuos alimentarios ricos en celulosa o almidón, la hidrogenólisis de la lignina para obtener altos rendimientos de bioaceite enriquecido predominantemente en monómeros fenólicos alquilados y oxigenados, la oxidación parcial selectiva fotocatalítica, sonocatalítica o sonofotocatalítica de 5-HMF a 2,5-diformilfurano (DFF) y la descomposición de contaminantes orgánicos en matrices acuosas. Los materiales carbonosos utilizados como catalizadores independientes o como soportes de (nano)metales son varios tipos de carbones micro/mesoporosos activados, grafeno/grafito y sus homólogos modificados químicamente, como el óxido de grafito y el óxido de grafito reducido, los nanotubos de carbono, los puntos cuánticos de carbono, el nitruro de carbono grafítico y los fullerenos.The continuous increase of the demand in merchandise and fuels augments the need of modern approaches for the mass-production of renewable chemicals derived from abundant feedstocks, like biomass, as well as for the water and soil remediation pollution resulting from the anthropogenic discharge of organic compounds. Towards these directions and within the concept of circular (bio)economy, the development of efficient and sustainable catalytic processes is of paramount importance. Within this context, the design of novel catalysts play a key role, with carbon-based nanocatalysts (CnCs) representing one of the most promising class of materials. In this review, a wide range of CnCs utilized for biomass valorization towards valuable chemicals production, and for environmental remediation applications are summarized and discussed. Emphasis is given in particular on the catalytic production of 5-hydroxymethylfurfural (5-HMF) from cellulose or starch-rich food waste, the hydrogenolysis of lignin towards high bio-oil yields enriched predominately in alkyl and oxygenated phenolic monomers, the photocatalytic, sonocatalytic or sonophotocatalytic selective partial oxidation of 5-HMF to 2,5-diformylfuran (DFF) and the decomposition of organic pollutants in aqueous matrixes. The carbonaceous materials were utilized as stand-alone catalysts or as supports of (nano)metals are various types of activated micro/mesoporous carbons, graphene/graphite and the chemically modified counterparts like graphite oxide and reduced graphite oxide, carbon nanotubes, carbon quantum dots, graphitic carbon nitride, and fullerenes.https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000192503https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000436798https://orcid.org/0000-0003-1166-1982https://orcid.org/0000-0001-5996-6510https://orcid.org/0000-0002-3184-7656https://orcid.org/0000-0003-3701-6340https://orcid.org/0000-0001-8658-8500https://scienti.minciencias.gov.co/gruplac/jsp/visualiza/visualizagr.jsp?nro=00000000005961ramon.colmenaresq@campusucc.edu.cohttps://scholar.google.com/citations?user=9HLAZYUAAAAJ&hl=eshttps://scholar.google.com/citations?user=f0_QSeMAAAAJ&hl=es&oi=srahttps://scholar.google.com/citations?hl=es&user=Ju7Vte4AAAAJhttps://scholar.google.com/citations?user=9spgFMUAAAAJ&hl=es&oi=srahttps://scholar.google.com/citations?hl=es&user=Wz-do_IAAAAJ1 - 40Universidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Mecánica, Medellín y EnvigadoIngeniería mecanicaMedellínhttps://www.mdpi.com/2079-4991/12/10/1679#citeNanomaterialsCabana, L.; Ke, X.X.; Kepic, D.; Oro-Sole, J.; Tobias-Rossell, E.; Van Tendeloo, G.; Tobias, G. 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[CrossRef]Nanocatalizadores de carbonoCatálisis heterogéneaFotocatálisisSonocatálisisSonofotocatálisisHidrogenólisis de la lignina5-hidroximetilfurfural (5-HMF) a 2,5-diformilfurano (DFF)Valorización de la biomasaSaneamiento de sustancias orgánicas peligrosasCarbon-based nanocatalystsHeterogeneous catalysisPhotocatalysisSonocatalysisSonophotocatalysislignin hydrogenolysis5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF)Biomass valorizationHazardous organics remediationCarbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediationArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionAtribucióninfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2PublicationLICENSElicense.txtlicense.txttext/plain; charset=utf-84334https://repository.ucc.edu.co/bitstreams/80774b32-2839-4cc3-8d08-3ba5de8d6a9a/download3bce4f7ab09dfc588f126e1e36e98a45MD5120.500.12494/52484oai:repository.ucc.edu.co:20.500.12494/524842024-08-10 21:01:32.685metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de 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Carbon-based nanocatalysts (CnCs) for biomass valorization and hazardous organics remediation

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